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Journal of Energy Chemistry 2025年第1期100卷 760-769页

作者： Lin Peng Yu Bai Hang Li Meixiu Qu Zhenhua Wang Kening Sun Advanced research institute of multidisciplinary Science Beijing Institute of Technology Beijing Key Laboratory of Chemical Power Source and Green Catalysis School of Chemistry and Chemical Engineering Beijing Institute of Technology

Lithium-sulfur （Li-S） batteries have gained great attention due to the high theoretical energy density and low cost,yet their further commercialization has been obstructed by the notorious shuttle effect and sluggish redox ***,we supply a strategy to optimize the electron structure of Ni2P by concurrently introducing B-doped atoms and P vacancies in Ni2P （Vp-B-Ni2P）,thereby enhancing the bidirectional sulfur *** study indicates that the simultaneous introduction of B-doped atoms and P vacancies in Ni2P causes the redistribution of electron around Ni atoms,bringing about the upward shift of d-band center of Ni atoms and effective d-p orbital hybridization between Ni atoms and sulfur species,thus strengthening the chemical anchoring for lithium polysulfides （LiPSs） as well as expediting the bidirectional conversion kinetics of sulfur ***,theoretical calculations reveal that the incorporation of B-doped atoms and P vacancies in Ni2P selectively promotes Li2S dissolution and nucleation ***,the Li-S batteries with Vp-B-Ni2P-separators present outstanding rate ability of 777 m A h g-1at 5 C and high areal capacity of 8.03 mA h cm-2under E/S of 5μL mg-1and sulfur loading of 7.20 mg *** work elucidates that introducing heteroatom and vacancy in metal phosphide collaboratively regulates the electron structure to accelerate bidirectional sulfur conversion.

关键词： Lithium sulfur batteries

Context-dependent integrated stress resistance promotes a global invasive pest

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Insect Science 2022年第6期29卷 1790-1804页

作者： Vimbai L.Tarusikirwa Ross N.Cuthbert Reyard Mutamiswa Casper Nyamukondiwa Department of Biological Sciences and Biotechnology Botswana International University of Science and TechnologyPalapyeBotswana GEOMAR Helmholtz-Zentrum fur Ozeanforschung Kiel KielGermany School of Biological Sciences Queen's University BelfastNorth ern IrelandUnited Kingdom Department of Zoology and Entomology University of the Free StateBloemfonteinSouth Africa tugwi-mukosi multidisciplinary research institute Midlands State UniversityGweruZimbabwe Department of Zoology and Entomology.Rhodes University MakhandaSouth Africa

In nature,insects concurrently face multiple environmental stressors,a sce-nario likely increasing with climate *** stress resistance(ISR)thus often improves fitness and could drive invasiveness,but how physiological mechanisms influ-ence invasion has lacked ***,we investigated cross-tolerance to abiotic stress factors which may influence range limits in the South American tomato pinworm a global invader that is an ecologically and socially damaging crop ***,we tested the effects of prior rapid cold-and heat-hardening(RCH and RHH),fasting,and desiccation on cold and heat tolerance traits,as well as starvation and desiccation sur-vivability between *** life *** effects on critical thermal minima(CT_(min))and maxima(CT_(max))were inconsistent,showing significantly deleterious effects of RCH on adult CT_(max) and CT_(min) and,conversely,beneficial acclimation effects of RCH on larval CT_(min).While no beneficial effects of desiccation acclimation were recorded for desiccation tolerance,fasted individuals had significantly higher survival in adults,whereas fasting negatively affected larval ***,fasted and desiccation acclimated adults had significantly higher starvation tolerance,showing strong evidence for *** results show context-dependent ISR traits that may promote *** fitness and *** the frequent overlapping occurrence of these divergent stressors,ISR reported here may thus partly elucidate the observed rapid global spread of *** into more stressful environments than *** information is vital in determining the underpinnings of multistressor responses,which are fundamental in forecasting species responses to changing environments and management responses.

关键词： acclimation cross-talk cross-tolerance invasive species thermal tolerance tomato leaf miner

Synthesis of Nitrogen-doped Titania by Solvothermal Reactions in Alcohols

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过程工程学报 2006年第3期6卷 472-476页

作者： Tsugio Sato Yohei Aida Masakazu Komatsu 殷澍 institute of multidisciplinary research for Advanced Materials Tohoku UniversitySendai 980-8577Japan

Nitrogen-doped titania nanoparticles were obtained by the homogeneous precipitation in hexamethylenetetraminetitanium trichloride-alcohol aqueous solutions at 90 ℃ followed by heating at 190 ℃. Anatase, rutile and brookite were obtained, where the crystallite size, specific surface area and color greatly changed as 5～50 nm, 20～200 m2/g and light gray to yellow, depending on the solvent and pH. The products after calcination were yellow, indicating doping with nitrogen ion. All colored titania showed photocatalytic activity under visible light irradiation for the oxidative decomposition of nitrogen monoxide in air. Especially, the nanoparticles of anatase type nitrogen-doped titania obtained using methanol aqueous solution showed excellent photocatalytic activity.

