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Improved oxygen electrocatalysis at Fe N4 and Co N4 sites via construction of axial coordination

Chinese Chemical Letters 2025年第2期36卷 482-487页

作者： Ze Zhang Lei Yang Jin-Ru Liu Hao Hu Jian-Li Mi Chao Su Bei-Bei Xiao Zhi-Min Ao School of Energy and Power Engineering Jiangsu University of Science and Technology institute for Computation in Molecular and Materials Science School of Chemistry and Chemical Engineering Nanjing University of Science and Technology institute for Advanced Materials School of Materials Science and Engineering Jiangsu University Advanced Interdisciplinary institute of Environment and Ecology Beijing Normal University

The quest for efficient and durable catalysts using abundant resources has garnered significant interest in the field of bifunctional oxygen *** this contribution,we have designed a FeN4or CoN4embedded graphene-based bilayer as active layer and TMC3or TMN3doped graphene as supporting layer,named as FeN4/TMC3or FeN4/TMN3and CoN4/TMC3or CoN4/TMN3,wherein TM strands for transition *** on density functional theory calculations,our results demonstrate that the interaction formed between dual metal atoms in the bilayer interspace leads to the coordination environment altered from flat four-coordination to spatial five-coordination,further stabilizing the bilayer structure and impairing its affinity toward the O-containing *** to thermodynamic analysis,the bilayers of CoN4/CoN3,FeN4/FeC3,FeN4/CoC3,FeN4/NiC3,FeN4/ZnC3,FeN4/FeN3,FeN4/CrN3and FeN4/ZnN3are attractively promising for bifunctional oxygen electrocatalysis due to the small overpotential differenceΔη between oxygen reduction and oxygen evolution that are less than 1 *** functional theory calculations combined with machine learning analysis directly identify the key role played by the interbinding formed between bilayers,that boosts catalytic activity,which establishes a predictable framework for a fast screen for graphene-based bilayer vertical *** work opens up a new path for designing the efficient electrocatalysts via modification of coordination environment.

关键词： Density functional theory Machine learning Oxygen electrocatalysis Thermodynamic analysis

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Five-user quantum virtual local area network with an AlGaAs entangled photon source

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Science China(Physics,Mechanics & Astronomy) 2025年第3期68卷 61-73页

作者： Cheng Qian Hongkai Tian Xu Jing Yichen Liu Zhe Chen Huiran Luo Yuan Du Xiaodong Zheng Tangsheng Chen Yuechan Kong Hua-Lei Yin Dong Jiang Bin Niu Liangliang Lu Key Laboratory of State Manipulation and Advanced Materials in Provincial Universities School of Physical Science and TechnologyNanjing Normal UniversityNanjing210023China School of Internet Anhui UniversityHefei230039China National Key Laboratory of Solid-State Microwave Devices and Circuits Nanjing Chip Valley Industrial Technology InstituteNanjing Electronic Devices InstituteNanjing210016China Research Center for Quantum Optics and Quantum Communication School of ScienceQingdao University of TechnologyQingdao266520China Department of Physics and Beijing Key Laboratory of Opto-electronic Functional Materials and Micro-nano Devices Key Laboratory of Quantum State Construction and Manipulation(Ministry of Education)Renmin University of ChinaBeijing100872China Beijing Academy of Quantum Information Sciences Beijing100193China National Engineering Research Center of Agro-Ecological Big Data Analysis and Application Anhui UniversityHefei230601China National Laboratory of Solid-State Microstructures and School of Physics Nanjing UniversityNanjing210093China Hefei National Laboratory Hefei230088China

The promotion of quantum network applications demands the scalable connection of quantum *** is preferable to set up multiple logical networks coexisting on a single physical network infrastructure to accommodate a larger number of *** we present a quantum virtual network architecture that offers this level of scalability,without being constrained to a fixed physical-layer network relying solely on passive multiplexing *** architecture can be understood as arising from the superposition of a fully connected entanglement distribution network and port-based virtual local area network,which group multiusers by access *** terms of hardware,we leverage a semiconductor chip with a high figure-of-merit modal overlap to directly generate high-quality polarization entanglement,and a streamlined polarization analysis module,which requires only one single-photon detector for each end *** experimentally perform the BBM92 QKD protocol on the five-user quantum virtual network and demonstrate voice and image encryption on a campus area *** results may provide insights into the realization of large-scale quantum networks with integrated and cost-efficient photonic architecture.

