检索结果-南通市图书馆

Honeycomb-like biochar framework coupled with Fe_(3)O_(4)/FeS nanoparticles as efficient heterogeneous Fenton catalyst for phenol degradation

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2024年第2期136卷 390-399页

作者： Aihua Cheng Yi He xiaohe Liu Chi He Department of Environmental Engineering College of Geology and EnvironmentXi’an University of Science and TechnologyXi’an 710054China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China National Engineering Laboratory for VOCs Pollution Control Material and technology University of Chinese Academy of SciencesBeijing 101408China

Achieving an efficient and stable heterogeneous Fenton reaction over a wide pH range is of great significance for wastewater ***,a pollen-derived biochar catalyst with a unique honeycomb-like structure,coupled with the dispersion of magnetic Fe_(3)O_(4)/FeS(Fe/S)nanoparticles,was synthesized by simple impregnation precursor,followed by *** prepared Fe/S-biochar catalyst demonstrated outstanding phenol degradation efficiency across a wide pH range,with 98%of which eliminated even under neutral conditions(pH 7.0).The high catalytic activity was due to the multilevel porous structure of pollenderived biochar provided enough active sites and allowed for better electron transfer,then increases oxidation ability to promote the ***,the acid microenvironment formed by SO_(4)^(2-)group from Fe/S composite extended the pH range for Fenton reaction,and S^(2-)facilitated the conversion of≡Fe^(3+)to≡Fe^(2+),resulting in remarkable degradation ***,biochar can effectively promote cycling stability by limiting Fe *** work may provide a general strategy for designing 3D framework biochar-based Fe/S catalysts with excellent performance for heterogeneous Fenton reactions.

关键词： Biomass Biochar Fenton reaction Fe_(3)O_(4)/FeS(Fe/S) Phenol degradation

Modulated noble metal/2D MOF heterostructures for improved hydrogen storage of MgH_(2)

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第4期43卷 1672-1685页

作者： Zeng-Yi Li Li-xian Sun Fen Xu Yu-Mei Luo Yong-Peng xia Sheng Wei Chen-Chen Zhang Ri-Guang Cheng Chao-Feng Ye Meng-Yuan Liu Ju-Lan Zeng Zhong Cao Hong-Ge Pan School of Material Science and Engineering Guilin University of Electronic TechnologyGuilin541004China School of Chemistry and Chemical Engineering Changsha University of Science and TechnologyChangsha410114China Institute of Science and technology for New Energy Xi’an Technological UniversityXi’an710021China

The conjugation of external species with twodimensional(2D)materials has broad application *** this study,we have explored the potential of noble metal/2D MOF heterostructures in hydrogen ***,the MgH_(2)-Ni-MOF@Pd system has shown remarkable hydrogen desorption/sorption performances,starting to liberate hydrogen at 1810C,which is 2300C lower than that of pristine *** the catalytic effect of Ni-MOF@Pd,the dehydrogenation apparent activation energy of MgH2 is noticeably decreased from(133.5±17.5)to(34.58±1.87)kJ·moL^(-1),and the hydrogenation apparent activation energy is reduced from(70.41±7.43)to(25.78±4.64)kJ·moL^(-1),which is lowered by 63.4%.The fully-dehydrogenated MgH2-NiMOF@Pd composite rapidly uptakes hydrogen,with 2.62wt%at 100℃and 6.06 wt%at 150℃within 300 s,*** mechanism analysis of MgH2 catalyzed by Ni-MOF@Pd has revealed that the transformation of Mg_2Ni and Mg_2NiH_4 could act as a"hydrogen pump",providing numerous channels for fast diffusion and transport of hydrogen ***,in the dehydrogenation process,the element Pd reacts with MgH_(2)to form the MgPd alloy phase,which makes MgH_(2)take precedence to decompose through the Mg-Pd alloy rather than self-decomposition,further reducing thermal stability and improving de/hydrogenation *** synergistic effect of Mg-Pd,Mg_2Ni,and the special ultra-thin 2D sheet structure of the additive is the main reason for the good hydrogen storage property of MgH_(2)-Ni-MOF@*** findings provide inspiration for designing efficient multifunctional additives with unique morphologies to optimize the hydrogen desorption/sorption behaviors of hydrogen storage materials.

关键词： Hydrogen storage Magnesium hydride 2D metal-organic framework nanosheets Ni/Pd Synergistic catalysis

Recycling the spent electronic materials to construct a highperformance Cu_(1.94)S/ZnS heterostructure anode of sodium-ion batteries

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第5期17卷 4006-4015页

作者： xiaowei He Tianshuai Wang Lidong Tian Qiuyu Zhang School of Chemistry and Chemical Engineering Xi’an Key Laboratory of Functional Organic Porous MaterialsKey Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information TechnologyNorthwestern Polytechnical UniversityXi’an 710072China Chongqing Science and technology Innovation Center of Northwestern Polytechnical university Chongqing 401135China College of Materials Science and Engineering Xi’an University Science and TechnologyXi’an 710054China

