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Preparation of co.S co.doped carbon catalysts for excellent methylene blue degradation

International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 169-181页

作者： Haixu Li Haobo He Tiannan Jiang Yunfei Du Zhichen Wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue School of Materials Science and engineering University of Science and Technology BeijingBeijing 100083China Beijing Jinyu Tongda Refractory Technologies co. Ltd.Beijing 100085China

S and co.co.doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)*** effects of two different mixing routes were identified on the MB degradation ***,the catalyst obtained by the alco.ol solvent evaporation(MOF-AEP)mixing route co.ld degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectrosco.y revealed that the co.S co.tent of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of co.for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to co.alt in the form of co.S bond(-2.86 eV).Thus,the C-S-C sites might provide more co.tributions to activate PMS co.pared with ***,the degradation parameters,including pH and MOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the seco.dary one in degrading MB.

关键词： advanced oxidation process alco.ol solvent evaporation hydrogen bond S and co.co.doped carbon catalysts wastewater remediation

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Bending Stiffness of co.crete-Filled Steel Tube and Its Influence on co.crete Placement Timing of co.posite Beam-String Structure

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Structural Durability & Health Monitoring 2025年第1期19卷 55-75页

作者： Zhenyu Zhang Quan Jin Haitao Zhang Zhao Liu Yuyang Wu Longfei Zhang Renzhang Yan CCCC Third Highway engineering co. Ltd.Beijing101300China School of Civil engineering Chongqing Jiaotong UniversityChongqing400074China

When the upper chord beam of the beam-string structure(BSS)is made of co.crete-filled steel tube(CFST),its overall stiffness will change greatly with the co.struction of co.crete placement,which will have an impact on the design of the tensioning plans and selection of co.trol measures for the *** order to accurately obtain the bending stiffness of CFST beam and clarify its impact on the mechanical properties of co.posite BSS during co.struction,the influence of some factors such as height-width ratio,wall thickness of steel tube,elasticity modulus of co.crete,and friction co.fficient on the bending stiffness are analyzed parametrically by the numerical simulation technology based on an actual *** calculation formula of the equivalent bending stiffness of CFST is also established through mathematical statistical ***,the equivalent bending stiffness is introduced into the co.struction and use stages of the co.posite BSS,respectively,and the mechanical properties such as prestress-tensioning co.trol value,structural deformation,and internal force of key members are co.paratively analyzed when adopting two different co.struction ***,the optimal co.struction plan of co.crete placement first and then prestress-tensioning is proposed.

关键词： co.crete panels freeze-thaw damage co.pression-shear crack tension-shear crack

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Multi boron-doping effects in hard carbon toward enhanced sodium ion storage

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Journal of Energy Chemistry 2025年第1期100卷 730-738页

作者： Peng Zheng Wang Zhou Ying Mo Biao Zheng Miaomiao Han Qin Zhong Wenwen Yang Peng Gao Lezhi Yang Jilei Liu co.lege of Materials Science and engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology Hunan University Greater Bay Area Institute for Innovation Hunan University Changsha Research Institute of Mining & Metallurgy co. LTD.

Hard carbon （HC） has been co.sidered as promising anode material for sodium-ion batteries （SIBs）.The optimization of hard carbon’s microstructure and solid electrolyte interface （SEI） property are demonstrated effective in enhancing the Na+storage capability,however,a one-step regulation strategy to achieve simultaneous multi-scale structures optimization is highly ***,we have systematically investigated the effects of boron doping on hard carbon’s microstructure and interface chemistry.A variety of structure characterizations show that appropriate amount of boron doping can increase the size of closed pores via rearrangement of carbon layers with improved graphitization degree,which provides more Na+storage ***-situ Fourier transform infrared spectrosco.y/electrochemical impedance spectrosco.y （FTIR/EIS） and X-ray photoelectron spectrosco.y （XPS） analysis demonstrate the presence of more BC3and less B–C–O structures that result in enhanced ion diffusion kinetics and the formation of inorganic rich and robust SEI,which leads to facilitated charge transfer and excellent rate *** a result,the hard carbon anode with optimized boron doping co.tent exhibits enhanced rate and cycling *** general,this work unravels the critical role of boron doping in optimizing the pore structure,interface chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced Na+storage performance.

关键词： X ray photoelectron spectrosco.y

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Investigation of non-co.esive levee breach by overtopping flow

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Journal of Hydrodynamics 2013年第4期25卷 572-579页

作者：余明辉魏红艳梁艳洁赵勇 State Key Laboratory of Water Resources and Hydropower engineering Sciences Wuhan University State Yellow River engineering consulting co. Ltd. Changjiang engineering Supervision and consulting co.

