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3D printing of optical materials by processes based on photopolymerization:materials,technologies,and recent advances

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Photonics Research 2022年第6期10卷 1344-1360页

作者： EMMA GEISLER MAXIME LECOMPèRE OLIVIER SOPPERA Universitéde Haute-Alsace CNRSIS2M UMR 7361F-68100 MulhouseFrance universitéde Strasbourg F-67000 StrasbourgFrance Essilor International 94000 CréteilFrance

3D printing technologies have expanded beyond the research laboratories where they were used solely for prototyping and have become widely used in several industries.The production of custom 3D objects has significant potential in optical applications.However,this necessitates extremely specific material properties,such as transparency,homogeneity,birefringence,and surface finish.Currently,the majority of optical objects are manufactured using plastics.Moreover,the 3D printing processes using polymers to produce optical objects have significant advantages,such as limited wastage,short manufacturing time,and easy customization.However,despite extensive efforts,no technology has achieved the production of objects perfectly suited for optical applications.The objective of this review is to summarize recent advances in the field of 3D printing for optics,with an emphasis on specific developments for dedicated applications,and to explore new candidate processes.

关键词： printing expanded transparency

Effects of Conjugated Systems on UV-Visible Light-sensitive D-π-A Type Sulfonium Salt Photoacid Generators

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Chinese Journal of Polymer Science 2016年第12期34卷 1456-1468页

作者： Xing-yu Wu 金明 Jian-chao Xie de-cheng Wan Jean Pierre Malval School of Materials Science and Engineering Tongji UniversityShanghai 201804China Institut de Science des Mattériaux de Mulhouse UMR CNRS 7361Universitéde Haute-Alsace15 rue Jean Starcky68057 MulhouseFrance

A series of D-π-A type sulfonium salt photoacid generators with different π-conjugated structures, such as triphenyl, phenylstilbene, styryl-biphenyl, and stilbene, were designed to determine the effect of molecular structures on the photochemical and photophysical properties. The mechanisms of photochemical generation of H＋ were studied by UV-Vis spectroscopy, theoretical calculations, and fluorescence spectroscopy. It is found that the frontier orbits determine the absorption, the molar extinction coefficients, and the quantum yields of photoacid generation. Triphenyl systems connected with sulfonium are beneficial to increase the quantum yields of acid generation. The photoreactivity of four sulfonium salts was further evaluated through the polymerizations of various epoxide monomers at different irradiation wavelengths （365- 425 nm） by using the real-time infrared spectroscopy with light-emitting diodes. The high quantum yields for acid generation （ФH＋ = -0.32 to 0.58） and the high molar extinction coefficients （ε = -23500 L.mol-1.cm-1 to 31000 L.mol-1.cm-1） of the sulfonium salts lead to high conversion rates （over 50%-80%）. Hence, these photoinitiators exhibit potential for the photocuring applications.

关键词： Sulfonium salt Photoacid generators π-conjugated structures.

Validating the CorrectWearing of Protection Mask by Taking a Selfie:design of a Mobile Application“CheckYourMask”to Limit the Spread of COVID-19

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Computer Modeling in Engineering & Sciences 2020年第9期124卷 1049-1059页

作者： Karim Hammoudi Adnane Cabani Halim Benhabiles Mahmoud Melkemi department of Computer Science Universitéde Haute-AlsaceIRIMASMulhouseF-68100France universitéde Strasbourg Strasbourg67081France Normandie Univ UNIROUENESIGELECIRSEEMRouen76000France Univ.Lille CNRSCentrale LilleUniv.Polytechnique Hauts-de-FranceYncrea Hauts-de-FranceUMR 8520-IEMNLille

In a context of a virus that is transmissive by sputtering,wearing masks appear necessary to protect the wearer and to limit the propagation of the disease.Currently,we are facing the 2019-2020 coronavirus pandemic.Coronavirus disease 2019(COVID-19)is an infectious disease with first symptoms similar to the flu.The symptom of COVID-19 was reported first in China and very quickly spreads to the rest of the world.The COVID-19 contagiousness is known to be high by comparison with the flu.In this paper,we propose a design of a mobile application for permitting everyone having a smartphone and being able to take a picture to verify that his/her protection mask is correctly positioned on his/her face.Such application can be particularly useful for people using face protection mask for the first time and notably for children and old people.The designed method exploits Haar-like feature descriptors to detect key features of the face and a decision-making algorithm is applied.Experimental results show the potential of this method in the validation of the correct mask wearing.To the best of our knowledge,our work is the only one that currently proposes a mobile application design“CheckYourMask”for validating the correct wearing of protection mask.

