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Journal of Energy Chemistry 2025年第2期101卷 744-750页

作者： Yao-Lu Ye Yan Zhou Huan Ye Fei-Fei Cao college of Chemistry Huazhong Agricultural University Institute of Applied Mycology College of Plant Science and Technology Huazhong Agricultural University

Lithium plating/stripping occurs at the a node/electrolyte interface which involves the flow of electrons from the current collector and the migration of lithium ions from the solid-electrolyte interphase（SEI）.The dual continuous rapid transport of interfacial electron/ion is required for homogeneous Li ***,we propose a strategy to improve the Li metal anode performance by rationally regulating the interfacial electron density and Li ion transport through the SEI *** key technique involves decreasing the interfacial oxygen density of biomass-derived carbon host by regulating the arrangement of the celluloses precursor *** higher specific surface area and lower interfacial oxygen density decrease the local current density and ensure the formation of thin and even SEI film,which stabilized Li+transfer through the Li/electrolyte ***,the improved graphitization and the interconnected conducting network enhance the surface electronegativity of carbon and enable uninterruptible electron *** result is continuous and rapid coupled interfacial electron/ion transport at the anode/electrolyte reaction interface,which facilitates uniform Li deposition and improves Li anode *** Li/C anode shows a high initial Coulombic efficiency of 98% and a long-term lifespan of over 150cycles at a practical low N/P（negative-to-positive） ratio of 1.44 in full cells.

关键词： Cellulose Electron/ion conducting Interfacial oxygen density Lithium metal batteries Lithium-lean metal anodes

In-situ formation of a new cation renders perovskite solar modules with a record efficiency and long-term stability

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Science China Chemistry 2025年第2期68卷 409-410页

作者： Shanxiao Lin Xixing Wen Xiuwen Xu college of Electronic and Optical Engineering and college of Flexible Electronics(Future Technology) Nanjing University of Posts and TelecommunicationsNanjing 210023China

Over the past 14 years,the efficiency of perovskite solar cells has surged from 3.8% to 26.7%[1],establishing it as an unrivaled choice for next-generation ***,maintaining the long-term stability of perovskite solar modules(PSMs)remains a *** particular,the thermal-and light-induced changes in crystal structure,composition,and optoelectronic properties are the primary causes of device degradation,currently considered the Achilles’heel that hinders its commercialization[2–4].Now,writing in Science,Ding et al.[5]achieve a milestone by overcoming the thermal-and light-induced degradation,rendering the PSM with a record efficiency of 23.2% and a T80(time to 20% efficiency loss)over 4,000 h at 85℃ and 85%relative humidity(RH)under light *** key behind this milestone is to utilize the cation reactivity to in-situ form methyl tetrahydrotriazinium([MTTZ]+,a new cation)and dimethylammonium([DMA]+)in precursor solution(Figure 1a).These cations remarkably modulate perovskite crystallization and stabilize the perovskite.

关键词： perovskite stability modules

Stability switches mechanism and PID control in reaction-diffusion network-organized neural systems with transmission delays

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Science China(Technological Sciences) 2025年第2期68卷 199-215页

作者： Xiangyu DU Min XIAO Wenwu YU Jiajin HE college of Automation&college of Artificial Intelligence Nanjing University of Posts and TelecommunicationsNanjing 210023China college of Mathematics Southeast UniversityNanjing 211189China

Traditionally,the spatiotemporal dynamics of neural networks have been analyzed in the locally continuous *** this modeling approach is straightforward and practical,it fails to encapsulate real-world networks’intricate topological structures and ***,the mechanisms of stability switches induced by time delays and diffusion effects in networkorganized systems are still ***,effective dynamic optimization strategies for network-organized models remain to be *** this study,we develop a delayed reaction-diffusion neural network model on complex *** system incorporates the effects of inter-nodal diffusion coupling and exhibits profound architectural *** then pioneer the proportional-integral-derivative(PID)feedback control into the network-organized model to modulate dynamic *** linear stability analysis is conducted firstly,demonstrating that Turing patterns and Hopf bifurcation can be induced in the controlled neural network by varying diffusion coefficients and time ***,the bifurcation direction is deduced via the center manifold ***,a series of simulations are performed to validate the theoretical analysis and substantiate the efficacy of the PID control *** results exhibit that the PID feedback controller can flexibly regulate the dynamics of the network-organized systems and possesses excellent disturbance rejection capabilities.

