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Growth,optical dispersion and magnetic behavior of Dy^(3+) doped yttrium iron garnet crystals

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Journal of Rare Earths 2024年第6期42卷 1110-1117,I0004页

作者： Yating Fang Hui shen Yudie Ma shijie Liao shuang Xia Tian Tian Ding Zhou Yunfeng Ma Jiayue Xu Institute of Crystal Growth School of Materials Science and EngineeringShanghai Institute of Technology national Engineering Center of Electromagnetic Radiation Control Materials School of Electronic Science and EngineeringUniversity of Electronic Science and Technology of China

Y_(3)Fe_(5)O_(12)(YIG)crystals are highly desirable for the fabrication of mid-infrared isolators with the rapid growth of optical communications,although it is rather challenging to grow large size and high-quality single ***^(3+)doping is expected to improve the optical and magneto-optical prope ***,high quality Dy:YIG crystals and the adjustment of Dy^(3+)on the structure and optical behavior of YIG crystal remain unclear,impeding its practical ***,a series of Y_(3-x)Dy_(x)Fe_(5)O_(12)(x=0,0.5,1.0,1.5,3)solid solution crystals was grown by the flux-Bridgman method and single crystals up to 25 mm were *** the introduction of Dy^(3+),lattice parameters are gradually enlarged from 1.2379 nm(YIG)to 1.2420 nm(DyIG).Typical Dy^(3+)absorption peaks are observed around 1070,1265 and 1670 *** refractive index decreases from 2.37(500 nm)to 2.10(2500 nm)for YIG crystal,and it reduces from 2.47(500 nm)to 2.16(2500 nm)for DyIG *** optical bandgaps remain almost unchanged for Dy:YIG *** optical dispersion of the refractive indices was finely fitted by the Wemple and DiDomenico(WDD)and the sellmeier models,*** the increase of Dy^(3+)content,the saturation magnetization(Ms)decreases significantly from 23.62 emu/g(YIG)to 5.33 emu/g(DyIG).small coercive field is persisted for this system,endowing small external magnetic *** results provide valuable references for the manipulation of rare earths on the properties of magnetooptical crystals,which is beneficial to the design of high-performance garnet crystals for the application of optical switching and non-reciprocal related devices.

关键词： Magneto-optical crystal Yttrium iron garnet Dy^(3+)doping Crystal growth Optical dispersion Rare earths

Flow characterization of macroporous W-4.8 vol.%ZrO2 alloy during hot deformation with improved constitutive equation and processing maps

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Tungsten 2024年第3期6卷 610-620页

作者： Jia-Hao Ye Liu-Jie Xu Ji-Kang Hu school of Materials science and Engineering Henan University of Science and Technology national Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials Henan University of Science and Technology

In this work,isothermal compression experiments of macroporous W-4.8 vol.%ZrO2（W-4.8ZrO2） at 1300-1600℃ and strain rate of 0.005-1 s-1were carried out on a Gleeble-1500D thermo-mechanical *** dynamic recovery of W-4.8ZrO2is the main "softening" *** the basis of Arrhenius model,the initial constitutive equation is established by exploring the influence of temperature,strain rate and rheological *** on Arrhenius model,the relationship between flow stress,strain rate and deformation temperature is *** the influence of strain,the improved constitutive equation and the law of material constant changing with the strain are *** that,the hot processing maps were drawn on the basis of the dynamic material model,which is used to analyze the instability mechanism of the W-4.8ZrO2,and determine the appropriate hot working process parameters(temperature:1350-1450℃,strain rate:0.1-1 s-1).

关键词： Tungsten alloy Flow characteristics Constitutive equation Hot processing maps

stereoselective recognition of morphine enantiomers by μ-opioid receptor

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national science Review 2024年第3期11卷 183-191页

