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Precipitation of metal oxide nanoparticles using a miniemulsion technique

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Particuology 2011年第5期9卷 502-505页

作者： Marion Winkelmann Heike Petra Schuchmann Institute of process Engineering in Life Sciences Section I: Food Process Engineering Karlsruhe Institute of Technology

A method to precipitate nanoparticles using a miniemulsion technique is described, in which miniemulsion droplets between 100 and 1000 nm in size serve as nanoreactors enabling both the control of particle formation and particle growth. The application of miniemulsion droplets to synthesise nanoparticles comprises three advantages： first, the size of the precipitated particles is limited by the reactant concentration within the emulsion droplet; second, particle agglomeration is prevented as nanoparticle collision outside the nanoreactor is avoided; and third, easy technical scale up can be realized by increasing emulsion volume and thus the number of nanoreactors, while local conditions within the reactors are not changed, The miniemulsion technique is an easy scalable process which allows defined synthesis of particles by precipitation reactions. The miniemulsion technique involves first the preparation of a stable water-in- oil miniemulsion by high pressure homogenisation. Whereas a water soluble reactant is provided within the aqueous droplets, another oilas well as water-soluble reactant can be introduced to the emulsion after homogenisation. The precipitation reaction is induced by the diffusion of the second reactant into the emulsion droplet. Together with this contribution, a method is described and discussed which uses a high pressure homogenisation process to produce stable water-in-oil miniemulsions serving as a reaction medium to precipitate metal oxides.

关键词： Precipitation Miniemulsion Nanoparticles Metal oxide High pressure homogenisation

3D Printing of Tough Hydrogel Scaffolds with Functional Surface Structures for Tissue Regeneration

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Nano-Micro Letters 2025年第2期17卷 18-45页

作者： Ke Yao Gaoying Hong Ximin Yuan Weicheng Kong Pengcheng Xia Yuanrong Li Yuewei Chen Nian Liu Jing He Jue Shi Zihe Hu Yanyan Zhou Zhijian Xie Yong He State Key Laboratory of Fluid Power and Mechatronic Systems School of Mechanical EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China Liangzhu Laboratory Zhejiang UniversityHangzhou 310027People’s Republic of China Key Laboratory of 3D Printing process and Equipment of Zhejiang Province College of Mechanical EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China Stomatology Hospital School of StomatologyZhejiang University School of MedicineHangzhou 310027People’s Republic of China State Key Laboratory of Advanced welding and Joining Harbin Institute of TechnologyHarbin 150001People’s Republic of China Institute of Digital Medicine Nanjing First HospitalNanjing Medical UniversityNanjing 210006People’s Republic of China

Hydrogel scaffolds have numerous potential applications in the tissue engineering ***,tough hydrogel scaffolds implanted in vivo are seldom reported because it is difficult to balance biocompatibility and high mechanical *** by Chinese ramen,we propose a universal fabricating method(printing-P,training-T,cross-linking-C,PTC&PCT)for tough hydrogel scaffolds to fill this ***,3D printing fabricates a hydrogel scaffold with desired structures(P).Then,the scaffold could have extraordinarily high mechanical properties and functional surface structure by cycle mechanical training with salting-out assistance(T).Finally,the training results are fixed by photo-cross-linking processing(C).The tough gelatin hydrogel scaffolds exhibit excellent tensile strength of 6.66 MPa(622-fold untreated)and have excellent ***,this scaffold possesses functional surface structures from nanometer to micron to millimeter,which can efficiently induce directional cell ***,this strategy can produce bionic human tissue with mechanical properties of 10 kPa-10 MPa by changing the type of salt,and many hydrogels,such as gelatin and silk,could be improved with PTC or PCT *** experiments show that this scaffold can effectively promote the new generation of muscle fibers,blood vessels,and nerves within 4 weeks,prompting the rapid regeneration of large-volume muscle loss injuries.

关键词： 3D printing Tough hydrogel scaffold Functional surface structure Tissue regeneration Biomaterials

Borides at interfacial zone of IC6 TLP bonded joints

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中国有色金属学会会刊：英文版 2003年第4期13卷 885-889页

作者：谢永慧毛唯刘效方颜鸣皋 Laboratory of welding and Forging

Transient liquid phase (TLP) bonding technique was used in joining IC6 alloy, a newly developed Ni 3Al based intermetallic material. Studies were focused on the borides at the interfacial zone, which were formed through the diffusion of boron from the interlayer into the base metal during the bonding process. The morphology and microstructure of the borides were investigated, as well as their growth mechanism and microstructure evolution with increasing holding time. Both the needle like and the blocky borides were testified by EDS and TEM as Mo 2NiB 2, with (110) and (211) as interfacial planes. The results show that the borides have some orientation relationship with that of the base metal, that is (211) borides ∥(111) substrate ,〈111〉 borides ∥〈123〉 substrate . The growth of the borides is controlled by long range diffusion of solute atoms. The borides are always enveloped by γ ′ Ni 3 (Al, Mo) films, which would influence the growth behavior of the borides greatly.

