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Evaluation of the Hydroxynitrile Lyase Activity in Cell Cultures of Capulin (Prunus serotina)

生物工程学报 2008年第7期24卷 1199-1201页

作者： Liliana Hemandez Hector Luna Arturo Navarro-Ocafia Ma Teresa de Jesus Olivera-Flores Ivon Ayala universidadautdnoma metropolitana UnidadXochimilco Depto. Sistemas Biologicos A. P. 23/181 Mgxico D. F. Mexico Facultad de Qufmica Universidad Nacional Autdnoma de Mexico Ciudad Universitaria Mgxico D. F. 04510 Mexico

Enzymatic preparations obtained from young plants and cell cultures of capulin were screened for hydroxynitrile lyase activity. The threeweek old plants, grown under sterile conditions, were used to establish a solid cell culture. Crude preparations obtained from this plant material were evaluated for the transformation of benzaldehyde to the corresponding cyanohydrin (mandelonitrile). The results show that the crude material from roots, stalks, and leaves of young plants and calli of roots, stalks, internodes and petioles biocatalyzed the addition of hydrogen cyanide (HCN) to benzaldehyde with a modest to excellent enantioselectivity.

关键词：细胞裂解酶活性柳叶野黑桃

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Influence of metal support in-plane symmetry on the corrugation of hexagonal boron nitride and graphene monolayers

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Nano Research 2018年第9期11卷 4643-4653页

作者： Antonio d. Martinez-Galera Jose M. Gomez-Rodriguez Departamento de Fisica de la Matefia Condensada Universidad Autonoma de Madrid Madrid E-28049 Spain Condensed Matter Physics Center (IFIMAC) UniversidadAutdnoma de Madrid Madrid E-28049 Spain Instituto Nicolds Cabrera Universidad Autonoma de Madrid Madrid E-28049 Spain

Predicting the properties of two-dimensional （2D） materials as graphene and hexagonal boron nitride （h-BN） monolayers after their growth on any given substrate is a major challenge. While the influence of the electron configuration of the atoms of the underlying surface is well-understood, the effect of substrate geometry still remains unclear. The structural properties of h-BN monolayers grown on a rectangularly packed Rh（110） surface were characterized in situ by ultrahigh vacuum scanning tunneling microscopy and were compared to those that this material exhibits when grown on substrates showing different crystallographic orientations. Although the h-BN monolayer grown on Rh（110） was dominated by a unique quasiunidimensional moir6 pattern, suggesting considerable interface interaction, the moir6 corrugation was unexpectedly smaller than those reported for strongly interacting interfaces with hexagonal-terminated substrates, owing to differences in the possible binding landscapes at interfaces with differently oriented substrates. Moreover, a rule was derived for predicting how interface corrugation and the existence and extent of subregions within moir6 supercells containing favorable sites for orbital mixing between h-BN monolayers and their supports depend on substrate symmetry. These general symmetry considerations can be applied to numerous 2D materials, including graphene, thereby enabling the prediction of how substrate choice determines the properties of these materials. Furthermore, they could also provide new routes for tuning 2D material properties and for developing nanotemplates showing different geometries for Krowing adsorbate superlattices.

关键词： hexagonal boron nitride graphene two-dimensional materials scanning tunneling microscopy moire superstructures nanotemplates

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