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Applied Mathematics and Mechanics(English Edition) 2025年第1期46卷 25-36页

作者： Jue ZHU Longyuan LI Ningtao ZHU Zhejiang Provincial Engineering Research center for the Safety of Pressure Vessel and Pipeline Key Laboratory of Impact and Safety Engineering (Ningbo University) Ministry of Education School of Engineering Computing and Mathematics University of Plymouth Xi'an Zhanshi testing & Engineering Co.Ltd.

Carbon nanotubes(CNTs) have garnered great attention in recent years due to their outstanding electrical, thermal, and mechanical properties. The incorporation of small amounts of CNTs in polymers can substantially improve the sensitivity of the polymer's electrical conductivity. This paper presents a modified Maxwell model to evaluate the electrical conductivity of CNTs-filled polymer composites by introducing a transition zone to account for the tunneling effect. In this modified Maxwell model, the CNTs-filled polymer composite is modeled as a three-phase composite, consisting of a matrix(polymer), inclusions(CNTs), and a transition zone(tunneling zone). The effective electrical conductivity(EEC) of the composite is calculated based on the volume fractions and electrical conductivities of the matrix, inclusions, and transition zone. The model's validity is confirmed through the use of available test data, which demonstrates its capability to accurately capture the nonlinear conductivity behavior observed in CNTs-polymer composites. This study offers valuable insights into the design of high-performance conductive polymer nanocomposites, and enhances the understanding of electrical conduction mechanisms in CNT-dispersed polymer composites.

关键词： carbon nanotube (CNT) polymer composite electrical conductivity tunneling Maxwell model O242.2 O441.1

Establishing a new testing protocol of the electrochemical stability window for electric double-layer capacitors

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Science China Chemistry 2025年第01期 217-225页

作者： Ruilin Hou Xiaoxi Zhao Tingting Liang Qingyun Dou Shan Xu Xingbin Yan School of Materials Science and Engineering Sun Yat-sen University Laboratory of Clean Energy Chemistry and Materials Lanzhou Institute of Chemical Physics Chinese Academy of Sciences College of Engineering and Applied Sciences Nanjing University center of Industrial Analysis and testing Guangdong Academy of Science

The electrochemical stability window(ESW) is crucial for determining the energy density of electric double-layer capacitors(EDLCs). However, current ESW testing protocols of EDLCs are strongly affected by artificial factors, thereby leading to unreliable result. To solve this problem, we first identify the key shortcomings of the traditional protocols by analyzing their test principles. Subsequently, taking an aqueous carbon-based EDLC as an example, we design a side reaction descriptor to represent the response difference in the charging capacitance to side reactions between the cyclic voltammetry and galvanostatic chargedischarge methods. With the aid of this descriptor, we propose a new ESW testing protocol, which is not only able to completely avoid the adverse influence of subjective factors but also fully consider the operating condition limitations. The protocol can be extended from the single electrode to the full device. This work proposes a more rigorous definition of ESW and provides a reliable protocol for evaluating the ESW of EDLCs.

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High-selectivity electroreduction of low-concentration CO2 with large concentration fluctuation

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Science China Chemistry 2025年

作者： Mengyu Qi Yanbin Ma Chao Zhang Bingwei Li Xueqing Yang Zhaolin Shi Simeng Liu Changhua An Jiqing Jiao Tongbu Lu MOE International Joint Laboratory of Materials Microstructure Analysis and Testing CenterInstitute for New Energy Materials and Low Carbon TechnologiesSchool of Materials Science and EngineeringSchool of Chemistry and Chemical EngineeringTianjin University of Technology Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Nankai University

Electrochemical CO2reduction reaction（CO2RR） has been regarded as one of the most promising solutions to achieving “zero carbon emission”. In most of the CO2RR-related studies, high-purity CO2has been employed as the feed gas; however, in practice, CO2is generally emitted in low concentrations, so it is of great significance to realize high-selectivity electroreduction of low-concentration CO2with large concentration fluctuation. In this work, we constructed a dual-active-site catalyst and successfully achieved CO2local enrichment and conversion for low-concentration CO2. Operando experiments reveal that the catalyst has one type of site for activating CO2and one type of site for binding the reaction intermediates. The dual-active-site catalyst displays a selectivity for formic acid consistently above 97% over a broad potential window（from-0.9 to-1.6 V ***）. Even when fed with a low-concentration CO2stream（volume ratio from 50% down to 10%）, the dual-active-site catalyst could display high activity and selectivity（>91%）. In particular, the selectivity is still above 85% when the CO2volume ratio is as low as 5%. This work offers a feasible route for converting low-concentration CO2via a synergistic effect for dual-active-site catalysts.

