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The dynamic evolution of aggregated lithium dendrites in lithium metal batteries

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Chinese Journal of Chemical Engineering 2021年第9期34卷 137-143页

作者： Xin Shen Rui Zhang Shuhao Wang Xiang Chen Chuan Zhao Elena Kuzmina Elena Karaseva Vladimir Kolosnitsyn Qiang Zhang Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Advanced Research institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China School of chemistry The University of New South WalesSydneyNSW 2052Australia ufa institute of chemistry ufrc ras Ufa450054Russia

Lithium(Li)metal anodes promise an ultrahigh theoretical energy density and low redox potential,thus being the critical energy material for next-generation ***,the formation of Li dendrites in Li metal anodes remarkably hinders the practical applications of Li metal ***,the dynamic evolution of discrete Li dendrites and aggregated Li dendrites with increasing current densities is visualized by in-situ optical microscopy in conjunction with ex-situ scanning electron *** revealed by the phase field simulations,the formation of aggregated Li dendrites under high current density is attributed to the locally concentrated electric field rather than the depletion of Li *** specifically,the locally concentrated electric field stems from the spatial inhomogeneity on the Li metal surface and will be further enhanced with increasing current *** the above two factors with the help of the constructed phase field model is able to regulate the electrodeposited morphology from aggregated Li dendrites to discrete Li dendrites,and ultimately columnar Li *** methodology and mechanistic understanding established herein give a significant step toward the practical applications of Li metal anodes.

关键词： Electrochemistry Li dendrites Rechargeable Li batteries In-situ optical microscopy Phase field model Electrochemical engineering

Interaction of edge dislocations with voids in tungsten

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Tungsten 2024年第3期6卷 633-646页

作者： Arseny Kazakov Rita I.Babicheva Aleksandr Zinovev Dmitry Terentyev Kun Zhou Elena A.Korznikova Sergey V.Dmitriev Research Laboratory for Metals and Alloys under Extreme Impacts Ufa University of Science and TechnologyUfa 450008Russia institute for Metals Superplasticity Problems of ras Ufa 450001Russia School of Mechanical and Aerospace Engineering Nanyang Technological UniversitySingapore 639798Singapore institute for Nuclear Energy Technology Belgian Nuclear Research Center2400 MolBelgium Technological Machines and Equipment Department Ufa State Petroleum Technological UniversityUfa 450064Russia institute of Mechanical Science Problems of ras Saint Petersburg 199178Russia institute of Molecule and Crystal Physics UFRC of Russian Academy of SciencesUfa 450075Russia

Tungsten is widely used as a material capable of withstanding extreme operating conditions and is one of the candidates for use in fusion and GenerationⅣfission *** modelling implemented to solve various material science problems is an indispensable approach for improving material *** work analyzes the interaction of an edge dislocation with a void in single-crystal tungsten with the help of molecular dynamics *** different approaches for studying the dynamics of dislocations in tungsten that differ in boundary conditions are *** interactions of the dislocation and void at different temperatures are investigated,and based on the obtained stress-strain curves,the dislocation obstacle strength for voids having various diameters is *** is shown that when applied to a crystal with small voids,the model with the fixed boundary conditions returns incorrect ***,the influence of the cell size for the model with periodic boundary conditions is analyzed,and the case of a non-central interaction of a dislocation with a void is *** obtained results improve our understanding of the mechanical response of irradiated materials.

关键词： Tungsten Molecular dynamics method Dislocations Voids Boundary conditions

Impact of lanthanum on the modification of HfO_2 films structure

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Journal of Rare Earths 2015年第8期33卷 857-862页

作者： T.P.Smirnova L.V.Yakovkina V.O.Borisov Nikolaev institute of Inorganic chemistry SB ras

LaxHf1-xOy thin films with various concentrations of La, homogeneous and nonhomogeneous distributions of elements throughout the films thickness was purposefully grown by CVD. The composition of the films and their chemical structures were characterized throughout the films thickness by X-ray photoelectron spectroscopy （XPS） and energy-dispersive X-ray spectrometry （EDXA）. A full picture of the film crystallinity was provided by the combination of grazing incidence X-ray diffraction （GIXRD） synchrotron radiation （SR） and high resolution transmission electron microscopy （HR TEM）. It was shown that La acted as ＂molar volume modulator＂ and stabilized the nonequilibrium at T≤1300 ℃ cubic phases. The samples with La content in range of 7 at.%〈CLa〈22 at.% were materials with fluorite-type （Fm-3m） structure. The pyroehlore phase formation was observed at -18 at.% La content. The correlation between the La-doped content and the films microstructure was revealed.