关键词： Face protection masks public health support health education COVID-19 coronavirus e-health m-health mobile health public health system epidemic prevention and control

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线状卡宾碳的研究进展和稳定性讨论(英文)

新型炭材料 2005年第1期20卷 83-92页

作者：传秀云王统宽 Jean Baptiste DONNET 北京大学地球与空间学院北京100871 URCOM/UFRST Ecole Nationale Supérieurede Chimiede Mulhouse/universitéde haute alsace

综合评述了所有存在的太空星际空间、地球和多种生物体中的线状卡宾碳以及在实验室合成的各种线状卡宾碳,重点评述了线状卡宾碳的稳定性和存在性。分析认为线状卡宾碳的稳定性与其类型、所处气氛、环境有关,提出可以通过插层化合物和端... 详细信息

综合评述了所有存在的太空星际空间、地球和多种生物体中的线状卡宾碳以及在实验室合成的各种线状卡宾碳,重点评述了线状卡宾碳的稳定性和存在性。分析认为线状卡宾碳的稳定性与其类型、所处气氛、环境有关,提出可以通过插层化合物和端部基团连接等方法获得稳定的线状卡宾碳。

关键词：线状卡宾碳稳定性插层化合物化学结构化学性质

Nonaqueous potassium-ion full-cells:Mapping the progress and identifying missing puzzle pieces

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Journal of Energy Chemistry 2024年第6期93卷 384-399页

作者： Badre Larhrib Louiza Larbi Léna?c Madec universite de Pau et des Pays de l'Adour E2S UPPA CNRS IPREM université de haute-alsace Institut de Science des Matériaux de Mulhouse (IS2M) université de Strasbourg Réseau sur le Stockage Electrochimique de l'Energie Institut des Matériaux Jean Rouxel (IMN) CNRS UMR 6502 Univ. Nantes

This review addresses the growing interest for potassium-ion full-cells(KIFCs) in view of the transition from potassium-ion half-cells(KIHCs) toward commercial K-ion batteries(KIBs).It focuses on the key parameters of KIFCs such as the electrode/electrolyte interfaces challenge,major barriers,and recent advancements in KIFCs.The strategies for enhancing KIFC performance,including interfaces co ntrol,electrolyte optimization,electrodes capacity ratio,electrode material screening and electrode design,are discussed.The review highlights the need to evaluate KIBs in full-cell configurations as half-cell results are strongly impacted by the K metal reactivity.It also emphasizes the importance of understanding solid electrolyte interphase(SEI) formation in KIFCs and explores promising nonaqueous as well as quasiand all-solid-state electrolytes options.This review thus paves the way for practical,cost-effective,and scalable KIBs as energy storage systems by offering insights and guidance for future research.

关键词： K-ion full-cells Potassium-ion batteries Cross-talk Solid-state batteries Potassium reactivity Electrolyte design Electrode design

Surface Modification of Barium Sulfate Particles

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Materials Sciences and Applications 2021年第1期12卷 1-14页

作者： Jérémy Longlade Christelle delaite Anne-Sophie Schuller Laboratoire de Photochimie et d’Ingénierie Macromoléculaires Université de Haute Alsace (UHA) Mulhouse Cedex France

In this study, surface modification of barium sulfate was investigated using several model molecules for chemical treatment: ethanesulfonic acid, butyric acid, trimethoxy(propyl) silane and phosphoric acid 2-hydroxyethyl methacrylate. Samples were characterized by FT-IR and TGA to check the capability of these model molecules to interact with BaSO4 surface. The results pointed out the presence of an organic layer around the surface after the chemical treatment even after several washings to remove all species in excess. Model molecules were grafted onto BaSO4 surface and grafted density was determined. It reveals that phosphoric acid and carboxylic acid are the best candidates for the modification of BaSO4 surface. Both can be used as anchoring groups to modify the hydrophilic balance of barium sulfate surface in order to avoid the formation of aggregates and to improve the compatibility of this filler within hydrophobic polymer matrix.

关键词： Barium Sulfate Surface Modification Grafted density

Sliding Mode Controller for Three-Phase Hybrid Active Power Filter with Photovoltaic Application

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Smart Grid and Renewable Energy 2012年第1期3卷 17-26页

作者： Ayman Blorfan Jean Mercklé Damien Flieller Patrice Wira Guy Sturtzer INSA de Strasbourg GREEN Laboratory Strasbourg France. université de haute alsace MIPS Laboratory Mulhouse France université de haute alsace MIPS Laboratory Mulhouse France

This paper presents a new three-phase hybrid active power filter configuration that interconnects a passive high-pass filter in parallel with an active power filter and a photovoltaic system. The proposed configuration can improves the filtering performance of the conventional active power filter, as well as simultaneously supply the power from the photovoltaic arrays to the load and utility. This paper will describe the proposed hybrid active power filter control using sliding mode with photovoltaic system. The proposed technique effectively filters harmonics under 1 kHz but also higher frequency to achieve wideband harmonics compensation. The THD of source current is reduced from 30.09% to 1.95%. The result indicates that the sliding mode controller can track the reference signals and have good dynamic characteristics.

