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Journal of Zhejiang university-Science A(Applied Physics & Engineering) 2024年第3期25卷 268-274页

作者： Jjijie YE Xuan XU Chuande WU department of Chemistry Zhejiang UniversityHangzhou 310058China

Three polyoxometalate-based hybrid coordination materials,[Co_(8)(H_(2)O)_(34)(pz)_(2){Co_(4)(H_(2)O)_(2)P_(4)W_(30)O_(112)}]·16H_(2)O(compound 1),[H_(3)O]_(4)[Co_(6)(H_(2)O)_(22)(pz)_(2){Co_(4)(H_(2)O)_(2)P_(4)W_(30)O_(112)}]·21H_(2)(compound 2),and[H_(3)O]_(4)[Co_(6)(H_(2)O)_(22){Co_(4)(H_(2)O)_(2)P_(4)W_(30)O_(112)}]·29H_(2)O(compound 3)(pz-pyrazine),were built from the linkage of[Co_(4)(H_(2)O)_(2)(P_(2)W_(15)O_(56)_(2)]^(16-)-(abbreviated as{Co_(4)P_(4)W_(30})polyanions and pz and/or cobalt(II)*** compounds 1 and 2 consisted of the same components,their lamellar networks were quite *** inorganic lamellar network in compound 3 was constructed by connecting{Co_(4)P_(4)W_(30)}units with cobalt(I)*** work demonstrates that the coordination modes of{Co_(4)P_(4)W_(30)}are very sensitive to synthesis conditions,while the ring-belt tetrametals are easily substituted by different transition metal cations under mild reaction conditions.

关键词： Cobalt Crystal structure Cyclic voltammetry Hybrid Polyoxometalate

The unitary subgroups of group algebras for a class of finite 2-groups with the derived subgroup of order 2

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Science China Mathematics 2024年第9期67卷 1989-2018页

作者： Yulei Wang Heguo Liu department of Mathematics Henan University of TechnologyZhengzhou 450001China department of Mathematics Hainan UniversityHaikou 570228China

Let p be a prime and F be a finite field of characteristic *** that FG is the group algebra of the finite p-group G over the field *** V(FG)denote the group of normalized units in FG and let V_(*)(FG)denote the unitary subgroup of V(FG).If p is odd,then the order of V_(*)(FG)is|F|^((|G-1)/2).However,the case p=2 still is *** this paper,the order of V*(FG)is computed when G is a nonabelian 2-group given by a central extension of the form 1→Z_(2^(n))×Z_(2^(m))→G→Z_(2)×…×Z_(2)→1 and G'≌Z_(2),n,m≥***,a conjecture is confirmed,i.e.,the order of V_(*)(FG)can be divisible by|F|^(1/2(|G|+|Ω1(G)|)-1),where Ω_(1)(G)={g∈G|g^(2)=1}.

关键词： normalized unit unitary subgroup inner abelian p-group central extension

Model Reference Adaptive Controller for Simultaneous Voltage and Frequency Restoration of Autonomous AC Microgrids

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Journal of Modern Power Systems and Clean Energy 2024年第4期12卷 1194-1202页

作者： Farahnaz Ahmadi Yazdan Batmani Hassan Bevrani department of Electrical Engineering University of KurdistanSanandajIran

In an autonomous droop-based microgrid,the sys-tem voltage and frequency(VaF)are subject to deviations as load *** the existence of various control methods aimed at correcting system frequency deviations at the second-ary control level without any communication network,the chal-lenges associated with these methods and their abilities to simul-taneously restore microgrid VaF have not been fully *** this paper,a multi-input multi-output(MIMO)model ref-erence adaptive controller(MRAC)is proposed to achieve VaF restoration while accurate power sharing among distributed generators(DGs)is *** proposed MRAC,without any communication network,is designed based on two meth-ods:droop-based and inertia-based *** the microgrid,the suggested design procedure is started by defining a model reference in which the control objectives,such as the desired settling time,the maximum tolerable overshoot,and steady-state error,are ***,a feedback-feedforward con-troller is established,of which the gains are adaptively tuned by some rules derived from the Lyapunov stability *** some simulations in MATLAB/SimPowerSystem Tool-box,the proposed MRAC demonstrates satisfactory perfor-mance.