作者： Yibo Wang Van A.Ngo Xiaohui Wang Laboratory of Chemical Biology Changchun Institute of Applied ChemistryChinese Academy of Sciences Advanced Computing for Life sciences and Engineering Group Science Engagement Section National Center for Computational Sciences Oak Ridge National Lab school of Applied Chemistry and Engineering University of Science and Technology of China Beijing national Laboratory for Molecular sciences

stereospecific recognition of chiral molecules plays a crucial role in biological systems. The μ-opioid receptor（MOR） exhibits binding affinity towards（-）-morphine, a well-established gold standard in pain management, while it shows minimal binding affinity for the（+）-morphine enantiomer, resulting in a lack of analgesic activity. understanding how MOR stereoselectively recognizes morphine enantiomers has remained a puzzle in neuroscience and pharmacology for over half-a-century due to the lack of direct observation techniqu.s. To unravel this mystery, we constructed the binding and unbinding processes of morphine enantiomers with MOR via molecular dynamics simulations to investigate the thermodynamics and kinetics governing MOR's stereoselective recognition of morphine enantiomers. Our findings reveal that the binding of（-）-morphine stabilizes MOR in its activated state, exhibiting a deep energy well and a prolonged residence time. In contrast,（+）-morphine fails to sustain the activation state of ***, the results suggest that specific residu.s. namely D1142.50and D1473.32, are deprotonated in the active state of MOR bound to（-）-morphine. This work highlights that the selectivity in molecular recognition goes beyond binding affinities, extending into the realm of residence time.

关键词： stereoselective recognition thermodynamics and kinetics residence time morphine enantiomers μ-opioid receptor

Numerical analysis for the free-boundary current reversal equilibrium in the AC plasma current operation in a tokamak

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Plasma science and Technology 2024年第2期26卷 22-30页

作者：胡业民王柳青白书航于治夏天阳 Institute of Plasma Physics Chinese Academy of SciencesHefei 230031People's Republic of China university of science and Technology of China Hefei 230026People's Republic of China Institutes of Physical science and Information Technology Anhui UniversityHefei 230601People's Republic of China

In recent decades, tokamak discharges with zero total toroidal current have been reported in tokamak experiments, and this is one of the key problems in alternating current(AC) *** efficient free-boundary equilibrium code is developed to investigate such advanced tokamak discharges with current reversal equilibrium configuration. The calculation results show that the reversal current equilibrium can maintain finite pressure and also has considerable effects on the position of the X-point and the magnetic separatrix shape, and hence also on the position of the strike point on the divertor plates, which is extremely useful for magnetic design, MHD stability analysis, and experimental data analysis etc. for the AC plasma current operation on tokamaks.

关键词： current reversal equilibrium AC operation free-boundary equilibrium tokamak

A review on ultra-small undoped Mos_(2) as advanced catalysts for renewable fuel production

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Carbon Energy 2024年第2期6卷 92-112页

作者： Guoping Liu Lingling Ding Yuxuan Meng Ahmad Ali Guifu Zuo Xianguang Meng Kun Chang Oi Lun Li Jinhua Ye Hebei Provincial Laboratory of Inorganic Nonmetallic Materials College of Materials Science and EngineeringNorth China University of Science and TechnologyTangshanChina College of Materials science and Technology Nanjing University of Aeronautics and AstronauticsNanjingChina school of Materials science and Engineering Pusan National UniversityBusanKorea International Center for Materials Nanoarchitectonics(WPIMANA) National Institute for Materials Science(NIMS)1-1 NamikiTsukubaIbarakiJapan

Molybdenum disulfide(Mos_(2))has garnered significant attention in the field of catalysis due to the high density of active sites in its unique two-dimensional(2D)structure,which could be developed into numerous high-performance *** synthesis of ultra-small Mos2 particles(s highly desired in various experimental *** ultra-small structure could often lead to a distinct s-Mo coordination state and nonstoichiometric composition in Mosx,minimizing in-plane active sites of the 2D structure and making it probable to regulate the atomic and electronic structure of its intrinsic active sites on a large extent,especially in Mosx *** article summarizes the recent progress of catalysis over ultra-small undoped Mos_(2) particles for renewable fuel *** a systematic review of their synthesis,structural,and spectral characteristics,as well as the relationship between their catalytic performance and inherent defects,we aim to provide insights into catalysis over this matrix that may potentially enable advancement in the development of high-performance Mos_(2)-based catalysts for sustainable energy generation in the future.

