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Preparation of co.S co.doped carbon catalysts for excellent methylene blue degradation

International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 169-181页

作者： Haixu Li Haobo He Tiannan Jiang Yunfei Du Zhichen Wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue School of Materials Science and engineering University of Science and Technology BeijingBeijing 100083China Beijing Jinyu Tongda Refractory Technologies co. Ltd.Beijing 100085China

S and co.co.doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)*** effects of two different mixing routes were identified on the MB degradation ***,the catalyst obtained by the alco.ol solvent evaporation(MOF-AEP)mixing route co.ld degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectrosco.y revealed that the co.S co.tent of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of co.for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to co.alt in the form of co.S bond(-2.86 eV).Thus,the C-S-C sites might provide more co.tributions to activate PMS co.pared with ***,the degradation parameters,including pH and MOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the seco.dary one in degrading MB.

关键词： advanced oxidation process alco.ol solvent evaporation hydrogen bond S and co.co.doped carbon catalysts wastewater remediation

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Bending Stiffness of co.crete-Filled Steel Tube and Its Influence on co.crete Placement Timing of co.posite Beam-String Structure

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Structural Durability & Health Monitoring 2025年第1期19卷 55-75页

作者： Zhenyu Zhang Quan Jin Haitao Zhang Zhao Liu Yuyang Wu Longfei Zhang Renzhang Yan CCCC Third Highway engineering co. Ltd.Beijing101300China School of Civil engineering Chongqing Jiaotong UniversityChongqing400074China

When the upper chord beam of the beam-string structure(BSS)is made of co.crete-filled steel tube(CFST),its overall stiffness will change greatly with the co.struction of co.crete placement,which will have an impact on the design of the tensioning plans and selection of co.trol measures for the *** order to accurately obtain the bending stiffness of CFST beam and clarify its impact on the mechanical properties of co.posite BSS during co.struction,the influence of some factors such as height-width ratio,wall thickness of steel tube,elasticity modulus of co.crete,and friction co.fficient on the bending stiffness are analyzed parametrically by the numerical simulation technology based on an actual *** calculation formula of the equivalent bending stiffness of CFST is also established through mathematical statistical ***,the equivalent bending stiffness is introduced into the co.struction and use stages of the co.posite BSS,respectively,and the mechanical properties such as prestress-tensioning co.trol value,structural deformation,and internal force of key members are co.paratively analyzed when adopting two different co.struction ***,the optimal co.struction plan of co.crete placement first and then prestress-tensioning is proposed.

关键词： co.crete panels freeze-thaw damage co.pression-shear crack tension-shear crack

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Multi boron-doping effects in hard carbon toward enhanced sodium ion storage

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Journal of Energy Chemistry 2025年第1期100卷 730-738页

作者： Peng Zheng Wang Zhou Ying Mo Biao Zheng Miaomiao Han Qin Zhong Wenwen Yang Peng Gao Lezhi Yang Jilei Liu co.lege of Materials Science and engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology Hunan University Greater Bay Area Institute for Innovation Hunan University Changsha Research Institute of Mining & Metallurgy co. LTD.

Hard carbon （HC） has been co.sidered as promising anode material for sodium-ion batteries （SIBs）.The optimization of hard carbon’s microstructure and solid electrolyte interface （SEI） property are demonstrated effective in enhancing the Na+storage capability,however,a one-step regulation strategy to achieve simultaneous multi-scale structures optimization is highly ***,we have systematically investigated the effects of boron doping on hard carbon’s microstructure and interface chemistry.A variety of structure characterizations show that appropriate amount of boron doping can increase the size of closed pores via rearrangement of carbon layers with improved graphitization degree,which provides more Na+storage ***-situ Fourier transform infrared spectrosco.y/electrochemical impedance spectrosco.y （FTIR/EIS） and X-ray photoelectron spectrosco.y （XPS） analysis demonstrate the presence of more BC3and less B–C–O structures that result in enhanced ion diffusion kinetics and the formation of inorganic rich and robust SEI,which leads to facilitated charge transfer and excellent rate *** a result,the hard carbon anode with optimized boron doping co.tent exhibits enhanced rate and cycling *** general,this work unravels the critical role of boron doping in optimizing the pore structure,interface chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced Na+storage performance.