关键词： AC microgid communication-free secondary control droop-based method inertia-based method model reference adaptive controller(MRAC) simultaneous voltage and frequency restoration

Electrochemical conversion of organic compounds and inorganic small molecules

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Science China Chemistry 2024年第10期67卷 3223-3246页

作者： Weimei Zeng Youai Qiu department of Chemistry Nankai UniversityTianjin 300071China

Electrochemical synthesis presents a facile and sustainable strategy to produce valuable *** review summarizes the most recent advances in electrosynthesizing value-added compounds with inorganic small ***“small molecules”refers to a broad spectrum of chemicals,we mainly focus on the electrochemical conversion of CO_(2),H_(2)O/D_(2)O,NH_(3)and SO_(2)until March *** review intends to compare the results and display general trends throughout the field,with an emphasis on the substrate scope and mechanical ***,we propose several techniques and protocols that can enable a more fundamental understanding of the electrochemical reaction involving inorganic small molecules and help drive this methodology toward commercialization.

关键词： electrochemical synthesis inorganic small molecule organic synthesis carbon dioxide water

Late Ordovician Mass Extinction: Earth, fire and ice

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National Science Review 2024年第1期11卷 51-65页

作者： David A.T.Harper Palaeoecosystems Group Department of Earth SciencesDurham University

The Late Ordovician Mass Extinction was the earliest of the ‘big’ five extinction events and the earliest to affect the trajectory of metazoan life. Two phases have been identified near the start of the Hirnantian period and in the middle. It was a massive taxonomic extinction, a weak phylogenetic extinction and a relatively benign ecological extinction. A rapid cooling, triggering a major ice age that reduced the temperature of surface waters, prompted a drop in sea level of some 100 m and introduced toxic bottom waters onto the shelves. These symptoms of more fundamental planetary processes have been associated with a range of factors with an underlying driver identified as volcanicity. Volcanic eruptions, and other products, may have extended back in time to at least the Sandbian and early Katian, suggesting the extinctions were more protracted and influential than hitherto documented.

关键词： Ordovician LOME paleoecology palaeobiogeography biotas

Manipulation of internal blockage in triangular triple quantum dot

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Chinese Physics B 2024年第5期33卷 588-593页

作者：齐月魏建华 department of Physics Renmin UniversityBeijing 100876China

We utilize the calculation of hierarchical equations of motion to demonstrate that the spin-dependent properties between adjacent quantum dots(QDs)can be changed by breaking the internal symmetry configuration,corresponding to the inversion of dominant chiral *** the linear triple quantum dots(LTQDs)connected to two electron reservoirs,we can observe that the blockage appears at the triangle triple quantum dots(TTQDs)by gradually increasing the coupling strength between next-nearest double *** the initial coupling between LTQDs has altered,the internal chiral circulation also undergoes the corresponding transform,thus achieving qualitative regulation and detection of the blocking *** also investigate the response of the chiral circulation to the dot–lead coupling strength,indicating the overall robust chiral circulation of the TTQDs frustration.

关键词： quantum dots chiral topology blocking

Molecular Dynamics Simulations of Displacement Cascade in Ni-Based Concentrated Solid Solution Alloys

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Acta Mechanica Solida Sinica 2024年第1期37卷 82-89页

作者： Chaoquan Zhao Rongxuan Xie Chuanlong Xu Xiaobao Tian Qingyuan Wang Wentao Jiang Haidong Fan department of Mechanics Sichuan UniversityChengdu 610065China

Single-phase concentrated solid solution alloys(SP-CSAs),including high-entropy alloys,have received extensive attention due to their excellent irradiation *** this work,displacement cascade simulations are conducted using the molecular dynamics method to study the evolution of defects in Ni-based *** with pure Ni,the NiCr,NiCo,and NiCu alloys exhibit a larger number of Frankel pairs(FPs)in the thermal peak stage,but a smaller number of surviving ***,the NiFe alloy displays the opposite *** explain these different observations for NiFe and other alloys,the formation energy and migration energy of interstitials/vacancies are *** the NiFe alloy,both the formation energy and migration energy barrier are *** the other hand,in NiCr and other alloys,the formation energy of interstitials/vacancies is lower,as is the migration energy barrier of *** energy analysis agrees well with previous *** present work provides new insights into the mechanism behind the irradiation resistance of binary Ni-based SP-CSAs.

