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Promoted monolithic perovskite/organic tandem solar cells through elaborate manipulation of light transmission and carrier tunneling in interconnect junction

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Science China Chemistry 2024年第9期67卷 3131-3139页

作者： Rongbo Wang Jiawei Zhang Juntao Zhao Ya Wang Yi Ding Ying Zhao Xiaodan Zhang Guofu Hou Institute of Photoelectronic Thin Film Devices and Technology Renewable Energy Conversion and Storage CenterSolar Energy Conversion CenterNankai UniversityTianjin 300350China Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin Tianjin 300350China Engineering Research center of Thin Film Photoelectronic Technology of Ministry of Education Tianjin 300350China State Key Laboratory of Photovoltaic Materials and Solar Cells Tianjin 300350China

Monolithic perovskite/organic tandem solar cells(TSCs)have emerged as promising thin film solar *** is recognized that interconnect junction plays a pivotal role in tandem ***,wide bandgap Cs_(0.25)FA_(0.75)Pb(I_(0.6)Br_(0.4))_(3)perovskite top-cell and narrow bandgap PM6:Y6:PC_(61)BM ternary organic bottom-cell were integrated in this study with several kinds of thin metal interconnect layers,which provides feasibility to elaborately manipulate light transmission and carrier tunneling process in interconnect *** is confirmed that,in comparison with Au,employing an Ag interconnect layer elevates integrated transmittance of light in longer wavelength regions,mainly because of the alleviated screening effect with a lower free electron concentration,which offers sufficient light harvest for the ***,established energy barriers with moderate height afford convenient extraction and recombination for both holes and ***,the performance of TSCs is promoted ***,an innovative Ag/Au double interconnect layer is proposed accordingly,which can preserve exceptional conductivity and light transmission and further reduce barrier height,especially for hole tunneling,by optimizing the band alignment between the interconnect layer and ***,the monolithic perovskite/organic TSC with a striking efficiency of 23.26% is *** a word,this study can pave a general approach toward high-performance TSCs integration.

关键词： tandem solar cells band alignment perovskite organic solar cells interconnect junction

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Chemical vapor deposition for perovskite solar cells and modules

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Journal of Semiconductors 2024年第4期45卷 1-4页

作者： Zhihao Tao Yuxuan Song Baochang Wang Guoqing Tong Liming Ding School of Materials Science and Engineering Hefei University of TechnologyHefei 230009China center for Excellence in Nanoscience(CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication(CAS)National Center for Nanoscience and TechnologyBeijing 100190China

Metal halide perovskites are promising materials for solar cells because of high power conversion efficiency(PCE),tun-able bandgap,high defect tolerance,long carrier diffusion length,and low-cost fabrication[1-7].The PCE for perovskite solar cells(PSCs)reaches 26.14%for single-junction cells,29.1%for perovskite/perovskite tandem cells and 33.9%for perovskite/silicon tandem cells,being comparable to that for silicon and other thin-film solar cells[8-10].Perovskite solar cells have been made by solution methods including spin-coat-ing,blade coating and printing[11,12].

关键词： perovskite blade film

Propane dehydro-aromatization reaction over PtFe@S-1 coupling with Zn/ZSM-5 tandem catalysts: the role of Zn species

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Frontiers of Chemical Science and Engineering 2024年第8期18卷 25-35页

作者： Kai Bian Sirui Liu Huahua Fan Guanghui Zhang Xinwei Zhang Gideon Abaidoo Ocran Mingrui Wang Quanjie Liu Xiaowa Nie Shuandi Hou Xinwen Guo Sinopec Dalian Research Institute of Petroleum and Petrochemicals Dalian 116045China State Key Laboratory of Fine Chemicals Frontier Science Center for Smart MaterialsPSU-DUT Joint Center for Energy ResearchSchool of Chemical EngineeringDalian University of TechnologyDalian 116024China

Unraveling the structure-activity relationship and improving the catalytic performance is paramount in propane dehydro-aromatization reactions. Herein, a tandem catalyst with high propane dehydro-aromatization reaction performance was prepared via coupling the PtFe@S-1 with Zn/ZSM-5 zeolites (PtFe@S-1&1.0Zn/ZSM-5), which exhibits high dehydrogenation activity, aromatics selectivity (~60% at ~78% propane conversion), and stability. The addition of zinc inhibits the cleavage of C_(6)^(=) intermediates on ZSM-5 and promotes the aromatization pathway by weakening zeolite acid strength, significantly improving the selectivity to aromatics. This understanding of the structure-activity relationship in propane dehydro-aromatization reaction helps develop future high-performance catalysts.