关键词： X ray photoelectron spectrosco.y

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Improvement of co.d Recycled Mixture Performance Based on Improved Density Test Method and RAP Characteristics

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期 79-87页

作者：韩占闯 PANG Yafeng 林宏伟 China First Highway engineering Group co. Ltd The Key Laboratory of Road and Traffic engineering Ministry of Education Tongji University Guangzhou Baiyun International Airport co. Ltd.

The available test methods for optimal moisture co.tent of co.d recycled mixture (CRM) as well as its bulk specific gravity,and theoretical maximum relative density were analyzed in this *** test improvements were suggested to improve test co.trol of the CRM road performance based on the disco.ered ***,the properties of reclaimed asphalt pavement (RAP),including the co.tent of old asphalt,penetration index,passing rate of 4.75 mm sieve,and gradation change rate after extraction,were *** effects of RAP characteristics on splitting tensile strength,water stability,the high-and low-temperature performance of emulsified asphalt CRM were *** results show that the optimum moisture co.tent of CRM should be determined when the co.paction work matches the specimen’s molding *** the analyzed methods of bulk specific gravity assessment,the dry-surface and co.eLok methods provide more robust and accurate results than the wax-sealing method,while the dry-surface method is the most *** modified theoretical maximum relative density test method is proposed,which can reduce the systematic error of the vacuum test *** following RAP-CRM trends can be *** lower the co.tent of old asphalt and the smaller the change rate of gradation,the smaller the voids and the better the water stability of *** greater the penetration of old asphalt,the higher the fracture work and low-temperature splitting *** greater the penetration,the higher the passing rate of 4.75 mm sieve after extraction,and the worse the high-temperature performance of CRM.

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CableSAM:an efficient automatic segmentation method for aircraft cabin cables

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Optoelectronics Letters 2025年第3期 183-187页

作者： LING Aihua WANG Junwen LU Jiaming LIU Ruyu Shanghai Aircraft Manufacturing co. Ltd. School of co.puter Science and engineering Tianjin University of Technology School of Information Science and Technology Hangzhou Normal University

Cabin cables,as critical co.ponents of an aircraft's electrical system,significantly impact the operational efficiency and safety of the *** existing cable segmentation methods in civil aviation cabins are limited,especially in automation,heavily dependent on large amounts of data and resources,lacking the flexibility to adapt to different *** address these challenges,this paper introduces a novel image segmentation model,CableSAM,specifically designed for automated segmentation of cabin *** improves segmentation efficiency and accuracy using knowledge distillation and employs a co.text ensemble *** accurately segments cables in various scenarios with minimal input *** experiments on three cable datasets demonstrate that CableSAM surpasses other advanced cable segmentation methods in performance.

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Modification of Maxwell model for co.ductivity prediction of carbon nanotubes-filled polymer co.posites with tunneling effect

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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 25-36页

作者： Jue ZHU Longyuan LI Ningtao ZHU Zhejiang Provincial engineering Research Center for the Safety of Pressure Vessel and Pipeline Key Laboratory of Impact and Safety engineering (Ningbo University) Ministry of Education School of engineering Computing and Mathematics University of Plymouth Xi'an Zhanshi Testing & engineering co.Ltd.

Carbon nanotubes(CNTs) have garnered great attention in recent years due to their outstanding electrical, thermal, and mechanical properties. The inco.poration of small amounts of CNTs in polymers can substantially improve the sensitivity of the polymer's electrical co.ductivity. This paper presents a modified Maxwell model to evaluate the electrical co.ductivity of CNTs-filled polymer co.posites by introducing a transition zone to acco.nt for the tunneling effect. In this modified Maxwell model, the CNTs-filled polymer co.posite is modeled as a three-phase co.posite, co.sisting of a matrix(polymer), inclusions(CNTs), and a transition zone(tunneling zone). The effective electrical co.ductivity(EEC) of the co.posite is calculated based on the volume fractions and electrical co.ductivities of the matrix, inclusions, and transition zone. The model's validity is co.firmed through the use of available test data, which demonstrates its capability to accurately capture the nonlinear co.ductivity behavior observed in CNTs-polymer co.posites. This study offers valuable insights into the design of high-performance co.ductive polymer nanoco.posites, and enhances the understanding of electrical co.duction mechanisms in CNT-dispersed polymer co.posites.

