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Precursor chemistry towards highly efficient and phase-stable red emitting CsPbI_(3) perovskite nanocrystals

Nano Research 2022年第1期15卷 644-652页

作者： Dejian Chen Decai Huang Mingwei Yang Kunyuan Xu Jie Hu Sisi Liang Haomiao Zhu CAS key laboratory of Design and Assembly of functional Nanostructures and Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen 361021China

All-inorganic cesium lead halide perovskite nanocrystals(CsPbX_(3),X=Cl,Br,I)have attracted considerable scientific and technological interest due to their precise bandgap tunability,high color purity and efficient ***,their poor stability in harsh conditions such as moisture,ultraviolet(UV)light irradiation and high temperature,is a major obstacle for their further commercial ***,by simply using a new type of precursor,namely“HPbX_(3)”(X=Cl,Br,I),we can achieve the coordination equilibrium for Pb precursors during reaction and obtain high-quality perovskite nanocrystals with tremendously enhanced luminous efficiency and chemical stability based on hot-injection *** prepared a-CsPbb nanocrystals exhibit an extremely high photoluminescence quantum yield of 96%and keep stable in air for more than two months without any post-synthesis ***,stability evaluations under UV light irradiation,water or thermal impact are also performed and the results show substantially improved stability of these nanocrystals as compared with the samples prepared using traditional Pbl_(2) as *** temperature-dependent(10-300 K)steady and transient spectral analysis combined with compositional measurements,it is revealed that the lower structural defect density,which is guaranteed by abundant halogen when using HPbX3 as precursor,is the most important reason for such performance enhancement.

关键词： perovskite nanocrystals CsPbX_(3) precursor stability vacancy defect

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Grain growth behavior and properties of high-entropy pseudobrookite(Mg,Co,Ni,Zn)Ti_(2)O_(5) ceramics

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Journal of Advanced Ceramics 2024年第6期13卷 757-768页

作者： Xiaohui Ma Jinyu Wu Lingyi Meng Jinfeng Zhang Heng Chen Liwen Yan Anran Guo Jiachen Liu key laboratory of Advanced Ceramics and Machining Technology of Ministry of Education School of Materials Science and EngineeringTianjin UniversityTianjin 300072China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China

It is well known that the grain size of high-entropy ceramics is quite small owing to the sluggish diffusion effect. However, abnormal grain growth often occurs in high-entropy pseudobrookite ceramics, ultimately resulting in the formation of many abnormally grown grains with a grain size as large as 50 μm. To study this phenomenon, the grain growth behavior of high-entropy pseudobrookite ceramics was systematically investigated in this paper. The results demonstrate that the starting material powders first react with each other to form a high-entropy intermediate phase and calcined TiO_(2) powders (TiO_(2)-1100 ℃), and then as the sintering temperature increases, the formed high-entropy intermediate phase further reacts with TiO_(2)-1100 ℃ to form high-entropy pseudobrookite ceramics. Thus, in this system, in addition to the sluggish diffusion effect, the grain sizes of the high-entropy intermediate phase and TiO_(2)-1100 ℃ also affect the morphology of high-entropy pseudobrookite. Compared to nanosized TiO_(2), micron-sized TiO_(2) has a lower sintering activity. Therefore, the high-entropy intermediate phases (Mg,Co,Ni,Zn)TiO_(3) and TiO_(2)-1100 ℃ prepared with micron-sized starting materials exhibit lower grain sizes, finally resulting in the formation of high-entropy (Mg,Co,Ni,Zn)Ti_(2)O_(5) with small grain sizes. Moreover, nano-indentation and thermal conductivity tests were carried out on high-entropy (Mg,Co,Ni,Zn)Ti_(2)O_(5) with different morphologies. The results show that the hardness of high-entropy (Mg,Co,Ni,Zn)Ti_(2)O_(5) increases from 6.05 to 9.95 GPa as the grain size increases, whereas the thermal conductivity decreases from 2.091±0.006 to 1.583±0.006 W·m^(−1)·K^(−1). All these results indicate that high-entropy (Mg,Co,Ni,Zn)Ti_(2)O_(5) with a small grain size is a potential material for thermal protection.

