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Catalytic co-combustion of biomass and brown coal in a fluidized bed:Economic and environmental benefits

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Journal of Environmental Sciences 2024年第6期140卷 24-36页

作者： Yury V.Dubinin Nikolay A.Yazykov Petr M.Yeletsky Roman B.Tabakaev Aleksandra I.Belyanovskaya Vadim A.Yakovlev Federal Research Center Boreskov Institute of Catalysis SB RAS Lavrentiev Ave.5Novosibirsk630090Russia university of tyumen Volodarskogo str.6Tyumen625003Russia

The work is devoted to the study of combustion of brown coal,pine sawdust,and their mixtures in a fluidized bed of catalyst at 600-750℃.It is shown that an increase in the content of sawdust in a mixture with brown coal leads to an increase in the burnout degree of solid fuel from 94.4%to 99.9%,while the emission of greenhouse gases in the form of CO_(2)CO and NOxis reduced(CO_(2)from the biomass is not included in the balance).The high content of alkaline earth metal oxides(CaO and MgO)in the mineral part of brown coal,sawdust,and their mixtures eliminates the emission of sulfur oxides and the slagging of heat-exchange surfaces during the combustion in a fluidized bed of *** optimal temperature,when the highest burnout degree of the above fuels is achieved in the combustion is 750℃.It is also shown that the increase in temperature and the content of sawdust in the composition of the fuel mixtures has a positive effect on the economic and environmental process indicators.

关键词： Co-combustion Fluidized catalyst bed Biomass Coal Economic effect Environmental impact

A new method for precise optical measurements of the sub-micron height of levitation of droplet clusters

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Particuology 2024年第4期87卷 173-178页

作者： Alexander A.Fedorets Eduard E.Kolmakov Leonid A.Dombrovsky university of tyumen 6 Volodarskogo StTyumen625003Russia Engineering Faculty Ariel UniversityP0.B.3407000ArielIsrael Joint Institute for High Temperatures 17A Krasnokazarmennaya StMoscow111116Russia

Droplet clusters levitating over the locally heated water surface are considered a very promising phe-nomenon of microfluidics for the potential use of the droplets as unique microreactors for microbio-logical experiments.A new optical method is suggested for precise measurements of the sub-micron levitation height of single *** method is based on the analysis of variable colors of the inter-ference halo around the *** the first time,it is possible to measure the extremely low downward velocity of droplets,which grow due to steam *** velocity was found to be 5-8 nm/*** height of the levitation of various droplets just before their coalescence with a layer of water was also *** measurements might be used for the verification of sophisticated models for the droplet levitation to be developed for a very thin layer of humid air under the droplet when the Knudsen effect should be taken into account.

关键词： Precise measurements Interferometric method Droplet cluster Levitation height

Origin of iron-rich minerals,ooids and pisoids in the Jurassic ooidal ironstones of the Labino-Malkin region(Caucasus)

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Journal of Palaeogeography 2024年第3期13卷 475-494页

作者： Natalia A.Kalinina Maxim A.Rudmin Mikhail Sherstyukov Prokopiy Maximov Abdul-Gapur Kerimov Division for Geology School of Earth Sciences&EngineeringTomsk Polytechnic University634050TomskRussia Laboratory of Sedimentology and Paleobiosphere Evolution University of Tyumen625003 TyumenRussia Institute of Earth Science North-Caucasus Federal University355009StavropolRussia

This study investigates the Middle Jurassic rocks of the Labino-Malkin zone(Caucasus),represented by ooidal ironstones,biogenic limestones,and nodular *** rocks contain ooids/*** on the mineral composition,nine types of ooids and three possible scenarios for their formation have been *** mineral composition of ooids indicates the variable conditions of their deposition and repeated changes in physical and chemical conditions of the environment,including fluctuations in theredox *** access of oxygen in the bottom environment as a factor of increasing oxic conditions was associated with the regression of the sea and/or the inflow of meteoric *** main sources of ooids are the drift of material from the continent and convecting metal-bearing meteoric and/or deep solutions.