This paper presents an experimental study of the overtopping breach of homogeneous non-co.esive levee or dike in a 180°bend rectangular flume. Detailed experimental and numerical results provide information on the breach flow discharge and longitudi- nal and transversal breach profiles for this type of levee. It is indicated that the water level and the flow discharge in the river and the levee material properties are significant influencing factors for the breach evolution. The plane form of the breach is approximately an asymmetrical hyperbola. A formula with a non-co.stant flow factor is proposed to co.pute this kind of breach discharge.

关键词： non-co.esive levee overtopping breach discharge experiments

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Improvement of co.d Recycled Mixture Performance Based on Improved Density Test Method and RAP Characteristics

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期 79-87页

作者：韩占闯 PANG Yafeng 林宏伟 China First Highway engineering Group co. Ltd The Key Laboratory of Road and Traffic engineering Ministry of Education Tongji University Guangzhou Baiyun International Airport co. Ltd.

The available test methods for optimal moisture co.tent of co.d recycled mixture (CRM) as well as its bulk specific gravity,and theoretical maximum relative density were analyzed in this *** test improvements were suggested to improve test co.trol of the CRM road performance based on the disco.ered ***,the properties of reclaimed asphalt pavement (RAP),including the co.tent of old asphalt,penetration index,passing rate of 4.75 mm sieve,and gradation change rate after extraction,were *** effects of RAP characteristics on splitting tensile strength,water stability,the high-and low-temperature performance of emulsified asphalt CRM were *** results show that the optimum moisture co.tent of CRM should be determined when the co.paction work matches the specimen’s molding *** the analyzed methods of bulk specific gravity assessment,the dry-surface and co.eLok methods provide more robust and accurate results than the wax-sealing method,while the dry-surface method is the most *** modified theoretical maximum relative density test method is proposed,which can reduce the systematic error of the vacuum test *** following RAP-CRM trends can be *** lower the co.tent of old asphalt and the smaller the change rate of gradation,the smaller the voids and the better the water stability of *** greater the penetration of old asphalt,the higher the fracture work and low-temperature splitting *** greater the penetration,the higher the passing rate of 4.75 mm sieve after extraction,and the worse the high-temperature performance of CRM.

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CableSAM:an efficient automatic segmentation method for aircraft cabin cables

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Optoelectronics Letters 2025年第3期 183-187页

作者： LING Aihua WANG Junwen LU Jiaming LIU Ruyu Shanghai Aircraft Manufacturing co. Ltd. School of co.puter Science and engineering Tianjin University of Technology School of Information Science and Technology Hangzhou Normal University

Cabin cables,as critical co.ponents of an aircraft's electrical system,significantly impact the operational efficiency and safety of the *** existing cable segmentation methods in civil aviation cabins are limited,especially in automation,heavily dependent on large amounts of data and resources,lacking the flexibility to adapt to different *** address these challenges,this paper introduces a novel image segmentation model,CableSAM,specifically designed for automated segmentation of cabin *** improves segmentation efficiency and accuracy using knowledge distillation and employs a co.text ensemble *** accurately segments cables in various scenarios with minimal input *** experiments on three cable datasets demonstrate that CableSAM surpasses other advanced cable segmentation methods in performance.

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Modification of Maxwell model for co.ductivity prediction of carbon nanotubes-filled polymer co.posites with tunneling effect

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 25-36页

作者： Jue ZHU Longyuan LI Ningtao ZHU Zhejiang Provincial engineering Research Center for the Safety of Pressure Vessel and Pipeline Key Laboratory of Impact and Safety engineering (Ningbo University) Ministry of Education School of engineering Computing and Mathematics University of Plymouth Xi'an Zhanshi Testing & engineering co.Ltd.

Carbon nanotubes(CNTs) have garnered great attention in recent years due to their outstanding electrical, thermal, and mechanical properties. The inco.poration of small amounts of CNTs in polymers can substantially improve the sensitivity of the polymer's electrical co.ductivity. This paper presents a modified Maxwell model to evaluate the electrical co.ductivity of CNTs-filled polymer co.posites by introducing a transition zone to acco.nt for the tunneling effect. In this modified Maxwell model, the CNTs-filled polymer co.posite is modeled as a three-phase co.posite, co.sisting of a matrix(polymer), inclusions(CNTs), and a transition zone(tunneling zone). The effective electrical co.ductivity(EEC) of the co.posite is calculated based on the volume fractions and electrical co.ductivities of the matrix, inclusions, and transition zone. The model's validity is co.firmed through the use of available test data, which demonstrates its capability to accurately capture the nonlinear co.ductivity behavior observed in CNTs-polymer co.posites. This study offers valuable insights into the design of high-performance co.ductive polymer nanoco.posites, and enhances the understanding of electrical co.duction mechanisms in CNT-dispersed polymer co.posites.

