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Journal of Energy Chemistry 2025年第1期100卷 26-38页

作者： Xiaodong Yang Haochen Shen Xiaoming Xiao Zhichao Li Qi Zhou Wei Yang Bin Jiang Yongli Sun Luhong Zhang Zhenhua Yan School of Chemical Engineering and Technology Tianjin University Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Nankai University

This study presents a novel method to fabricate metal-decorated,sulfur-doped layered double hydroxides （M/SLDH） through spontaneous redox and sulfurization *** developed Ag/SLDH and Pt/SLDH catalysts with abundant heterogeneous interfaces and hierarchical nanostructures demonstrated outstanding oxygen evolution reaction （OER） and hydrogen evolution reaction （HER） performance,achieving low overpotentials of 212 and 35 mV at 10 mA cm-2in 1 M KOH,*** both anode and cathode in water splitting,they required only 1.47 V to reach 10 mA cm-2and exhibited high structural robustness,maintaining stability at 1000 mA cm-2for 300 ***-situ Raman analysis revealed that the synergistic effects of metal nanoparticles and S doping significantly promote the transformation into the S-Co1-xFexOOH layer,which serves as the active phase for water ***,ultraviolet photoelectron spectroscopy （UPS） and density functional theory （DFT） analyses indicated that incorporating metal nanoparticles and S doping increase electron density near the Fermi level and reduce reaction energy barriers,thus enhancing intrinsic OER and HER *** study provides a scalable strategy for synthesizing high-performance electrocatalysts for water splitting,with promising potential for broader applications.

关键词： LDH Spontaneous reaction Metal nanoparticles Water splitting

Reconfigurable intelligent surfaces for smart wireless environments: channel estimation, system design and applications in 6G networks

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Science China(Information Sciences) 2021年第10期64卷 52-72页

作者： Ying-Chang LIANG Jie CHEN Ruizhe LONG Zhen-Qing HE Xianqi LIN Chenlu HUANG Shilin LIU Xuemin (Sherman) SHEN Marco DI RENZO Center for Intelligent Networking and Communications University of Electronic Science and Technology of China School of Electronic Science and Engineering University of Electronic Science and Technology of China Department of Electrical and Computer Engineering University of Waterloo Université paris-saclay CNRS CentraleSupélec Laboratoire des Signaux et Systèmes

Reconfigurable intelligent surface(RIS), one of the key enablers for the sixth-generation(6G)mobile communication networks, is considered by designers to smartly reconfigure the wireless propagation environment in a controllable and programmable manner. Specifically, an RIS consists of a large number of low-cost and passive reflective elements(REs) without radio frequency chains. The system gain of RIS wireless systems can be achieved by adjusting the phase shifts and amplitudes of the REs so that the desired signals can be added constructively at the receiver. However, an RIS typically has limited signal processing capability and cannot perform active transmitting/receiving in general, which leads to new challenges in the physical layer design of RIS wireless systems. In this paper, we provide an overview of the RIS-aided wireless systems, including the reflection principle, channel estimation, and system design. In particular,two types of emerging RIS systems are considered: RIS-aided wireless communications(RAWC) and RISbased information transmission(RBIT), where the RIS plays the role of the reflector and the transmitter,respectively. We also envision the potential applications of RIS in 6G networks.

关键词： reconfigurable intelligent surface channel estimation RIS-aided wireless communications RIS-based information transmission 6G

Microstructural evolution during the progressive transformation-induced plasticity effect in a Fe-0.1C-5Mnmedium manganese steel

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 369-379页

作者： Mei Zhang Wenhao Li Yangfei Chen Yang Jiang Xiaofei Guo Han Dong School of Materials Science and Engineering Shanghai UniversityShanghai 200444China State Key Laboratory of Advanced Special Steel Shanghai UniversityShanghai 200444China

The microstructural evolution of a cold-rolled and intercritical annealed medium-Mn steel(Fe-0.10C-5Mn)was investigated during uniaxial tensile ***-situ observations under scanning electron microscopy,transmission electron microscopy,and X-ray diffraction analysis were conducted to characterize the progressive transformation-induced plasticity process and associated fracture initiation *** findings were discussed with the local strain measurements via digital image *** results indicated that Lüders band formation in the steel was limited to 1.5%strain,which was mainly due to the early-stage martensitic phase transformation of a very small amount of the less stable large-sized retained austenite(RA),which led to localized stress concentrations and strain hardening and further retardation of *** small-sized RA exhibited high stability and progressively transformed into martensite and contributed to a stably extended Portevin-Le Chatelier *** volume fraction of RA gradually decreased from 26.8%to 8.2%prior to *** the late deformation stage,fracture initiation primarily occurred at the austenite/martensite and ferrite/martensite interfaces and the ferrite phase.

