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Polymer: Non-fullerene acceptor heterojunction-based phototransistor for short-wave infrared photodetection

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Nano Research 2024年第4期17卷 3087-3095页

作者： Jing Li Weigang Zhu Yang Han Yanhou Geng Wenping Hu key laboratory of Organic Integrated Circuits of Ministry of Education&key laboratory of molecular optoelectronic sciences School of Science&Collaborative Innovation Center of Chemical Science and Engineering(Tianjin)Tianjin UniversityTianjin 300072China key laboratory of Organic Integrated Circuits of Ministry of Education&key laboratory of molecular optoelectronic sciences School of Materials Science and EngineeringTianjin UniversityTianjin 300072China

It remains full of challenge for extending short-wave infrared(SWIR)spectral response and weak-light detection in the context of broad spectral responses for phototransistor.In this work,a novel poly(2,5-bis(4-hexyldodecyl)-2,5-dihydro-3,6-di-2-thienyl-pyrrolo[3,4-c]pyrrole-1,4-dione-alt-thiophene)(PDPPT3-HDO):COTIC-4F organic bulk-heterojunction is prepared as active layer for bulk heterojunction phototransistors.PDPPT3-HDO serves as a hole transport material,while COTIC-4F enhances the absorption of SWIR light to 1020 nm.As a result,smooth and connected PDPPT3-HDO film is fabricated by blade coating method and exhibits high hole mobility up to 2.34 cm^(2)·V^(-1)·s^(-1) with a current on/off ratio of 4.72×10^(5) in organic thin film transistors.PDPPT3-HDO:COTIC-4F heterojunction phototransistors exhibit high responsivity of 2680 A·W^(-1) to 900 nm and 815 A·W^(-1) to 1020 nm,with fast response time(rise time~20 ms and fall time~100 ms).The photosensitivity of the heterojunction phototransistor improves as the mass ratio of non-fullerene acceptors increases,resulting in an approximately two orders of magnitude enhancement compared to the bare polymer phototransistor.Importantly,the phototransistor exhibits decent responsivity even under ultra-weak light power of 43μW·cm^(-2) to 1020 nm.This work represents a highly effective and general strategy for fabricating efficient and sensitive SWIR light photodetectors.

关键词： photodetection phototransistor organic semiconductor heterojunction non-fullerene acceptor

Dihydroanthracene bridged bis-naphthopyrans:A multimodal chromophore with mechano-and photo-chromic properties

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Chinese Chemical Letters 2024年第5期35卷 166-170页

作者： Yanbing Shen Yuan Yuan Yaxin Wang Xiaonan Ma Wensheng Yang Yulan Chen Institute of molecular Plus Tianjin UniversityTianjin 300072China Department of Chemistry Tianjin Key Laboratory of Molecular Optoelectronic ScienceTianjin UniversityTianjin 300354China State key laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China

Mechanochromophores based on bichromic molecular switches,such as bis-naphthopyanes,allow multimodal mechanochromic behavior beyond the typical binary response from single chromophores,which is important for distinguishing between multiple stress states through discrete changes in color.Spontaneously generated persistent and distinguishable multi-colors from activated bis-naphthopyanes remain challenging.And the versatility of bis-mechanophore design for advanced optical molecular systems and the fundamental insights into the corresponding mechano-reactivity are not enough.Here,we identify a dihydroanthracene bridged bis-naphthopyrans as a multimodal mechanochromophore in polymers.Bridging two pyrans with the sterically constrained dihydroanthracene is helpful to control the steric effect for the favorable formation of a distinctly appreciable bis-merocyanine(bis-MC)product.By varying the length of the polymer chains,the force delivered to the mechanophore is modulated,resulting in a gradient change in the relative distribution of two distinctly colored MC products and a multicolor mechanochromism.Mechanical activation of this bis-naphthopyanes proceeds via a mechanistically distinct pathway compared to the photochemical process.In addition,the bulk films can also achieve pronounced color changes when subjected to mechanical force.This study thus further expands the molecular diversity of mechanochromophores and tune the multimodal switch properties of bis-naphthopyrans based polymers.

