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Locally Enhanced Flow and Electric Fields Through a Tip Effect for Efficient Flow‑Electrode Capacitive Deionization

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Nano-Micro Letters 2025年第2期17卷 1-17页

作者： Ziquan Wang Xiangfeng Chen Yuan Zhang Jie Ma Zhiqun Lin Amor Abdelkader Maria‑Magdalena Titirici Libo Deng College of Chemistry and environmental Engineering Shenzhen UniversityShenzhen 518060People’s Republic of China Research Center for environmental Functional Materials College of Environmental Science and EngineeringTongji University1239 Siping RoadShanghai 200092People’s Republic of China Department of Chemical and Biomolecular Engineering National University of SingaporeSingapore 117585Singapore Department of Engineering Faculty of Science and TechnologyBournemouth UniversityTalbot CampusFern BarrowPooleEngland BH125BBUK Institut de Chimie de Nice UniversitéCôte d’AzurUMR CNRS 727228 Av.Valrose06108 NiceFrance Department of Chemical Engineering Imperial College LondonSouth Kensington CampusExhibition RdLondon SW72AZUK

Low-electrode capacitive deionization(FCDI)is an emerging desalination technology with great potential for removal and/or recycling ions from a range of ***,it still suffers from inefficient charge transfer and ion transport kinetics due to weak turbulence and low electric intensity in flow electrodes,both restricted by the current ***,a new tip-array current collector(designated as T-CC)was developed to replace the conventional planar current collectors,which intensifies both the charge transfer and ion transport *** effects of tip arrays on flow and electric fields were studied by both computational simulations and electrochemical impedance spectroscopy,which revealed the reduction of ion transport barrier,charge transport barrier and internal *** the voltage increased from 1.0 to 1.5 and 2.0 V,the T-CC-based FCDI system(T-FCDI)exhibited average salt removal rates(ASRR)of 0.18,0.50,and 0.89μmol cm^(-2) min^(-1),respectively,which are 1.82,2.65,and 2.48 folds higher than that of the conventional serpentine current collectors,and 1.48,1.67,and 1.49 folds higher than that of the planar current ***,with the solid content in flow electrodes increased from 1 to 5 wt%,the ASRR for T-FCDI increased from 0.29 to 0.50μmol cm^(-2) min^(-1),which are 1.70 and 1.67 folds higher than that of the planar current ***,a salt removal efficiency of 99.89%was achieved with T-FCDI and the charge efficiency remained above 95%after 24 h of operation,thus showing its superior long-term stability.

关键词： Flow-electrode Capacitive deionization Current collector Tip effect Desalination

Modeling the effect of wetting on the mechanical behavior of crushable granular materials

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Geoscience Frontiers 2020年第2期11卷 487-494页

作者： Carlos Ovalle Pierre-Yves Hicher Research Institute of Mining and environment(RIME UQAT-Polytechnique) Department of CivilGeological and Mining EngineeringPolytechnique MontrealQuebecCanada GeM umr cnrs 6183 Ecole Centrale de NantesFrance

It is well known that the compressibility of crushable granular materials increases with the moisture content,due to the decrease of particle strength in a humid *** existing approach to take into account the effect of grain breakage in constitutive modeling consists in linking the evolution of the grain size distribution to the plastic *** how the material humidity can affect this relationship is not clear,and experimental evidence is quite *** on compression tests on dry and saturated crushable sand recently reported by the present authors,a new non-linear relationship is proposed between the amount of particle breakage and the plastic *** expression contains two parameters:(1)a material constant dependent on the grain characteristics and(2)a constant depending on the wetting condition(in this study,dry or saturated).A key finding is that the relationship does not depend on the stress path and,for a given wetting condition,only one set of parameters is necessary to reproduce the results of isotropic,oedometric,and triaxial compression *** relationship has been introduced into an elastoplastic constitutive model based on the critical state concept with a double yield surface for plastic sliding and *** breakage ratio is introduced into the expression of the elastic stiffness,the critical state line and the hardening compression *** stress-strain computations with the model allow the plastic work to be calculated and,therefore,the evolution of particle crushing can be predicted through the proposed non-linear relationship and reintroduced into the constitutive *** predictions of the experimental results in terms of both stress-strain relationships and breakage ratio were obtained.