关键词： Molecular dynamics simulation Displacement cascade Point defect Ni-based concentrated solid solution alloys

Inorganic ionic polymerization:From biomineralization to materials manufacturing

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Nano Research 2024年第2期17卷 550-569页

作者： Yanhua Sang Kexin Qin Ruikang Tang Zhaoming Liu department of Chemistry Zhejiang UniversityHangzhou 310058China

Biomineralization process regulates the growth of inorganic minerals by complex molecules,proteins,and cells,endowing bio-materials with marvels structures and excellent *** intricate structures and compositions found in biominerals have inspired scientists to design and synthesize numerous artificial biomimetic *** methodology for controlling the formation of inorganics plays a pivotal role in achieving biomimetic structures and ***,the current approach predominantly relies on the classical nucleation theory,which hinders the precise preparation of inorganic materials by replicating the biomineralization ***,the development of“inorganic ionic polymerization”strategy has enabled us to regulate the arrangement of inorganic ions from solution to solid phase,which establishes an artificial way to produce inorganic materials analogous to the biomineralization *** on inorganic ionic polymerization,a series of achievements have been realized for the biomimetic preparation,including moldable construction of inorganic materials,hard tissue regeneration,and high-performance biomimetic ***,the utilization of inorganic ionic polymerization has also facilitated the production of numerous advanced materials,including novel structures that exceed the current knowledge of materials *** inorganic ionic polymerization system provides new artificial strategies and methodologies for the controllable synthesis of inorganics,which mimics the biomineralization process,paving the way for the future development of more high-performance materials.

关键词： biomineralization inorganic ionic polymerization biomimetic materials crystal growth synthetic methodology

Structural,optical,electrical,and dielectric relaxation properties of rare earth containing sodium bismuth titanate Na_(0.5)Bi_(0.5)TiO_(3) perovskite:Effect of ionic radius

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Journal of Rare Earths 2024年第2期42卷 383-391,I0006页

作者： Rajdip Roy Abhigyan Dutta department of Physics The University of BurdwanBurdwan713104India

The main focus of this work is to study the effect of the ionic radius of different rare earth dopant cations RE^(3+)(RE=La,Sm,Dy,and Ho) on structural and various physical properties of sodium bismuth titanate(Na_(0.5)B_(0.5)TiO_(3),NBT) based perovskite *** X-ray diffraction data indicate the successful formation of the rhombohedral phase(space group R3c) of NBT nano perovskite incorporated with various rare earth ions in *** lattice parameters were found to increase linearly with the ionic radius of the dopant *** ionic radii and atomic mass of rare earth dopants appear to be essential factors in the grain growth of the prepared *** grain growth results in better crystallinity of the sample by reducing the microstrain with the increase of dopant ionic *** emission scanning electron microscopy and energy-dispersive X-ray spectra confirm the prepared compositions' phase purity and *** UV-Vis spectra reveal that La-doped NBT composition exhibits the lowest optical band gap,which unfolds the application of NBT-based perovskite as photoactive *** ac conductivity and complex impedance spectra unveil that the composition with the largest ionic radius,i.e.,La-doped NBT compound,exhibits the highest dc and bulk conductivity with the lowest activation *** frequency-dependent dielectric data follows Havriliak-Negami(HN) formalism and non-Debye type relaxation *** also indicate that La-doped NBT composition exhibits the highest dielectric strength ***,this study first elaborates that the increasing ionic radius of the rare earth dopant cation in the Bi-site of NBT perovskite improves its microstructural,optical,and electrical properties.

关键词： Rare earth doped NBT Microstructural analysis Optical band gap AC Conductivity Dielectric relaxation Rare earths

Dynamic and electrical responses of a curved sandwich beam with glass reinforced laminate layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact

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Applied Mathematics and Mechanics(English Edition) 2024年第1期45卷 155-178页

作者： N.SHAHVEISI S.FELI department of Mechanical Engineering Razi UniversityKermanshah ***Iran

The dynamic responses and generated voltage in a curved sandwich beam with glass reinforced laminate(GRL)layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact(LVI)are *** current study aims to carry out a dynamic analysis on the sandwich beam when the impactor hits the top face sheet with an initial *** the layer analysis,the high-order shear deformation theory(HSDT)and Frostig's second model for the displacement fields of the core layer are *** classical non-adhesive elastic contact theory and Hunter's principle are used to calculate the dynamic responses in terms of *** order to validate the analytical method,the outcomes of the current investigation are compared with those gained by the experimental tests carried out by other researchers for a rectangular composite plate subject to the *** element(FE)simulations are conducted by means of the ABAQUS *** effects of the parameters such as foam modulus,layer material,fiber angle,impactor mass,and its velocity on the generated voltage are reviewed.

关键词： analytical model piezoelectric layer curved sandwich beam glass reinforced laminate(GRL) pliable core low-velocity impact(LVI) classical non-adhesive elastic contact theory