关键词： medium-Mn steel retained austenite progressive transformation-induced plasticity effect local strain fracture initiation

CaH2-promoted activity of Ni-carbonate interface for CO2 methanation

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Journal of Energy Chemistry 2025年第1期100卷 522-532页

作者： Jin-Peng Wang Guo-Cui Mao Hui-Lin Jiang Bao-Xia Dong Yun-Lei Teng School of Chemistry and Chemical Engineering Yangzhou University

Transition metal-carbonate interfaces often act as active sites in heterogeneous catalytic *** interface between transition metal and metal carbonate exhibits a dynamic equilibrium during the CO2hydrogenation reaction,involving surface carbonate hydrogenation and ***,there have been few reports on engineering the activity of the interface between transition metal and alkaline earth metal carbonate for catalytic *** work demonstrated that the incorporation of CaH2in Ni/CaCO3enhances the CO2methanation activity of the *** CO2conversion for Ni/CaH2-CaCO3reached 68.5%at 400°C,which was much higher than that of the Ni/CaCO3（31.6%） and Ni/CaH2-CaO （42.4%） ***,the Ni/CaH2-CaCO3catalysts remained stable during the stability test for 24 h at 400°C and 8 *** research revealed that CaH2played a crucial role in promoting the activity of the Ni-carbonate interface for ***2could modify the electronic structure of Ni and tune the structural properties of CaCO3to generate medium basic sites （OH groups）,which are favorable for the activation of H2and ***-situ Fourier transform infrared spectroscopy （FTIR） analysis combined with density functional theory calculations demonstrated that CO2activation occurs at the hydroxyl group （OH） on the CaH2-modified Ni-carbonate surface,leading to the formation of CO3H****,our study has confirmed that CO2methanation over the Ni/CaH2-CaCO3catalysts proceeds via the formate pathway.

关键词： Metal hydride Ni catalysts Carbonate Metal-carbonate interface

Multi-layer multi-pass friction rolling additive manufacturing of Al alloy:Toward complex large-scale high-performance components

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 425-438页

作者： Haibin Liu Run Hou Chenghao Wu Ruishan Xie Shujun Chen College of Mechanical&Energy Engineering Beijing University of TechnologyBeijing 100124China Chongqing Research Institute of Beijing university of Technology Chongqing 401121China

At present,the emerging solid-phase friction-based additive manufacturing technology,including friction rolling additive man-ufacturing(FRAM),can only manufacture simple single-pass *** this study,multi-layer multi-pass FRAM-deposited alumin-um alloy samples were successfully prepared using a non-shoulder tool *** material flow behavior and microstructure of the over-lapped zone between adjacent layers and passes during multi-layer multi-pass FRAM deposition were studied using the hybrid 6061 and 5052 aluminum *** results showed that a mechanical interlocking structure was formed between the adjacent layers and the adja-cent passes in the overlapped center *** friction and rolling of the tool head led to different degrees of lateral flow and plastic deformation of the materials in the overlapped zone,which made the recrystallization degree in the left and right edge zones of the over-lapped zone the highest,followed by the overlapped center zone and the non-overlapped *** tensile strength of the overlapped zone exceeded 90%of that of the single-pass deposition *** is proved that although there are uneven grooves on the surface of the over-lapping area during multi-layer and multi-pass deposition,they can be filled by the flow of materials during the deposition of the next lay-er,thus ensuring the dense microstructure and excellent mechanical properties of the overlapping *** multi-layer multi-pass FRAM deposition overcomes the limitation of deposition width and lays the foundation for the future deposition of large-scale high-performance components.