关键词： applications catalytic Mos_(2) structure synthesis

Polarimeter–interferometer diagnostic using terahertz solid-state sources for fluctuation measurements on Keda Torus e Xperiment(KTX)

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Plasma science and Technology 2024年第3期26卷 61-65页

作者：汪兴康毛文哲谢锦林兰涛李弘刘阿娣周楚温晓辉卫子安吴捷陈晨刘东宽饶贤昊蔡虎邬佳仁邓鹏刘海庆丁卫星庄革刘万东 school of Nuclear science and Technology University of Science and Technology of ChinaHefei 230026People's Republic of China Institute of Plasma Physics Chinese Academy of SciencesHefei 230031People's Republic of China

A multi-channel polarimeter-interferometer has been developed on the Keda Torus eXperiment(KTX)for the study of equilibrium dynamics and internal magnetic fluctuations.A three-wave technique based on terahertz solid-state sources(-650 GHz)is applied for simultaneous measurements of electron density and Faraday rotation *** output power of the microwave source is 2 *** rotation effect using a rotating wave plate is tested with phase noise less than 0.8°,and the density phase noise is less than 0.9°.Measurement of Faraday rotation angle and density for discharges on KTX have demonstrated high sensitivity to internal MHD activities.

关键词： plasma diagnostics interferometry terahertz polarimeter

Enabling an Inorganic-Rich Interface via Cationic surfactant for High-Performance Lithium Metal Batteries

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Nano-Micro Letters 2024年第8期16卷 1-17页

作者： Zejun sun Jinlin Yang Hongfei Xu Chonglai Jiang Yuxiang Niu Xu Lian Yuan Liu Ruiqi su Dayu Liu Yu Long Meng Wang Jingyu Mao Haotian Yang Baihua Cui Yukun Xiao Ganwen Chen Qi Zhang Zhenxiang Xing Jisheng Pan Gang Wu Wei Chen Department of Chemistry National University of Singapore3 Science Drive 3Singapore 117543Singapore Agency for science Technology and Research(A*STAR)Institute of High-Performance Computing1 Fusionopolis Way#16‑16 ConnexisSingapore 138632Singapore Department of Physics National University of Singapore2 Science Drive 3Singapore 117542Singapore Joint school of national university of singapore and Tianjin university International Campus of Tianjin UniversityBinhai New CityFuzhou 350207People’s Republic of China Agency for science Technologyand Research(A*STAR)Institute of Materials Research and EngineeringInnovis2 Fusionopolis Way#08‑03Singapore 138634Singapore

An anion-rich electric double layer(EDL)region is favorable for fabricating an inorganic-rich solid-electrolyte interphase(sEI)towards stable lithium metal anode in ester ***,cetyltrimethylammonium bromide(CTAB),a cationic surfactant,is adopted to draw more anions into EDL by ionic interactions that shield the repelling force on anions during lithium *** situ electrochemical surface-enhanced Raman spectroscopy results combined with molecular dynamics simulations validate the enrichment of NO_(3)^(−)/FsI−anions in the EDL region due to the positively charged CTA^(+).In-depth analysis of sEI structure by X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry results confirmed the formation of the inorganic-rich sEI,which helps improve the kinetics of Li^(+)transfer,lower the charge transfer activation energy,and homogenize Li *** a result,the Li||Li symmetric cell in the designed electrolyte displays a prolongated cycling time from 500 to 1300 h compared to that in the blank electrolyte at 0.5 mA cm^(-2) with a capacity of 1 mAh cm^(-2).Moreover,Li||LiFePO_(4) and Li||LiCoO_(2) with a high cathode mass loading of>10 mg cm^(-2) can be stably cycled over 180 cycles.

关键词： Cationic surfactant Lithium nitrate additive solid-electrolyte interphase Electric double layer Lithium metal batteries

Enhancing Defect-Induced Dipole Polarization strategy of siC@MoO_(3)Nanocomposite Towards Electromagnetic Wave Absorption

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Nano-Micro Letters 2024年第12期16卷 406-426页