关键词： Mechanochromic Photochromic Naphthopyan Multicolor Dihydroanthracene

Thermoelectric Properties of an Indandione-Terminated Quinoidal Compound:Effect of the n-Type Dopants

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Chinese Journal of Chemistry 2024年第9期42卷 997-1003页

作者： Yingying Liu Cheng Wang Tianzuo Wang Fei Jiao Shaoqiang Dong Yunfeng Deng Yanhou Geng School of Materials Science and Engineering and tianjin key laboratory of molecular optoelectronic Science Tianjin Universityand Collaborative Innovation Center of Chemical Science and Engineering(Tianjin)Tianjin 300072China Institute of molecular Aggregation Science Tianjin UniversityTianjin 300072China tianjin key laboratory of molecular optoelectronic Science Department of ChemistrySchoolof ScienceTianjin UniversityTianjin300072China Joint Schoolof NationalUniversity of Singapore and tianjin University International Campus of Tianjin UniversityBinhai New City FuzhouFujian350207China

The investigation of n-type doping holds a significant interest for the application of thermoelectrics.Herein,the doping of an indandione-terminated compound Q-4F with a singlet open-shell ground state was studied using two n-dopants N-DMBI and LCV.Both of these two dopants can effectively dope Q-4F due to the large offset between the singly occupied molecular orbital(SOMO)of dopants and the lowest unoccupied molecular orbital(LUMO)of Q-4F.N-DMBI has a higher doping ability than LCV as demonstrated by the UV-vis-NIR and EPR measurements.However,in comparison to N-DMBI doped Q-4F,LCV doped system exhibits much higher electrical conductivity and power factor due to its unperturbed molecular packing and favorable morphology after doping.The optimal conductivity of LCV doped Q-4F is 7.16×10^(-2)±0.16 S·cm^(-1) and the highest power factor reaches 12.3±0.85μW·m–1·K^(-2).These results demonstrate that the modulation of n-dopants is a powerful strategy to balance the doping efficiency and microstructure toward a maximum thermoelectric performance.

关键词： n-Doping Indandione Quinoidal compounds Organic thermoelectrics Electron transfer Organic electronics Energy conversion

Ultrafast micro/nano-manufacturing of metastable materials for energy

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National Science Review 2024年第4期11卷 283-298页

作者： Xiaoya Cui Yanchang Liu Yanan Chen School of Materials Science and Engineering Key Laboratory of Advanced Ceramics and Machining Technology(Ministry of Education) and Tianjin Key Laboratory of Composite and Functional MaterialsTianjin University Ministry of Education key laboratory of Protein sciences School of Life SciencesTsinghua University

The structural engineering of metastable nanomaterials with abundant defects has attracted much attention in energy-related fields. The high-temperature shock(HTS) technique, as a rapidly developing and advanced synthesis strategy, offers significant potential for the rational design and fabrication of high-quality nanocatalysts in an ultrafast, scalable, controllable and eco-friendly way. In this review, we provide an overview of various metastable micro-and nanomaterials synthesized via HTS, including single metallic and bimetallic nanostructures, high entropy alloys, metal compounds(e.g. metal oxides) and carbon nanomaterials. Note that HTS provides a new research dimension for nanostructures, i.e. kinetic modulation. Furthermore, we summarize the application of HTS—as supporting films for transmission electron microscopy grids—in the structural engineering of 2D materials, which is vital for the direct imaging of metastable materials. Finally, we discuss the potential future applications of high-throughput and liquid-phase HTS strategies for non-equilibrium micro/nano-manufacturing beyond energy-related fields.It is believed that this emerging research field will bring new opportunities to the development of nanoscience and nanotechnology in both fundamental and practical aspects.

关键词： high-temperature shock technique defect engineering metastable phase kinetic modulation non-equilibrium micro/nano-manufacturing

High-timing-precision detection of single X-ray photons by superconducting nanowires

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National Science Review 2024年第1期11卷 194-203页

作者： Shuya Guo Jingrou Tan Hengbin Zhang Jinguang Wang Tianhao Ji Labao Zhang Xiaolong Hu Jian Chen Jun Xie Kai Zou Yun Meng Xiaomin Bei Ling-An Wu Qi Chen Hao Wang Xuecou Tu Xiaoqing Jia Qing-Yuan Zhao Lin Kang Peiheng Wu Research Institute of Superconductor Electronics Nanjing University Qian Xuesen laboratory of Space Technology Beijing National laboratory of Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Hefei National laboratory School of Precision Instrument and optoelectronic Engineering Tianjin University key laboratory of optoelectronic Information Science and Technology Ministry of Education