关键词： aluminum alloy additive manufacturing solid-state friction stir welding multi-layer multi-pass

Polypeptide analysis for nanopore-based protein identification

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Nano Research 2022年第11期15卷 9831-9842页

作者： Mazdak Afshar Bakshloo Safia Yahiaoui Fabien Piguet Manuela Pastoriza-Gallego Régis Daniel Jérôme Mathé John J.Kasianowicz Abdelghani Oukhaled CY Cergy paris Université CNRSLAMBE95000CergyFrance Universitéparis-saclay Univ EvryCNRSLAMBE91025Evry-CourcouronnesFrance university of South Florida Dept.of PhysicsTampaFL 33620USA Freiburg Institute for Advanced Studies Universität FreiburgFreiburg 79104Germany

Presently,proteins are identified by cleaving them with proteases,measuring the mass to charge ratio of the fragments with a mass spectrometer,and matching the fragments to segments within known proteins in *** earlier demonstrated that a nanometer-scale pore formed by aerolysin(AeL)can discriminate between,and therefore identify,three similar size proteins from their trypsin-cleaved polypeptide *** this nanopore-protease method,the protein’s identity is instead determined from characteristic ionic current blockade patterns caused by the polypeptide fragments that enter the *** results also suggested that not all of the theoretically expected cleavage products partition into the *** better understand the mechanism by which polypeptide fragments are captured,and how different polypeptides reduce the pore’s ionic current,we studied the effects of 11 identical length polypeptides with different net charges and charge *** show that under certain experimental conditions,negative,positive,and neutral polypeptides are driven into the AeL pore by the same applied voltage *** capture rate and dwell time of polypeptides in the pore depend strongly on the ionic strength,the magnitude of the applied voltage,and the net charge and charge distribution of the *** dwell time distribution depends nonmonotonically on the applied voltage(regardless of the polymer’s net charge),and its maximum value depends on the polypeptide net charge and charge *** maximum dwell time for different polypeptides does not occur at the same applied voltage amplitude,which conceivably might complicate the detection and discrimination of some polypeptide *** additional experiments,computer simulations,and artificial intelligence research are needed to better understand how to optimize the partitioning of enzymatically cleaved fragments into the AeL nanopore,the method is still capable of accurately identifying

关键词： protein identification nanopores trypsin enzymatic degradation

Application of reliability technologies in civil aviation: Lessons learnt and perspectives

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Chinese Journal of Aeronautics 2019年第1期32卷 143-158页

作者： Enrico ZIO Mengfei FAN Zhiguo ZENG Rui KANG Chair System Science and the Energy Challenge Fondation Electricité de France (EDF)CentraleSupélecUniversité Paris Saclay Energy Department Politecnico di Milano Sino-French Risk Science and Engineering Lab Beihang University School of Reliability and Systems Engineering Beihang University

We consider reliability engineering in modern civil aviation industry, and the related engineering activities and methods. We consider reliability in a broad sense, referring to other system characteristics that are related to it, like availability, maintainability, safety and durability. We covered the entire lifecycle of the equipment, including reliability requirement identification, reliability analysis and design, verification and validation of reliability requirements(typically involved in the equipment design and development phase), quality assurance(which typically enters in the manufacturing phase), and fault diagnosis and prognosis and maintenance(which are connected to the operation phase). Lessons learnt from reliability engineering practices in civil aviation industry are given, which might serve as reference for reliability managers and engineers, also from other industries with high reliability requirements.

关键词： Civil aviation Commercial aircraft Fault diagnosis and prognosis Human reliability analysis Maintenance Quality control Reliability design Reliability engineering

Maximizing biomass utilization: An integrated strategy for coproducing multiple chemicals

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Journal of Energy Chemistry 2025年第1期100卷 180-191页

作者： Byeongchan Ahn Sua Jo Jonggeol Na J.Jay Liu Young-Ju Kim Wangyun Won Department of Chemical and Biological Engineering Korea University Department of Chemical Engineering (Integrated process) Kyung Hee University Department of Chemical Engineering and Materials Science Ewha Womans University Department of Chemical Engineering Pukyong National University Resources Engineering Plant Research Department Korea Institute of Geoscience and Mineral Resources