关键词： grain size sluggish diffusion effect two-step solid phase process high-entropy intermediate phase high-entropy pseudobrookite ceramic

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Pillar effect induced by ultrahigh phosphorous/nitrogen doping enables graphene/MXene film with excellent cycling stability for alkali metal ion storage

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Journal of Energy Chemistry 2024年第6期93卷 146-156,I0004页

作者： Meng Qin Yiwei Yao Junjie Mao Chi Chen Kai Zhu Guiling Wang Dianxue Cao Jun Yan key laboratory of Superlight materials and Surface Technology Ministry of EducationCollege of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001HeilongjiangChina xiamen key laboratory of rare earth photoelectric functional materials and Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen 361021FujianChina

Graphene's large theoretical surface area and high conductivity make it an attractive anode material for potassium-ion batteries(PIBs).However,its practical application is hindered by small interlayer distance and long ion transfer ***,this paper aims to address the issue by introducing MXene through a simple and scalable method for assembling graphene and realizing ultrahigh P doping *** findings reveal that MXene and P-C bonds have a "pillar effect" on the structure of graphene,and the P-C bond plays a primary *** addition,N/P co-doping introduces abundant defects,providing more active sites for K^(+) storage and facilitating K^(+) *** expected,the developed ultrahigh phosphorous/nitrogen co-doped flexible reduced graphene oxide/MXene(NPrGM) electrode exhibits remarkable reversible discharge capacity(554 mA hg^(-1) at 0.05 A g^(-1)),impressive rate capability(178 mA h g^(-1) at 2 A g^(-1)),and robust cyclic stability(0.0005% decay per cycle after 10,000 cycles at 2 A g^(-1)).Furthermore,the assembled activated carbon‖NPrGM potassium-ion hybrid capacitor(PIHC) can deliver an impressive energy density of 131 W h kg^(-1) and stable cycling performance with 98.1% capacitance retention after5000 cycles at 1 A g^(-1).Such a new strategy will effectively promote the practical application of graphene materials in PIBs/PIHCs and open new avenues for the scalable development of flexible films based on two-dimensional materials for potential applications in energy storage,thermal interface,and electromagnetic shielding.

关键词： Graphene MXene Phosphorous doping Pillar effect Potassium-ion batteries

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Bio-inspired materials for Photocatalytic Hydrogen Production

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Chinese Journal of Structural Chemistry 2020年第12期39卷 2123-2130,2054页

作者： JIANG Xia CHEN Yan-Xin LU Can-Zhong CAS key laboratory of Design and Assembly of functional Nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Institute of Rare-earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China

After millions of years of evolution,species in nature have structures and complex elements that are difficult to synthesize ***,these fine structures and compositions are often beneficial to improve the photocatalytic ***,various materials with special morphology,pore structure and element composition derived from biomass have emerged and are widely *** mini review focuses on the preparation of bio-inspired materials and their current status in photocatalytic hydrogen ***,this will bring new perspectives to researchers and make them learn more about the advantages of"learning from nature"and pay more attention to the green design of material structures.

关键词： biomass bio-inspired materials photocatalytic hydrogen production

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Room-temperature synthesis of layered open framework cathode for sodium-ion batteries

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Chinese Chemical Letters 2023年第5期34卷 576-579页

作者： Ruding Zhang Huixin Chen Hongjun Yue CAS key laboratory of Design and Assembly of functional Nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China

The synthesis of active electrode materials at room temperature is one of the effective strategies to reduce the fabrication cost of sodium ion batteries(SIBs).Herein,a layered material(Na_(2)[(VO)_(2)(HPO_(4))_(2)C_(2)O_(4)]·2H_(2)O,abbreviated as NVPC followingly)with open-framework structures has been successfully prepared at room temperature under ambient conditions and is evaluated as a cathode for *** is revealed that NVPC cathode can deliver a maximum reversible capacity of ca.70 mAh/g at 10 mA/g,and exhibit superior rate capability and cycling performance:at 50 mA/g,maximum reversible capacity ca.50 m Ah/g with capacity retention of 88.4%over 250 cycles corresponds to only 0.046%capacity decay per cycle;at 100 mA/g,a maximum reversible capacity of 35 mAh/g with capacity retention of60.9%over 500 *** study demonstrates a practical example of a low-cost synthesis of the cathode materials for *** the same time,the systematic electrochemical research results also show promising prospects for long lifespan low-cost SIBs.

