检索结果-南通市图书馆

In situ reconstruction induced oxygen-deficient multiphase Cu based species hybridized with Ni single atoms as tandem platform for CO_(2) electroreduction

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第5期17卷 3888-3894页

作者： Juzhe Liu Yuheng Wang Pengpeng Mo Feng Yang Kaiqi Jiang Zhixiang Cheng Yuxuan Liu Zhiyi Sun Zheng Liu Yimei Zhang Wenxing Chen the key laboratory of resources and environmental system optimization Ministry of EducationCollege of Environmental Science and EngineeringNorth China Electric Power UniversityBeijing 102206China Energy&Catalysis Center School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China State key laboratory of environmental Criteria and Risk Assessment Chinese Research Academy of Environmental SciencesBeijing 100012China SEPA key laboratory of Eco-Industry Chinese Research Academy of Environmental SciencesBeijing 100012China

Tandem catalysis,capable of decoupling individual steps,provides a feasible way to build a high-efficiency CO_(2) electro-conversion system for multicarbons(C_(2+)).The construction of electrocatalytic materials is one of focusing ***,we fabricated a single atom involved multivalent oxide-derived Cu composite material and found it inclined to reconstruct into oxygen-deficient multiphase Cu based species hybridized with monatomic Ni on N doped C *** this prototype,rapid CO generation and C-C coupling are successively achieved on NiN4 sites and surface amorphized Cu species with defects,resembling a micro-production *** this way,the in situ formed tandem catalyst exhibited a high Faradaic efficiency(FE)of~78%for C_(2+)products along with satisfactory durability over 50 ***,the reconstruction-induced amorphous layer with abundant asymmetric sites should be favorable to improve the ethanol selectivity(FE:63%),which is about 10 times higher than that of the non-tandem Cu-based contrast *** work offers a new approach for manipulating tandem catalyst systems towards enhancing C_(2+)products.

关键词： tandem catalysis single atom reconstruction amorphous CO_(2)reduction reaction

A New Integrated Interpolation Method for High Missing Unstable Disease Surveillance Data—12 Urban Agglomerations,China,2009-2020

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

China CDC weekly 2024年第27期6卷 670-676,I0005-I0012页

作者： Yuanhao Shi Yilan Liao The State key laboratory of resources and environmental Information system Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijingChina University of Chinese Academy of Science BeijingChina

Introduction:The prevalence of unstable and incomplete monitoring data significantly complicates syndromic *** data interpolation methods currently available demonstrate inadequate effectiveness in overcoming this ***:To improve the accuracy of interpolation,we propose the integration of the SHapley Additive exPlanation model(SHAP)with the structural equation model(SEM),forming a combined SHAP-SEM approach.A case study is then performed to assess the enhanced performance of this novel model compared to traditional ***:The SHAP-SEM model was utilized to develop an interpolation model employing data from the Chinese respiratory syndrome surveillance *** executed three distinct experiments to establish the model datasets,comprising a total of 100 *** performance of the model was evaluated using the root mean square error(RMSE),correlation coefficient(r),and *** findings demonstrate that the SHAP-SEM model consistently achieves superior accuracy in data interpolation,which is evident across different seasons and in overall ***:We conclude that the SHAP-SEM model demonstrates an exceptional capacity for accurately interpolating volatile and incomplete *** capability is crucial for developing a comprehensive database that is essential for conducting risk assessments related to syndromes.

关键词： interpolation incomplete exceptional

Holocene Hydroclimatic Variations in the Asian Drylands:Current Understanding and Future Perspectives

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Earth Science 2024年第1期35卷 292-295页

作者： Guoqiang Ding Shengqian Chen Yuanhao Sun Shuai Ma Jianhui Chen MOE key laboratory of West China's environmental system College of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China Alpine Paleoecology and Human Adaptation Group State Key Laboratory of Tibetan Plateau Earth SystemEnvironment and ResourcesInstitute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China

0 *** intensification of global warming is generating increasing risks to human society and sustainable development,which are of growing concern to the international scientific community and policymakers(Sun,2023).The ecosystems of the Asian drylands are fragile and highly sensitive to global changes;moreover,while these drylands are the most important areas of oasis agriculture on Earth,their water resources are being adversely impacted by ongoing climate change(Zhang et al.,2023).Hence,an improved understanding of the patterns of climate change in this region is important and attracting increasing research attention.

