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Multi-environment BSA-seq using large F3 populations is able to achieve reliable QTL mapping with high power and resolution: An experimental demonstration in rice

能源与环境材料（英文） 2023年第6期6卷 251-258页

作者： Yuhua Liu Xiaoyu Zhang Wei Zhang Xin Ge Yan Wang Xu Zou Xinyan Zhou Weitao Zheng key laboratory of Automobile Materials moe and School of Materials Science & Engineeringand Jilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy Materialsand Electron Microscopy Centerand International Center of Future ScienceJilin UniversityChangchun 130012China

MXene quantum dots(MQDs)offer wide applications owing to the abundant surface chemistry,tunable energy-level structure,and unique ***,the application of MQDs in electrochemical energy conversion,including hydrogen evolution reaction(HER),remains to be realized,as it remains a challenge to precisely control the types of surface groups and tune the structure of energy levels in MQDs,owing to the high surface energy-induced strong agglomeration in ***,the determination of the exact catalytically active sites and processes involved in such an electrocatalysis is challenging because of the complexity of the synthetic process and reaction ***,we demonstrated the spontaneous evolution of the surface groups of the Ti2CTx MQDs(x:the content of O atom),i.e.,replacement of the-Cl functional groups by O-terminated ones during the cathode *** process resulted in a low Gibbs free energy(0.26 eV)in *** steady Ti2COx/Cu2O/Cu foam systems exhibited a low overpotential of 175 mV at 10 mA cm-2 in 1 M ***,and excellent operational stability over 165 h at a constant current density of-10 mA cm-2.

关键词： HF free hydrogen evolution MXene quantum dots surface group

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The Crop Journal 2024年第2期12卷 549-557页

作者： Yan Zheng Ei Ei Khine Khin Mar Thi Ei Ei Nyein Likun Huang Lihui Lin Xiaofang Xie Min Htay Wai Lin Khin Than Oo Myat Myat moe San San Aye Weiren Wu College of Life Sciences Fujian Agriculture and Forestry UniversityFuzhou 350002FujianChina Fujian Provincial key laboratory of Crop Breeding by Design Fujian Agriculture and Forestry UniversityFuzhou 350002FujianChina key laboratory of Genetics Breeding and Multiple Utilization of CropsMinistry of EducationFujian Agriculture and Forestry UniversityFuzhou 350002FujianChina Department of Botany Mawlamyine UniversityMon StateMawlamyineMyanmar Department of Botany Dagon UniversityNorth DagonYangonMyanmar

Bulked-segregant analysis by deep sequencing(BSA-seq) is a widely used method for mapping QTL(quantitative trait loci) due to its simplicity, speed, cost-effectiveness, and efficiency. However, the ability of BSA-seq to detect QTL is often limited by inappropriate experimental designs, as evidenced by numerous practical studies. Most BSA-seq studies have utilized small to medium-sized populations, with F2populations being the most common choice. Nevertheless, theoretical studies have shown that using a large population with an appropriate pool size can significantly enhance the power and resolution of QTL detection in BSA-seq, with F_(3)populations offering notable advantages over F2populations. To provide an experimental demonstration, we tested the power of BSA-seq to identify QTL controlling days from sowing to heading(DTH) in a 7200-plant rice F_(3)population in two environments, with a pool size of approximately 500. Each experiment identified 34 QTL, an order of magnitude greater than reported in most BSA-seq experiments, of which 23 were detected in both experiments, with 17 of these located near41 previously reported QTL and eight cloned genes known to control DTH in rice. These results indicate that QTL mapping by BSA-seq in large F_(3)populations and multi-environment experiments can achieve high power, resolution, and reliability.