Heterostructure engineering by coupling different nanocrystals has received extensive attention because it can enhance the reaction kinetics of the anode of sodium-ion batteries(SIBs).However,constructing high-quality heterostructure anode materials through green and environmentally friendly methods remains a ***,we have proposed a simple one-step method by recycling the electronic waste metal materials to synthesize the Cu_(1.94)S/ZnS heterostructure *** with the experimental analysis and first principle calculations,we find that the synergistic effect of different components in heterostructure structures can significantly enhance the reversible capacity and rate performance of anode *** on the constructed Cu_(1.94)S/ZnS anode,we obtain a superior reversible capacity of 440 mAh·g^(-1) at 100 mA·g^(-1) and 335 mAh·g^(-1) after 3000 cycles at 2000 mA·g^(-1).Our work sheds new light on designing high-rate and capacity anodes for SIBs through the greenness synthesis method.

关键词： sodium-ion batteries heterostructure reversible capacity environmentally synthesis process

Enhanced visible light absorption of Bi_(2)WO_(6)/SiO_(2) with abundant adsorbed oxygen for the degradation of organic pollutant

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Particuology 2024年第5期88卷 210-217页

作者： Yuanting Wu xiaoying Wang Wenlong Zhong Shan Zhang School of Material Science and Engineering Shaanxi University of Science and TechnologyXi'an 710021China

Heterogeneous photocatalysts exhibit high catalytic efficiency in the degradation of pollutants,but their stability and repeatability is not very good and requires high structural *** by nanosizing the pure Bi_(2)WO_(6)(BWO)photocatalyst without constructing a heterojunction,there is a significant improvement in its performance,with an enhancement effect of about 2.3 times(99.43%).The high photocatalytic degradation efficiency of the material can be attributed to the enhanced light absorption effect brought by the three-dimensional inverse-opal structure SiO_(2)(IS)and the abundant surface adsorbed oxygen generated after the formation of Si–O–W *** addition,the introduction of IS greatly increases the surface area of nanostructured BWO,which accelerates the charge transfer process,while the adsorbed oxygen promotes the participation of·O^(2−) in the photocatalytic reaction,thereby accelerating the consumption of photo-generated electrons and ultimately improving the separation of charge ***,the matched photonic bandgap further improves the absorption and utilization of light of the *** this work,we constructs Si–O–W bonds to obtain inverse-opal SiO_(2)/Bi_(2)WO_(6) with uniformly growth of pure phase nano BWO,which provides a feasible strategy for the preparation of high-performance pure-phase photocatalysts.

关键词： Bi_(2)WO_(6) SiO_(2) inverse-opal structure Photocatalysis Adsorbed oxygen

Method of Single Event Effects Radiation Hardened Design for DC-DC Converter Based Load Transient Detection

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Electronics 2024年第5期33卷 1154-1164页

作者： Zhongjie GUO Nan LIU Hu LU Mengli LI Ziyi QIU School of Automation and Information Engineering Xi'an University of Technology

Aiming at the impact of load current change on single-event transient, the essential difference between single-event transient and load transient of DC-DC converter is deeply studied. A hardened circuit based on load transient detection is proposed. The circuit detects the load transient information in time and outputs a control signal to control the single event hardened circuit, thereby realizing the improvement of the transient characteristics of the system under dynamic conditions. Based on the 180 nm bipolar-CMOS-DMOS（BCD） process, the design and physical verification of a boost converter are completed. The experimental results show that the input voltage range is 2.9–4.5 V, the output voltage range is 5.8–7.9 V, and the load current is 0–55 mA. During load transients, the load detection circuit turns off the hardened circuit in time, avoiding system oscillation and widening the dynamic range of the hardening circuit. Under the single-event transient, the output voltage fluctuation of the system does not exceed the maximum ripple voltage, and the single-event transient suppression ability reaches more than 86%, the system can work well with linear energy transfer of about 100 Me V·cm2/mg.

关键词： Voltage fluctuations Fluctuations Radiation hardening (electronics) Energy exchange DC-DC power converters Dynamic range Transient analysis DC-DC converter Analog single-event transient effect Load transient detection Radiation hardened by design TMR

同方期刊数据库

Microscopic mechanism of plasmon-mediated photocatalytic H_(2) splitting on Ag-Au alloy chain

在线全文

学校读者我要写书评

暂无评论

Chinese Physics B 2024年第3期33卷 322-326页

作者：宋玉慧芦一瑞郭阿鑫曹逸飞李金萍付正坤严蕾张正龙 School of Physics and Information technology Shaanxi Normal UniversityXi'an 710119China

Alloy nanostructures supporting localized surface plasmon resonances has been widely used as efficient photocatalysts,but the microscopic mechanism of alloy compositions enhancing the catalytic efficiency is still *** using time-dependent density functional theory(TDDFT),we analyze the real-time reaction processes of plasmon-mediated H_(2) splitting on linear Ag-Au alloy chains when exposed to femtosecond laser *** is found that H_(2) splitting rate depends on the position and proportion of Au atoms in alloy chains,which indicates that specially designed Ag-Au alloy is more likely to induce the reaction than pure Ag ***,more electrons directly transfer from the alloy chain to the anti-bonding state of H_(2),thereby accelerating the H_(2) splitting *** results establish a theoretical foundation for comprehending the microscopic mechanism of plasmon-induced chemical reaction on the alloy nanostructures.