关键词： Asian Holocene climatic

Non-contact gaseous microplasma electrode as anode for electrodeposition of metal and metal alloy in molten salt

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2024年第4期35卷 166-169页

作者： Junhan Luo Qi Qing Liqin Huang Zhe Wang Shuang Liu Jing Chen Yuexiang Lu Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China The MOE key laboratory of resources and environmental system optimization College of Environmental Science and EngineeringNorth China Electric Power UniversityBeijing 102206China Nuclear Research Institute for Future Technology and Policy Seoul National UniversitySeoul 08826Republic of Korea

Microplasma based on glow discharge could act as a non-contact gaseous electrode and has attracted much attention in both fundamental research and application. Herein, with microplasma as the anode,the electrodeposition process of a series of metal and metal alloys in molten salt has been systemically studied. Four metal cations with different valence states, silver(Ag~+), nickel(Ni^(2+)), copper(Cu^(2+)), and iron(Fe^(3+)), could all be reduced on the solid cathode with high current efficiency and the corresponding metal products were of high purity. The electrodeposition of aluminum-lanthanum(Al-Ln) alloy on the aluminum cathode was also successfully carried out with microplasma as the anode, and the same alloy was obtained by using the conventional anode electrode. These results indicated that microplasma anode based on non-contact direct-current(DC) glow discharge is a promising electrode to be applied in molten salt electrolysis.

关键词： Microplasma Anode Molten salt Electrodeposition Al-Ln alloy

Biophotoelectrochemistry for the treatment of emerging contaminants

在线全文

学校读者我要写书评

暂无评论

Science China Technological Sciences 2024年第10期67卷 3051-3066页

作者： HU Jing CHEN Man GU WenZhi DENG WenEr HONG MingQiu HU AnDong YE Jie ZHOU ShunGui Fujian Provincial key laboratory of Soil environmental Health and Regulation College of Resources and EnvironmentFujian Agriculture and Forestry University

Emerging contaminants(ECs) of significant concern are widely distributed throughout the environment due to various industrial practices and human activities. Given the alarming ecological threats and potential risks that ECs pose to human health and aquatic life, even at trace concentrations, it is imperative to develop innovative technologies to effectively address these challenges. The biophotoelectrochemistry(BPEC) system, which integrates microbial cells with photosensitizers for solar-tochemical conversion, holds great potential as an efficient strategy for the removal of ECs. In this review, we provide new insights into the BPEC system for the ECs treatment by systematically summarizing the classification, sources, and environmental occurrence of ECs. Additionally, we explore the research progress and degradation mechanisms in ECs removal with ***, the current challenges and future perspectives for the applications of the BPEC system in the ECs treatment are *** review aims to promote the development of BPEC technology for ECs treatment, offering a promising prospect for environmental remediation, circular economy, and clean-energy production.

关键词： emerging contaminants biophotoelectrochemistry photocatalysis biodegradation

同方期刊数据库

Impacts of land surface darkening on frozen ground and ecosystems over the Tibetan Plateau

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2024年第10期67卷 3213-3225页

作者： Shuchang TANG Tao WANG Dan LIU Tandong YAO Shilong PIAO Sino-French Institute for Earth system Science College of Urban and Environmental SciencesPeking UniversityBeijing 100101China State key laboratory of Tibetan Plateau Earth system Resources and EnvironmentInstitute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China

Tibetan Plateau(TP) is known as the “Third Pole” of the Earth. Any changes in land surface processes on the TP can have an unneglectable impact on regional and global climate. With the warming and wetting climate, the land surface of the TP saw a darkening trend featured by decreasing surface albedo over the past decades, primarily due to the melting of glaciers, snow,and greening vegetation. Recent studies have investigated the effects of the TP land surface darkening on the field of climate, but these assessments only address one aspect of the feedback loop. How do these darkening-induced climate changes affect the frozen ground and ecosystems on the TP? In this study, we investigated the impact of TP land surface darkening on regional frozen ground and ecosystems using the state-of-the-art land surface model ORCHIDEE-MICT. Our model results show that darkening-induced climate changes on the TP will lead to a reduction in the area of regional frozen ground by 1.1×10~4±0.019×10~4km~2, a deepening of the regional permafrost active layer by 0.06±0.0004 m, and a decrease in the maximum freezing depth of regional seasonal frozen ground by 0.06±0.0016 m compared to the scenario without TP land surface ***, the darkening-induced climate change on the TP will result in an increase in the regional leaf area index and an enhancement in the regional gross primary productivity, ultimately leading to an increase in regional terrestrial carbon stock by0.81±0.001 PgC. This study addresses the remaining piece of the puzzle in the feedback loop of TP land surface darkening, and improves our understanding of interactions across multiple spheres on the TP. The exacerbated regional permafrost degradation and increasing regional terrestrial carbon stock induced by TP land surface darkening should be considered in the development of national ecological security barrier.