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Microsco.ic Analysis of Cementitious Sand and Gravel Damming Materia

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Fluid Dynamics & Materials Processing 2024年第4期20卷 749-769页

作者： Ran Wang Aimin Gong Shanqing Shao Baoli Qu Jing Xu Fulai Wang Feipeng Liu co.lege of Water co.servancy Yunnan Agricultural UniversityKunming650201China tianqi engineering consulting co. Ltd.Kunming650000China Institute of International Rivers and Eco.ogical Security Yunnan UniversityKunming650500China

The mechanical properties of cementitious sand and gravel damming material have been experimentally determined by means of microsco.ic SEM(Scanning Electron Microsco.y)image *** results show that the co.bination of fly ash and water can fill the voids in cemented sand and gravel test blocks because of the presence of hydrated calcium silicate and other substances;thereby,the co.pactness and mechanical properties of these materials can be greatly *** every 10 kg/m^(3) increase in the amount of cementitious material,the density increases by about 2%,and the water co.tent decreases by 0.2%.The amount of cementitious material used in the sand and gravel in these tests was 80-110 kg/m^(3),the water-binder ratio was ***,the splitting tensile strength was 1/10 of the co.pressive strength,and the maximum strength was 7.42 MPa at 90 *** optimal mix ratio has been found to be 50 kg of cement,60 kg of fly ash and 120 kg of water(C50F60W120).The related dry density was 2.6 g/cm^(3),the water co.tent was 6%,and the water-binder ratio was 1.09.

关键词： Cementitious sand gravel material scanning electron microsco.y optimal mix ratio maximum strength

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Numerical simulation of turbulent flow behind sluice gate under submerged discharge co.ditions

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Journal of Hydrodynamics 2015年第2期27卷 257-263页

作者：刘士和廖庭庭罗秋实 State Key Laboratory of Water Resources and Hydropower engineering Science Wuhan University Yellow River engineering consulting co. Ltd

The turbulent flow discharging under a sluice gate is one kind of typical flows with co.plicated boundaries in hydraulic and hydroelectric engineering, and the characteristics of its flow field and flow evolution are important in engineering hydraulics. Although there were many studies in this regard, which mainly focus on the discharge capacity, the local sco.r and the mean flow field, some issues remain to be further investigated, for example, the variation of the mechanical energy during the sco.ring process, and the adjustment of the unsteady turbulent flow after the local sco.r with the downstream steady uniform flow. In this paper, the turbulent flow behind a sluice gate is divided into a rapidly varied flow region and a gradually varied flow region, and the above problems are investigated by theoretical analysis and numerical simulation. The main co.clusions are as follows：（1） In the discharging process of the turbulent flow under a sluice gate, the river bed would be sco.red co.tinuously and the water–air interface is adjusted acco.dingly, which leads to a decrease of the mechanical energy of the total flow in the rapidly varied flow region, and the mechanical energy loss would also decrease with the increase of the time, yet the variation of the flow discharge under the sluice gate is very small.（2） In the link between the rapidly varied flow and the uniform flow downstream, the mean wall shear stress and the co.fficient for the mechanical energy loss would decrease in the longitudinal direction, the decay of the turbulent kinetic energy near the free surface is much more significant than that near the bed in the longitudinal direction, and the mean turbulent kinetic energy in the section would decrease in the longitudinal direction and the decreasing rate is smaller than that of the mean wall shear stress.

关键词： sluice gate turbulent flow sco.ring process mechanical energy loss

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Assessment of impact of water diversion projects on eco.ogical water uses in arid region

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Water Science and engineering 2013年第2期6卷 119-130页

作者： Song-hao SHANG Hui-jie WANG State Key Laboratory of Hydroscience and engineering Tsinghua University Yellow River engineering consulting co. Ltd.

In arid regions, large-scale water diversion from rivers leads to significant changes in river flow regimes, which may have large impacts on eco.ogical water uses of river-dependent eco.ystems, such as river, lake, wetland, and riparian eco.ystems. To assess the integrated impact of water diversion on eco.ogical water uses, we proposed a hierarchy evaluation model co.posed of four layers representing the evaluation goal, sub-areas of the influenced region, evaluation criteria, and water diversion schemes, respectively. The evaluation criteria for different types of eco.ogical water uses were proposed, and the analytical hierarchy process was used for the integrated assessment. For a river eco.ystem, the percentage of mean annual flow was used to define the grade of environmental flow. For a lake eco.ystem, water recharge to the lake to co.pensate the lake water losses was used to assess the eco.ogical water use of a lake. The flooding level of the wetland and the groundwater level in the riparian plain were used to assess the wetland and riparian eco.ogical water uses, respectively. The proposed model was applied to a basin in northern Xinjiang in northwest China, where both water diversion and inter-basin water transfer projects were planned to be carried out. Based on assessment results for the whole study area and two sub-areas, an appropriate scheme was reco.mended from four planning schemes. With the reco.mended scheme, eco.ogical water uses of the influenced eco.ystems can be maintained at an acceptable level. Meanwhile, eco.omical water requirements can be met to a great extent.

关键词： arid region water diversion project environmental impact assessment eco.ogical water use environmental flow riparian forest analytic hierarchy process

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