关键词： quantum network quantum entanglement distribution integrated photonics image and voice encryption

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Experiments of Reconstructing Discrete Atmospheric Dynamic Models from Data (I)

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Advances in Atmospheric Sciences 1995年第1期12卷 121-125页

作者：林振山朱焰宇邓自旺 the climatic and global change institute of nanjing university Nanjing 210093

In this paper, we give some experimental results of our study in reconstructing discrete atmospheric dynamic models from data. After a great deal of numerical experiments, we found that the logistic map, xn +1= 1-uxn2 could be used in monthly mean temperature prediction when it was approaching the chaotic region, and its predictive results were in reverse states to the practical data. This means that the nonlinear developing behavior of the monthly mean temperature system is bifurcating back into the critical chaotic states from the chaotic ones.

关键词： Reconstruction Discrete dynamic model Chaos Bifurcation Logistic map

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Dynamic properties of low-density expandable polystyrene concrete materials

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Defence Technology(防务技术) 2025年第1期43卷 94-108页

作者： Jue Han Hualin Fan Army Engineering university of PLA Nanjing 210007China Research Center of Lightweight Structures and Intelligent Manufacturing State Key Laboratory of Mechanics and Control of Aerospace StructuresNanjing University of Aeronautics and AstronauticsNanjing 210016China Henan International Joint Laboratory of Dynamics of Impact and Disaster of Engineering Structures Department of Civil EngineeringNanyang Institute of TechnologyNanyang 473004China

Expanded polystyrene(EPS)concrete,known for its environmental friendliness,energy absorption capacity,and low impedance,has significant potential application in the fields of wave absorption and vibration *** study designed and prepared EPS concrete materials with four levels of ***-static uniaxial compression and Split Hopkinson Pressure Bar(SHPB)impact tests were conducted to obtain stress-strain curves,elastic moduli,failure modes,energy absorptions,and strain rate effects of the EPS concrete under quasi-static and dynamic loading *** influences of density on various performance indicators were *** combining the Zhu-Wang-Tang(ZWT)constitutive model with a modified elastic-brittle model,a modified dynamic constitutive model was *** accuracy of the model was validated by the experimental *** results indicate that the addition of EPS particles enhances the ductility of the EPS *** EPS concrete has significant strain rate effect,which gets stronger as density *** modifiedconstitutive model accurately characterizes the dynamic stress-strain curves of the EPS concrete.

关键词： EPS concrete Impact behavior Constitutive model SHPB test

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Compound hot drought events in the Mei-yu region:influences from polar and tropical regions

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Science Bulletin 2025年第2期70卷 273-282页

作者： Huixin Li Bo Sun Zhongshi Zhang Huijun Wang Yeran Zhou Jiani Zeng Botao Zhou Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters/Key Laboratory of Meteorological Disasters Ministry of Education/Joint International Research Laboratory of Climate and Environment ChangeNanjing University of Information Science and TechnologyNanjing 210044China Southern Marine Science and Engineering Guangdong Laboratory Zhuhai 519000China Nansen-Zhu International Research Centre Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China Department of Atmospheric Science School of Environmental StudiesChina University of GeosciencesWuhan 430074China School of Geographic Science Nantong UniversityNantong 226019China

In the Mei-yu region,there has been noticeable increase in the occurrence of compound hot drought(CHD)events in recent ***,the underlying causes of these occurrences remain poorly *** address this knowledge gap,we conducted a comprehensive study utilizing observational datasets,reanalysis datasets,and four numerical experiments to investigate the associated physical *** findings indicated that the prevalence of CHD events in the Mei-yu region is influenced strongly by two key factors:the decline in Barents Sea ice during February and the presence of a La Ni?alike pattern of sea surface temperature(SST)in *** decline in Barents Sea ice generates an anomalous Rossby wave in the Arctic that propagates *** La Ni?a-like SST pattern regulates a Rossby wave over western America,propagating along the subtropical jet *** two Rossby waves induce northward movement and strengthened intensity of the subtropical westerly jet in East *** local circulation patterns in the Mei-yu region are influenced by the position and intensity of the subtropical jet,leading to downward motion in accordance with the secondary circulation theory for high-altitude jet ***,these local circulation patterns might contribute to occurrence of CHD ***,our analysis revealed that the impact of Barents Sea ice and the La Ni?a-like SST pattern can explain approximately two-thirds of the mild CHD events in the Mei-yu region,and that the influence of each is relatively *** research underscores influences of polar–tropical systems on climate extremes in eastern Asia.