Precisely acquiring the timing information of individual X-ray photons is important in both fundamental research and practical applications. The timing precision of commonly used X-ray single-photon detectors remains in the range of one hundred picoseconds to microseconds. In this work, we report on high-timing-precision detection of single X-ray photons through the fast transition to the normal state from the superconductive state of superconducting nanowires. We successfully demonstrate a free-running X-ray single-photon detector with a timing resolution of 20.1 ps made of 100-nm-thick niobium nitride film with an active area of 50 μm by 50 μm. By using a repeated differential timing measurement on two adjacent X-ray single-photon detectors, we demonstrate a precision of 0.87 ps in the arrival-time difference of X-ray photon measurements. Therefore, our work significantly enhances the timing precision in X-ray photon counting, opening a new niche for ultrafast X-ray photonics and many associated applications.

关键词： single-photon detection timing precision superconductor ultrafast phenomenon pulsar X-ray navigation

Interfacial molecular screening of polyimide dielectric towards high-performance organic field-effect transistors

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Chinese Chemical Letters 2024年第2期35卷 268-271页

作者： Yingshuang Zheng Huchao Li Ting Jiang Fei Jiao Jie Li Yong Lei Guofeng Tian Jinshun Bi Yundong Xuan Liqiang Li Deyang Ji Wenping Hu Department of Chemistry Tianjin Key Laboratory of Molecular Optoelectronic SciencesInstitute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China GPL Photonics laboratory State Key Laboratory of Applied OpticsChangchun Institute of OpticsFine Mechanics and PhysicsChinese Academy of SciencesChangchun 130033China Haihe laboratory of Sustainable Chemical Transformations Tianjin 300192China Department of Chemistry Tianjin Key Laboratory of Molecular Optoelectronic SciencesSchool of ScienceCollaborative Innovation Center of Chemical Science and EngineeringTianjin UniversityTianjin 300072China Joint School of National University of Singapore and tianjin University Fuzhou 350207China Fachgebiet Angewandte Nanophysik Institut für Physik & IMN MacroNanoTechnische Universität IlmenauIlmenau 98693Germany State key laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Institute of Microelectronics Chinese Academy of SciencesBeijing 100029China University of Chinese Academy of sciences Beijing 100101China

The compatibility of the gate dielectrics with semiconductors is vital for constructing efficient conducting channel for high charge transport.However,it is still a highly challenging mission to clearly clarify the relationship between the dielectric layers and the chemical structure of semiconductors,especially vacuum-deposited small molecules.Here,interfacial molecular screening of polyimide(Kapton)dielectric in organic field-effect transistors(OFETs)is comprehensively studied.It is found that the semiconducting small molecules with alkyl side chains prefer to form a high-quality charge transport layer on polyimide(PI)dielectrics compared with the molecules without alkyl side chains.On this basis,the fabricated transistors could reach the mobility of 1.2 cm^(2) V^(−1)s^(−1) the molecule with alkyl side chains on bare PI dielectric.What is more,the compatible semiconductor and dielectric would further produce a low activation energy(E_(A))of 3.01 meV towards efficient charge transport even at low temperature(e.g.,100 K,0.9 cm^(2) V^(−1)s^(−1)).Our research provides a guiding scheme for the construction of high-performance thin-film field-effect transistors based on PI dielectric layer at room and low temperatures.

关键词： Interfacial molecular screening Polyimide dielectrics Organic semiconductors Interface engineering Thin-film transistors

Rational Design of Capping Ligands of Quantum Dots for Biosensing

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Chemical Research in Chinese Universities 2024年第2期40卷 162-172页

作者： XU Xinran LIU An-an PANG Daiwen State key laboratory of Medicinal Chemical Biology Tianjin Key Laboratory of Biosensing and Molecular RecognitionResearch Center for Analytical SciencesCollege of ChemistryNankai UniversityTianjin300071P.R.China

Quantum dots have been widely applied in biosensing due to their outstanding optical properties.The emissions of quantum dots are mainly determined by their composition and size,as described by the Brus’s equation.Somehow,in this case,their emissions are hardly regulated reversibly and responsively,which are unsuitable for biosensing and biodetection.In the last decade,capping ligands have been used for designing biosensors because of their responsive regulation on the photoluminescence of quantum dots.Here,we first summarize the advances in characterization and calculation specific for ligands,which have helped to provide insights into the photoluminescence process and energy band theory of quantum dots.We then review two ways of ligand design that influence the optical properties of quantum dots:affecting the process of photoluminescence,or the orbital/electronic structure.In the latter case,the atoms on both the ligand and the surface of the quantum dot interact to affect the energy band structure of the quantum dot core.Examples are presented of how these quantum dots that possess responsive properties due to the design of the ligands have been applied to sensing.With further exploration,we hope to see advances in the fundamental understanding of the energy band structures and practical applications of these quantum dots.

