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Manipulation of magnetocaloric and elastocaloric effects in Ni-Mn-In alloys by lattice volume and magnetic variation:Effect of Co and Fe co-doping

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Journal of Materials Science & Technology 2024年第5期172卷 156-165页

作者： Xinzeng Liang Chi Zhang Jing Bai Jianglong Gu Yudong Zhang Claude Esling Xiang Zhao Liang Zuo School of Materials Science and Engineering Shenyang University of TechnologyShenyang 110870China Key Laboratory for Anisotropy and Texture of Materials Northeastern UniversityShenyang 110819China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004China State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao 066004China Laboratoire d’Étude des Microstructures et de Mécanique des Matériaux LEM3 CNRSUMR 7239University of Lorraine57045 MetzFrance

The effects of Co and Fe co-doping Ni-Mn-In alloy on the phase stability,lattice parameters,mag-netic properties,and electronic structures are systematically investigated by using the first-principles *** indicate that Fe atoms replace the excess Mn2 atoms by direct and indirect coex-istence(Fe→Mn 2 and Fe→In→Mn2);Co substitutes the Ni atoms by direct substitution(Co→Ni)for the Ni-Mn-In *** austenites all exhibit the ferromagnetic(FM)state for the studied *** NM martensites are in the ferrimagnetic(FIM-1)state for the Ni_(2)Mn_(1.5)In_(0.5),Ni_(2)Mn_(1.25)In_(0.5)Fe 0.25,Ni_(1.75)Mn_(1.5)In_(0.5)Co_(0.25),and Ni_(1.75)Mn_(1.25)In_(0.5)Co_(0.25)Fe 0.25 alloys,while the other compositions are in the FM *** phase stability of austenite and martensite decreases with increasing Co and Fe co-doping.A magnetic-structural coupling transition occurs at x<0.25 and y<*** Ni_(1.91)Mn_(1.5)In_(0.5)Co_(0.08)and Ni_(1.91)Mn_(1.42)In_(0.5)Co_(0.08)Fe_(0.08)alloys exhibit an A→6M→NM transformation,accompanied by a magnetic *** Co and Fe are co-doped,the hybridization strength between Co and Fe is greater than that between Co/Fe and *** enhancement of magnetocaloric and elastocaloric effects is favored by larger magnetization difference(△M)and lattice volume change(△V/V_(0)).Based on the calculated phase stability,magneto-structure coupling,△V/V 0 and c/a ratio,one can predict that the Ni_(2)-x Mn_(1.5)-y In_(0.5)Co x Fe y alloy with Co content 0≤x≤0.25 and Fe content 0≤y≤0.05 is predicted to have good magneto-controlled functional behavior.

关键词： Ni-Mn-In-Co-Fe Phase stability Magnetocaloric effect Elastocaloric effect

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A Comprehensive Analysis of the Thermo-Chemical Properties of Sudanese Biomass for Sustainable Applications

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Journal of Renewable Materials 2024年第4期12卷 721-736页

作者： Wadah Mohammed Zeinab Osman Salah Elarabi Bertrand Charrier Institute of Analytical Sciences and Physical-Chemistry for the Environment and Materials-Xylomat University of Pau and the Adour RegionE2S UPPACNRSIPREM-UMR 5254Mont de Marsan40004France Institute of Engineering Research and Materials Technology(IERMT) National Center for Research(NCR)Ministry of Higher Education and Scientific ResearchKhartoum11111Sudan Faculty of Industries Engineering and Technology University of GeziraGezira State21111Sudan

The chemical composition and thermal properties of natural fibers are the most critical variables that determine the overall properties of the fibers and influence their processing and use in different sustainable applications,such as their conversion into bioenergy and *** thermal and mechanical properties can be estimated by evaluating the content of cellulose,lignin,and other extractives in the *** this research work,the chemical composition and thermal properties of three fibers,namely bagasse,kenaf bast fibers,and cotton stalks,were evaluated to assess their potential utilization in producing biocomposites and bioenergy *** chemical composition analysis followed the Technical Association of the Pulp and Paper Industry Standards(TAPPI)*** total phenol content was quantified using the Folin-Ciocalteu method,while Fourier Transform Infrared Spectroscopy(FTIR)was employed to assess the light absorption by the *** evaluate thermal stability and higher heating values,Thermogravimetric Analysis(TGA),Differential Scanning Calorimetry(DSC),and bomb calorimetry were *** chemical analysis revealed that bagasse contained 50.6%cellulose and 21.6%lignin,kenaf bast fibers had 58.5%cellulose and 10%lignin,and cotton stalks exhibited 40.3%cellulose and 21.3%*** FTIR curves demonstrated a notable similarity among the *** TGA analysis showed degradation temperatures of 321°C for bagasse,354°C for kenaf bast fibers,and 289°C for cotton *** DSC analysis revealed glass transition temperatures of 81°C for bagasse,66.3°C for cotton stalks,and 64.5°C for kenaf bast *** higher heating values were measured as 17.3,16.6 and 17.1 MJ/kg for bagasse,kenaf bast fibers,and cotton stalks,*** three fibers have a high potential for biocomposites and bioenergy material manufacturing.