关键词： BSA-seq QTL mapping Large F3 population Multi-environment experiment Cross-validation

Inverted-design for highly-active hydrogen evolution electrocatalyst of MoS_(2)@Ni_(3)S_(2)core-shell via unlocking the potential of Mo

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颗粒学报:英文版 2023年第6期77卷 56-61页

作者： Chao Song Yuhua Liu Chengxiang Huang Miao Liu Nailin Yue Zunhao Zhang Zizhun Wang Xu Zou Wei Zhang Weitao Zheng key laboratory of Automobile Materials moe School of Materials Science&EngineeringJilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy MaterialsElectron Microscopy CenterInternational Center of Future ScienceJilin UniversityChangchun130012China

Through inverted-design rather than modifying the generally-assumed S active sites in popular MoS_(2),we unlock the potential of Mo sites and successfully prepared novel MoS_(2)@Ni_(3)S_(2)/NF core-shell nanospheres as a catalyst for the high-performance hydrogen evolution reaction(HER).TheΔGH at the Mo site is optimized via Ni_(3)S_(2)to achieve excellent HER *** low current densities,it has similar activity to the Pt/***,its performance is better than Pt/C at high ***,our catalyst shows a considerable stability at a variety of current densities for 50 h,promising to substitute noble metal catalysts in application of commercial alkaline electrocatalysts.

关键词： Inverted design Hydrogen evolution reaction Electrocatalyst Electronicinteraction MoS_(2)@Ni_(3)S_(2)/NF

Enhanced homing of mesenchymal stem cells for in situ niche remodeling and bone regeneration

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Nano Research 2024年第8期17卷 7449-7460页

作者： Yin Yuan Lijun Chen Jing Yang Sining Zhou Yangxin Fang Qi Zhang Ning Zhang Yifei Li Li Yuan Fan Jia Shuo Ni Charlie Xiang State key laboratory for Diagnosis and Treatment of Infectious Diseases National Clinical Research Center for Infectious DiseasesNational Medical Center for Infectious DiseasesCollaborative Innovation Center for Diagnosis and Treatment of Infectious DiseasesThe First Affiliated HospitalZhejiang University School of MedicineHangzhou 310003China Department of Biology The David H.Koch Institute for Integrative Cancer Research at MITMassachusetts Institute of TechnologyCambridgeMA 02139USA Research Units of Infectious disease and Microecology Chinese Academy of Medical SciencesHangzhou 310003China Innovative Precision Medicine(IPM)Group Hangzhou 311215China moe key laboratory of Macromolecule Synthesis and Functionalization of Ministry of Education Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China key laboratory of Cardiovascular Intervention and Regenerative Medicine of Zhejiang Province Department of CardiologySir Run Run Shaw HospitalZhejiang University School of MedicineHangzhou 310016China Department of Cancer Immunology and Virology Dana-Farber Cancer InstituteBostonMA 02215USADepartment of ImmunologyHarvard Medical SchoolBoston MA 02115USA Department of Orthopedic Surgery and Shanghai Institute of Microsurgery on Extremities Shanghai Sixth People’s Hospital Affiliated to Shanghai Jiaotong University School of MedicineShanghai 200233China

Mesenchymal stem cells(MSCs)transplantation is a promising strategy for osteoporosis ***,limited sources and poor tissue-homing efficiency limit their clinical *** this study,we isolated a kind of MSCs from women’s menstrual blood(MenSCs)noninvasively and established a novel MSCs bone marrow-targeted delivery system by utilizing waterin-oil-in-water droplet *** were encapsulated withinβ-cyclodextrin-functionalized alginate microcapsules loaded with zoledronates,which has a high affinity for *** this delivery system,MenSCs could be preferentially delivered to the bone marrow tissues via intravenous infusion,and restored bone mass by remodeling the bone marrow niche in situ in ovariectomized mouse ***,scRNA-seq analysis demonstrated that those MenSCs homed to the bone marrow recruited CD4^(+)FOXP3^(+)natural regulatory T(nT_(reg))cells by secreting *** recruited nTreg promoted CD8^(+)T cells to secret Wnt family member 10B(WNT10B),activating the Wnt signaling in osteoblasts and thus promoting bone formation in situ in the bone *** study reveals a promising application of MenSCs in postmenopausal osteoporosis treatment and highlights the clinical value of MenSCs by encouraging women to reserve autologous MenSCs before menopause to prevent and alleviate postmenopausal osteoporosis.