关键词： TLP连接 IC6合金 Ni3Al基合金异种金属连接硼化物

Local melting mechanism and its effects on mechanical properties of friction spot welded joint for Al-Zn-Mg-Cu alloy

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Journal of Materials Science & Technology 2018年第1期34卷 185-191页

作者： Yunqiang Zhao Chungui Wang Jizhong Li Jinhong Tan Chunlin Dong Guangdong welding Institute (China-Ukraine E.O.Paton Institute of welding) Guangzhou 510651 China

Local melting and the eutectic film and liquation crack formation mechanisms during friction spot weld- ing （FSpW） of Al-Zn-Mg-Cu alloy were studied by both experiment and finite element simulation. Their effects on mechanical properties of the joint were examined. When the welding heat input was high, the peak temperature in the stir zone was higher than the incipient melting temperature of the Al-Zn-Mg-Cu alloy. This resulted in local melting along the grain boundaries in this zone. In the retreating stage of the welding process, the formed liquid phase was driven by the flowing plastic material and redistributed as a ＂U-shaped＂ line in the stir zone. In the following cooling stage, this liquid phase transformed into eutectic films and liquation cracks. As a result, a new characteristic of＂U＂ line that consisted of eutectic films and liquation cracks is formed in the FSpWjoin. This ＂U＂ line was located in the high stress region when the FSpW joint was loaded, thus it was adverse to the mechanical properties of the FSpW joint. During tensile shear tests, the ＂U＂ line became a preferred crack propagation path, resulting in the occurrence of brittle fracture.

关键词： Friction spot welding Numerical simulation Local melting Liquation crack Mechanical property

Indirect Measurement of Material Thermal and Mechanical Properties during welding

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Journal of Materials Science & Technology 2003年第Z1期19卷 173-175页

作者： Dongqing LI Jun TAO Qingguo Meng Hongyuan FANG State Key Laboratory of welding Harbin Institute of Technology 150001 Chins State Key Laboratory of Welding Harbin Institute of Technology 150001 Chins State Key Laboratory of Welding Harbin Institute of Technology 150001 Chins State Key Laboratory of Welding Harbin Institute of Technology 150001 Chins

By means of a newly developed non-contact detecting method, electronic speckle pattern interferometry (ESPI), a method of determining material property data during welding is studied. A TIG fixed-point welding process is modeled in which some achievements of simulation, such as the effect of welding pool on temperature field and nonlinear relation between convection coefficient and temperature, are all considered. In addition, by taking into account effect of heating rate, the workpiece is divided into near-weld zone and far-weld zone, which will be treated with different property values. When the displacement field computed with original property data is compared and matched with the experimental displacement field, which is measured by ESPI, these original data are adjusted properly. A group of raw properties are obtained and are corrected by statistical regression before they enter the simulation process *** such a loop of "simulation-comparison-modification", a set of property data that best satisfy the real condition are achieved finally. In such a way, a new method for measuring material properties during welding is found.

关键词： Material properties, welding displacement field, Numerical simulation, ESPI

3D FEM analysis of welding residual stress and deformation of aero-engine blisk

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China welding 2014年第4期23卷 63-68页

作者：杨建国周号雷靖方洪渊张学秋曲伸 Institute of process Equipment and Control Engineering Zhejiang University of TechnologyHangzhou 310014. State Key Laboratory of Advanced welding and Joining HarbinInstitute of Technology Harbin 150001t

Aero-engine blisk welded by electron beam welding（EBW） method is a complicated structure. Fixtures were used to control the deformation of blisk during its manufacturing process. Finite element method was utilized to study the evolution of the welding residual stress and deformation of this structure. In which an attenuation function was applied to the double ellipsoid heat source model based on the characteristic of EBW, and the effects of fixtures on the welding residual stresses and deforamtion were also reserached. The simulation results showed that the temperature contour of weld cross section vertical to the weld centerline followed a ＇＂ V＂ shape. Moreover, large welding residual stress and distortion were found in the interface between blisk and fixtures. The stress concentration was reduced sufficiently in starting and end part of weldment as the fixtures were renmved after welding process, while the removing operation had almost no effects on the welding residual stress in the middle section of weld bead.