Lignocellulosic biomass is one of the viable solutions to alleviate the global warming. However, the limited utilization of biomass majorly focused on cellulose and hemicellulose restricts the economic and environmental feasibilities. To cope with this issue, we proposed an integrated process of co-producing 1,6-hexanediol（1,6-HDO） with tetrahydrofuran and adipic acid from biomass, referred to as Strategy A. To compare the impacts of lignin upgrading and feedstock, Strategy B, which co-produces tetrahydrofuran alone, and Strategy C, which is the traditional route to produce 1,6-HDO from fossil fuels, were used. Heat networks are also designed to reduce operating costs and indirect carbon emissions due to energy consumption, saving 87% and 83% of the heat and cooling requirements, respectively, in Strategy A. The market competitiveness of Strategy A was evaluated by determining the minimum selling price through techno-economic analysis, and sustainability was thoroughly investigated by quantifying the environmental impacts through both midpoint and endpoint life-cycle assessments（LCAs）.Strategy A was found to be the most favorable both economically（USRDSCHARDOLLAR3,402/ton） and environmentally（-26.9 kg CO2eq.）. This indicates that lignin valorization is not only economically but also environmentally preferred. Finally, changes in economic and environmental feasibilities depending on economic, process, and environmental parameters were investigated using sensitivity and uncertainty analyses. The results of these analyses provide valuable insight into bio-based chemical production.

关键词： Biorefinery Carbon mitigation Climate change Global warming Lignin utilization Bioeconomy

Recent development in metal halide perovskites synthesis to improve their charge-carrier mobility and photocatalytic efficiency

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Science China Materials 2023年第7期66卷 2545-2572页

作者： Marija Knezevic Thi-Hieu Hoang Nusrat Rashid Mojtaba Abdi-Jalebi Christophe Colbeau-Justin Mohamed Nawfal Ghazzal Universite paris-saclay Institut de Chimie PhysiqueUMR 8000 CNRS91405OrsayFrance Institute for Materials Discovery University College LondonMalet PlaceLondonWC1E 7JEUK

Over the past decade,all-inorganic metal halide perovskites(MHPs,CsPbX_(3):X=Cl,Br,I)have been widely investigated as promising materials for optoelectronic devices such as solar cells and light-emitting *** are defecttolerant,which allows tuning of their bandgap without altering their photophysical *** a fundamental point of view,MHPs are excellent candidates for photocatalytic reactions due to their light-harvesting capability,high photogenerated charge-carrier mobility,long diffusion lengths,and tunable bandgap *** this review,we provide an overview of various MHP engineering strategies(e.g.,surface,morphological,and structural modifications,heterojunction coupling,and encapsulation)which are directly linked to the charge-carrier mobility and lifetimes,and then to the photocatalytic ***,we outline different synthetic approaches resulting in surface and morphological modifications,anion/cation substitution,metallic doping,coupling,and encapsulation that tremendously influence MHPs’stability,optical properties,and charge-carrier dynamics at variable time scales(from fs toμs).We also provide an in-depth evaluation of the MHPs for variable photoredox reactions,discussing how the optical and electronic properties help to improve their stability and efficiency.

关键词： all-inorganic halide perovskite charge-carrier dynamics stability photocatalysis

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Not so black,not so white:differences in microorganism load of contiguous feathers from white stork chicks

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Current Zoology 2021年第3期67卷 263-270页

作者： Zaid Al Rubaiee Haider Al Murayati Marcin Tobolka Piotr Tryjanowski Anders Pape MФller Department of Biology College of ScienceMustansiriya UniversityBaghdadIraq Institute of Zoology Poznan University of Life SciencesPoznanPL-60-625Poland Ecologie Systematique Evolution Universite Paris-SudCNRSAgroParisTechUniversite Paris-SaclayOrsay CedexF-91405France College of Life Sciences Beijing Normal UniversityBeijing100875China

Many organisms are characterized by strikingly contrasting black and white coloration,but the function of such contrasts has been inadequately *** this article,we tested the function of black and white contrasting plumage in white stork Ciconia ciconia *** found greater abundance and diversity of microorganisms on black compared with adjacent white *** addition,nest size was positively correlated with the abundance and diversity of microorganisms on white *** initiation distance(FID),defined as the distance at which adult white storks took flight when approached by a human,was negatively correlated with most measurements of microorganism *** success was generally positively correlated with the abundance and diversity of microorganisms on black *** feather growth rate was positively correlated with some and negatively correlated with other measurements of microbial abundance and ***,chick growth was negatively correlated with the number of microbial species on black feathers and positively with the abundance and diversity of microorganisms on white *** findings are consistent not only with the role of microorganisms in the maintenance of a benign microbial environment which differs between black and white feathers,but also with the hypothesis that several taxa of microorganisms found in black and white plumage are virulent,with negative effects on the fitness of their hosts.

关键词： accumulation of microorganisms Ciconia ciconia fungi microbiome