作者： Ting Wang Wenxin Zhao Yukun Miao Anguo Cui Chuanhui Gao Chang Wang Liying Yuan Zhongning Tian Alan Meng Zhenjiang Li Meng Zhang College of Chemical Engineering Qingdao University of Science and TechnologyQingdao 266042People’s Republic of China College of Materials science and Engineering Qingdao University of Science and TechnologyQingdao 266042People’s Republic of China shandong Engineering Laboratory for Preparation and Application of High-Performance Carbon-Materials College of Electromechanical EngineeringQingdao University of Science and TechnologyQingdao 266061People’s Republic of China Key Laboratory of Optic-Electric sensing and Analytical Chemistry for Life science MOEShandong Key Laboratory of Biochemical AnalysisCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042People’s Republic of China

Defect engineering in transition metal oxides semiconductors(TMOs)is attracting considerable interest due to its potential to enhance conductivity by intentionally introducing defects that modulate the electronic structures of the ***,achieving a comprehensive understanding of the relationship between micro-structures and electromagnetic wave absorption capabilities remains elusive,posing a su.s.antial challenge to the advancement of TMOs *** current research describes a process for the deposition of a MoO_(3)layer onto siC nanowires,achieved via electro-deposition followed by high-temperature ***,intentional creation of oxygen vacancies within the MoO_(3)layer was carried out,facilitating the precise adjustment of electromagnetic properties to enhance the microwave absorption performance of the ***,the siC@MO-t4 sample exhibited an excellent minimum reflection loss of-50.49 dB at a matching thickness of 1.27 ***,the siC@MO-t6 sample exhibited an effective absorption bandwidth of 8.72 GHz with a thickness of 2.81 mm,comprehensively covering the entire Ku *** results not only highlight the pivotal role of defect engineering in the nuanced adjustment of electromagnetic properties but also provide valuable insight for the application of defect engineering methods in broadening the spectrum of electromagnetic wave absor ption ***@MO-t samples with varying concentrations of oxygen vacancies were prepared through in-situ etching of the siC@MoO_(3)*** presence of oxygen vacancies plays a crucial role in adjusting the band gap and local electron distribution,which in turn enhances conductivity loss and induced polarization loss *** finding reveals a novel strategy for improving the absorption properties of electromagnetic waves through defect engineering.

关键词： Defect engineering Oxygen vacancies siC@MoO_(3)nanocomposite Electromagnetic wave absorption Induced dipole polarization

Insight into the synergistic effect of defect and strong interface coupling on ZnIn_(2)s_(4)/CoIn_(2)s_(4)heterostructure for boosting photocatalytic H_(2) evolution

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Journal of Energy Chemistry 2024年第5期92卷 151-161页

作者： Xuehua Wang Tianyu.s.i Xianghu Wang Aili song Guicun Li Lei Wang Jianfeng Huang Alan Meng Zhenjiang Li College of Materials science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Key Laboratory of Optic-electric sensing and Analytical Chemistry for Life science MOECollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042ShandongChina Qingdao Huanghai university Qingdao 266000ShandongChina school of Material science and Engineering International S&T Cooperation Foundation of Shaanxi ProvinceXi’an Key Laboratory of Green Manufacture of Ceramic MaterialsShaanxi University of Science and TechnologyXi’an 710021ShaanxiChina

steering the directional carrier migration across the interface is a central mission for efficient photocatalytic *** this work,an atomic-shared heterointerface is constructed between the defect-rich ZnIn_(2)s_(4)(HVs-ZIs)and CoIn_(2)s_(4)(CIs)via a defect-guided heteroepitaxial growth *** strong interface coupling induces adequate carriers exchanging passageway between HVs-ZIs and CIs,enhancing the internal electric field(IEF)in the ZnIn_(2)s_(4)/CoIn_(2)s_(4)(HVs-ZIs/CIs)*** defect structure in HVs-ZIs induces an additional defect level,improving the separation efficiency of ***,promoted by the IEF and intimate heterointerface,photogenerated electrons trapped by the defect level can migrate to the valence band of CIs,contributing to massive photogenerated electrons with intense reducibility in HVs-ZIs/***,the HVs-ZIs/CIs heterostructure performs a boosted H_(2)evolution activity of 33.65 mmol g^(-1)h^(-1).This work highlights the synergistic effects of defect and strong interface coupling in regulating carrier transfer and paves a brave avenue for constructing efficient heterostructure photocatalysts.

关键词： Defect-guided heteroepitaxial growth Heterointerface coupling Photocatalytic H_(2)evolution Mechanism HVs-ZIs/CIs