关键词： Ooidal ironstones Mineral formation Ooids Pisoids Mineral chemistry

Elucidating elusive quaternary selenide EuCeCuSe3:Synthesis,crystal structure,properties and theoretical studies

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Journal of Rare Earths 2024年第1期42卷 163-171,I0006页

作者： Maxim V.Grigoriev Anna V.Ruseikina Maxim S.Molokeev Vladimir A.Chernyshev Aleksandr S.Aleksandrovsky Alexander S.Krylov Svetlana N.Krylova Nikolai P.Shestakov Dmitriy A.Velikanov Alexander A.Garmonov Alexey V.Matigorov Evgeny A.Ostapchuk Thomas Schleid Damir A.Safin Laboratory of Theory and Optimization of Chemical and Technological Processes University of TyumenVolodarskogo Str.6625003TyumenRussian Federation Kirensky Institute of Physics Federal Research Center KSC SB RASAkademgorodok 50 Bld.38660036KrasnoyarskRussian Federation Department of Physics Far Eastern State Transport UniversitySerysheva Str.47680021KrasnoyarskRussian Federation Institute of Natural Sciences and Mathematics Ural Federal University Named After the First President of Russia B.N.YeltsinMira Str.19620002EkaterinburgRussian Federation Department of Photonics and Laser Technology Siberian Federal UniversitySvobodnii Ave.79660079KrasnoyarskRussian Federation Institute of Physics and Technology University of TyumenVolodarskogo Str.6625003 TyumenRussian Federation Institute for Inorganic Chemistry University of StuttgartPfaffenwaldring 55D-70569StuttgartGermany Scientific and Educational and Innovation Center for Chemical and Pharmaceutical Technologies Ural Federal University named after the First President of Russia B.N.YeltsinMira Str.19620002 EkaterinburgRussian Federation university of tyumen Volodarskogo Str.6625003TyumenRussian Federation

We report on the novel heterometallic quaternary selenide EuCeCuSe3,the fabrication of which has been a challenge until this *** structure of the reported selenide was elucidated from the powder X-ray diffraction data,which revealed the formation of EuCeCuSe3with excellent yield(96.7%)accompanied with a minor fraction of CeSe2(3.3%),and was best solved in orthorhombic space group Pnma with the BaLaCuS3structural ***,the crystal structure of the title compound completes the row of the heterometallic quaternary selenides EuRECuSe3(RE=La,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y),of which the cerium-based derivative exclusively belongs to the BaLaCuS3structural *** distortion of the CuSe4polyhedron was compared for the whole series of EuRECuSe3compounds using theτ4-descriptor for four coordinated ions,which revealed the highest degree of distortion for the Ce3+-containing selenide,followed by the La3+-based ***,the crystallographic and geometrical parameters of the reported selenide were discussed in comparison to the Ce3+-based sulfides SrCeCuS3and *** initio calculations of the crystal structure,a phonon spectrum and elastic constants for the crystal of EuCeCuSe3were also *** types and wavenumbers of fundame ntal modes were determined and the involvement of ions participating in the phonon modes was *** experimental IR spectrum of the reported selenide was interpreted and found to be in agreement with the calculated *** experimental direct band gap of EuCeCuSe3was measured to be 1.36 eV that is consistent with the concept of its origin due to interband transitions between orbitals emerging mainly from 4f(valence band)and 5d(conduction band)levels of the Eu2+*** dependence of the Young’s modulus on the direction demonstrates the anisotropy of the elastic properties,while the Vickers hardness for EuCeCuSe3was calculated to be 5.2 ***,the title compound is paramagnetic above 4 K.

关键词： Quaternary selenide Synthesis Crystal structure Ab initio calculations Magnetic measurements Spectroscopy

Hypoxia-inducible factor-1αin myocardial infarction

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World Journal of Cardiology 2024年第4期16卷 181-185页

作者： IvanaŠkrlec Sergey N Kolomeichuk Faculty of Dental Medicine and Health Josip Juraj Strossmayer University of OsijekOsijek 31000Croatia Institute of Biology Karelia Research Center of Russian Academy of SciencesPetrozavodsk 185910Russia Laboratory for Genomics Proteomicsand MetabolomicsResearch Institute of Biomedicine and Biomedical TechnologiesTyumen State Medical UniversityTyumen 625023Russia