关键词： Grain crushing Wetting Constitutive modeling

Validation of a conductometric bienzyme biosensor for the detection of proteins as marker of organic matter in river samples

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Journal of environmental Sciences 2009年第4期21卷 545-551页

作者： KHADRO Basma NAMOUR Philippe BESSUEILLE Franois LEONARD Didier JAFFREZIC-RENAULT Nicole University of Lyon Laboratory of AnalyticalCNRS UMR 5180 69622 Villeurbanne France Cemagref of Lyon

This article describes a conductometric bi-layer based bienzyme biosensor for the detection of proteins as a marker of organic matter in rivers. Proteins were chosen to be used as indicators of urban pollution. The working mechanism of the bienzyme biosensor is based on the enzymatic hydrolysis of proteins into several fractions （peptides and amino acids）, which results in a local conductivity change depending of the concentration of proteins. In this work, we began with the optimization of biosensor response using bovine serum albumin （BSA） as standard protein. For this objective seven enzymatic biosensors were prepared： four enzymatic sensors with only one layer of enzyme （proteinase K, trypsin, pronase or protease X） and three other enzymatic sensors with two layers （first layer： membrane containing proteinase K; second layer： one of the three other enzymes： trypsin, pronase or protease X）. The biosensors were obtained through the deposition of enzymatic layers and the cross-linking process between enzymes and BSA in saturated glutaraldehyde vapour. The response of the various biosensors, described previously, were compared with the values of total organic carbon （TOC）, and those of organic nitrogen （No~）, as determined by the laboratory accredits （CEMAGREF of Lyon） using the traditional method of analysis （NF EN 1484, infrared spectroscopy） and （NF EN 25663, mineralization/colorimetry assay） respectively for each water sample obtained from different sites in Lyon （France）. The linear correlations obtained with the response of the seven biosensors showed the most important indices of correlations for the biosensor with two enzymatic layers： proteinase K ＋ pronase （pkp）. The optimum conditions for the preparation of the pkp biosensor increased the sensitivity and gave a limit of quantification of 0.583 μg/L for TOC and 0.218 μg/L for Norg in water samples. This sensor shows good reproducibility （2.28%）, a capacity to be used at temperatures range 10-- 30℃ （dependi

关键词： conductometric biosensor proteins enzyme natural water analyses total organic carbon organic nitrogen

Thermoelectric properties of high-entropy rare-earth cobaltates

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Journal of Materiomics 2023年第1期9卷 191-196页

作者： Ashutosh Kumar Diana Dragoe David Berardan Nita Dragoe ICMMO(umr cnrs 8182) University of Paris-SaclayOrsay91405France

High-entropy concept introduced with a promising paradigm to obtain exotic physical properties has motivated us to explore the thermoelectric properties of Sr-substituted high-entropy rare-earth cobaltates i.e.,(LaNdPrSmEu)_(1-x)Sr_(x)CoO_(3)(0≤x≤0.10).The structural analysis of the samples,synthesized using the standard solid-state route,confirms the orthorhombic structure with the Pbnm space *** Seebeck coefficient and electrical resistivity decrease with rising Sr concentration as well as with an increase in *** multiple A-site ions in high-entropy rare-earth cobaltates result in an improved Seebeck coefficient(α)compared to La_(0.95)Sr_(0.05)CoO_(3),associated with a decrease in the Cosingle bondOsingle bondCo bond angle,which further enhances the power *** random distribution of cations at the rare-earth site results in a significant lowering of phonon thermal *** a result,a maximum figure of merit(zT)of 0.23 is obtained at 350K for(LaNdPrSmEu)_(0.95)Sr_(0.05)CoO_(3),which is one of the highest values of zT reported at this temperature for oxide *** study shows promise to decouple thermoelectric parameters using the high-entropy concept in several materials.

关键词： materials. temperature. entropy

Increase in the variability of terrestrial carbon uptake in response to enhanced future ENSO modulation

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Atmospheric and Oceanic Science Letters 2025年第1期18卷 32-38页

作者： Younong Li Li Dan Jing Peng Qidong Yang Fuqiang Yang Key Laboratory of Regional Climate-environment for Temperate East Asia Institute of Atmospheric PhysicsChinese Academy of SciencesBeijingChina Key Laboratory of Atmospheric environment and Processes in the Boundary Layer over the Low-Latitude Plateau Region Department of Atmospheric ScienceYunnan UniversityKunmingChina

El Niño-Southern Oscillation(ENSO)is a major driver of climate change in middle and low latitudes and thus strongly influences the terrestrial carbon cycle through land-air *** the ENSO modulation and carbon flux variability are projected to increase in the future,but their connection still needs further *** investigate the impact of future ENSO modulation on carbon flux variability,this study used 10 CMIP6 earth system models to analyze ENSO modulation and carbon flux variability in middle and low latitudes,and their relationship,under different scenarios simulated by CMIP6 *** results show a high consistency in the simulations,with both ENSO modulation and carbon flux variability showing an increasing trend in the *** higher the emissions scenario,especially SSP5-8.5 compared to SSP2-4.5,the greater the increase in *** flux variability in the middle and low latitudes under SSP2-4.5 increases by 30.9%compared to historical levels during 1951-2000,while under SSP5-8.5 it increases by 58.2%.Further analysis suggests that ENSO influences mid-and low-latitude carbon flux variability primarily through *** occurrence may potentially be attributed to the increased responsiveness of gross primary productivity towards regional temperature fluctuations,combined with the intensified influence of ENSO on land surface temperatures.