关键词： mesenchymal stem cells microfluidics bone marrow homing stem cell niche postmenopausal osteoporosis

Reducing surficial and interfacial defects by thiocyanate ionic liquid additive and ammonium formate passivator for efficient and stable perovskite solar cells

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Nano Research 2023年第5期16卷 6849-6858页

作者： Mengfei Zhu Yuren Xia Lina Qin Kaiqiang Zhang Junchuan Liang Cheng Zhao Daocheng Hong Minghang Jiang Xinmei Song Jie Wei Pengbo Zhang Yuxi Tian Zhong Jin State key laboratory of Coordination Chemistry MOE Key Laboratory of Mesoscopic ChemistryMOE Key Laboratory of High Performance Polymer Materials and TechnologyJiangsu Key Laboratory of Advanced Organic MaterialsSchool of Chemistry and Chemical EngineeringNanjing UniversityNanjingJiangsu 210023China

Organic–inorganic metal halide perovskites have attained extensive attention owing to their outstanding photovoltaic performances,but the existence of numerous defects in crystalline perovskites is still a serious constraint for the further development of perovskite solar cells(PSCs).In particular,the rapid crystallization guided by anti-solvents leads to plenty of surficial and interfacial defects in perovskite ***,we report the adoption of a pseudo-halide anion based ionic liquid additive,1-butyl-3-methylimidazolium thiocyanate(BMIMSCN)for growing ternary cation(CsFAMA,where FA=formamidinium and MA=methylammonium)perovskites with large-scale crystal grains and strong preferential orientation via the enhanced Ostwald ***,a novel halide-free passivator,benzylammonium formate(BAFa),was employed as a buffering layer on the perovskite films to suppress surface-dominated charge *** a result,the cooperative effects of BMIMSCN additive and BAFa passivator lead to significant enhancements on fluorescence lifetime(from 79.41 to 201.01 ns),open-circuit voltage(from 1.13 to 1.19 V),photoelectric conversion efficiency(from 18.90%to 22.33%).Moreover,the BMIMSCN/BAFa-CsFAMA PSCs demonstrated greatly improved stability against moisture and *** work suggests a promising strategy to improve the quality of perovskite materials via reducing the surficial and interfacial defects by the synergistic effects of lattice doping and interface engineering.

关键词： organic–inorganic perovskite solar cells pseudo-halide ion liquid additive non-halide ammonium formate passivator crystalline and interface engineering efficiency and stability improvements

The surface of metal boride tinted by oxygen evolution reaction for enhanced water electrolysis

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Journal of Energy Chemistry 2022年第9期31卷 509-515,I0014页

作者： Xu Zou Wei Zhang Xinyan Zhou Kexin Song Xin Ge Weitao Zheng key laboratory of Automobile Materials moe School of Materials Science&Engineeringand Jilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy MaterialsElectron Microscopy Centerand International Center of Future ScienceJilin UniversityChangchun 130012JilinChina

Oxygen evolution reaction(OER)is a bottleneck half-reaction in many important energy conversion processes(e.g.,water splitting),and one of the key issues lies to develop high-efficiency,cost-effective OER *** than those popular extrinsic modulations of any catalysts with gradually degraded performance,we aim at the utilization of the intermediates offered from the undergoing OER as long-standing ***,by inverted design,we extracted the bimetallic borides(FeCoB_(2))-derived intermediates metal borates in the OER,unlocking their potential as a selffunctionalized highly active catalytic phase in-situ formed on the metal boride surface for continuing OER ***,the surface metal atoms are oxidized to oxyhydroxides,and the surface metalloids(B)are further transformed to the corresponding oxoanions to form metal *** OER self-produced electrocatalyst exhibits a small overpotential of 295 mV at 10 mA/cm2 and its high catalytic activity lasts even after 200 *** with FeCoB_(2),the catalytic activity of this electrochemically activated FeCoB_(2) is~7 times *** in-situ formed metal borate is dominatingly responsible for the obtained high catalytic *** unique OER-produced self-functionalization surfaces of metal borates afford to greatly reduce the energy barrier of the continuing OER,thereby accelerating the reaction process.