关键词： Compound hot drought events Mei-yu region June-July Barents Sea ice La Niña-like SST Respective and combined influences

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Association between Per and Polyfluoroalkyl Substance and Abdominal Fat Distribution:A Trait Spectrum Exposure Pattern and Structure-Based Investigation

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Biomedical and Environmental Sciences 2025年第1期38卷 3-14页

作者： Zhi Li Shilin Shan Chenyang Song Chengzhe Tao Hong Qian Qin Yuan Yan Zhang Qiaoqiao Xu Yufeng Qin Yun Fan Chuncheng Lu State Key Laboratory of Reproductive Medicine Center for Global HealthSchool of Public HealthNanjing Medical UniversityNanjing 211166JiangsuChina Key Laboratory of Modern Toxicology of Ministry of Education School of Public HealthNanjing Medical UniversityNanjing 211166JiangsuChina Department of Public Health Kangda College of Nanjing Medical UniversityLianyungang 222000JiangsuChina Department of Microbes and Infection School of Public HealthNanjing Medical UniversityNanjing 211166JiangsuChina

Objective To investigate the associations between eight serum per-and polyfluoroalkyl substances(PFASs)and regional fat depots,we analyzed the data from the National Health and Nutrition Examination Survey(NHANES)2011-2018 *** Multiple linear regression models were developed to explore the associations between serum PFAS concentrations and six fat compositions along with a fat distribution score created by summing the concentrations of the six fat *** associations between structurally grouped PFASs and fat distribution were assessed,and a prediction model was developed to estimate the ability of PFAS exposure to predict obesity *** Among females aged 39-59 years,trunk fat mass was positively associated with perfluorooctane sulfonate(PFOS).Higher concentrations of PFOS,perfluorohexane sulfonate(PFHxS),perfluorodecanoate(PFDeA),perfluorononanoate(PFNA),and n-perfluorooctanoate(n-PFOA)were linked to greater visceral adipose tissue in this *** men,exposure to total perfluoroalkane sulfonates(PFSAs)and long-chain PFSAs was associated with reductions in abdominal fat,while higher abdominal fat in women aged 39-59 years was associated with short-chain *** prediction model demonstrated high accuracy,with an area under the curve(AUC)of 0.9925 for predicting obesity *** PFAS exposure is associated with regional fat distribution,with varying effects based on age,sex,and PFAS *** findings highlight the potential role of PFAS exposure in influencing fat depots and obesity risk,with significant implications for public *** prediction model provides a highly accurate tool for assessing obesity risk related to PFAS exposure.

关键词： Per-and polyfluoroalkyl substances Regional fat depots Obesity Structure-based NHANES

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Quercus acutissima exhibits more adaptable water uptake patterns in response to seasonal changes compared to Pinus massoniana

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Forest Ecosystems 2025年第1期12卷 29-37页

作者： Suimeng Zhang Xiaodi Wang Zhaowang Huang YiTao Bao Jiang Jiang Ziqiang Liu Yinshanbeilu Grassland Eco-hydrology National Observation and Research Station China Institute of Water Resources and Hydropower ResearchBeijing100038China Co-Innovation Center for Sustainable Forestry in Southern China Nanjing Forestry UniversityNanjing 210037China

Background:Seasonal precipitation variability significantly affects water use in forests;however,whether water uptake is adapted to changes in precipitation,particularly whether it could affect the coexistence of tree species,has rarely been quantified in forest ***:In this study,dual stable isotopes and the Li-6400 portable photosynthesis system were used to determine the water sources of a mixed conifer(Pinus massoniana)and broadleaf(Quercus acutissima)forest and changes in hydraulic characteristics during the dry and wet seasons in a southern hilly region of ***:Although the hydraulic characteristics of *** were lower than those of ***,it maintained a stable water source from the deep soil layer and a higher stomatal conductance(Gs),leading to a higher transpiration rate(Tr)during the growing *** mainly absorbed water from deeper soil layers in the dry season and took up from shallow soil layers in the wet *** Gs values exhibited sensitivity to precipitation,while it maintained a lower Tr value during the growing *** excessive water-use strategy observed in *** may confer weak drought-tolerance during higher frequency and more intense extreme precipitation events,whereas *** may exhibit better ecological adaption to precipitation ***:The overlap of water niches in mixed forests did not appear to affect the coexistence of tree *** present study provides insights into reforestation and water management in the southern hilly regions of China.

关键词： Water use Transpiration Stable isotope Hydraulic characteristics

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The CmCYC2 factors regulated the different biosynthesis and distribution of phenolic compounds in the capitulum of Chrysanthemum morifolium‘Hangju’

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Horticultural Plant Journal 2025年第1期11卷 336-350页

作者： Feng Yang Qiaosheng Guo Qingjun Zou Man Zhang Yong Su Shuyan Yu Jingzhe Pu Tao Wang institute of Chinese Medicinal Materials Nanjing Agricultural UniversityNanjingJiangsu 210095China NMPA Key Laboratory for Quality Research and Evaluation of Traditional Chinese Medicine Anhui Institute for Food and Drug ControlHefeiAnhui 230051China