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A New Inorganic-organic Hybrid Based on Biisoquinoline and Hexachloridostannate:Structure, Photoluminescence, Electrochemical Behavior and Theoretical Study

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Chinese Journal of Structural Chemistry 2014年第11期33卷 1689-1696页

作者：肖光参 testing center of Fuzhou University

A new inorganic-organic hybrid constructed from biisoquinoline dication and tin halide, [（BIQBT）（Sn Cl6）]n（1, BIQBT = 1,4-bis（isoquinoline） butane）, has been synthesized and structurally determined by X-ray diffraction method. 1 crystallizes in the monoclinic system, space group Cc with Mr = 644.82, a = 16.589（3）, b = 18.388（4）, c = 8.5532（17）A, β = 108.75（3）°, V = 2470.6（9） A3, Z = 4, Dc = 1.736 g/cm^3, F（000） = 1281, μ（Mo Kα） = 1.697 mm^–1, the final R = 0.0197 and wR = 0.0493 for 4614 observed reflections with I 〉 2（I）. 1 consists of BIQBT^2＋dications and mononuclear hexachloridostannate Sn Cl62- anion, and hydrogen bonds among them contribute to the formation of a 1-D chain. Strong fluorescence can be detected in 1, which was explained by theoretical calculation. Its electrochemical behavior was investigated, and the theoretical calculations reveal that the π···π stacking interaction is dominated for their structural stabilization.

关键词： inorganic-organic hybrid tin halide biisoquinoline electrochemical property DFT calculation

Determination of paraquat in water samples using a sensitive fluorescent probe titration method

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Journal of Environmental Sciences 2013年第6期25卷 1245-1251页

作者： Feihu Yao Hailong Liu Guangquan Wang Liming Du Xiaofen Yin Yunlong Fu Analytical and testing center Shanxi Normal University

Paraquat （PQ）, a nonselective herbicide, is non-fluorescent in aqueous solutions. Thus, its determination through direct fluorescent methods is not feasible. The supramolecular inclusion interaction of PQ with cucurbit[7]uril was studied by a fluorescent probe titration method. Significant quenching of the fluorescence intensity of the cucurbit[7]uril-coptisine fluorescent probe was observed with the addition of PQ. A new fluorescent probe titration method with high selectivity and sensitivity at the ng/mL level was developed to determine PQ in aqueous solutions with good precision and accuracy based on the significant quenching of the supramolecular complex fluorescence intensity. The proposed method was successfully used in the determination of PQ in lake water, tap water, well water, and ditch water in an agricultural area, with recoveries of 96.73% to 105.77%. The fluorescence quenching values （AF） showed a good linear relationship with PQ concentrations from 1.0 × 10^-8 to 1.2× 10^-5 mol/L with a detection limit of 3.35 x 10-9 mol/L. In addition, the interaction models of the supramolecular complexes formed between the host and the guest were established using theoretical calculations. The interaction mechanism between the cucurbit[7]uril and PQ was confirmed by 1H NMR spectroscopy.

关键词： paraquat coptisine cucurbituril supramolecular interaction fluorescent probe titration

Fabrication and measurement of traceable pitch standard with a big area at trans-scale

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Chinese Physics B 2014年第9期23卷 143-147页

作者：邓晓李同保雷李华马艳马蕊翁浚婧李源 School of Physics Science and Engineering Tongji University Shanghai Institute of Measurement and testing Technology National Center of Measurement and Testing for East ChinaNational Center of Testing Technology

Atom lithography with chromium can be utilized to fabricate a pitch standard, which is chrectly traceable to me wavelength of the laser standing waves. The result of a calibrated commercial AFM measurement demonstrates that the pitch standard is （212.8±0.1） nm with a peak-to-valley-height （PTVH） better than 20 nm. The measurement results show the high period accuracy of traceability with the standing laser wavelength （λ/2 = 212.78 nm）. The Cr nano-grating covers a 1000μm×500 μm area, with a PTVH better than 10 nm. The feature width broadening of the Cr nanostructure has been experimentally observed along the direction of the standing waves. The PTVH along the Gaussian laser direction is similar to a Gaussian distribution. Highly uniform periodic nanostructures with a big area at the millimeter scale, and the surface growth uniformity of the Cr nano-grating, show its great potential in the application of a traceable pitch standard at trans-scales.