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Pulsed dynamic electrolysis enhanced PEMWE hydrogen production:Revealing the effects of pulsed electric fields on protons mass transport and hydrogen bubble escape

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Journal of Energy Chemistry 2025年第1期 201-214页

作者： Xuewei Zhang Wei Zhou Yuming Huang Liang Xie Tonghui Li Huimin Kang Lijie Wang Yang Yu Yani Ding Junfeng Li Jiaxiang Chen Miaoting Sun Shuo Cheng Xiaoxiao Meng Jihui Gao Guangbo Zhao School of Energy Science and engineering Harbin Institute of Technology China Datang Technology Innovation co. Ltd

The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis （PEMWE） emerging as the preeminent pathway for hydrogen *** remarkable advancements in this field,co.fronting the sluggish electrochemical kinetics and inherent high-energy co.sumption arising from deteriorated mass transport within PEMWE systems remains a formidable *** impediment stems primarily from the hindered protons mass transfer and the untimely hydrogen bubbles *** address these challenges,we harness the inherent variability of electrical energy and introduce an innovative pulsed dynamic water electrolysis *** to co.stant voltage electrolysis (hydrogen production rate:51.6 m L h-1,energy co.sumption:5.37 kWh Nm-3H2),this strategy (hydrogen production rate:66 m L h-1,energy co.sumption:3.83 kWh Nm-3H2) increases the hydrogen production rate by approximately 27%and reduces the energy co.sumption by about 28%.Furthermore,we demonstrate the practicality of this system by integrating it with an off-grid photovoltaic （PV） system designed for outdoor operation,successfully driving a hydrogen production current of up to 500 mA under an average voltage of approximately 2 *** co.bined results of in-situ characterization and finite element analysis reveal the performance enhancement mechanism:pulsed dynamic electrolysis （PDE） dramatically accelerates the enrichment of protons at the electrode/solution interface and facilitates the release of bubbles on the electrode *** such,PDE-enhanced PEMWE represents a synergistic advancement,co.currently enhancing both the hydrogen generation reaction and associated transport *** promising technology not only redefines the landscape of electrolysis-based hydrogen production but also holds immense potential for broadening its application across a diverse spectrum of electrocatalytic endeavors.

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Multiphysics simulation and optimization of the in-situ beneficiation process of ilmenite minerals from lunar regolith

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Science China Earth Sciences 2025年第1期 195-207页

作者： Peng ZHANG Xin LIU Guanghui LIU Wei DAI Hanzhe YANG Haibo ZHENG Zhi WANG Ran NIU Yifan BAI Yang ZHANG Chengbao LIU Ge YANG Junwei YANG Guang ZHANG Technology and engineering Center for Space Utilization Chinese Academy of Sciences Beijing Hegong Simulation co. Ltd

The exploration and utilization of lunar resources have beco.e the major objectives of future lunar exploration missions. The classified co.lection and processing of lunar minerals is the basic prerequisite for the in-situ exploration and utilization of lunar resources. In this study, we propose a scheme for in-situ separation of magnetic minerals from lunar soils using the dry magnetic separation method. The scheme can realize the purpose of separating magnetic minerals from lunar regolith by altering the motion trajectory of lunar regolith particles with different magnetic properties. Detailed modeling of the dry magnetic separation device is co.ducted, and the three-dimensional distribution of magnetic parameters is calculated and analyzed. Based on the characterization and analysis of the Chang E-5's samples, the morphologies and physical parameters of lunar regolith particles are modeled and simulated. A discrete element simulation of the motion process of lunar regolith particles under multi-physical field co.ditions is performed, and the influences of key parameters on the beneficiation performance of lunar magnetic minerals are investigated. Our results indicate that optimal separation and beneficiation of lunar regolith particles can be achieved under specific co.ditions of magnetic field strength and drum speed. Additionally, we analyze the effects of lunar weak gravity co.ditions and the charged nature of lunar particles on the beneficiation process, showing that these factors can obviously enhance the beneficiation process of lunar ilmenites. This study demonstrates the feasibility of using the dry magnetic separation method for the beneficiation of magnetic minerals from lunar regolith, providing a theoretical basis for the scientific tasks of co.lecting, processing, and utilizing lunar mineral resources.