关键词： Tibetan Plateau Albedo Land surface darkening Frozen ground Ecosystem

同方期刊数据库

Synthesis of carbon nitride in potassium hydroxide molten salt for efficient uranium extraction from radioactive wastewater

在线全文

学校读者我要写书评

暂无评论

Frontiers of environmental Science & Engineering 2024年第8期18卷 89-99页

作者： Shuang Liu Junhan Luo Daniel-James Maguire Liyuan Zheng Zhe Wang Yuexiang Lu Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China Nuclear Research Institute for Future Technology and Policy Seoul National UniversitySeoul 08826Republic of Korea Department of Earth Sciences University of CambridgeCambridge CB23EQUK The MOE key laboratory of resources and environmental system optimization College of Environmental Science and EngineeringNorth China Electric Power UniversityBeijing 102206China

Photocatalysis-assisted removal of uranium has been proven as an effective method for the elimination of radioactive pollution from *** this work,carbon nitride materials were synthesized in potassium hydroxide(KOH)molten salt and applied to photocatalytic uranyl *** materials were confirmed to possess the triazine-s-heptazine structure by NMR,XPS and UV-Vis characterization,and exhibited a wider visible light absorption than graphitic carbon nitride(g-C_(3)N_(4)).The photocatalytic activity of the carbon nitride materials was tailored by varying the precursor mass *** carbon nitride obtained at 80%melamine as precursor(K-CN-80)exhibited the highest photocatalytic extraction ability and its photocatalytic reaction rate is 6.6 times faster than that of g-C_(3)N_(4).The influence of sacrificial agents was studied and the results showed that triethanolamine inhibited U(Ⅵ)photoreduction,but methanol can accelerate U(Ⅵ)photoreduction by consuming photogenerated *** unary KOH molten salt synthesis method has exceptional potential applications in the preparation of carbon nitrides,and the obtained products showed potential in extracting U(Ⅵ)from aqueous solutions for use in nuclear fuel industry and for U(Ⅵ)environmental pollution cleanup.

关键词： Uranium Carbon nitride Molten salt Photocatalysis Radioactive wastewater

Ordered mesoporous materials for water pollution treatment: Adsorption and catalysis

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Green Energy & Environment 2024年第8期9卷 1239-1256页

作者： Peng Zhang Mingming He Wei Teng Fukuan Li Xinyuan Qiu Kexun Li Hao Wang College of environmental Science and Engineering MOE Key Laboratory of Pollution Processes and Environmental CriteriaTianjin Key Laboratory of Environmental Remediation and Pollution TreatmentTianjin Key Laboratory of Environmental Technology for Complex Trans-Media PollutionNankai University Department of Chemistry and State key laboratory Marine Pollution Hong Kong Institute for Advanced Study City University of Hong Kong State key laboratory for Pollution Treatment College of Environmental Science and EngineeringShanghai Institute of Pollution Treatment and Ecological SecurityTongji University State key laboratory of Simulation and Regulation of Water Cycles in River Basins China Institute of Water Resources and Hydropower Research

To meet the growing emission of water contaminants,the development of new materials that enhance the efficiency of the water treatment system is *** mesoporous materials provide opportunities in environmental processing applications due to their exceptionally high surface areas,large pore sizes,and enough pore *** properties might enhance the performance of materials concerning adsorption/catalysis capability,durability,and *** this review,we enumerate the ordered mesoporous materials as adsorbents/catalysts and their modifications in water pollution treatment from the past decade,including heavy metals (Hg2+,Pb2+,Cd2+,Cr6+,etc.),toxic anions （nitrate,phosphate,fluoride,etc.）,and organic contaminants （organic dyes,antibiotics,etc.）.These contributions demonstrate a deep understanding of the synergistic effect between the incorporated framework and homogeneous active ***,the challenges and perspectives of the future developments of ordered mesoporous materials in wastewater treatment are *** work provides a theoretical basis and complete summary for the application of ordered mesoporous materials in the removal of contaminants from aqueous solutions.

关键词： Water pollution treatment Ordered mesoporous materials Toxic contaminants Adsorption Catalysis

Does the continuous wetting of the Tibetan Plateau contribute to the accelerated degradation of permafrost?

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Science China Earth Sciences 2024年第5期67卷 1714-1718页

作者： Yuyang WANG Jinzhi DING Shilong PIAO Sino-French Institute for Earth system Science College of Urban and Environmental SciencesPeking UniversityBeijing 100871China State key laboratory of Tibetan Plateau Earth system Environment and ResourcesInstitute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China

Global warming is causing the Tibetan permafrost to degrade, as evidenced by rising ground temperatures, thicker active layer thickness, thinner permafrost layer, and melting underground ice, etc.(Ran et al., 2018;Wang et al., 2020).The degradation of permafrost not only profoundly alters the carbon cycling processes in high-altitude ecosystems,thereby influencing the regional climate system, but also affects landscape hydrological connectivity。

关键词： Tibetan landscape altitude