关键词： Hf1-xLaxOy films solid solutions X-ray diffraction microstructure rare earths

Nucleation of methane hydrate and ice in emulsions of water in crude oils and decane under non-isothermal conditions

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Chinese Journal of Chemical Engineering 2019年第3期27卷 668-676页

作者： Andrey S. Stoporev Lidiya I. Svarovskaya Larisa A. Strelets Lubov’ K. Altunina Galina V. Villevald Tamara D. Karpova Tatyana V. Rodionova Andrey Yu. Manakov Nikolaev institute of Inorganic chemistry SB ras Novosibirsk State University institute of Petroleum chemistry

Achievable supercooling for the formation of methane hydrate from water emulsions was studied in seven different crude oils and in decane. The experiments were performed under constant rate cooling from + 20 to-15 °C and a pressure of methane of 12 MPa. It was demonstrated that the shapes and positions of the resulting survival curves depend on the density, viscosity and dispersive power of oil samples used in the experiments, as well as on the degree of oil oxidation. In addition, results of the experiments on ice freezing under the same emulsions are presented. The results obtained in the work allowed us to discuss the possibility and features of primary and secondary nucleation of the hydrate and ice in the systems under consideration.

关键词： Methane hydrate Crude oil Oil dispersive system Nucleation

Transformation of the TiNi Alloy Microstructure and the Mechanical Properties Caused by Repeated B2-B190' Martensitic Transformations

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Acta Metallurgica Sinica(English Letters) 2015年第10期28卷 1230-1237页

作者： Anna Churakova Dmitry Gunderov Alexander Lukyanov Niklas Nollmann institute of Molecule and Crystal Physics ras ufa State Aviation Technical University institute of Materials Physics University of Münster

The influences of thermal cycling treatment in the temperature range of B2-B19 martensitic transformations（-150 to 150 °C） on the Ti Ni alloy structure and properties were studied. Different states named the initial coarse-grained（CG） state, the ultrafine-grained（UFG） state after ECAP（with a grain size of 200 nm）, the state after ECAP and cold upsetting by 30% were considered. The results show that the microhardness and the strength increase in all the three *** to the XRD analysis, a more significant increment in the dislocation density, resulting from thermal cycling, is observed in the UFG alloy than in the CG alloy.

关键词： Thermal cycling TiNi alloy Equal-channel angular pressing Martensitic transformation

Magnetic field hyperactivity during the early Neoproterozoic: A paleomagnetic and cyclostratigraphic study of the Katav Formation, southern Urals, Russia

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Geoscience Frontiers 2023年第4期14卷 42-56页

作者： Inessa V.Golovanova Konstantin N.Danukalov Raushaniia Yu.Salmanova Natalia M.Levashova Nikita P.Parfiriev Nina D.Sergeeva Joseph G.Meert institute of Geology-Subdivision of the ufa Federal Research Centre of the Russian Academy of Sciences(IG ufrc ras) Russia Geological institute Russian Academy of SciencesMoscowRussia Department of Earth and Planetary Sciences Neil Opdyke Paleomagnetic LaboratoryUniversity of FloridaGainesvilleFL 32611United States

We present a detailed magnetostratigraphic and cyclostratigraphic profile through the Riphean(Tonian)Katav Formation in the southern *** study confirms the primary nature of the magnetization in these *** cyclostratigraphic study identified several orbital periods including the 405 ka long *** allows us to quantify the reversal frequency in the Katav and our estimates range of 7–12 reversals per million *** on our study,we identify an interval of magnetic field reversal hyperactivity in the Neoproterozoic *** estimates for the Katav are contentious and range somewhere between 800 Ma and 900 Ma based on carbonate Pb-Pb ages and stable isotope *** paleomagnetic poles obtained in this study of the Katav(and overlying Inzer)Formation do not fit anywhere on the Baltica apparent polar wander path between 1100 Ma and 900 ***,they lie 90away from the 900 Ma segment of the *** tentatively estimate their age to be closer to 800 Ma and perhaps confirm a previously hypothesized pulse of rapid true polar wander between 825 Ma and 790 Ma.

