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Journal of Rare Earths 2024年第6期42卷 1182-1186,I0007页

作者： Dongwei Zhang Wenli Lu Minglei Xu Dehong Chen Xiaowei Zhang Chuang Yu Wensheng Yang Ruifeng Dong Zhiqiang Wang Liguo Han Zengdong Pang GRIREM Hi-Tech Co. Ltd.Langfang065201China National Engineering Research Center for Rare Earth China GRINM Group Co.Ltd.Beijing100088China GRIREM Advanced Materials Co. Ltd.Beijing100088China

In light of the difficult removal of harmful impurity tungsten(W)in Ce metal,in this paper a combined vacuum gravity sedimentation-directional solidification method was innovatively designed and the W separation behavior was *** reducing the electron beam power instantly and gradually at reduction rates of 1,3 and 5 kW/min,it is found that W is enriched at the bottom of ingots as the melt *** enrichment effect is much better than that of single purification method and the enrichment degree increases as the beam reduction rate decreases,attributed to the k0(W)>1 andρ(W)>ρ(Ce).Overall,the minimum content of W impurity can decrease from 630 to 0.1 ppm at the top of the ingot,and the purity of Ce increases from 99.932 wt%to 99.995 wt%by this combined ***,this paper provides a new method for the removal of high density and low evaporation coefficient impurities in low vapor pressure rare earth metals.

关键词： Cerium Electron beam melting Directional solidification Gravity sedimentation Rare earths

基于微震多参数的大规模岩体垮塌前兆特征研究

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Journal of Central South University 2024年第3期31卷 878-889页

作者：柳建新杨顺李磊潘新朋尹贤刚胡静云彭府华 Key Laboratory of Metallogenic Prediction of Nonferrous metals and Geological Environment Monitoring(Central South University) Ministry of EducationChangsha 410083China Hunan Key Laboratory of Nonferrous Resources and Geological Hazard Exploration Changsha 410083China School of Geosciences and Info-Physics Central South UniversityChangsha 410083China Changsha Institute of Mining Research Co. Ltd.Changsha 410012China

微震监测技术能进行工程岩体失稳垮塌前兆特征的辨识和分析,对于地质灾害预警防控具有重要意义。本文基于已有室内岩石受压损伤破坏声发射实验规律,通过开展现场微震多参数定量分析,探究了柿竹园矿山6·21大爆破诱发山体滑移垮塌的前兆... 详细信息

微震监测技术能进行工程岩体失稳垮塌前兆特征的辨识和分析,对于地质灾害预警防控具有重要意义。本文基于已有室内岩石受压损伤破坏声发射实验规律,通过开展现场微震多参数定量分析,探究了柿竹园矿山6·21大爆破诱发山体滑移垮塌的前兆特征。大爆破诱发微震事件的b值和空间分形维数表现出下降趋势,b值急剧下降和分形维数降到最低可作为工程岩体失稳垮塌的前兆特征。此外,能量指数和累计视体积的变化可以分别表征应力和应变的变化。能量指数快速下降和累计视体积持续增加的组合特征反映了岩体的失稳状态。经过多个失稳破坏阶段后岩体发生最终的失稳垮塌。该案例表明微震监测能为工程岩体失稳垮塌的预警和防控提供重要信息,也为涉及爆破作业的诸多地质工程活动的安全监测提供了参考。

关键词：微震监测岩体垮塌前兆特征预警

Unlocking single-atom catalysts via amorphous substrates

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Nano Research 2024年第5期17卷 3533-3546页

作者： Bohua Sun Mingyuan Xu Xiaoxia Li Baohong Zhang Rui Hao Xiaoyu Fan Binbin Jia Dingshun She School of Engineering and Technology China University of Geosciences(Beijing)Beijing 100083China Zhengzhou Institute China University of Geosciences(Beijing)Zhengzhou 451283China College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion MaterialsChina Three Gorges UniversityYichang 443002China School of Chemistry Beihang UniversityBeijing 100191China Chinese Academy of Sciences(CAS)Key Laboratory of Nanosystem and Hierarchy Fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190China National Engineering Research Center of Nonferrous metals Materials and Products for New EnergyChina GRINM Group Co.Ltd.Beijing 100088China

