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RE-SEGNN:recurrent semantic evidence-aware graph neural network for temporal knowledge graph forecasting

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Science China(Information Sciences) 2025年第2期68卷 103-119页

作者： Wenyu CAI Mengfan LI Xuanhua SHI Yuanxin FAN Quntao ZHU Hai JIN National Engineering Research Center for Big Data Technology and System Services Computing Technology and System LabCluster and Grid Computing LabSchool of Computer Science and TechnologyHuazhong University of Science and Technology

Temporal knowledge graph(TKG) reasoning, has seen widespread use for modeling real-world events, particularly in extrapolation settings. Nevertheless, most previous studies are embedded models, which require both entity and relation embedding to make predictions, ignoring the semantic correlations among different entities and relations within the same timestamp. This can lead to random and nonsensical predictions when unseen entities or relations occur. Furthermore, many existing models exhibit limitations in handling highly correlated historical facts with extensive temporal depth. They often either overlook such facts or overly accentuate the relationships between recurring past occurrences and their current counterparts. Due to the dynamic nature of TKG, effectively capturing the evolving semantics between different timestamps can be *** address these shortcomings, we propose the recurrent semantic evidenceaware graph neural network(RE-SEGNN), a novel graph neural network that can learn the semantics of entities and relations simultaneously. For the former challenge, our model can predict a possible answer to missing quadruples based on semantics when facing unseen entities or relations. For the latter problem, based on an obvious established force, both the recency and frequency of semantic history tend to confer a higher reference value for the current. We use the Hawkes process to compute the semantic trend, which allows the semantics of recent facts to gain more attention than those of distant facts. Experimental results show that RE-SEGNN outperforms all SOTA models in entity prediction on 6 widely used datasets, and 5 datasets in relation prediction. Furthermore, the case study shows how our model can deal with unseen entities and relations.

关键词： knowledge graph reasoning temporal knowledge graph Hawkes process semantic evidence

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Effect of divalent cations(Co^(2+) and Ni^(2+)) on microstructure,physical properties and application of NdFeO_(3)

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Journal of Rare Earths 2025年第1期43卷 89-97,I0004页

作者： M.M.Arman Materials Science lab(1) Physics DepartmentFaculty of ScienceCairo UniversityGiza12613Egypt

The nanocrystalline samples Nd_(1-x)M_(x)FeO_(3)(x=0.0 and 0.1;M:Co^(2+)and Ni^(2+))were prepared using the citrate combustion *** X-ray diffraction(XRD)pattern confirmed that the nanoparticles were synthesized in an orthorhombic *** particle size of Nd_(1-x)M_(x)FeO_(3) is in the range of 29-59 *** selected area electron diffraction(SAED)indicates the samples were prepared in a polycrystalline *** samples Nd_(1-x)M_(x)FeO_(3)(x=0.0 and 0.1;M:Co^(2+)and Ni^(2+))have anti ferromagnetic *** Fe^(3+)spins are aligned antiparallel,forming the antiferromagnetic(AFM)properties,which are affected by many factors such as the bond angle between the Fe^(3+)(Fe^(3+)-O_(2)--Fe^(3+))and the Dzyaloshinskii-Moriya(D-M)*** doping of Co^(2+)and Ni^(2+)ions in NdFeO_(3) enhances the magnetic properties of the NdFeO_(3).The saturation magnetization(Ms)of Nd_(0.90)Co_(0.10)FeO_(3) increases 1.8times more than that of NdFeO_(3).The exchange bias field(HEX)of the Co-doped sample is two times greater than that of NdFeO_(3).The magnetic anisotropy constant(K)of the 10%Co-doped sample increases by 11 factors compared to that of NdFeO_(3).The Tauc plot illustrates that the samples have a direct optical *** divalent cation substitution(Co^(2+)and Ni^(2+))decreases the optical band gap of NdFeO_(3),leading to the recommendation of using the samples Nd_(0.90)Co_(0.10)FeO_(3) and Nd_(0.90)Ni_(0.10)FeO_(3) in photocatalysis of dye degradation from *** removal efficiencies of Cr6+at pH=6 are 88.06%,85.54%,and 85.52%for the samples NdFeO_(3),Nd_(0.90)Co_(0.10)FeO_(3),and Nd_(0.90)Ni_(0.10)FeO_(3),*** Freundlich isotherm mode is the best-fit model for NdFeO_(3) to adsorb Cr6+ions from aqueous solutions.