关键词： propane dehydro-aromatization reaction tandem catalysts the structure-activity relationship of zinc species

The evolution and functional divergence of 10 Apolipoprotein D-like genes in Nilaparvata lugens

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Insect Science 2024年第1期31卷 91-105页

作者： Jia-Bao Lu Peng-Peng Ren Qiao Li Fang He Zhong-Tian Xu Sai-Nan Wang Jian-Ping Chen Jun-Min Li Chuan-Xi Zhang Citrus Research Institute Southwest University/Chinese Academy of Agricultural SciencesNational Engineering Research Center for CitrusChongqingChina Technology center of Wuhan Customs District HubeiChina Institute of Insect Science Zhejiang UniversityHangzhouChina

Apolipoprotein D(ApoD),a member of the lipocalin superfamily of proteins,is involved in lipid transport and stress *** only a single copy of the ApoD gene is found in humans and some other vertebrates,there are typically several ApoD-like genes in *** date,there have been relatively few studies that have examined the evolution and functional differentiation of ApoD-like genes in insects,particularly hemi-metabolous *** this study,we identified 10 ApoD-like genes(NlApoD1−10)with distinct spatiotemporal expression patterns in Nilaparvata lugens(BPH),which is an important pest of ***1−10 were found to be distributed on 3 chromosomes in a tandem array of NlApoD1/2,NlApoD3−5,and NlApoD7/8,and show sequence and gene structural divergence in the coding regions,indicating that multiple gene duplication events occurred during *** analysis revealed that NlApoD1−10 can be clustered into 5 clades,with NlApoD3−5 and NlApoD7/8 potentially evolving exclusively in the Delphacidae *** screening using an RNA interference approach revealed that only NlApoD2 was essential for BPH development and survival,whereas NlApoD4/5 are highly expressed in testes,and might play roles in ***,stress response analysis revealed that NlApoD3−5/9,NlApoD3−5,and NlApoD9 were up-regulated after treatment with lipopolysaccharide,H2O2,and ultraviolet-C,respectively,indicating their potential roles in stress resistance.

关键词： Apolipoprotein D BPH evolution functional divergence gene duplication NIApoD

Reduced exciton binding energy and diverse molecular stacking enable high-performance organic solar cells with V_(OC)over 1.1 V

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Science China Chemistry 2024年第9期67卷 3140-3152页

作者： Tingting Dai Jiahao Lu Ailing Tang Yuhan Meng Peiqing Cong Zongtao Wang Erjun Zhou National center for Nanoscience and Technology Beijing 100190China center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China College of Chemistry and Chemical Engineering Guangxi Minzu UniversityNanning 530006China Henan Institute of Advanced Technology Zhengzhou UniversityZhengzhou 450003China

High-voltage organic solar cells(OSCs)have received increasing attention because of their promising applications in tandem devices and indoor photovoltaics,but the trade-off between energy loss and charge generation induced by exciton binding energy(E_(b))has become one of the biggest bottlenecks limiting the development of this ***,a wide bandgap(WBG)nonfullerene acceptor BTA503 with reduced E_(b) is designed by changing the phenyl side chain on the central core of Cl-BTA5 to an alkyl *** diverseπ-πinteractions and enhanced molecular stacking of BTA503 are responsible for its reduced E_(b).Furthermore,both the diminished charge recombination and the fast exciton dissociation caused by the small E_(b) favor the generation of more charge carriers for the PTQ10:BTA503 *** efficient Forster resonance energy transfer(FRET)and multiple π-π stacking patterns provide additional charge transfer and transport ***,the PTQ10:BTA503-based OSC device achieves a V_(OC)of 1.112 V and a PCE of 12.70%,which is higher than that of PTQ10:Cl-BTA5(PCE=10.92%).Simultaneously,the thick film(~300 nm)binary device of PTQ10:BTA503 achieves a PCE of 10.13% with a V_(OC)of 1.102 V,which is the best result for thick film high-voltage *** importantly,the ternary device of PTQ10:BTA503:Cl-BTA5(1:0.9:0.1)realizes a champion PCE of 13.12% with a V_(OC)of 1.126 *** study demonstrates that it is an effective strategy to reduce E_(b) of A_(2)-A_(1)-D-A_(1)-A_(2) type WBG acceptors by modulating the side chains on D unit,which further favors the corresponding devices to obtain world-record PCE and improves their potential for commercial applications.