Hypoxia-inducible factor 1(HIF1)has a crucial function in the regulation of oxygen levels in mammalian cells,especially under hypoxic *** importance in cardiovascular diseases,particularly in cardiac ischemia,is because of its ability to alleviate cardiac *** oxygen-responsive subunit,HIF1α,plays a crucial role in this process,as it has been shown to have cardioprotective effects in myocardial infarction through regulating the expression of genes affecting cellular survival,angiogenesis,and ***,HIF1αexpression induced reperfusion in the ischemic skeletal muscle,and hypoxic skin wounds in diabetic animal models showed reduced HIF1α*** expression of HIF1αhas been shown to reduce apoptosis and oxidative stress in cardiomyocytes during acute myocardial *** variations in HIF1αhave also been found to correlate with altered responses to ischemic cardiovascular *** addition,a link has been established between the circadian rhythm and hypoxic molecular signaling pathways,with HIF1αfunctioning as an oxygen sensor and circadian genes such as period circadian regulator 2 responding to changes in *** editorial analyzes the relationship between HIF1αand the circadian rhythm and highlights its significance in myocardial adaptation to *** the changes in molecular signaling pathways associated with diseases,specifically cardiovascular diseases,provides the opportunity for innovative therapeutic interventions,especially in low-oxygen environments such as myocardial infarction.

关键词： Cardiovascular pathologies Circadian genes Hypoxia-inducible factor 1 Hypoxia Gene-gene interaction

Effect of biochar aging in agricultural soil on its wetting properties and surface structure

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Biochar 2023年第1期5卷 1288-1304页

作者： Natalia Ivanova Gardoon Luqman Obaeed Obaeed Farid Sulkarnaev Natalya Buchkina Alexey Gubin Andrei Yurtaev Photonics and Microfluidics Lab X-BIO InstituteUniversity of Tyumen6 Volodarskogo625003 TyumenRussia International Integrated Research Lab for Climate Change Land Use and BiodiversityX-BIO InstituteUniversity of Tyumen6 Volodarskogo625003 TyumenRussia Department of Soil Physics Physical Chemistry and BiophysicsAgrophysical Research InstituteGrazhdansky Pr.14195220 St.PetersburgRussia X-BIO Institute University of Tyumen6 Volodarskogo625003 TyumenRussia Nanomaterials and Nanoelectronics Laboratory CNIEUniversity of Tyumen6 Volodarskogo625003 TyumenRussia

Biochar wettability and ability to accumulate moisture inside the porous space are crucial for improving soil fertility,regulating soil water balance,and regulating ***,a long-term interaction of biochar with agricultural soils may drastically alter the wetting properties and,eventually,influence water holding capacity and the structure of *** this work,the structure and wetting properties of biochar samples after 6-year long exposure to a sandy loam Spodosol with a crop rotation and mineral fertilizers application were *** was found that the elemental composition of the aged biochars was richer and more"soil-like",which is explained by the presence of the mineral crust on the biochar *** temporal evolution of biochar in the soil without any mineral fertilizer application resulted in significant improvement of its surface wettability due to the effects of various environmental *** lateral surface of biochar after 6-year interaction with the soil changes into a loose porous layer in a form of grooved base filled with adherent mineral soil and clay ***,the application of the mineral fertilizer to the soil resulted in decreased wettability of the biochar lateral surfaces due to a decrease in the polar component of surface energy and the crusting of the surface with fine material,which blocks the pore space of the *** a result,water capacity of the biochar from the treatment with the fertilizer decreased compared to the biochar samples collected from the soil without the fertilizer *** radial biochar surfaces of both types of samples collected from the soil were open vessels filled with soil particles that slow down complete wetting and water *** treatment of the biochar samples with surfactants drastically increased wettability of lateral surface and water absorption capacity of control samples as compared to the samples collected from the *** obtained results support the idea t

关键词： Light-textured Spodosol 6-year field experiment Biochar surface Wettability Water absorbing Soil capacity

Gas flaring cause shifts in mesophyll and stomatal functional traits of Betula pubescens Ehrh.

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林业研究:英文版 2023年第6期34卷 2079-2087页

作者： Dina A.Ronzhina Svetlana V.Migalina Irek A.Yusupov Institute Botanic Garden Ural BranchRussian Academy of Sciences202a 8 Marta Str.EkaterinburgRussia 620144 tyumen State university 6 Volodarskogo Str.TyumenRussia 625003