关键词： Room temperature solution synthesis Open framework structure Cathode materials Sodium-ion batteries Full cell

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Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries

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Chinese Chemical Letters 2024年第7期35卷 473-479页

作者： Yan Wang Huixin Chen Fuda Yu Shanyue Wei Jinhui Song Qianfeng He Yiming Xie Miaoliang Huang Canzhong Lu Engineering Research Center of Environment-Friendly functional materials Ministry of EducationInstitute of Materials Physical ChemistryHuaqiao UniversityXiamen 361021China CAS key laboratory of Design and Assembly of functional Nanostructures and Fujian Provincial Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China

Lithium-sulfur(Li-S)batteries with high theoretical capacity and energy density need to solve problems such as the high decomposition energy barrier of Li_(2)S and large volume change of sulfur in the charging process caused by the shuttle effect before practical ***,a green synthesis method is used to prepare polyacrylic acid(PAA)superabsorbent material,and then the pyrolyzed PAA(P/PAA)material is obtained as the positive electrode of Li-S *** functional calculation reveals that the oxygen self-doping pyrolyzed polyacrylic acid(P/PAA)delivered stronger binding energy toward Li2S species in carbonyl C=O than that of graphite powder(GP)which are-1.58 eV and-1.02 eV,*** with the distribution of relaxation time analysis and the in-situ electrochemical impedance approach,it is further demonstrated that the designed P/PAA as sulfur host plays a physical/chemical adsorption dual function in maintaining the stability and rate performance of *** an initial discharge capacity of 1258 mAh/g at 0.1 C and a minimal capacity decline of 0.05%per cycle even after 800 cycles at 0.5 C,the produced cathode demonstrated outstanding electrochemical *** average Coulombic efficiency is nearly 100%.The P/PAA electrodes may typically retain 96%of their capacity while declining on average only 0.033%per cycle after 130 cycles at 3 *** effort provides a new method for the future development of heteroatomic self-doping superabsorbent with promising adsorption properties for polysulfides as cathode materials of Li-S batteries.

关键词： Polyacrylic acid Oxygen self-doping Green synthetic Pore mesh polymer cathodes Lithium-sulfur batteries

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X-ray-activated Bi^(3+)/Pr^(3+)co-doped LiYGeO_4 phosphor with UV and NIR dual-emissive persistent luminescence

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Journal of rare earths 2024年第5期42卷 955-961,I0005页

作者： Xianggui Yin Hongyun Zhong Lin Liu Junpeng Shi Xia Sun Yun Zhang State key laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen361021China Fujian Science and Technology Innovation laboratory for Optoelectronic Information of China Fuzhou350108China

X-ray-activated luminescence materials have broad application prospects in photodynamic therapy of deep *** them,X-ray-activated persistent luminescence materials(PLMs)exhibiting multiple emission peaks have drawn extensive attention for the ir capacity to achieve a combination of bioimaging and therapeutic ***,we developed a novel PLM,LiYGeO_4:Bi^(3+),Pr^(3+),that simultaneously exhibits UV and NIR dual persistent luminescence(PersL)emissions after irradiation by *** material can be re peatedly excited by X-ray and emits similar lumine scence intensity every time,which shows good PersL *** addition,LiYGeO_4:Bi^(3+),Pr^(3+)exhibits photostimulated PersL properties by stimulation with a red light-emitting diode(LED)or NIR laser after long-term *** work provides a new choice of X-ray-excited PLMs with UV and NIR dual emission and the novel phosphor shows promise as a potential candidate for the integration of treatment and diagnosis of deep tumors.

关键词： Co-doping X-ray-activated Dual emissions Persistent luminescence rare earths

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Synthesis and optical properties of highly efficient Na_(3)KMg_(7)(PO_(4))_(6):Eu^(2+)blue phosphor for full-spectrum white-light-emitting diodes:The role of Li_(2)CO_(3)flux

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Journal of rare earths 2024年第7期42卷 1217-1223,I0001页

作者： Zihao Wang Sisi Liang Chenyang Zhan Kunyuan Xu Jie Hu Dejian Chen Liping Song Haomiao Zhu School of Physics and materials Science Nanchang UniversityNanchang330000China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou341000China CAS key laboratory of Design and Assembly of functional Nanostructures and Fujian Key Laboratory of NanomaterialsFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Research Center of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen361021China