Single-atom catalysts(SACs)reveal great potential for application in catalysis due to their fully exposed active *** general,single atoms(SAs)and the coordination substrates need to have strong interactions or charge transfer to ensure the atomic dispersion,which requires the selection of a suitable substrate to stabilize the target *** studies have demonstrated that amorphous materials with abundant defects and coordinatively unsaturated sites can be used as substrates for more efficient capturing SAs,further enhancing the catalytic *** this review,we discuss recent research progress of SAs loaded on amorphous substrates for enhanced catalytic ***,we summarize the commonly used amorphous substrates for stabilizing ***,we present several advanced applications of amorphous SACs in the field of catalysis,including electrocatalysis and *** then,we also clarify the synergistic mechanism between SAs and amorphous substrate on catalytic ***,we summarize the challenges with our personal views and provide a critical outlook on how amorphous SACs continue to evolve.

关键词： single-atoms amorphous substrate synthetic strategy catalysis

A novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite oxide with surface doping of Y and its application in Pd-only three-way catalyst

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Rare metals 2024年第2期43卷 749-757页

作者： Zheng Zhao Wei-Xin Zhao Yong-Qi Zhang Mei-Sheng Cui Yong-Ke Hou Dong-Ming Chen Juan-Yu Yang Zong-Yu Feng Xiao-Wei Huang National Engineering Research Center for Rare Earth Grirem Advanced Materials Co.Ltd.GRINM Group Corporation LimitedBeijing100088China Griem Hi-Tech Co.ltd. Langfang065000China Rare Earth Functional Materials(Xiong’an)Innovation Venter Co.ltd. Baoding071700China

The ceria-zirconia compound oxide-supported noble metal Pd(Pd@CZ)is widely used in three-way ***,the surface structure of CZ plays an important role in catalytic activity of ***,how to regulate the surface structure of CZ and clarify the structure–activity relationship is still a *** this paper,a strategy is proposed to develop high activity Pd@CZ nanocatalysts by tuning Y doping sites in *** precipitate-deposition method is developed to prepare the novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite with surface doping of Y(CZ-Y-S).In addition,the Pd@CZ-Y-S(Pd supported on CZ-Y-S)exhibits superior catalytic activity for HC,CO,and NO oxide,wherein,for CO and C_(3)H_(6) oxidation,the low-temperature activity of Pd@CZ-Y-S is still 20%higher than that of Pd@CZ-Y-B(Y bulk doping)and commercial Pd@CZ after 1000℃/4 h *** effect mechanism is further studied by density functional theory(DFT)*** with Pd@CZ-Y-B,Pd@CZ-Y-S shows the lower CO oxide reaction energy barriers due to the weaker adsorption strength of *** Y surface doping strategy could provide valuable insights for the development of highly efficient Pd@CZ catalyst with extensive applications.

关键词： Rare earth Ceria-zirconia-supported Pd Surface doping Experiment and theory Catalytic application

Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries:Process analysis and evaluation

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Chinese Chemical Letters 2024年第7期35卷 178-182页

作者： Yun Wei Lei Zhou Wenbin Hu Liming Yang Guang Yang Chaoqiang Wang Hui Shi Fei Han Yufa Feng Xuan Ding Penghui Shao Xubiao Luo National-Local Joint Engineering Research Center of Heavy metals Pollutants Control and Resource Utilization Nanchang Hangkong UniversityNanchang 330063China School of Life Science Jinggangshan UniversityJi’an 343009China CAS Key Laboratory of Green Process and Engineering National Engineering Research Center of Green Recycling for Strategic Metal ResourcesInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China Biomass Molecular Engineering Center and Anhui Provincial Key Laboratory of Microbial Pest Control Anhui Agricultural UniversityHefei 230036China Jiangxi Ganfeng Recycling Technology Co.ltd. Xinyu 338004China