关键词： Optical properties Nanoparticles Magnetic properties Perovskites Removal efficiency Rareearths

Excellent high-temperature strength of (HfZrTiTaNb)C high-entropy carbide diffusion-bonded joint via in-situ alloying of Ni/Nb/Ni composite interlayer

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JOURNAL OF ADVANCED CERAMICS 2025年第1期14卷 127-133,136-139页

作者： Mu, Ruijie Wang, Ying Niu, Shiyu Sun, Kongbo Yang, Zhenwen Tianjin Univ Sch Mat Sci & Engn Tianjin Key Lab Adv Joining Technol Tianjin 300350 Peoples R China Minist Educ Key Lab Adv Ceram & Machining Technol Tianjin 300350 Peoples R China

To obtain high-entropy carbide (HEC) joints with excellent high-temperature performance, a (HfZrTiTaNb)C HEC joint featuring a direct diffusion-bonded interface with a Nb-based interlayer was successfully fabricated at relatively low temperatures of 1150-1250 degrees C for 60 min under 10 MPa. Starting from a modified Ni/Nb/Ni composite interlayer with a Nb content of > 64 at%, an alloyed Nb2Ni layer was constructed in situ by accelerating the directional diffusion of Ni atoms from the high-entropy interface into the remaining pure Nb through the Ni-Nb eutectic liquid. Moreover, the excess liquid phase was squeezed out of the bonding region, ensuring the absence of Ni-based compounds. Leveraging the intrinsic interfacial stability and sluggish diffusion effect, the HEC with its original lattice structure, was capable of developing diffusion bonding with the Nb2Ni layer instead of interacting with the liquid phase. The high reliability of the HEC/Nb2Ni bonded interface was confirmed by the coherence of (1 3) (HEC)// (141) (Nb2Ni) and a calculated lattice misfit of 0.044. The HEC joint had a high room-temperature strength of 174 MPa because of the homogenous Nb2Ni layer, which exhibited nanohardness (15.2 +/- 1.5 GPa) and an elastic modulus of 219.9 +/- 17.5 GPa. Furthermore, the strength of the HEC joint did not decrease at 1000 degrees C, increasing by similar to 49% over that of HEC/Ni/HEC diffusion-bonded joints, which have stringent surface flatness requirements. This suggested that the HEC/Nb2Ni interface had excellent resistance to high-temperature softening, even though it was invariably the initial failure location. This work is informative for designing bonding structures and preparing HEC components.

关键词： high-entropy ceramic diffusion bonding in situ alloyed interlayer mechanical properties

Secretome of polarized macrophages:potential for targeting inflammatory dynamics in spinal cord injury

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Neural Regeneration Research 2025年第11期20卷 3231-3232页

作者： Andreia Monteiro Susana Monteiro Nuno A.Silva Life and Health Sciences Research Institute(ICVS) School of MedicineUniversity of MinhoBragaPortugal ICVS/3B’s Associate lab PT Government Associated LabBraga/GuimaraesPortugal

Spinal cord injury(SCI)involves an initial traumatic phase,followed by secondary events such as ischemia,increased blood-spinal cord barrier permeability,ionic disruption,glutamate excitotoxicity,and metabolic alterations.A pe rsistent and exagge rated inflammato ry response within the spinal cord accompanies these events(Lima et al.,2022).The complexity and interplay of these mechanisms exacerbate the initial injury,leading to a degenerative process at the injury *** the initial trauma is unavoidable,the secondary injury begins within minutes and can last for months,creating an optimal window for therapeutic intervention.

关键词： alterations injury companies

Propagating subduction initiation of the Caroline Plate at the Mussau Trench

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Science China Earth Sciences 2025年第1期68卷 253-269页

作者： Chun-Feng LI Yongkang DENG Tao WU Dongdong DONG Guoliang ZHANG Jiazheng ZHANG Yutao LIU Yaqing LI Fugui TANG Lulu ZHANG Department of Marine Sciences Zhejiang UniversityZhoushan316021China laboratory of Marine Mineral Resources Laoshan LaboratoryQingdao266237China Key lab of Marine Geology and Environment Institute of OceanologyChinese Academy of SciencesQingdao266071China Key lab of Ocean and Marginal Sea Geology South China Sea Institute of OceanologyChinese Academy of SciencesGuangzhou510301China Science&Technology on Integrated Information System lab Institute of SoftwareChinese Academy of SciencesBeijing100190China