Full-spectrum phosphor-converted white-light-emitting diodes(pc-WLED)are emerging as a mainstream technology in semiconductor ***,high-performance blue phosphor which can be excited efficiently by a 400 nm NUV diode chip is still ***,we present a blue-emitting Na_(3)KMg_(7)(PO_(4))6:Eu^(2+)phosphor synthesized by the solid-reaction ***,we find that the using of Li_(2)CO_(3)as flux can significantly improve the crystal quality and thus the emission efficiency of the ***,the excitation peak of the phosphor shifts from 365 to 400 nm,which is pivotal for efficient NUV(400 nm)diode chip *** practical Eu^(2+)concentration is also enhanced by using Li_(2)CO_(3)as flux,and the absorption efficiency is greatly *** phosphor exhibits superior PL thermal stability,namely retains 94%integrated photoluminescence intensity at 150℃of that at 25℃.As a result,the optimized phosphor shows an emission band peaked at 437 nm with a bandwidth of 40 nm and a high external photoluminescence quantum yield of 51.7%.Finally,a pc-WLED was fabricated by using NKMPO:Eu^(2+)blue,Sr_(2)SiO_(4):Eu^(2+)green,CaAlSiN_(3):Eu^(2+)red phosphors,and a 400 nm NUV diode *** shows a high color rendering index of R_(a)=96.4 and a correlated color temperature of 4358 *** results prove that NKMPO:Eu^(2+)is a promising blue phosphor for full-spectrum WLED based on NUV diode chips.

关键词： Eu^(2+) Blue phosphor Na_(3)KMg_(7)(PO_(4))_(6) Full-spectrum white LEDs rare earths

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‘Radicalize’the Performance of Perovskite Solar Cells with Radical Compounds

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Chemical Research in Chinese Universities 2023年第2期39卷 176-186页

作者： WANG Can GAO Peng State key laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou350002P.R.China laboratory for Advanced functional materials Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen361021P.R.China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Institute of Rare Earth MaterialsChinese Academy of SciencesXiamen361021P.R.China University of Chinese Academy of Sciences Beijing100049P.R.China

Perovskite solar cells(PSCs)have attracted tremendous attention due to their outstanding performance within a short *** molecules with unpaired single electrons have been widely used in energy-related fields,such as organic light-emitting diodes(OLEDs),organic field-effect transistors(OFETs),organic and dye-sensitized solar cells,batteries,thermoelectric conversion devices,***,as far as we know,there has never been a systemic collection and analysis of the application of radical molecules in ***,we summarized the role of the radical molecule on perovskite(passivate trap defects,enhance oxygen stability and make perovskite band-bending)and charge transport layer(improve conductivity and mobility,enhance oxygen stability,modulate work function and decrease by-product generating).Meanwhile,future directions of making full use of radical molecules in improving the performances of PSCs were envisioned.

关键词： Radical molecule Perovskite solar cell Unpaired single electron Modulate W_(F)

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Organic polystyrene and inorganic silica double shell protected lead halide perovskite nanocrystals with high emission efficiency and superior stability

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Nano Research 2023年第7期16卷 10507-10514页

作者： Shujian Wang Dejian Chen Kunyuan Xu Jie Hu Decai Huang Maochun Hong Haomiao Zhu University of Science and Technology of China Hefei 230026China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou 341000China CAS key laboratory of Design and Assembly of functional Nanostructures and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China xiamen key laboratory of rare earth photoelectric functional materials Xiamen Research Center of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China

The practical application of all-inorganic semiconductor lead halide perovskite nanocrystals(LHP NCs)has been limited by their poor ***,a lot of research on core-shell structure has been done to improve the stability of perovskite NCs,but the effect was far from the application ***,we,for the first time,report a convenient approach to synthesize organic-inorganic double shell CsPbBr_(3)@SiO_(2)@polystyrene(PS)NCs with an inter-core of CsPbBr_(3),the intermediate layer of SiO_(2)shell,and outmost PS ***,the CsPbBr_(3)@SiO_(2)@PS NCs maintained more than 90%of their initial photoluminescence(PL)intensity under one month's ultraviolet lamp irradiation or in 85℃ and 85%relative humidity(RH)*** white-light-emitting-diodes(WLEDs)were fabricated by encapsulating commercial InGaN chip with CsPbBr_(3)@SiO_(2)@PS NCs and K2SiF6:Mn^(4+)(KSF:Mn^(4+))phosphor with a luminous efficacy of~100 lm/W at 20 mA current and a color gamut of 128%of the National Television Standards Committee(NTSC)*** addition,these WLEDs still maintain 91%of the initial luminous efficacy after 1200 h of continuous *** results demonstrated that double shell-protected CsPbBr_(3)perovskite NCs have great potential in the field of WLEDs.

关键词： core-shell structure organic polystyrene(PS)inorganic SiO_(2)double shell CsPbBr_(3)@SiO_(2)@PS nanocrystals(NCs) high stability

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