关键词： Carbon variability ENSO modulation CMIP6 models

Nanostructured gold films exhibiting almost complete absorption of light at visible wavelengths

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Frontiers of Chemical Science and Engineering 2018年第2期12卷 247-251页

作者： Hanbin Zheng Christine Picard Serge Ravaine cnrs CRPP UMR 5031 Universite de Bordeaux F-33600 Pessac France

Nanostructured known to exhibit properties metal surfaces have been that deviate from that of the bulk material. By simply modifying the texture of a metal surface, various unique optical properties can be observed. In this paper, we present a simple two step electrochemical process combining electrodeposition and anodization to generate black gold surfaces. This process is simple, versatile and up-scalable for the production of large surfaces. The black gold films have remarkable optical behavior as they absorb more than 93% of incident light over the entire visible spectrum and also exhibit no specular reflectance. A careful analysis by scanning electron microscopy reveals that these unique optical properties are due to their randomly rough surface, as they consist in a forest of dendritic microstructures with a nanoscale roughness. This new type of black films can be fabricated to a large variety of substrates, turning them to super absorbers with potential applications in photovoltaic solar cells or highly sensitive detectors and so on.

关键词： nanostructuration light absorption coating gold electrodeposifion anodization

Solving the Dyson-Schwinger equation around its first singularities in the Borel plane

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Frontiers of physics 2016年第6期11卷 25-30页

作者： Clavier, Pierre J. Bellon, Marc P. Sorbonne Universites UPMC Univ Paris 06 UMR 7589 LPTHE Paris France cnrs UMR 7589 LPTHE Paris France

The Dyson-Schwinger equation of the massless Wess-Zumino model is written as an equation over the anomalous dimension of the theory. Its asymptotic behavior is derived and the procedure to compute the perturbations of this asymptotic behavior is detailed. This procedure uses ill-defined objects. To solve this, the Dyson-Schwinger equation is rewritten for the Borel plane. It is shown that the ill- defined procedure in the physical plane can be applied in the Borel plane. Other results obtained in the Borel plane are stated and the proof for one result is described.

关键词： Dyson-Schwinger equation Wess-Zumino model Borel transform

Chemical substances present in discharge water generated by laundry industry:Analytical monitoring

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Water Science and Engineering 2023年第4期16卷 324-332页

作者： Dario Lacalamita Chiara Mongioví Grégorio Crini chrono-environnement Laboratory University of Franche-Comté16 Route de GrayBesançon 25000France

To our knowledge,precise data concerning the pollution in terms of qualitative and quantitative fluctuations in discharge water from the laundry sector have seldom been *** study investigated the chemical composition of the discharge water from a laundry *** 160 chemical substances and 15 standard water parameters were *** results showed that the discharge water presented both inorganic and organic polycontamination with a high degree of qualitative and quantitative ***,of all monitored substances,only five metals(Al,Cu,Fe,Sr,and Zn),five minerals(P,Ca,K,Na,and S),and alkylphenols were systematically present and *** a daily average water flow of 129 m^(3),the released metal flux was 356 g/***,such as trichloromethane,brominated diphenyl ether(BDE)47,and fluorides,were occasionally found and *** substances,such as chlorophenols,organo-tins,and pesticides were never *** the samples had quantifiable levels in the chemical oxygen demand(COD),biological oxygen demand(BOD),and *** the concentrations of Zn(8.3 g/d),Cu(21.4 g/d),and BOD(57.4 g/d)were close to or above the regulatory values:74.0 g/d for Zn,9.0 g/d for Cu,and 57.0 kg/d for *** data obtained from this study are useful to the choice of additional treatments for the reduction of pollutant fluxes.

关键词： Laundry Discharge water Chemical analysis Water parameter Chemical substance

Effect of Scanning Beam Profile to Fabricate Fused Fiber Tapers by CO_2 Laser Irradiation Method

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光学学报 2003年第S1期23卷 121-122页

作者： Bayle Fabien Luo Aiping Marin Emmanuel Meunier Jean-Pierre Laboratoire TSI UMR CNRS 5516 Saint Etienne FranceLaboratoire TSI UMR CNRS 5516 Saint Etienne FranceLaboratoire TSI UMR CNRS 5516 Saint Etienne FranceLaboratoire TSI UMR CNRS 5516 Saint Etienne France

Beam uniformity is a crucial building block of CO2 experiments aimed at fusing and stretching optical fibers in a lossless manner. When the irradiation beam is expanded through a galvanometer mirror, ways to achieve b... 详细信息

关键词： of in on as it by Effect of Scanning Beam Profile to Fabricate Fused Fiber Tapers by CO2 Laser Irradiation Method