关键词： Inverted design Self-functional surfaces Metal borate Water splitting Oxygen evolution reaction

Quantum Dots Compete at the Acme of MXene Family for the Optimal Catalysis

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Nano-Micro Letters 2022年第10期14卷 36-82页

作者： Yuhua Liu Wei Zhang Weitao Zheng key laboratory of Automobile Materials moe and School of Materials Science and Engineeringand Jilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy Materialsand Electron Microscopy Centerand International Center of Future ScienceJilin UniversityChangchun 130012People’s Republic of China

It is well known that two-dimensional(2D)MXene-derived quan-tum dots(MQDs)inherit the excellent physicochemical properties of the parental MXenes,as a Chinese proverb says,“Indigo blue is extracted from the indigo plant,but is bluer than the plant it comes from.”Therefore,0D QDs harvest larger surface-to-volume ratio,outstanding optical properties,and vigorous quantum confinement ***,MQDs trigger enormous research enthusiasm as an emerging star of functional materials applied to physics,chemistry,biology,energy conversion,and *** the surface properties of small-sized MQDs include the type of surface functional groups,the functionalized surface directly determines their *** the Nobel Laureate Wolfgang Pauli says,“God made the bulk,but the surface was invented by the devil,”and it is just on the basis of the abundant surface functional groups,there is lots of space to be thereof excavated from *** are witnessing such excellence and even more promising to be ***,MQDs have been widely applied to catalysis,whereas the related reviews are rarely ***,we provide a state-of-the-art overview of MQDs in catalysis over the past five years,ranging from the origin and development of MQDs,synthetic routes of MQDs,and functionalized MQDs to advanced characterization *** explore the diversity of catalytic application and perspectives of MQDs,our review will stimulate more efforts toward the synthesis of optimal MQDs and thereof designing high-performance MQDs-based catalysts.

关键词： MXene Quantum dots Catalysis Surface groups Structure

Individually-atomic governing d-π*orbital interactions via Cupromoted optimization of Fe-d band centers for high-efficiency zinc-air battery

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Nano Research 2023年第4期16卷 4634-4642页

作者： Xinyan Zhou Kexin Song Yu Feng Chao Jiang Zhongjun Chen Zizhun Wang Nailin Yue Xin Ge Wei Zhang Weitao Zheng key laboratory of Automobile Materials moe School of Materials Science&EngineeringJilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy MaterialsElectron Microscopy Centerand International Center of Future ScienceJilin UniversityChangchun 130012China Institute of high Energy Physics Chinese Academy of SciencesBeijing 100049China

It is challenging for precise governing of electronic configuration of the individually-atomic catalysts toward optimal electrocatalysis,as d-band configuration of a metal center determines the adsorption behavior of reactive species to the center in oxygen reduction reaction(ORR).The addition of Cu atom modifies the d-band center position of Fe central atom,thus strengthening the d-π*orbital ***,FeCu-NC catalyst in the nitrogen-doped carbon(NC)support containing individual dual-metal CuN4/FeN4 sites was prepared by the surface confinement strategy of zeolitic imidazolate framework(ZIF),treated as a model *** and theoretically co-verified dual-metal CuN4/FeN4 sites highly dispersed in the NC support,enable transferring more electrons from FeN4 sites to*OH intermediates,thereby accelerating the desorption process of*OH *** to those commercial Pt/C,Our FeCu-NC catalyst exhibited extraordinary ORR activity(with a E1/2 as high as 0.87 V)and cycling stability in 0.1 M KOH electrolyte,and thereof demonstrated excellent discharge performance in zinc-air *** construction of dual-atom catalysts(DACs)provides a strategy for atom-by-atom designing high-efficiency catalysts via orbital regulation.