关键词： Bagasse kenaf bast fibers cotton stalks TGA DSC FTIR

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Structural effects of reedbed grazing and its cessation on reed-nesting songbird densities

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Avian Research 2024年第2期15卷 238-248页

作者： Thomas Pagnon Clemence Pechinot Lea Sgro Jeremie Demay Remi Jullian Regis Gallais Brigitte Poulin Cyril Marmoex Theria Ecologie 6 avenue des martyrs05400VeynesFrance umr 6249 Chrono-Environnement CNRSUniversite de Franche-Comte16 route de Gray25000BesanconFrance Conservatoire d’Espaces Naturels d’Occitanie 26 alle de Mycenes34000MontpellierFrance Office Français de la Biodiversite 12 cours Lumiere94300VincennesFrance Tour du Valat Research Institute for the Conservation of Mediterranean Wetlands Le Sambuc13200ArlesFrance

Reedbeds are crucial breeding habitats for vulnerable songbird *** of their protection status,these habitats may be threatened by organic matter accumulation,progressively leading to structural homoge-nization and habitat succession towards *** prevent excessive litter build-up with various in-terventions opening-up the reedbeds,such as grazing,which may be detrimental or suitable for some reed bird *** assessed the effects of extensive grazing by horses and its cessation in the medium and long terms on reedbed structure,and the consequences on reed-nesting songbird densities in Estagnol Nature Reserve,a pro-tected wetland near the French Mediterranean *** compared reedbed structural features between grazed,newly ungrazed and old-ungrazed *** nine years,we censused four songbird species in spring and collected water level data in the same survey *** reduced reedbed extent,rejuvenated the vegetation with more short green stems on a thinner litter,and produced higher structural heterogeneity and discontinuity compared to long-lasting non *** ungrazed plot showed intermediate *** surveyed songbird total densities were similar among plots while species numbers and densities *** reedbed was more attractive to Moustached Warblers(Acrocephalus melanopogon)and Great Reed Warblers(Acrocephalus arundi-naceus),likely due to the large edges and the high vegetation structural ***,Moustached Warblers were more negatively affected by higher water level in grazed reedbed,presumably because flooding prevents litter *** newly ungrazed reedbed was not preferred by any *** warbler species were found under low density in the old-ungrazed reedbed,where Reed Buntings(Emberiza schoeniclus)were exclu-sively *** availability related to thick litter layer may explain this *** Reed Warblers(Acrocephalus scirpaceus)were found everywhere in similar

关键词： Bird conservation Edge complexity Fragmentation Habitat management Horse grazing Phragmites australis Reed passerine

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Application of near-infrared spectroscopy for fast germplasm analysis and classification in multi-environment using intact-seed peanut(Arachis hypogaea L.)

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Oil Crop Science 2024年第2期9卷 132-141页

作者： Fentanesh Chekole Kassie Gilles Chaix Hermine Bille Ngalle Maguette Seye Coura Fall Hodo-Abalo Tossim Aissatou Sambou Olivier Gibert Fabrice Davrieux Joseph Martin Bell Jean-Francois Rami Daniel Fonceka Joel Romaric Nguepjop Department of Plant Biology and Physiology Faculty of SciencesUniversity of Yaounde IYaoundeP.O.Box 337Cameroon Department of Plant Science College of AgricultureWolaita Sodo UniversitySodoP.O.Box 138Ethiopia CIRAD UMR AGAP InstitutMontpellierFrance AGAP Institut Univ MontpellierCIRADINRAEInstitut AgroMontpellierFrance ChemHouse Research Group MontpellierFrance Centre D’Etudes Regional Pour L’Amelioration de L’Adaptation a La Secheresse(CERAAS/ISRA) Route de KhomboleThiesBP 3320Senegal Dispositif de Recherche et de Formation en Partenariat Innovation et Amelioration Varietale en Afrique de L’Ouest(IAVAO)CERAASRoute de KhomboleThiesBP 3320Senegal CIRAD UMR QUALISUDSaint PierreFrance