In petroleum-producing territories of West Siberia(Russia),oil well gas flares have a thermal effect on nearby plant *** communities can be used as models for studying plant acclimation to global *** the present study on the effect of the hydrothermal regime at the flare sites on mesophyll and stomatal functional traits of Betula pubescens,leaves were collected from trees at250 m(control site[CS]),200,150 and 100 m(maximum impact site[MIS])from a *** the CS to MIS site,the average annual air temperature increased by 0.5℃and bog water level decreased by 17 *** plants from the MIS,stomata were 16%smaller and density was 20%lower compared to those at the CS,resulting in lower maximum stomatal conductance in plants from the MIS(mean±SE:MIS 0.84±0.05 mol·m^(-2)s^(-1),CS 1.24±0.06 mol·m^(-2)s^(-1);F=12.6,P<0.01).Mesophyll cell volume was 1.9 times lower at MIS than at *** numbers per cell also declined with distance from the flares,from 21(MIS)to18(CS;F=15.6,P<0.001),and chloroplast volume was 24%higher at the CS,whereas the number of mesophyll cells and chloroplasts numbers per unit leaf area were 1.9 and 1.8 times higher at the MIS than at the CS,*** a result,leaves from the MIS had a large total mesophyll cell(Ames/A)and chloroplast(Achl/A)surface area per unit leaf area,resulting in a 46%increase in mesophyll conductance in plants from the ***,structural changes in leaf epidermis consisted of a decrease in stomatal size and number,could lower transpiration losses with higher temperatures and less *** compensate for the reduction in leaf conductance due to a decrease in stomatal conductance under these conditions,an increase in the number of mesophyll cells and chloroplasts per unit area provides a greater gas-exchange area and mesophyll conductance.

关键词： Leaf traits Mesophyll cell volume Chloroplast numbers Mesophyll conductance Stomatal conductance

Melatonin, circadian rhythms and glaucoma: current perspective

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Neural Regeneration Research 2022年第8期17卷 1759-1760页

作者： Denis Gubin Dietmar Weinert Chronobiology&Chronomedicine Laboratory Medical UniversityTyumen/Department of BiologyMedical UniversityTyumen/Tyumen Cardiology Research CenterTomsk National Research Medical CenterRussian Academy of ScienceTomskRussia Institute of Biology/Zoology Martin Luther UniversityHalle-WittenbergGermany

Primary open-angle glaucoma as a causal factor for circadian disruption:Living by the clock,in alignment with external time cues is an important condition for human health and *** changes in the ambient light serve as a key factor to synchronize the endogenously generated circadian *** retina perceives the photic signals and transmits them to the central body clock,the suprachiasmatic nuclei(SCN),via the retinohypothalamic tract.

关键词： ambient alignment Periodic

Investigation of the influences of asphaltene deposition on oilfield development using reservoir simulation

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Petroleum Exploration and Development 2022年第5期49卷 1138-1149页

作者： TANANYKHIN D S STRUCHKOV I A KHORMALI A ROSCHIN P V Saint-Petersburg Mining university Saint-Petersburg 199106Russia LLC tyumen Petroleum Research Center Tyumen 625000Russia Department of Chemistry Faculty of Basic Sciences and EngineeringGonbad Kavous UniversityGonbad Kavous 49717-99151Iran LLC SamaraNIPIneft Samara 443010Russia

This paper investigates the deposition of asphaltenes in the porous medium of the studied field in Russia and predicts production profiles based on uncertainty evaluation. This problem can be solved by dynamic modeling, during which production profiles are estimated in two scenarios: with and without the activation of the asphaltene option. Calculations are carried out for two development scenarios: field operation under natural depletion and water injection into the aquifer as a reservoir pressure maintenance system. A full-scale compositional reservoir simulation model of the Russian oilfield was created. Within a dynamic simulation, the asphaltene option was activated and the asphaltene behavior in oil and porous medium was tuned according to our own special laboratory experiments. The model was also matched to production historical data, and a pattern model was prepared using the full-scale simulation model. Technological and the asphaltene option parameters were used in sensitivity and an uncertainty evaluation. Furthermore, probable production profiles within a forecast period were estimated. The sensitivity analysis of the pattern model to input parameters of the asphaltene option allowed determining the following heavy-hitters on the objective function: the molar weight of dissolved asphaltenes as a function of pressure, the asphaltene dissociation rate, the asphaltene adsorption coefficient and the critical velocity of oil movement in the reservoir. Under the natural depletion scenario, our simulations show a significant decrease in reservoir pressure and the formation of drawdown cones leading to asphaltene deposition in the bottom-hole area of production wells, decreasing their productivity. Water injection generally allows us to significantly reduce the volume of asphaltene phase transitions and has a positive effect on cumulative oil production. Injecting water into aquifer can keep the formation pressure long above the pressure for asphaltene precipita

关键词： oilfield development asphaltene deposition uncertainty evaluation sensitivity analysis compositional reservoir simulation