关键词： plasmon photocatalysis time-dependent density functional theory(TDDFT)

Deployment analysis of composite thin-walled lenticular tubes with effect of storage time and temperature

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Aeronautics 2024年第1期37卷 162-172页

作者： Jinfeng DENG Ning AN Qilong JIA xiaofei MA School of Aeronautics and Astronautics Sichuan UniversityChengdu 610065China State Key Laboratory for Strength and Vibration of Mechanical Structures School of AerospaceXi’an Jiaotong UniversityXi’an 710049China State Key Laboratory of Structural Analysis for Industrial Equipment Dalian University of TechnologyDalian 116024China xi’an Institute of Space Radio technology Xi’an 710100China

Composite Thin-walled Lenticular Tube(CTLT)is increasingly utilized in small satellites missions as a lightweight,foldable,and rollable structural material that facilitates the construction of large deployable *** CTLT is initially flattened and coiled around a central hub for storage before launch,during which elastic energy is stored as deformation energy,allowing it to be self-deployed on demand for use in *** work presents a comprehensive investigation into the coiling,storage and deployment behaviors of CTLT that wraps around a central hub.A nonlinear explicit dynamic finite element model was developed with both deformable CTLT and rigidbodies mechanisms including the central hub and guide rollers,as well as the complex interactions among *** coiling mechanics characteristics such as stored strain energy and rotational moment were presented and validated against experimental data in the ***,the dynamic deployment behaviors were analyzed in terms of two different deployment methods,namely,controlled deployment and free *** effect of material property change during storage was also discussed through numerical experiments.

关键词： Composite deployable structures Deployment dynamics Finite element method Stress relaxation Thin-walled booms

Formation behaviors of rod-like reactive shaped charge penetrator and their effects on damage capability

在线全文

学校读者我要写书评

暂无评论

Defence technology（防务技术） 2024年第2期32卷 242-253页

作者： Tao Sun Haifu Wang Shipeng Wang Chao Ge Die Hu Pengwan Chen Yuanfeng Zheng Beijing Institute of technology State Key Laboratory of Explosion Science and TechnologyBeijing100081China xi'an Institute of Electromechanical Information technology Xi'an710065China

Formation behaviors of rod-like reactive shaped charge penetrator(RRSCP)and their effects on damage capability are investigated by experiments and numerical *** pulsed X-ray technology and a spaced aluminum/steel plate with the thicknesses of 5 mm/100 mm are *** types of sphericalsegment aluminum-polytetrafluoroethylene-copper(Al-PTFE-Cu)reactive liners with Cu contents of 0%,46.6%,and 66%are fabricated and *** experimental results show that the reactive liners can form excellent rod-shaped penetrators with tail skirts under the shaped charge effect,but the tail skirts disappear over ***,rupturing damage to the aluminum plate and penetration to the steel plate are caused by the RRSCP *** simulation analysis,the RRSCP is formed by a mechanically and chemically coupled response with the reactive liner activated by shock in its outer walls and bottom and then backward overturning,forming a leading reactive penetrator and a following chemical energy *** unique formation structure determines the damage modes of the aluminum plate and the steel *** analysis indicates that the formation behaviors and damage capability of Al-PTFE-Cu RRSCP strongly depend on Cu *** increasing Cu content,the velocity,activation extent,and reaction extent of Al-PTFE-Cu RRSCP decrease,which contribute to elongation and alleviate the negative effects of chemical reactions on elongation,significantly increasing the length-diameter ratio and thus enhancing the capability of steel plate ***,the lower activation extent and energetic density will weaken the RRSCP's capability of causing rupturing damage to the aluminum plate.

关键词： Reactive materials Al-PTFE composites Reactive liner X-ray Penetration

Heat management technology for solid-state high voltage and high repetitive pulse generators:Towards better effects and reliability

在线全文

学校读者我要写书评

暂无评论

High Voltage 2024年第1期9卷 2-21页

作者： Yanan Wang Linyuan Ren Zihao Yang Saikang Shen Zichen Deng Qi Yuan Weidong Ding Zhenjie Ding School of Electrical Engineering Xi'an Jiaotong UniversityXi'anChina School of Electronic and Information Engineering Xi'an Jiaotong UniversityXi'anChina

Solid-state high voltage high repetitive pulse generators have a broad prospect in various *** high power and high-frequency operation of the pulse generator suffer from the massive heat dissipation problem,which limits the improvement of the output parameters and even affects the *** article focuses on heat management technology for high voltage high repetitive pulse ***,the typical circuit topology of the high repetitive pulse generators was *** the perspective of different application requirements,the demands of the heat management design were ***,the heat generation characteristics and difficulties of solid-state high voltage high repetitive pulse generators were ***,the different stateof-art cooling techniques were reviewed,and their applicability and limitations for the high voltage high repetitive generators were ***,a flow chart for heat management design was given.

关键词： pulse state high