关键词： Magnetostratigraphy Cyclostratigraphy Hyperactive reversal True polar wander Tonian

On the liquid-phase technology of carbon fiber/aluminum matrix composites

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International Journal of Minerals,Metallurgy and Materials 2019年第12期26卷 1578-1584页

作者： Sergei Galyshev Andrew Gomzin Rida Gallyamova Igor Khodos Fanil Musin institute of Solid State Physics of Russian Academy of Sciences Chernogolovka 142432Russia ufa State Aviation Technical University Ufa 450000Russia ufa chemistry institute of Russian Academy of Sciences Ufa 450000Russia institute of Microelectronics Technology and High Purity Materials Russian Academy of Sciences Chernogolovka 142432Russia

The main problems with the liquid-phase technology of carbon fiber/aluminum matrix composites include poor wetting of the fiber with liquid aluminum and formation of aluminum carbide on the fibers’*** paper aims to solve these *** theoretical and experimental dependence of porosity on the applied pressure were *** possibility of obtaining a carbon fiber/aluminum matrix composite wire with a strength value of about 1500 MPa was *** correlation among the strength of the carbon fiber reinforced aluminum matrix composite,the fracture surface,and the degradation of the carbon fiber surface was discussed.

关键词： carbon fiber/aluminum matrix composite liquid-phase fabrication infiltration pressure composite porosity composite wire ultrasonic

Synthesis of MoO_3 by glow discharge in contact with water

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Plasma Science and Technology 2019年第2期21卷 97-104页

作者： A V KHLYUSTOVA N A SIROTKIN A S KRAYEV V A TITOV A V AGAFONOV Laboratory of chemistry of Carbohydrate Coordination Compounds and Supermolecular System G.A.Krestov Institute of Solution Chemistry of RAS

An atmospheric pressure glow discharge was ignited between a molybdenum anode and the water surface of a cathode for the synthesis of MoO_3 powders. The action of glow discharge leads to the non-equilibrium evaporation of water, sputtering of the metal anode and formation of molybdenum(VI) oxide, which deposited on the anode. The chemical composition and morphology of the obtained powder were performed by using x-ray diffraction spectroscopy,scanning electron microscopy and Fourier transform infrared spectroscopy. It was found that the synthesized powders are pure α-MoO_3. The possible mechanism of the formation of molybdenum trioxide during glow discharge treatment was described. The photocatalytic performance of MoO_3 was estimated through the degradation of Rhodamine B under dark and UV irradiation conditions. Orthorhombic MoO_3 exhibited the best photocatalytic activity for the photodegradation of Rhodamine B of 100% under UV irradiation for 15 min.

关键词： molybdenum oxide glow discharge photocatalytic activity

Sinterability of nanopowders of terbia solid solutions with scandia,yttria,and lutetia

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Journal of Advanced Ceramics 2018年第4期7卷 362-369页

作者： Stanislav S.BALABANOV Dmitry А.PERMIN Elena Ye.ROSTOKINA Sergey V.EGOROV ANDrey A.SOROKIN G.G.Devyatykh institute of chemistry of High-Purity Substances ras Federal Research Center the Institute of Applied Physics RAS

The synthesis of nanopowders of terbia compounds with scandia, yttria, and lutetia was carried out using a self-propagating high-temperature synthesis method involving a mixture of nitrates of metals and glycine as a precursor. The nanopowder phase transformations were investigated using X-ray diffraction analysis. It was found that lutetia has a negligible effect on the phase formation in terbia. On the other hand, yttrium and scandium ions significantly suppressed crystallization. The densification kinetics of nanopowders of the Tb_2O_3 compounds and the microstructure of ceramics after microwave sintering were studied using dilatometry and scanning electron microscopy. The introduction of scandia, yttria, or lutetia contributed to the intensification of the densification of the terbia ceramics when heated in a microwave field. Near full-density materials of terbia solid solutions with lutetia and yttria were obtained at about 1600–1640 ℃. The ceramics of scandia–terbia compounds contained the second phase, which causes light scattering.

关键词： terbia microwave sintering X-ray analysis ceramics