关键词： atom lithography nano-scale metrology standard traceability

Synthesis and photoluminescent properties of water-soluble TbF_3 nanoparticles

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Journal of Rare Earths 2011年第11期29卷 1018-1021页

作者：王振领张新磊常加忠李春阳 Analytical and testing center Zhoukou Normal University

Monodispersed and water-soluble TbF3 nanoparticles were synthesized at a relatively low temperature in aqueous solution using citric acid as an additive,and characterized by X-ray diffraction（XRD）,field emission scanning electron microscopy（FE-SEM）,Fourier transform infrared spectra（FTIR）,photoluminescence（PL） spectra and *** as-prepared TbF3 nanoparticles had orthorhombic structure and were composed of monodispersed spherical particles with an average particle size of 50 *** excitation spectrum of TbF3 nanoparticles obtained by monitoring the emission of Tb3＋ at 543 nm was composed of the characteristics f-f transition lines within the Tb3＋ 4f8 *** the UV light irradiation,the emission spectrum exhibited four obvious lines centered at 489,543,589,and 618 nm,which was corresponding to the 5D4→7FJ（J=6,5,4,3） transitions of the Tb3＋ ions in TbF3 nanoparticles.

关键词： Tphotoluminescence TbF3 monodispersed water-soluble rare earths

ESTIMATION OF BLENDING RATIO OF TWO-COMPONENT FIBER BUNDLE FROM BUNDLE LOAD-ELONGATION CURVE

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Journal of China Textile University(English Edition) 1989年第1期7卷 1-9页

作者：严灏景王国强 Fiber Science testing center

In this paper, two methods were developed to assess the blending ratio of two-componentfiber bundles. They were the peak-height method and the slope method. The relationship be-tween blending ratio and testing data was analysed, and the regression curves were obtained bystepwise regression method. It was pointed out that the testing errors of both methods were lessthan two percent. The validities of both methods were verified by experiments, All calculationsof both methods were completed by computer. The blending ratio was ascertained from the test-ing data of bundle fiber strength tester which was made by the authors themselves.

关键词： two-component fiber bundle tensile properties blending ratio pcak-height method slope method regression curve

An NIR-Ⅱ-emissive Ru(Ⅱ) metallacycle for efficient and safe immunotherapy

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Science China Chemistry 2025年第01期 5-7页

作者： Chonglu Li Jianbo Zhan Biao Dong Institute of Health Inspection and testing Hubei Provincial Center for Disease Control and Prevention State Key Laboratory on Integrated Optoelectronics College of Electronic Science and Engineering Jilin University

Immunotherapy, as a groundbreaking cancer treatment, has gained considerable attention for its utilization of the body’s immune system to combat tumors [1]. This therapy induces tumor cell apoptosis, triggering a sustained anti-tumor immune response and effectively preventing tumor recurrence and metastasis [2]. The fundamental principle lies in inducing tumor cell death through specific treatment modalities, leading to the release of a cascade of signaling molecules and antigens, thereby mobilizing the immune system to actively identify and attack tumor cells [3].

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Quantum Chemistry Calculation of Quercetin-silver Complex

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Chinese Journal of Structural Chemistry 2005年第11期24卷 1340-1346页

作者： JIANG Liu-Yun LIU Yu-Ming Analytical and testing center of Sichuan University Chengdu 610064 China

Three possible molecular structures of quercetin-silver complexes obtained from the reaction of quercetin and Ag^＋ in equivalent molar ratio were designed and optimized by using Gaussian 98 program at the B3LYP/LanL2DZ basis set. Through theoretical analysis, one of the three designed structures is discovered to have the most stable coordination position. Then its geometry structure, natural bond orbital analyses, vibrational frequency and biological activity were performed. The results show that it has good stability and relatively stronger antioxidative activity because it is favorably attacked by O2^-. Therefore theoretical foundation is provided for the development of new quercetin metal complexes with higher activity antioxidants.

关键词： quercetin,silver-complex quantum chemistry