New seismic imaging from the Mussau Trench confirms that,under horizontal compression on an oceanic plate boundary,it is within the young and weak oceanic plate that a trench will develop,and it is the young plate,not so long after its birth,that starts to subduct toward the old *** Mesozoic Pacific Plate cannot easily bend,under the joint horizontal compression and vertical gravity pull,even with a pre-existing weak zone in place and with a large age offset across the plate *** bending of the Caroline Plate near the northern end of the Mussau Trench started only after a long-time span of trench migration,and/or after a prolonged transition from initial compression to trench *** contrasting trench deformation and sedimentary accretion between two parallel seismic sections support an evident migration of underthrusting or significant longitudinal heterogeneity along the *** swift transition from underthrusting to non-thrusting can be explained by a counter-clockwise rotation of the Caroline *** miniature accretionary wedges develop even before the subduction initiates imply strong compression and uplifting before the underthrusting can *** of the Caroline Plate have been halted as the Mussau Trench is seismically rather quiet and the Lyra Trough to the east shows relaxational extension.

关键词： Mussau Trench Subduction initiation Seismic reflection Caroline Plate

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Streamlined photonic reservoir computer with augmented memory capabilities

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Opto-Electronic Advances 2025年第1期8卷 45-57页

作者： Changdi Zhou Yu Huang Yigong Yang Deyu Cai Pei Zhou Kuenyao Lau Nianqiang Li Xiaofeng Li School of Optoelectronic Science and Engineering&Collaborative Innovation Center of Suzhou Nano Science and Technology Soochow UniversitySuzhou 215006China Key lab of Advanced Optical Manufacturing Technologies of Jiangsu Province&Key lab of Modern Optical Technologies of Education Ministry of China Soochow UniversitySuzhou 215006China

Photonic platforms are gradually emerging as a promising option to encounter the ever-growing demand for artificial intelligence,among which photonic time-delay reservoir computing(TDRC)is widely *** such a computing paradigm can only employ a single photonic device as the nonlinear node for data processing,the performance highly relies on the fading memory provided by the delay feedback loop(FL),which sets a restriction on the extensibility of physical implementation,especially for highly integrated ***,we present a simplified photonic scheme for more flexible parameter configurations leveraging the designed quasi-convolution coding(QC),which completely gets rid of the dependence on *** delay-based TDRC,encoded data in QC-based RC(QRC)enables temporal feature extraction,facilitating augmented memory ***,our proposed QRC is enabled to deal with time-related tasks or sequential data without the implementation of ***,we can implement this hardware with a low-power,easily integrable vertical-cavity surface-emitting laser for high-performance parallel *** illustrate the concept validation through simulation and experimental comparison of QRC and TDRC,wherein the simpler-structured QRC outperforms across various benchmark *** results may underscore an auspicious solution for the hardware implementation of deep neural networks.

关键词： photonic reservoir computing machine learning vertical-cavity surface-emitting laser quasi-convolution coding augmented memory capabilities

Observer-based event-triggered formation tracking control for second-order multi-agent systems in constrained region

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Science China(Information Sciences) 2025年第2期68卷 151-169页

作者： Fenglan SUN Zhonghua XU Wei ZHU ■ KURTHS Key lab of Intelligent Analysis and Decision on Complex Systems School of ScienceChongqing University of Posts and Telecommunications Key lab of Intelligent Air-Ground Cooperative Control for Universities in Chongqing College of AutomationChongqing University of Posts and Telecommunications Department of Complexity Science Potsdam Institute for Climate Impact Research Institute of Physics Humboldt University of Berlin

In this paper, an event-triggered time-varying formation tracking control for a class of second-order nonlinear multiagent systems(MAS) operating within a constrained region is investigated. To mitigate the negative effects of external unknown disturbance, a novel disturbance observer with performance guarantees is proposed, enabling precise disturbance *** the artificial potential field(APF) method, a repulsive potential function is introduced to prevent inter-agent collisions as well as collisions with environmental obstacles. To reduce continuous communication and frequent system updates, a sliding mode technique is incorporated into the formation tracking controller, utilizing an event-triggered mechanism. The controller is also applicable to the formation control of MAS in switching-constrained regions. The achievement of the specified timevarying geometric formation is rigorously demonstrated through the Lyapunov framework. Numerical simulations are presented to validate the effectiveness of the theoretical results.