关键词： complex network neural networks PID control turing instability hopf bifurcation time delays turing pattern

Surface controllable wettability using amphiphilic rotaxane molecular shuttles

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Chinese Chemical Letters 2025年第2期36卷 422-425页

作者： Dongpu Wu Zheng Yang Yuchen Xia Lulu Wu Yingxia Zhou Caoyuan Niu Puhui Xie Xin Zheng Zhanqi Cao college of Science Henan Agricultural University

Herein,an alkyne-terminated acid/base responsive amphiphilic [2]rotaxane shuttle was synthesized,and then modified onto the glass surface through “click” *** XPS N 1s spectrum and contactangle measurement were performed to prove the successful *** amphiphilic [2]rotaxane functionalized surface presented controllable wettability responding to external acid-base *** bistable rotaxane modified material system promoted the practical application of molecular machines.

关键词： Amphiphilic rotaxane Controllable wettability Stimuli-responsive

Manufacture the conducting polymer with light

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Science China Chemistry 2025年第1期68卷 8-9页

作者： Yang Li Tianyu Li Yan Ji Baoguang Liu college of Electronic and Optical Engineering&college of Flexible Electronics(Future Technology) Nanjing University of Posts&TelecommunicationsNanjing 210023China

Poly(3,4-ethylenedioxythiophene)(PEDOT),heralded as the“king”of conducting polymers,is esteemed in bioelectronics for its mixed electronic and ionic conductivity,mechanical properties compatible with biological tissues,tunable healing ability and stability in diverse environments^([1]).Based on additive manufacturing of three-dimensional structures,PEDOT realizes the implementation in the efficient production of flexible bioelectronics,the construction of intricate electrode-neural implantations,and the development of smart brain-computer-interfaces^([2]).

关键词： conducting implantation additive

La3+ substitution-adjusted magnetic and optical properties with enhanced photocatalytic activity and stability of copper zinc nickel ferrites for wastewater treatment applications

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Journal of Rare Earths 2025年第2期43卷 319-328页

作者： N.S.Al-Bassami General Studies Department Jubail Industrial College

Copper-zinc-nickel（Cu-Zn-Ni） ferrite nanoparticles are used for wastewater treatment ***,low degradation efficiency and stability are two main issues that make them unsuitable for actual production *** this paper,the citrate-nitrate auto-combustion method was applied for the formation of Cu0.5Zn0.25Ni0.25LaxFe2-xO4;（0≤x≤0.1;step 0.02）(CZNL) *** the substitution process entails the replacement of a small ion with a larger one,the lattice constant and crystallite size does not exhibit a consistent incremental *** behavior is justified and *** size of all the CZNL ferrite nanoparticles is in the range of 8-12 nm,and the lattice constant is in the range of 8.6230 to 8.4865 *** morphological analysis conducted using field emission-scanning electron microscopy（FE-SEM） reveals that the CZNL exhibits agglomerated spherical *** energy dispersive X-ray spectrameter（EDAX） analysis was employed to confirm the elemental composition of CZNL *** the process entails the substitution of Fe3+magnetic ions with nonmagnetic ions La3+,the magnetic parameters of CZNL nanoferrites show a general decreasing trend as *** 20 K,saturation magnetization Ms shows an overall drop in its values from 59.302 emu/g at x=0.0-41.295 emu/g at x=0.1,the smallest value of 37.87 emu/g is recorded at x=*** highest coercivity（Hc=125.9 Oe） and remanence（Mr=13.32 emu/g） are recorded for x=0.08 and x=0.04 nanoferrite,*** band gap of all the CZNL nanoferrites was determined using the Kubelka-Munk function and Tauc plot for direct permitted *** doping modifies the band gap（within 1.86-1.75 eV）,increases light absorption,induces efficient e/h separation and charge migration to *** nanoferrite Cu0.5Zn0.25Ni0.25La0.06Fe1.94O4achieves a degradation efficiency of 97.3% for methylene blue（MB） dye removal after just 60 *** five recycling processes,the nanoc