The efficient and environmentally friendly recycling technology of waste residue that including abundant heavy metal produced during the recovery of lithium batteries has become a research ***,a novelty process of acid leaching-selective electrodeposition-deep impurity removal-regeneration was proposed to recovery of the CuS slag,which has been efficient transferred to high purity cathode copper and commercially available ternary *** cathode with a purity of 99.67%was prepared under electrochemical reaction conditions at-0.55 V for 2 h.A novel impurity remover-Mn powder,which was used to remove the residual impurities and as a feedstock for the ternary ***,NCM523 was regenerated by *** process is superior to the traditional process in economy,energy consumption,CO_(2)emissions,product purity and process *** study provides a new approach for solid waste recovery and precious metal enrichment.

关键词： CuS slag Electrodeposition Cathode copper Ternary precursor Solid waste recovery

Microstructure and properties of Cu-2.8Ni-0.6Si alloy

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Rare metals 2013年第3期32卷 228-233页

作者： Xiang-Peng Xiao Bai-Qing Xiong Guo-Jie Huang Lei Cheng Li-Jun Peng Qi-Ming Liang State Key Laboratory for Fabrication and Processing of Nonferrous metals General Research Institute for Nonferrous Metals China Nonferrous metals Processing Technology Albetter Albronze Co. Ltd.

The phase transformation behavior and heat treatment response of Cu-2.8Ni-0.6Si （wt%） alloy sub- jected to different heat treatments were studied by X-ray diffraction, transmission electron microscopy observation, and measurement of hardness and electrical conductivity. The variation of hardness and electrical conductivity of the alloy was measured as a function of aging time. On aging at the temperature below TR （500-550 ℃） in Cu-2.8Ni-0.6Si alloy, the transformation undergoes spinodal decomposi- tion, DO22 ordering, and δ-NiaSi phase. On aging at the temperature above TR （500-550 ℃）, the transformation products were precipitations of 8-Ni2Si. The free energy versus composition curves were employed to explain the microstructure observations.

关键词： Microstructure Hardness Electricalconductivity Spinodal decomposition DO22 ordering

多孔介质中膨润土悬浮液携带负载型纳米零价铁的强化传输

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Journal of Central South University 2024年第4期31卷 1149-1162页

作者：魏贺贺勇江钧宋相志娄伟张召张可能 Key Laboratory of Metallogenic Prediction of Nonferrous metals and Geological Environment Monitoring(Central South University) Ministry of EducationChangsha 410083China School of Geosciences and Info-Physics Central South UniversityChangsha 410083China School of Metallurgy and Environment Central South UniversityChangsha 410083China School of Chemistry and Chemical Engineering Central South UniversityChangsha 410083China Hunan HIKEE Environmental Technology Co. Ltd.Changsha 410221China

为强化纳米零价铁(nZVI)在多孔介质中的传输,采用膨润土悬浮液携带高岭土负载纳米零价铁(K-nZVI)。通过沉降试验和流变性试验确定了修复剂中膨润土和K-nZVI掺量最佳配比;开展模拟柱试验,探讨了不同注入压力下K-nZVI在多孔介质中的迁移特... 详细信息

为强化纳米零价铁(nZVI)在多孔介质中的传输,采用膨润土悬浮液携带高岭土负载纳米零价铁(K-nZVI)。通过沉降试验和流变性试验确定了修复剂中膨润土和K-nZVI掺量最佳配比;开展模拟柱试验,探讨了不同注入压力下K-nZVI在多孔介质中的迁移特性;结合数值模拟,分析了修复剂配比和注入压力对K-nZVI扩散半径的影响规律。试验结果表明,膨润土悬浮液能显著提高K-nZVI的稳定性和分散性;膨润土和K-nZVI最佳掺量分别为5%和0.4%;膨润土悬浮液携带K-nZVI修复剂注入多孔介质中时存在临界注入压力。数值模拟结果表明,K-nZVI扩散半径与注入压力呈正相关,与修复剂黏度呈负相关。本文研究结果可为有色冶炼场地重金属污染修复工程提供理论指导。

关键词：重金属污染膨润土悬浮液高岭土负载纳米零价铁扩散半径强化传输

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锌和锌合金的腐蚀(二)

腐蚀与防护 2006年第2期27卷 98-108页

作者：章小鸽加拿大teck Cominco metals ltd.