Peanut is a worldwide oilseed crop and the need to assess germplasm in a non-destructive manner is important for seed nutritional *** this study,Near Infrared Spectroscopy(NIRS)was applied to rapidly assess germplasm variability from whole seed of 699 samples,field-collected and assembled in four genetic and environmentbased sets:one set of 300 varieties of a core-collection and three sets of 133 genotypes of an interspecific population,evaluated in three environments in a large spatial scale of two countries,Mbalmayo and Bafia in Cameroon and Nioro in Senegal,under rainfed *** elemental spectra were gathered on six subsets of seeds of each sample,after three rotation scans,with a spectral resolution of 16 cm-1over the spectral range of867 nm to 2530 *** were then processed by principal component analysis(PCA)coupled with Partial least squares-discriminant analysis(PLS-DA).As results,a huge variability was found between varieties and genotypes for all NIR wavelength within and between *** magnitude of genetic variation was particularly observed at 11 relevant wavelengths such as 1723 nm,usually related to oil content and fatty acid *** yielded the most chemical attributes in three significant PCs(i.e.,eigenvalues>10),which together captured 93%of the total variation,revealing genetic and environment structure of varieties and genotypes into four clusters,corresponding to the four samples *** pattern of genetic variability of the interspecific population covers,remarkably half of spectrum of the core-collection,turning out to be the ***,a PLS-DA model was developed and a strong accuracy of 99.6%was achieved for the four sets,aiming to classify each seed sample according to environment *** confusion matrix achieved for the two sets of Bafia and Nioro showed 100%of instances classified correctly with 100%at both sensitivity and specificity,confirming that their seed quality was different f

关键词： Groundnut Oilseed Near infrared spectroscopy Germplasm analysis Environment Nutritional Breeding

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Numerical Modeling of Mass Transfer in the Interaction between River Biofilm and a Turbulent Boundary Layer

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Open Journal of Fluid Dynamics 2024年第1期14卷 1-23页

作者： Falilou Coundoul Evrad M. D. Ngom Frédéric Y. Moulin Institut Polytechnique de Saint-Louis Université Gaston Berger Saint-Louis Senegal Institut de Mécanique des Fluides de Toulouse UMR 5502-Université de Toulouse Occitanie France

In this article dedicated to the modeling of vertical mass transfers between the biofilm and the bulk flow, we have, in the first instance, presented the methodology used, followed by the presentation of various results obtained through analyses conducted on velocity fields, different fluxes, and overall transfer coefficients. Due to numerical constraints (resolution of relevant spatial scales), we have restricted the analysis to low Schmidt numbers (Sc=0.1, Sc=1, and Sc=10) and a single roughness Reynolds number (Re*=150). The analysis of instantaneous concentration fields from various simulations revealed logarithmic concentration profiles above the canopy. In this zone, the concentration is relatively homogeneous for longer times. The analysis of results also showed that the contribution of molecular diffusion to the total flux depends on the Schmidt number. This contribution is negligible for Schmidt numbers Sc≥0.1, but nearly balances the turbulent flux for Sc=0.1. In the canopy, the local Sherwood number, given by the ratio of the total flux (within or above the canopy) to the molecular diffusion flux at the wall, also depends on the Schmidt number and varies significantly between the canopy and the region above. The exchange velocity, a purely hydrodynamic parameter, is independent of the Schmidt number and is on the order of 10% of in the present case. This study also reveals that nutrient absorption by organisms near the wall depends on the Schmidt number. Such absorption is facilitated by lower Schmidt numbers.

关键词： Epilithic Biofilm Passive Scalar Transport Direct Numerical Simulation Navier-Stokes

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Structural Elucidation of the Polymeric Condensed Tannins of Acacia nilotica Subspecies by ^(13)C NMR, MALDI-TOF and TMA as Sources of Bioadhesives

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Journal of Renewable Materials 2024年第7期12卷 1291-1310页

作者： Zeinab Osman Antonio Pizzi Bertrand Charrier Institute of Engineering Research and Materials Technology National Center for ResearchP.O.Box 2404KhartoumSudan ENSTIB-LERMAB University of Lorraine27 rue Philippe SeguinEpinal88000France Department of Materials Science and Engineering Institute of Analytical Sciences and Physico-Chemistry for the Environment and Materials-Xylomat(IPREM-UMR5254)University of Pau and the Adour RegionE2S UPPACNRSMont de Marsan40004France