关键词： nitrogen-doped titania solvothermal synthesis alcohol photocatalysis nitrogen monoxide decomposition

Study of TiO_2 thin films on Si substrate by the photoacoustic elastic bending method

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Science China(Physics,Mechanics & Astronomy) 2013年第7期56卷 1285-1293页

作者： TODOROVI Dragan M RABASOVI Mihailo D MARKUSHEV Dragan D FRANKO Mladen TANGAR Urka Lavreni institute for multidisciplinary research University of Belgrade institute of Physics University of Belgrade Laboratory for Environmental research University of Nova Gorica

The quantitative photoacoustic investigation of different TiO2 thin films on Si substrates is presented using the elastic bending method. Photoacoustic signal amplitude and phase spectra versus modulation frequency were measured and analyzed using different sample thicknesses. Within the proposed method particular attention is given to the analysis of optical, thermal, elastic and structural sample parameters. Considerable focus is devoted to the fitting procedure of experimental results using the two-layer sample theoretical model. Characteristics of previously developed photoacoustic apparatus are discussed, attempting to search the ideal experimental conditions which can provide a good signal-to-noise ratio and sensitivity.

关键词： photoacoustic TiO2 thin films

Activities of liquid Fe-As and Fe-Sb alloys saturated with carbon

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Rare Metals 2006年第5期25卷 488-491页

作者： Leandro Voisin Kimio Itagaki institute of multidisciplinary research for Advanced Materials Tohoku UniversitySendai 980-8577Japan

A solid iron base alloy of the so-called furnace residue is often formed as a by-product in reduction smelting of lead sinter and scraps with high contents of arsenic and antimony. The use of phase separation into a liquid iron-rich alloy and a liquid lead-rich alloy in lead-iron-arsenic and lead-iron-antimony systems saturated with carbon at relatively low temperatures of about 1200~C was proposed in a new process for treating the fumace residue to recover valuable elements into the lead-rich alloy and fLx toxic arsenic into the iron-rich alloy. As a fundamental study for the proposed process, the activity coefficients and interaction parameters of the Fe-As and Fe-Sb systems saturated with carbon at 1200℃ were derived in this study, based on the determined phase relations in the Fe-Pb-As and Fe-Pb-Sb systems saturated with carbon.

关键词： activity coefficient phase relations Pb-Fe-As-C system Pb-Fe-Sb-C system lead-smelting lead-recycling

Morphology control of aluminum nitride(AlN)for a novel high-temperature hydrogen sensor

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International Journal of Minerals,Metallurgy and Materials 2020年第11期27卷 1560-1567页

作者： Angga Hermawan Yusuke Asakura Shu Yin institute of multidisciplinary research for Advanced Material(IMRAM) Tohoku UniversitySendai 980-8577Japan

Hydrogen is a promising renewable energy source for fossil-free transportation and electrical energy ***,leaking hydrogen in high-temperature production processes can cause an explosion,which endangers production workers and surrounding *** detect leaks early,we used a sensor material based on a wide bandgap aluminum nitride(AlN)that can withstand a high-temperature *** unique AlN morphologies(rod-like,nest-like,and hexagonal plate-like)were synthesized by a direct nitridation method at 1400℃usingγ-AlOOH as a *** gas-sensing performance shows that a hexagonal plate-like morphology exhibited p-type sensing behavior and showed good repeatability as well as the highest response(S=58.7)toward a 750 ppm leak of H2 gas at high temperature(500°C)compared with the rod-like and nest-like ***,the hexagonal plate-like morphology showed fast response and recovery times of 40 and 82 s,*** surface facet of the hexagonal morphology of AlN might be energetically favorable for gas adsorption–desorption for enhanced hydrogen detection.

关键词： aluminum nitride controllable morphology direct nitridation γ-AlOOH hydrogen sensor

PZT–NZF/CF ferrite flexible thick films:Structural,dielectric,ferroelectric,and magnetic characterization

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Journal of Advanced Ceramics 2019年第4期8卷 545-554页

作者： J.D.BOBIC G.Ferreira TEIXEIRA R.GRIGALAITIS S.GYERGYEK M.M.Vijatovic PETROVIC M.Ap.ZAGHETE B.D.STOJANOVIC institute for multidisciplinary research Belgrade University Belgrade Serbia Universidade Federal de Goiás - UFG Instituto de Química Goiânia Brazil Faculty of Physics Vilnius University Vilnius Lithuania institute Jozef Stefan Ljubljana Slovenia institute for multidisciplinary research Belgrade University Belgrade Serbia Instituto de Quimica-UNESP Araraquara Brazil institute for multidisciplinary research Belgrade University Belgrade Serbia