关键词： blisk residual stress distortion electron beam welding numerical simulation

Osmotic concentration of succinic acid by forward osmosis:Influence of feed solution pH and evaluation of seawater as draw solution

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Chinese Journal of Chemical Engineering 2018年第5期26卷 976-983页

作者： Jeng Yih Law Abdul Wahab Mohammad Department of Chemical and process Engineering Faculty of Engineering and Built Environment Universiti Kebangsaan Malaysia section of Chemical Engineering Technology Universiti Kuala Lumpur Malaysian Institute of Chemical & Bioengineering Technology

In this study, we investigated the essential role of feed solution pH so as to gain insights into the transport mechanisms of succinic acid concentration by osmotically-driven forward osmosis （FO） process. FO performances including water flux and bidirectional transport of succinate and chloride anions were systematically examined using cellulose triacetate-based FO membrane. Additionally, real seawater was explored as draw solution. Experimental results revealed that the pH-dependent speciation of succinic acid can affect the FO performances. Ionization of succinic acid at higher solution pH enhanced the osmotic pressure of feed solution, thus leading to lower water flux performance. A strong effect was pointed out on the succinate rejection for which nearly 100% rejections were achieved at pH above its pKa2 value. The rejection of succinate increased in the following order of chemical form： C2H4C2O4H2 〈 C2H4C2OH- 〈 C2H4C2O24-. With real seawater as the draw solution, low to moderate water fluxes （〈4 L. m- 2. h- 1 ） were observed. The divalent succinate anion was highly retained in the feed side despite differences in the succinic acid feed concentration at pH of approximately 6.90.

关键词： Forward osmosis Succinic acid pH Transport mechanism Seawater

Effect of sinter layer porosity distribution on flow and temperature fields in a sinter cooler

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International Journal of Minerals,Metallurgy and Materials 2009年第3期16卷 265-272页

作者： Jik-chang Leong Kai-wun Jin Jia-shyan Shiau Tzer-ming Jeng Chang-hsien Tai Department of Vehicle Engineering Pingtung University of Science and Technology Iron Making process Development section Steel & Aluminum Research & Development Department Department of Mechanical Engineering Air Force Institute of Technology

When sinters are filled into the sinter cooler from the sintering machine, it is commonly seen that, due to segregation effects, sinters of larger size usually accumulate closer to the inner wall of the sinter cooler, whereas those of smaller size are to the outer wall. This nonuniform distribution of sinters has led to uneven cooling effect throughout the cooler. This causes the sinters leaving the cooler at a large temperature difference. This undesired temperature difference leads to the deformation and even the destruction of the conveyors. The computational fluid dynamics （CFD） technique was used in the present work to investigate the heat and fluid flow phenomena within the sinter cooler corresponding to the different distribution of sinter layer porosity, which was highly dependent on the arrangement and orientation of sinters within the sinter cooler. It is confirmed that a high mass flow rate within the sinter layer causes a low temperature region and vice versa. The flow fields for vertically reducing porosity distribution and random distribution are almost identical indicating the relative insignificance of convective heat transfer mechanism.

关键词： steel plant sinter cooler sinter porosity heat transfer packed bed

Impact of crystalline and amorphous iron-and aluminum hydroxides on mechanisms of phosphate adsorption and desorption

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Journal of Environmental Sciences 2018年第8期30卷 175-189页

作者： Stella Gypser Florian Hirsch Anja M.Schleicher Dirk Freese Brandenburg University of Technology Cottbus-Senftenberg Faculty of Environment Process Engineering Biotechnology and Chemistry Department of Soil Protection and Recultivation Brandenburg University of Technology Cottbus-Senftenberg Faculty of Environment Process Engineering Biotechnology and Chemistry Department of Geopedology and Landscape Development German Research Centre for Geosciences Section 3.1 Inorganic and Isotope Geochchemistry

Fourier-transform infrared（FT-IR） spectroscopic experiments were carried out during phosphate adsorption on highly crystalline gibbsite, poorly crystalline 2-line-ferrihydrite and amorphous iron–aluminum–hydroxide mixtures in the molar ratio 1：0, 10：1, 5：1, 1：1, 1：5, 1：10 and 0：1. The OH stretching vibrational bands were utilized to analyze changes in structural and surface OH groups during adsorption, because the position of characteristic P／O vibrational bands can shift depending on reaction conditions, pH or adsorbed phosphate *** and desorption kinetics were studied at pH6 and different initial phosphate concentrations to achieve varying phosphate coverage on the mineral surfaces. For gibbsite the formation of AlHPO4 and Al2HPO4 can be assumed, while for ferrihydrite, a FeHPO4 or Fe2PO4 complex and the precipitation of FePO4 with longer equilibration time were ***2HPO4 or a Fe2PO4 surface complex was deduced for Fe-hydroxides, an AlH2PO4 surface complex was identified for Al-hydroxide, and both displayed either hydrogen bonds to neighboring hydroxyl groups or hydrogen bonds to outer-sphere complexes. Fe：Al-hydroxide mixtures with high Al ratios showed a low phosphate desorption rate, while ferrihydrite and the Fe：Al-hydroxide mixtures with high Fe ratios had almost negligible desorption rates. It was concluded that within the weakly associated amorphous FeO（OH） materials, FePO4 precipitated, which was bound by outer-sphere hydrogen bonds. With high Al ratios, desorption increased, which indicated weaker phosphate binding of both inner-sphere and outer-sphere complexes and hence, either no or minor quantities of precipitate. Ferrihydrite showed a more rigid structure and a lower extent of precipitation compared to amorphous Fe-hydroxide.

关键词： Phosphate Adsorption Desorption Surface complexation Precipitation FT-IR