Tannin was extracted from different subspecies of Acacia nilotica,Acacia nilotica nilotica(Ann),Acacia nilotica tomentosa(Ant)and Acacia nilotica adansonii(Ana).The aim was to elucidate their structure and evaluate their reactivity as bioadhesives in the wood *** extracts were prepared by hot water extraction(90°C tem-perature).Their gel time with paraformaldehyde was used atﬁrst to compare their *** tannin contents and the percentage of total polyphenolic materials in different solutions of the extracts spray dried powder were determined by the hide powder *** solutions(47%)were tested by both MALDI ToF,*** thermomechanical analysis(TMA)was performed to evaluate their modulus of elasticity(MOE)at different *** gel times of all the three tannin extracts showed that their reactivity and it was com-parable to other known procyanidin/prodelphinidin tannin extract ***,Ann and Ant showed highest per-cent of total polyphenolic materials at 70%,64%,and 57%,*** 13CNMR spectra showed that the three subspecies of condensed tannins were mainly constituted of procyanidins(PC)and prodelphinidins(PD)in slightly different ***(56.5%PC and 43.4%PD),Ant(57%PC and 43%PD)and Ana(58%PC and 42%PD).MALDI–TOF spectra showed the presence ofﬂavonoid monomers,and oligomers some of which linked to short carbohydrates monomers or *** revealed that the three types of tannins had high MOE at their initial pH(5).

关键词： Acacia nilotica condensed tannins procyanidins prodelphinidins 13C NMR MALDI-ToF

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Rubik's cube as in-situ programmable matter and a reconfigurable mechanical metamaterial

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Science China Technological Sciences 2024年

作者： ZHU ShaoWei CHEN Huan YANG XiaoQiang TAN Li JIN Shuai CHEN LiMing LIU Tao TAN XiaoJun WANG LianChao WANG Bing MUAMER Kadic College of Aerospace Engineering Chongqing University State Key Laboratory of Coal Mine Disaster Dynamics and Control Chongqing University School of Civil Aviation Northwestern Polytechnical University National Key Laboratory of Science and Technology on Advanced Composites in Special Environments Harbin Institute of Technology Institut FEMTO-ST CNRS UMR 6174 University Bourgogne

As part of the 4th industrial revolution, programmable mechanical metamaterials exhibit great application potential in flexible robotics, vibration control, and impact protection. However, maintaining a programmed state without sustaining the external stimulus is often challenging and leads to additional energy consumption. Inspired by Rubik's cube, we design and study an insitu programmable and distribution-reconfigurable mechanical metamaterial(IPDR-MM). A matrix model is developed to model IPDR-MMs and describe their morphological transitions. Based on this model, the reinforcement learning method is employed to find the pathways for morphological transitions. We find that IPDR-MMs have controllable stiffness across several orders of magnitude and a wide range of adjustable anisotropies through morphology transformation. Additionally, because of the independence of the directions of morphology transformation and bearing, IPDR-MMs exhibit good stability in bearing and can readily achieve high stiffness. The Rubik's cube-inspired design concept is also instructive for other deformable structures and metamaterials, and the current version of the proposal should be sufficiently illustrative to attract and broaden interdisciplinary interests.

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Effects of soil metal(loid)s pollution on microbial activities and environmental risks in an abandoned chemical smelting site

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Journal of Environmental Sciences 2024年第9期143卷 60-70页

作者： Hao Li Jun Yao Jianli Liu Ning Min Geoffrey Sunahara Dongyang Men Robert Duran School of Water Resources and Environment Research Center of Environmental Science and EngineeringChina University of Geosciences(Beijing)Beijing 100083China Department of Natural Resource Sciences McGill University21111Lakeshore DriveSte-Anne-de-BellevueQuebecH9X 3V9Canada Equipe Environnement et Microbiologie MELODY groupUniversitéde Pau et des Pays de l’AdourE2S-UPPAIPREM UMR CNRS 5254BP 115564013 Pau CedexFrance