5 水、溶液、土壤和其它环境中的腐蚀5.1 水和溶液中在室温敞开于空气的蒸馏水中,锌腐蚀形成小孔.这些小孔的形成依赖于水的氧含量.当水贫氧时,没有什么腐蚀,当氧压高时,腐蚀为均匀形式.

关键词：锌腐蚀锌合金蒸馏水氧含量溶液小孔室温

Effect of process parameters on the morphology of aluminum/copper alloy lap joints by red and blue hybrid laser welding

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China Welding 2024年第2期33卷 23-30页

作者：宋曜祥肖梦智黄德才张瑞华尹燕茹恩光吴怡霖 State Key Laboratory of Advanced Processing and Recycling of Nonferrous metals Lanzhou730050China China Iron&Steel Research Institute Group Beijing100081China Hardware Knife Cut Industrial Technology Research Institute Yangjiang Yangjiang529533China Guangdong Hall Laser Technology Co. Ltd.Foshan528251China

In order to overcome the problems of many pores,large deformation and unstable weld quality of traditional laser welded aluminumcopper alloy joints,a red-blue dual-beam laser source and a swinging laser were introduced for welding.T2 copper and 6063 aluminum thin plates were lap welded by coaxial dual-beam laser *** morphology of weld cross section was compared to explore the influence of process parameters on the formation of lap *** microstructure characteristics of the weld zone were observed and compared by optical *** results show that the addition of laser beam swing can eliminate the internal pores of the *** the increase of the swing width,the weld depth decreases,and the weld width increases first and then *** influence of welding speed on the weld cross section morphology is similar to that of swing *** the increase of welding speed,the weld width increases first and then decreases,while the weld depth decreases all the *** is because that the red laser is used as the main heat source to melt the base metals,with the increase of red laser power,the weld depth *** an auxiliary laser source,blue laser reduces the total energy consumption,consequently,the effective heat input increases and the spatter is restrained *** a result,the increase of red laser power has an enhancement effect on the weld width and weld *** the swing width is 1.2 mm,the red laser power is 550 W,the blue laser power is 500 W,and the welding speed is 35 mm/s,the weld forming is the *** lap joint of T2 copper and 6063 aluminum alloy thin plate can be connected stably with the hybrid of blue *** effect rules of laser beam swing on the weld formation were obtained,which improved the quality of the joints.

关键词： laser welding aluminum/copper alloy dual beam process parameters weld morphology

Mechanism of a dual-phase Ti-Nb alloy exhibiting near-linear elastic deformation

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Rare metals 2024年第5期43卷 2282-2289页

作者： Yan Guo Wang Ding Wen Ma Shun Guo Hao-Dong Meng Nian-Yao Xu School of Automotive Engineering Changzhou Institute of TechnologyChangzhou 213032China School of Materials Science and Engineering Jiangsu UniversityZhenjiang 212013China Youke Publishing Co. LtdChina Grinm Group Co.LtdBeijing 100088China

In this work,the underlying mechanism responsible for the near-linear elastic deformation behavior of a dual-phase Ti-Nb alloy consisting of β and α'' phase with large recoverable strain was systematically *** on in situ synchrotron X-ray diffraction(SXRD)analyses,it was found that besides intrinsic elastic deformation,a slight reversible β-α'' stress-induced martensitic(SIM)transformation,which proceeded in a consecutive mode under the retarding effect of micro-defects,took place during the near-linear elastic *** unloading,a small amount of residual macroscopic strain remained in the specimen due to the incomplete reverse α''→β transformation on *** high near-linear elastic deformability of the cold drawing(CD)Ti-Nb alloy has been revealed to be attributed to the coupling actions of intrinsic elasticity as well as the consecutive and reversible β-α'' SIM *** research may contribute to a new avenue for the design and development of novel dual-phase Ti-based alloys with desirable elastic deformability.

关键词： Titanium alloys Dual-phase Near-linear elastic deformation Martensitictransformation