The preparation and properties of thick flexible three-phase composite films based on lead zirconium titanate(PZT) and various ferrites(nickel zinc ferrite(NZF) and cobalt ferrite(CF)) were reported in this study. Properties of three-phase composite films were compared with pure polyvinylidene fluoride(PVDF) and PZT–PVDF films. X-ray diffraction data indicated the formation of well crystallized structure of PZT and NZF/CF phases, without the presence of undesirable phases. Scanning electron micrographs showed that the ceramic particles were dispersed homogeneously in the PVDF matrix and atomic force microscopy confirmed that the size of the particles is around 30 nm. Non-saturated hysteresis loops were evident in all samples due to the presence of highly conductive ferrite phases. Under magnetic field of 10 k Oe, composite films exhibited a typical ferromagnetic response. Dielectric properties were investigated in the temperature range from –128 to 250 ℃ and frequency range of 400 Hz–1 MHz. The results showed that the value of dielectric constant of the PVDF/PZT/ferrite composites increased about 25% above the one obtained for pure PVDF.

关键词： flexible thick films three-phase composites ferroelectricity magnetic materials

Magnetic properties of DNA-templated Co/Cu naonoparticle chains

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Chinese Physics B 2010年第8期19卷 628-631页

作者：高有辉卫玲高春蕾夏卫星進藤大輔 Department of Physics Beijing Normal University The First institute of Oceanography institute of multidisciplinary research for Advanced Materials Tohoku University

According to ultraviolet （UV）-vis absorption spectra recorded in the DNA metallization process, DNA-templated Co/Cu binary nanoparticle chains are fabricated by incubating genome DNA of paralichthys olivaceus muscle in CoCl2 and CuCl2 mixture solution for 20 hours and reducing the complex for 2 hours. Transmission electron microscopy observation indicates that Co and Cu nanoparticles with 20 nm in diameter were randomly dispersed on the DNA template. The superconducting quantum interference device （SQUID） measurements display that the magnetic interaction between cobalt particles is greatly decreased by the copper particle. With increasing copper content, the coercivity of the systems enhance from 9 Oe to 100 Oe （1 Oe=79.5775 A/m）.

关键词： DNA-templated Co/Cu nanoparticle magnetic interaction

Application of the Solvothermal Process in the Synthesis of High-performance Ag/γ-Al_2O_3 Catalysts

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过程工程学报 2006年第4期6卷 633-638页

作者：唐清李锐星殷澍 Shingo Goto Daisuke Nagai Tsugio Sato institute of Process Engineering Chinese Academy of Sciences institute of multidisciplinary research for Advanced Materials Tohoku UniversitySendai 980-8577Japan

Ag/γ-Al2O3 is a kind of promising catalyst with the relatively lower cost compared with those using noble metals,good resistance against catalytic poisoning and excellent behaviour for NOx *** the present study,Ag/γ-Al2O3 catalysts were synthesized by the solvothermal process and characterized by XRD,TG?DTA,TEM,UV?Vis and FT?*** was found that high-performance Ag/γ-Al2O3 catalysts could be synthesized by properly selecting starting materials,controlling the composition of solvent and other reaction *** microstructure evolution of the catalysts was also discussed.

关键词： Ag/γ-Al2O3 solvothermal process catalyst microstructure

Multidimensional(0D-3D)functional nanocarbon:Promising material to strengthen the photocatalytic activity of graphitic carbon nitride

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Green Energy & Environment 2021年第6期6卷 823-845页

作者： Bin He Mi Feng Xinyan Chen Jian Sun School of Life Science Beijing Institute of TechnologyBeijing100081China Advanced research institute of multidisciplinary Science Beijing Institute of TechnologyBeijing100081China

As a prospective visible-light-responsive photochemical material,graphitic carbon nitride(g-C_(3)N_(4))has become a burgeoning research hot topics and aroused a wide interest as a metal-free semiconductor in the area of energy utilization and conversion,environmental protection due to its unique properties,such as facile synthesis,high physicochemical stability,excellent electronic band structure,and ***,the shortcomings of high recombination rate of charge carriers,relatively low electrical conductivity and visible light absorption impede its practical *** strategies,such as surface photosensitization,heteroatom deposition,semiconductor hybridization,etc.,have been applied to overcome the *** all the strategies,functional nanocarbon materials with various dimensions(0D~3D)attract much attention as modifiers of g-C_(3)N_(4)due to their unique electronic properties,optical properties,and easy *** importantly,the properties of these functional nanocarbon materials can be tuned by various dimensions and thus there will be a way to overcome the defects of g-C_(3)N_(4)by choosing different dimensional carbon *** from some present reviews,this review starts with the fundamental physicochemical characteristics of g-C_(3)N_(4)materials,followed by analyzing the advantages of functional nanocarbon materials modifying gC_(3)N_(4).Then,we present a systematic introduction to various dimensional carbon *** design philosophy of carbon/g-C_(3)N_(4)composites and the advanced studies are exemplified in ***,a nichetargeting summary and outlook on the major challenges,opportunities for future research in high-powered carbon/g-C_(3)N_(4)composites was proposed.

关键词： Graphitic carbon nitride(g-C_(3)N_(4)) Carbon materials Multidimension Photocatalysis Visible light