Abandoned chemical smelting sites containing toxic substances can seriously threaten and pose a risk to the surrounding ecological *** samples were collected from different depths(0 to 13 m)and analyzed for metal(loid)s content and fractionation,as well as microbial *** potential ecological risk indices for the different soil depths(ordered from high to low)were:1 m(D-1)>surface(S-0)>5 m(D-5)>13 m(D-13)>9 m(D-9),ranging between 1840.65-13,089.62,and representing extremely high environmental risks,of which Cd(and probably not arsenic)contributed to the highest environmental risk.A modified combined pollution risk index(MCR)combining total content and mobile proportion of metal(loid)s,and relative toxicities,was used to evaluate the degree of contamination and potential environmental *** the near-surface samples(S-0 and D-1 layers),the MCR considered that As,Cd,Pb,Sb,and Zn achieved high and alarming degrees of contamination,whereas Fe,Mn,and Ti were negligible or low to moderate pollution *** microcalorimetry and enzymatic activity measurements of contaminated soil samples were used to assess the microbial metabolic activity *** analysis elucidated the relationship between metal(loid)s exchangeable fraction or content and microbial activity characteristics(p<0.05).The microbial metabolic activity in the D-1 layer was low presumably due to heavy metal *** activity indicators and microcalorimetric growth rate(k)measurements were considered sensitive indicators to reflect the soil microbial activities in abandoned chemical smelting sites.

关键词： Abandoned chemical smelting sites Microbial activities Modified combined pollution risk Microcalorimetry Enzymatic activities

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Aseismic performances of constrained damping lining structures made of rubber-sand-concrete

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第5期16卷 1522-1537页

作者： Xiancheng Mei Qian Sheng Jian Chen Zhen Cui Jianhe Li Chuanqi Li Daniel Dias State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China University of Chinese Academy of Sciences Beijing100049China Key Laboratory of Water Grid Project and Regulation of Ministry of Water Resources Changjiang Institute of SurveyPlanningDesign and ResearchWuhan430010China Laboratory 3SR CNRS UMR 5521Grenoble Alpes UniversityGrenoble38000France School of Automotive and Transportation Engineering Hefei University of TechnologyHefei23009China

Flexible damping technology considering aseismic materials and aseismic structures seems be a good solution for engineering *** this study,a constrained damping structure for underground tunnel lining,using a rubber-sand-concrete(RSC)as the aseismic material,is *** aseismic performances of constrained damping structure were investigated by a series of hammer impact *** damping layer thickness and shape effects on the aseismic performance such as effective duration and acceleration amplitude of time-domain analysis,composite loss factor and damping ratio of the transfer function analysis,and total vibration level of octave spectrum analysis were *** hammer impact tests revealed that the relationship between the aseismic performance and damping layer thickness was not linear,and that the hollow damping layer had a better aseismic performance than the flat damping layer *** aseismic performances of constrained damping structure under different seismicity magnitudes and geological conditions were *** effects of the peak ground acceleration(PGA)and tunnel overburden depth on the aseismic performances such as the maximum principal stress and equivalent plastic strain(PEEQ)were *** numerical results show the constrained damping structure proposed in this paper has a good aseismic performance,with PGA in the range(0.2-1.2)g and tunnel overburden depth in the range of 0-300 m.

关键词： Constrained damping structure Aseismic performance Hammer impact tests Damping layer Peak ground acceleration Overburden depth

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Late-onset Very long-chain acyl-CoA dehydrogenase deficiency diagnosis complicated by fulminant myocarditis in adult patient

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Journal of Intensive Medicine 2024年第3期4卷 400-402页

作者： Martin Gérard Clair Douillard Julien Poissy Mehdi Marzouk Christophe Vinsonneau Intensive Care Unit Centre Hospitalier de Bethune-BeuvryBethuneFrance Endocrinology diabetologymetabolism departmentLille reference centre of inborn errors of metabolismLille University HospitalLilleFrance Inserm U1285 CHU LillePôle de réanimationCNRSUMR 8576-UGSF-Unitéde Glycobiologie Structurale et FonctionnelleUniv.LilleLilleFrance

Introduction A 21-year-old woman presented to the emergency department with fatigue,abdominal pain and *** physical activity in school was strictly *** had no family medical history and no personal history but reported frequent episodes of nausea and vomiting lasting 2 to 7 days during the past two years,as well as a weight loss of 9 kg due to reactive anorexia(Body Mass Index 17.5),without triggering factors or *** gastrointestinal symptoms led to the detection of isolated elevated transaminases(aspartate aminotransferase[AST]190 U/L and alanine aminotransferase[ALT]170 U/L);however,the patient did not pursue the proposed etiological *** has been using cannabis once a day for several years,with an increase in consumption over the past year,but no *** reported no other recent change in her habits.

关键词： diagnosis patient elevated

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