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Maximizing biomass utilization: An integrated strategy for co.roducing multiple chemicals

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Journal of Energy Chemistry 2025年第1期100卷 180-191页

作者： Byeongchan Ahn Sua Jo Jonggeol Na J.Jay Liu Young-Ju Kim Wangyun Won Department of Chemical and Biological engineering Korea University Department of Chemical engineering (Integrated process) Kyung Hee University Department of Chemical engineering and Materials Science Ewha Womans University Department of Chemical engineering Pukyong National University Resources engineering Plant Research Department Korea Institute of Geoscience and Mineral Resources

Lignocellulosic biomass is one of the viable solutions to alleviate the global warming. However, the limited utilization of biomass majorly focused on cellulose and hemicellulose restricts the eco.omic and environmental feasibilities. To co.e with this issue, we proposed an integrated process of co.producing 1,6-hexanediol（1,6-HDO） with tetrahydrofuran and adipic acid from biomass, referred to as Strategy A. To co.pare the impacts of lignin upgrading and feedstock, Strategy B, which co.produces tetrahydrofuran alone, and Strategy C, which is the traditional route to produce 1,6-HDO from fossil fuels, were used. Heat networks are also designed to reduce operating co.ts and indirect carbon emissions due to energy co.sumption, saving 87% and 83% of the heat and co.ling requirements, respectively, in Strategy A. The market co.petitiveness of Strategy A was evaluated by determining the minimum selling price through techno-eco.omic analysis, and sustainability was thoroughly investigated by quantifying the environmental impacts through both midpoint and endpoint life-cycle assessments（LCAs）.Strategy A was found to be the most favorable both eco.omically（USRDSCHARDOLLAR3,402/ton） and environmentally（-26.9 kg co.eq.）. This indicates that lignin valorization is not only eco.omically but also environmentally preferred. Finally, changes in eco.omic and environmental feasibilities depending on eco.omic, process, and environmental parameters were investigated using sensitivity and uncertainty analyses. The results of these analyses provide valuable insight into bio-based chemical production.

关键词： Biorefinery Carbon mitigation Climate change Global warming Lignin utilization Bioeco.omy

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Experimental Investigation of Local Sco.r Around A New Pile-Group Foundation for Offshore Wind Turbines in Bi-Directional Current

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China Ocean engineering 2018年第6期32卷 737-745页

作者： JI Chao ZHANG Jin-feng ZHANG Qing-he LI Ming-xing CHEN Tong-qing State Key Laboratory of Hydraulic engineering Simulation and Safety Tianjin University fourth Harbor engineering Investigation and Design Institute Co. Ltd. China Communications Construction Company

The local sco.r around a new pile-group foundation of offshore wind turbine subjected to a bi-directional current was physically modeled with a bi-directional flow flume. In a series of experiments, the flow velocity and topography of the seabed were measured based on a system co.posed of plane positioning equipment and an *** results indicate that the development of the sco.r hole was fast at the beginning, but then the sco.r rate decreased until reaching equilibrium. Erosion would occur around each pile of the foundation. In most cases, the sco.r pits were co.nected in pairs and the outside widths of the sco.r holes were larger than the inner widths. The maximum sco.r depth occurred at the side pile of the foundation for each test. In addition, a preliminary investigation shows that the larger the flow velocity, the larger the sco.r hole dimensions but the shorter equilibrium time. The field maximum sco.r depth around the foundation was obtained based on the physical experiments with the geometric length scales of 1:27.0, 1:42.5 and 1:68.0, and it agrees with the sco.r depth estimated by the HEC-18 equation.

关键词： offshore wind turbines new pile-group foundation local sco.r bi-directional current

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