关键词： Copper-zinc-nickel Ferrite Photocatalytic properties Rare earths Wastewater treatment

An Online Exploratory Maximum Likelihood Estimation Approach to Adaptive Kalman Filtering

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IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 228-254页

作者： Jiajun Cheng Haonan Chen Zhirui Xue Yulong Huang Yonggang Zhang the college of Intelligent Systems Science and Engineering Harbin Engineering University the Engineering Research Center of Navigation Instruments Ministry of Education the college of Intelligent Systems Science and Engineering the college of Future Technology Harbin Engineering University IEEE

Over the past few decades, numerous adaptive Kalman filters(AKFs) have been proposed. However, achieving online estimation with both high estimation accuracy and fast convergence speed is challenging, especially when both the process noise and measurement noise covariance matrices are relatively inaccurate. Maximum likelihood estimation(MLE) possesses the potential to achieve this goal, since its theoretical accuracy is guaranteed by asymptotic optimality and the convergence speed is fast due to weak dependence on accurate state ***, the maximum likelihood cost function is so intricate that the existing MLE methods can only simply ignore all historical measurement information to achieve online estimation,which cannot adequately realize the potential of MLE. In order to design online MLE-based AKFs with high estimation accuracy and fast convergence speed, an online exploratory MLE approach is proposed, based on which a mini-batch coordinate descent noise covariance matrix estimation framework is developed. In this framework, the maximum likelihood cost function is simplified for online estimation with fewer and simpler terms which are selected in a mini-batch and calculated with a backtracking method. This maximum likelihood cost function is sidestepped and solved by exploring possible estimated noise covariance matrices adaptively while the historical measurement information is adequately utilized. Furthermore, four specific algorithms are derived under this framework to meet different practical requirements in terms of convergence speed, estimation accuracy,and calculation load. Abundant simulations and experiments are carried out to verify the validity and superiority of the proposed algorithms as compared with existing state-of-the-art AKFs.

关键词： Adaptive Kalman filtering coordinate descent maximum likelihood estimation mini-batch optimization unknown noise covariance matrix

Influence of Rhamnolipids Biosurfactant on the Anodic Electrochemical Performance in Marine Sediment Microbial Fuel Cell and the Acceleration Degradation of Crude Petroleum

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Journal of Ocean University of China 2025年第1期24卷 139-146页

作者： HOU Luyao ZAI Xuerong MENG Yao LIANG Shengkang CAO Yali CHEN Yan ZHANG Huaijing HUANG Xiang FU Yubin college of Materials Science and Engineering Ocean University of ChinaQingdao 266100China college of Chemistry and Chemical Engineering Ocean University of ChinaQingdao 266100China college of Marine Geosciences Ocean University of ChinaQingdao 266100China

Crude petroleum pollution causes some serious ecological disasters in the *** sediment microbial fuel cells(MSMFCs)have been utilized as a novel method for in-situ degradation and a long-term power ***,the effect of different concentrations of rhamnolipids biosurfactant on the electrochemical performance of MSMFCs anode and the higher efficiency of oil degradation are creatively *** results indicate that the anode in sediment containing rhamnolipids effectively enriches the indigenous electrogenic Pseudophaeobacter and Pseudomonas,which significantly enhances the electrochemical performance of the *** rhamnolipids at the concentration of 200 mg kg^(-1)in sediment,the anode specific capacitance(401.45 Fm^(-2)),exchange current density(4.87×10^(-2)mAm^(-2)),and cell maximum power density(140.24 mWm^(-2))increase by 2.50,38.65,and 2.11 times,respectively,in comparison with its natural *** the oil degradation rate(40.06%)was higher than the blank(17.55%).It demonstrates that the synergistic effect between electrochemical catalytic degradation and emulsifying solubilization of rhamnolipids surfactant directly accelerates the degradation of petroleum in marine sediment,which will provide a novel method and theoretical guidance for in-situ degradation and efficient removal of crude petroleum on ocean floor.