Chrysanthemum morifolium *** an important industrial crop with a high medicinal value,whose capitulum consists of ray and disc florets containing numerous bioactive components,such as flavonoids and phenolic ***,the distribution and accumulations of the bioactive metabolites in florets of Chrysanthemum morifolium were ***,the ray and disc florets of Chrysanthemum morifolium were separated for comparing the bioactive *** contents of phenolic compounds and antioxidant activities were significantly different between the two *** metabolomic analysis identified 203 and 241 differential metabolites between ray and disc florets at two flowering *** derivatives of quercetin,isorhamnetin,tricin,and caffeoylquinic acid were enriched in the disc florets,while apigenin,kaempferol,acacetin,and their glycosides mainly accumulated in the ray ***,the results of transcriptome and qRT-PCR suggested that the F3H,F3'H,and FLS genes highly expressed in disc florets,while the FNS gene was well expressed in ray florets,which explained the different distribution of phenolic compounds between ray and disc ***,the expression of CmCYC2 genes was found to be significantly related to the distribution of flavones by correlation *** was proved by the luciferase reporter assay that CmCYC2a and CmCYC2d factors could bind and activate the CmFNS promoter to regulate the flavones biosynthesis in ray *** results revealed the significant difference of metabolite contents and gene expression profile between ray and disc floret in Chrysanthemum morifolium and demonstrated that the quality of Chrysanthemum morifolium‘Hangju'was closely relevant to its flower morphology.

关键词： Chrysanthemum morifolium Ramat. Ray florets Disc florets Multi-omics analysis Flavonoids Phenolic acids

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Influence of material characteristics on the failure mode and process of landslide dam

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Journal of Mountain Science 2025年第1期22卷 89-109页

作者： HU Liang ZHONG Qiming CHEN Liang YANG Meng ZHANG Lucheng WU Hao College of Civil and Transportation Engineering Hohai UniversityNanjing 210098China Department of Geotechnical Engineering Nanjing Hydraulic Research Institute National Key Laboratory of Water Disaster Prevention Nanjing 210098China Key Laboratory of Reservoir and Dam Safety of the Ministry of Water Resources Nanjing 210029China

Landslide dams,as frequent natural hazards,pose significant risks to human lives,property,and ecological *** grading characteristics and density of dam materials play a crucial role in determining the stability of landslide dams and the potential for dam *** explore the failure mechanisms and evolutionary processes of landslide dams with varying soil properties,this study conducted a series of flume experiments,considering different grain compositions and material *** results demonstrated that grading characteristics significantly influence landslide dam stability,affecting failure patterns,breach processes,and final breach ***-graded materials exhibited a sequence of surface erosion,head-cut erosion,and subsequent surface erosion during the breach process,while well-graded materials typically experienced head-cut erosion followed by surface *** coarse-graded dams,the high permeability of coarse particles allowed the dam to remain stable,as inflows matched *** dam breach model experiments also showed that increasing material density effectively delayed the breach and reduced peak breach flow ***,higher fine particle content led to a reduction in the residual dam height and the base slope of the final breach profile,although the relationship between peak breach discharge and the content of fine and coarse particles was *** better understand breach morphology evolution under different soil characteristics and hydraulic conditions,three key points were identified—erosion point,control point,and scouring *** study,by examining the evolution of failure patterns,breach processes,and breach flow discharges under various grading and density conditions,offers valuable insights into the mechanisms behind landslide dam failures.

关键词： Landslide dams Overtopping Grain size distribution Breaching process Outflow discharge

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Molecular-based porous polymers with precise sites for photoreduction of carbon dioxide

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Chinese Chemical Letters 2025年第1期36卷 201-213页

作者： Wei-Jia Wang Kaihong Chen College of Biological and Chemical Engineering Zhejiang University of Science and TechnologyHangzhou 310023China The institute of Green Chemistry and Engineering School of Chemistry and Chemical EngineeringNanjing UniversitySuzhou 215163China

Photocatalytic CO_(2)reduction reaction(CO_(2)RR)is one of the promising strategies for sustainably producing solar *** precise identification of catalytic sites and the enhancement of photocatalytic CO_(2)conversion is imperative yet quite *** critical review summarizes recent advances in porous photo-responsive polymers,including covalent organic frameworks(COFs),covalent triazine frameworks(CTFs),and conjugated microporous polymers(CMPs),those can be rationally designed from the molecular level for visible-light-driven photocatalytic CO_(2)***,special emphasis is placed on how the well-defined active sites on these polymers can influence their properties and photocatalytic *** precise regulation and control of microenvironments and electronic properties of metal active centers are crucial for boosting catalytic efficiency and selectivity,as well as for the design of better photocatalysts for CO_(2)reduction.

关键词： Carbon dioxide reduction Photocatalysis Porous polymers Well-defined catalytic sites Molecular level

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