关键词： Quantum dot Ligand Photoluminescence Responsiveness Sensor

Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves

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CCS Chemistry 2024年第1期6卷 208-217页

作者： Xiaoyu Song Chao Jin Hongliang Chen Shuaishuai Ding Zhongyi Liu Yang Li Xiaoli Yan Wenbo Mi Long Chen Wenping Hu Department of Chemistry Tianjin Key Laboratory of Molecular Optoelectronic ScienceTianjin UniversityTianjin 300072 School of Chemistry and Chemical Engineering Yantai UniverisityYantaiShandong 264005 tianjin key laboratory of Low Dimensional Materials Physics and Processing Technology School of ScienceTianjin UniversityTianjin 300072 State key laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchunJilin 130012

Interface engineering in device fabrication is a significant but complicated issue.Although great successes have been achieved by conventional physical in situ or ex situ methods,it still suffers from complicated procedures.In this work,we present a facile method for fabricating phthalocyanine(Pc)-based two-dimensional conductive metal–organic framework(MOF)films.Based on PcM-Cu(M=Ni,Cu,H_(2))MOF films,spin valves with a vertical configuration of La_(0.67)Sr_(0.33)MnO_(3)/PcM-Cu MOFs/Co were constructed successfully,and exhibited notably high negative magnetoresistance(MR)up to -22% at 50 K.The penetrated Co atoms coordinated with the dehydrogenated hydroxy groups in the MOFs resulting in an antiferromagnetic layer of the PcM-Cu-Co hybrid structure.Interestingly,a significant exchange bias effect was demonstrated at the PcM-Cu MOF/Co interface,beneficial for the MR behavior.Thus,our present study provides new insights into developing high-performance organic spin valves via de novo molecular design.

关键词： two-dimensional conductive metal-organic framework two-dimensional polymer phthalocyanine spintronics organic spin valve

基于基态和激发态之间跃迁过程的DBTTF-TCNB共晶的光热转换机制

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Science China Materials 2024年第1期67卷 242-250页

作者：付思姚何旦张小涛 key laboratory of Organic Integrated Circuits Ministry of Education&Tianjin Key Laboratory of Molecular Optoelectronic SciencesDepartment of ChemistrySchool of ScienceTianjin UniversityTianjin 300072China key laboratory of Organic Integrated Circuits Ministry of Education&Tianjin Key Laboratory of Molecular Optoelectronic SciencesDepartment of ChemistryInstitute of Molecular Aggregation ScienceTianjin UniversityTianjin 300072China College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083China

有机共晶,由于其光热转换性质,为光热成像、生物应用和海水淡化等诸多领域带来了希望和活力.然而,有机共晶的光热转换机制尤其缺少详细且深入的理论研究.本研究使用含时密度泛函理论方法探索了激发和去激发过程,并解释了DBTTF-TCNB共晶... 详细信息

有机共晶,由于其光热转换性质,为光热成像、生物应用和海水淡化等诸多领域带来了希望和活力.然而,有机共晶的光热转换机制尤其缺少详细且深入的理论研究.本研究使用含时密度泛函理论方法探索了激发和去激发过程,并解释了DBTTF-TCNB共晶比其组分单晶具有更高光热转换效率的原因.结果显示,高激发态的高占比促进了非辐射跃迁的发生.基于DBTTF-TCNB共晶中给电子基团和吸电子基团间的电荷转移结果,我们发现给体和受体之间吸引电子的竞争可能会促进光热转换,且给电子基团在共晶结构中也十分重要.这些结果可为光热转换共晶的设计提供理论指导.轨道贡献和电子密度差进一步证明了我们的结论.因此,本研究从量子化学的角度给光热共晶在创新领域的应用提供了理论依据.

关键词：光热转换含时密度泛函理论激发过程生物应用吸电子基团非辐射跃迁高激发态共晶结构