关键词： dual-atom catalysts(DACs) electronic configuration oxygen reduction reaction(ORR) zinc-air battery

Building Feedback-Regulation System Through Atomic Design for highly Active SO_(2)Sensing

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Nano-Micro Letters 2024年第7期16卷 343-357页

作者： Xin Jia Panzhe Qiao Xiaowu Wang Muyu Yan Yang Chen Bao-Li An Pengfei Hu Bo Lu Jing Xu Zhenggang Xue Jiaqiang Xu NEST Lab Department of ChemistryCollege of SciencesShanghai UniversityShanghai 200444People’s Republic of China Shanghai Synchrotron Radiation Facility Zhangjiang LabShanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204People’s Republic of China School of Chemistry and Materials Science University of Science and Technology of ChinaHefei 230026People’s Republic of China key laboratory of Organic Compound Pollution Control Engineering(moe) School of Environmental and Chemical EngineeringShanghai UniversityShanghai 200444People’s Republic of China Shanghai University Instrumental Analysis&Research Center of Shanghai UniversityShanghai 200444People’s Republic of China

Reasonably constructing an atomic interface is pronouncedly essential for surface-related gas-sensing ***,we present an ingen-ious feedback-regulation system by changing the interactional mode between single Pt atoms and adjacent S species for high-efficiency SO_(2)*** found that the single Pt sites on the MoS_(2)surface can induce easier volatiliza-tion of adjacent S species to activate the whole inert S ***,the activated S species can provide a feedback role in tailoring the antibonding-orbital electronic occupancy state of Pt atoms,thus creating a combined system involving S vacancy-assisted single Pt sites(Pt-Vs)to synergistically improve the adsorption ability of SO_(2)gas ***-more,in situ Raman,ex situ X-ray photoelectron spectroscopy testing and density functional theory analysis demonstrate the intact feedback-regulation system can expand the electron transfer path from single Pt sites to whole Pt-MoS_(2)supports in SO_(2)gas *** with wireless-sensing modules,the final Pt1-MoS_(2)-def sensors array can further realize real-time monitoring of SO_(2)levels and cloud-data storage for plant *** a fundamental understanding of the intrinsic link between atomic interface and sensing mechanism is thus expected to broaden the rational design of highly effective gas sensors.

关键词： Feedback-regulation system Atomic interface SO_(2)sensor Single-atom sensing mechanism Intelligent-sensing array

Enhancing water-dissociation kinetics and optimizing intermediates adsorption free energy of cobalt phosphide via high-valence Zr incorporating for alkaline water electrolysis

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能源化学:英文版 2023年第8期83卷 119-127,I0005页

作者： Huafeng Fan Dongxu Jiao Jinchang Fan Dewen Wang Bilal Zaman Wei Zhang Lei Zhang Weitao Zheng Xiaoqiang Cui State key laboratory of Automotive Simulation and Control School of Materials Science and EngineeringKey Laboratory of Automobile Materials of MOEJilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy MaterialsElectron Microscopy CenterJilin UniversityChangchun 130012JilinChina College of Chemistry Jilin UniversityChangchun 130012JilinChina

Developing high-efficiency electrocatalysts for hydrogen evolution reaction(HER) and oxygen evolution reaction(OER) is required to enhance the sluggish kinetics of water dissociation and optimize the adsorption free energy of reaction ***,we tackle this challenge by incorporating high-valence Zr into CoP(ZrxCo_(1-x)P),which significantly accelerates the elementary steps of water *** calculations indicate that the appropriate Zr incorporation effectively expedites the sluggish H2O dissociation kinetics and optimizes the adsorption energy of reaction intermediates for boosting the alkaline water *** are confirmed by the experimental results of Zr_(0.06)Co_(0.94)P catalyst that delivers exceptional electrochemical *** overpotentials at the current density of 10 mA cm^(-2)(j10) are only 62(HER) and 240 mV(OER) in alkaline ***,the Zr_(0.06)Co_(0.94)P/CC‖Zr_(0.06)Co_(0.94)P/CC system exhibits superior overall water splitting activity(1.53 V/j10),surpassing most of the reported bifunctional *** high-valence Zr incorporation and material design methods explore new avenues for realizing high-performance non-noble metal electrocatalysts.

关键词： DFT simulation Water electrolysis Cobalt phosphide high-valence Zr