关键词： Hybrid Active Power Filter p-q Theorem Photovoltaic Boost Converter Wideband Harmonic Compensation

depleted uranium oxide supported nickel catalyst for autothermal CO_(2)methanation in non-adiabatic reactor under induction heating

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Journal of Energy Chemistry 2023年第10期85卷 310-323,I0010页

作者： Lai Truong-Phuoc Jean-Mario Nhut Loïc Vidal Cuong Duong-Viet Sécou Sall Corinne Petit Christophe Sutter Mehdi Arab Alex Jourdan Cuong Pham-Huu Institute of Chemistry and Processes for Energy Environment and Health(ICPEES)ECPMUMR 7515 CNRS-University of Strasbourg25 rue Becquerel67087 Strasbourg Cedex 02France BlackLeaf SAS 210 rue Geiler de Kaysersberg67400 IllkirchFrance Institute of Materials Science of Mulhouse IS2MUMR 7361Universitéde Haute-AlsaceCNRS15rue Jean Starcky-BP 248868057 MulhouseFrance ORANO Tricastin Direction de La Recherche&DéveloppementSite du TRICASTIN BP 1626701 Pierrelatte CedexFrance

Undoped nickel-based catalysts supported on depleted uranium oxide allow one to carry out CO_(2)methanation process under extremely low reaction temperature under atmospheric pressure and powered by a contactless induction heating.By adjusting the reaction conditions,the catalyst is able to perform CO_(2)methanation reaction under autothermal process operated inside a non-adiabatic reactor,without any external energy supply.Such autothermal process is possible thanks to the high apparent density of the UO_x which allows one to confine the reaction heat in a small catalyst volume in order to confine the exothermicity of the reaction inside the catalyst and to operate the reaction at equilibrium heat in-heat out.Such autothermal operation mode allows one to significantly reduce the complexity of the process compared to that operated using adiabatic reactor,where complete insulation is required to prevent heat disequilibrium,in order to reduce as much as possible,the heat exchange with the external medium.The catalyst displays an extremely high stability as a function of time on stream as no apparent deactivation.It is expected that such new catalyst with unprecedented catalytic performance could open new era in the field of heterogeneous catalysis where traditional supports show their limitations to operate catalytic processes under severe reaction conditions.

关键词： CO_(2)methanation Auto-methanation Induction heating depleted uranium oxide Electrification process Operando DRIFTS

Hard carbon derived from coconut shells,walnut shells,and corn silk biomass waste exhibiting high capacity for Na-ion batteries

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Journal of Energy Chemistry 2021年第7期30卷 207-218页

作者： Cristina Nita Biao Zhang Joseph dentzer Camélia Matei Ghimbeu Universitéde Haute-Alsace Institut de Science des Matériaux de Mulhouse(IS2M)CNRS UMR 7361F-68100 MulhouseFrance universitéde Strasbourg F-67081 StrasbourgFrance Center for Advanced Laser Technologies(CETAL) National Institute for LasersPlasma and Radiation PhysicsAtomistilor 409 bisRO-77125 MagureleRomania department of Applied Physics The Hong Kong Polytechnic UniversityKowloonHong KongChina Réseau sur le Stockage Electrochimique de l’Energie(RS2E) CNRS FR345933 Rue Saint Leu80039 Amiens CedexFrance

In recent years,hard carbon materials have gained significant interest as anode materials for Na-ion batteries.Biomass waste is considered one of the most interesting,renewable,available,and cost-effective precursor to obtain hard carbon(HC);however,HC properties must be finely tuned to achieve performance comparable to those provided by Li-ion batteries.In this work,three biomass wastes(coconut shells,walnut shells,and corn silk) were evaluated as potential precursors for HC preparation involving a pyrolysis process and subsequent acid washing to remove the inorganic impurities.All obtained materials exhibited low and similar specific surface areas(dered carbon and localized graphitized domains.All HCs delivered high initial reversible capacities between 293 and 315 mAh g^(-1) at 50 mA g^(-1) current rate,which remained rather stable during long-term cycling.The best capacity(293 mAh g^(-1) after 100 charge/discharge cycles) and highest capacity retention(93%) was achieved in walnut HCs in half-cells,which could be associated with its higher sp2 C content,better organized structure,and fewer impurities.An "adsorption-insertion" Na storage mechanism is suggested based on several techniques.The walnut HCs exhibited an attractive energy density of 279 Wh/kg when tested in full cells.

关键词： Biomass Pyrolysis Hard carbon Anode Na-ion batteries Energy storage