关键词： formation tracking control region constraints repulsive potential function event-triggered mechanism

Effects of bamboo invasion on forest structures and diameter-height allometries

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FOREST ECOSYSTEMS 2025年第1期12卷 38-45页

作者： Ouyang, Ming Eziz, Anwar Xiao, Shuli Fang, Wenjing Cai, Qiong Ma, Suhui Zhu, Jiangling Yang, Qingpei Hu, Jinming Tang, Zhiyao Fang, Jingyun Yunnan Univ Sch Ecol & Environm Sci Kunming Peoples R China Yunnan Univ Key Lab Transboundary Ecosecur Southwest Minist Educ Kunming Peoples R China Peking Univ Inst Ecol Coll Urban & Environm Sci Beijing Peoples R China Peking Univ Key Lab Earth Surface Proc Minist Educ Beijing Peoples R China Chinese Acad Sci Xinjiang Inst Ecol & Geog State Key Lab Desert & Oasis Ecol Key Lab Ecol Safety & Sustainable Dev Arid Lands Urumqi Peoples R China Jiangxi Agr Univ Jiangxi Prov Key Lab Bamboo Germplasm Resources & Nanchang Peoples R China Jiangxi Agr Univ Coll Forestry Nanchang Peoples R China

Forest structure is fundamental in determining ecosystem function, yet the impact of bamboo invasion on these structural characteristics remains unclear. We investigated 219 invasion transects at 41 sites across the distribution areas of Moso bamboo (Phyllostachys edulis) in China to explore the effects of bamboo invasion on forest structural attributes and diameter-height allometries by comparing paired plots of bamboo, mixed bamboo-tree, and non-bamboo forests along the transects. We found that bamboo invasion decreased the mean and maximum diameter at breast height, maximum height, and total basal area, but increased the mean height, stem density, and scaling exponent for stands. Bamboo also had a higher scaling exponent than tree, particularly in mixed forests, suggesting a greater allocation of biomass to height growth. As invasion intensity increased, bamboo allometry became more plastic and decreased significantly, whereas tree allometry was indirectly promoted by increasing stem density. Additionally, a humid climate may favour the scaling exponents for both bamboo and tree, with only minor contributions from topsoil moisture and nitrogen content. The inherent superiority of diameter-height allometry allows bamboo to outcompete tree and contributes to its invasive success. Our findings provide a theoretical basis for understanding the causes and consequences of bamboo invasion.

关键词： Moso bamboo Forest structure Stand density DBH-Height allometry Scaling exponent Wetness index

Boosting singlet oxygen generation for salinity wastewater treatment through co-activation of oxygen and peroxymonosulfate in photoelectrochemical process

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FUNDAMENTAL RESEARCH 2025年第1期5卷 165-173页

作者： Yang, Qianqian Feng, Zhiyuan Zhou, Yanbo Zhao, Hongying Zhao, Guohua Tongji Univ Sch Chem Sci & Engn Key Lab Yangtze River Water Environm Shanghai Key Lab Chem Assessment & Sustainabil Shanghai 200092 Peoples R China East China Univ Sci & Technol Minist Educ Key Lab Coal Gasificat & Energy Chem Engn Shanghai 200092 Peoples R China

High concentrations of inorganic ions in saline wastewater pose adverse effects on hydroxyl radical (HO' )dominated technologies. Here, we report a unique strategy for boosting singlet oxygen (1 O2 ) generation via coactivation of oxygen and peroxymonosulfate (PMS) by regulating the electron transfer regime in the photoelectrochemical process. The Fe-N bridge in atomic Fe-modified graphitic carbon nitride (denoted SA-FeCN) favors the construction of electron-defective Fe and electron-rich N vacancies (Nvs) to accelerate directional electron transfer. The produced intermediate (HSO4-O center dot center dot center dot Fe- Nvs center dot center dot center dot O-O) as a chemical channel accelerates the directional electron transfer from PMS to further reduce O2 to form activated products (SO5'-, O2'-), thereby transforming O2 into 1 O2 . An optimized 1 O2 generation rate of 39.4 mu mol L-1s- 1 is obtained, which is 15.7-945.0 times higher than that in traditional advanced oxidation processes. Fast kinetics are achieved for removing various phenolic pollutants in a nonradical oxidation pathway, which is less susceptible to the coexistence of natural organic matter and inorganic ions. The COD removal for coal wastewater and complex industrial wastewater in real scenarios is found to reach a value of 90%-96% in 3 h. This work provides a new direction for boosting the 1 O2 generation rate, especially for the selective degradation of target electron-rich contaminants in saline wastewater.

关键词： Photoelectrochemical process Singlet oxygen Oxygen activation Peroxymonosulfate activation Electron transfer Saline wastewater