关键词： marine sediment microbial fuel cells petroleum pollution rhamnolipids biosurfactant electrochemical performance

A six-variable quasi-3D isogeometric approach for free vibration of functionally graded graphene origami-enabled auxetic metamaterial plates submerged in a fluid medium

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 157-176页

作者： Wei CHEN Zhihong TANG Yufen LIAO Linxin PENG college of Civil Engineering University of South China college of Civil Engineering and Architecture Guangxi University Key Laboratory of Disaster Prevention and Structural Safety of Ministry of Education Guangxi University

This paper presents, for the first time, an effective numerical approach based on the isogeometric analysis(IGA) and the six-variable quasi-three dimensional(3D)higher-order shear deformation theory(HSDT) to study the free vibration characteristics of functionally-graded(FG) graphene origami(GOri)-enabled auxetic metamaterial(GOEAM) plates submerged in a fluid medium. The plate theory incorporates the thickness stretching and the effects of transverse shear deformation without using any shear correction factors. The velocity potential function and Bernoulli's equation are used to derive the hydrodynamic pressure acting on the plate surface. Both horizontally and vertically immersed plate configurations are considered here in the form of inertia *** plates are composed of multilayer GOEAMs, with the GOri content varying through the plate's thickness in a layer-wise manner. This design results in graded auxetic *** material properties are evaluated by mixing rules and a genetic programming(GP)-assisted micromechanical model. The governing equations of motion for the FG-GOEAM plates immersed in a fluid medium are derived by Hamilton's principle. After validating the convergence and accuracy of the present model, a comprehensive parametric study is carried out to examine the effects of the GOri content, GOri distribution pattern, GOri folding degree, fluid level, immersed depth, and geometric parameter on the natural frequencies of the FG-GOEAM plates. The results show that the natural frequencies for the four GOri distribution patterns increase with the increase in the layer number when the lay number is fewer than 10, and then stabilize after the layer number reaches ***, in general, the natural frequency of the FG-GOEAM plate in a vacuum or fluid increases when the GOri content increases, while decreases when the GOri folding degree increases. Some additional findings related to the numerical results are presented in the conclusions. It is belie

关键词： free vibration functionally-graded (FG) graphene origami (GOri)-enabled auxetic metamaterial (GOEAM) plate hydrodynamic pressure isogeometric analysis (IGA) O321 quasi-three dimensional (3D) higher-order shear deformation theory (HSDT)

Dual-role regulator of a novel miR-3040 in photoperiod-mediated wing dimorphism and wing development in green peach aphid

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Insect Science 2025年第1期32卷 80-94页

作者： Yun-Hui Zhang Xin Qian Xin Zong Shi-Heng An Shuo Yan Jie Shen college of Plant Protection Henan Agricultural UniversityZhengzhouChina Department of Plant Biosecurity College of Plant ProtectionChina Agricultural UniversityBeijingChina

Wing dimorphism is regarded as an important phenotypic plasticity involved in the migration and reproduction of ***,the signal transduction and regulatory mechanism of wing dimorphism in aphids are still ***,the optimal environmental conditions were first explored for inducing winged offspring of green peach aphid,and the short photoperiod was the most important environmental cue to regulate wing *** to 16 L:8 D photoperiod,the proportion of winged offspring increased to 90%under 8 L:16 D ***,5 differentially expressed microRNAs(miRNAs)in aphids treated with long and short photoperiods were identified using small RNA sequencing,and a novel miR-3040 was identified as a vital miRNA involved in photoperiod-mediated wing *** specifically,the inhibition of miR-3040 expression could reduce the proportion of winged offspring induced by short photoperiod,whereas its activation increased the proportion of winged offspring under long ***,the expression level of miR-3040 in winged aphids was about 2.5 times that of wingless aphids,and the activation or inhibition of miR-3040 expression could cause wing deformity,revealing the dual-role regulator of miR-3040 in wing dimorphism and wing *** summary,the current study identified the key environmental cue for wing dimorphism in green peach aphid,and the first to demonstrate the dual-role regulator of miR-3040 in photoperiod-mediated wing dimorphism and wing development.

关键词： miR-3040 Myzus persicae photoperiod wing development wing dimorphism