关键词： exciton binding energy intermolecular interaction wide-bandgap acceptor high V_(OC) organic solar cells

A New High-Spin Level Scheme of ^128I

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Chinese Physics Letters 2010年第8期27卷 58-61页

作者：王海霞张玉虎丁兵周小红张宁涛柳敏良马英君 Y. Sasakiz K. Yamada H. Ohshima S. Yokose M. Ishizuka T. Komatsubara K. Furuno Insititute of Modern Physics Chinese Academy of Sciences Lanzhou 730000 Graduate School of the Chinese Academy of Sciences Beijing 100049 Department of Physics Jilin University Changehun 130021 Institute of Physics and tandem accelerator center University of Tsukuba Ibaraki 305-0006 Japan

High-spin states in the beam energies. A new and 72 γ transitions odd-odd nucleus ^128I are investigated via the ^124 Sn（^7 Li,3n）^128 I reaction at 28 and 32 Me V level scheme of 12sI is established up to high-spin states at I^π = 16, including 48 levels The present level scheme is largely different from the one in a recent publication due to identification of several doublet and triplet γ transitions and their proper placements in the level scheme. The high-spin level structure exhibits no obvious collective properties and is possibly associated with two and multi-quasiparticle configurations.

关键词： ENERGY levels (Quantum mechanics) PHASE transformations (Physics) NUCLEAR reactions PARTICLE beams QUASIPARTICLES (Physics)

Design and Synthesis of NiO@Co_(3)O_(4)@ZSM-5 Heterogeneous Multitask Hollow Structures for tandem Catalysis

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Chemical Research in Chinese Universities 2024年第3期40卷 529-535页

作者： Muhammad Waqas Interdisciplinary Research center for Refining and Advanced Chemicals King Fahd University of Petroleum&MineralsDhahran 31261Saudi Arabia

Precipitation and impregnation procedures unevenly distribute metals on zeolite,limiting chemical transformation in Lewis-acid,Brönsted-acid and metal-catalyzed tandem ***,heterogeneous multitask transition metals oxides@zeolites are promising catalysts for sustainable processes;nevertheless,synthesis is fascinating and ***,the construction of purposely designed multitask materials segregated in selective shells reveals the remarkable spatial organization of metals-zeolite,resulting in them being suitable for a wide range of tandem *** synthesis of multi-site catalysts begins with a universal wet chemistry approach that yields nickel oxide(NiO)***,the NiO crystals are stabilized using cationic dodecyltrimethylammonium bromide,followed by achieving cross-linking carbon growth by emulsion polymerization of glucose in hydrothermal treatment to yield uniformed NiO@carbon spheres(NiO@CSs).Next,sequential adsorption of cobalt cations and colloidal ZSM-5(1%in H_(2)O,mass fraction),followed by calcination in air,yielded NiO@cobalt oxide@zeolite denoted as NiO@Co_(3)O_(4)@ZEO hollow *** hollowing mechanism and materials segregation within shells are revealed by scanning and transmission electron microscopy,thermogravimetric analysis,and X-ray *** finding advances the rational synthesis of heterogenous core-shell hollow structures for various gas phase catalytic tandem reactions to yield valuable chemicals.

关键词： Multifunctional Core-shell hollow spheres Gas-phase reaction Valuable chemical

Identification of Fusarium wilt resistance gene SiRLK1 in Sesamum indicum L.

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The Crop Journal 2024年第1期12卷 252-261页

作者： Yinghui Duan Wenwen Qu Shuxian Chang Ming Ju Cuiying Wang Cong Mu Hengchun Cao Guiting Li Qiuzhen Tian Qin Ma Zhanyou Zhang Haiyang Zhang Hongmei Miao The Shennong Laboratory Zhengzhou 450002HenanChina Henan Sesame Research center Henan Academy of Agricultural SciencesZhengzhou 450002HenanChina Key Laboratory of Specific Oilseed Crops Genomics of Henan Province Henan Sesame Research CenterHenan Academy of Agricultural SciencesZhengzhou 450002HenanChina

Sesame Fusarium wilt(SFW),caused by Fusarium oxysporum ***(Fos),is one of the most devastating diseases affecting sesame *** the genetic control of SFW resistance is pivotal for effective disease management in *** inheritance study on a cross between the highly resistant variety Yuzhi 11 and the highly susceptible accession Sp1 using a Fos pathogenicity group 1 isolate indicated that resistance was conferred by a single dominant *** target locus was located in a 1.24 Mb interval on chromosome 3 using a combination of cross-population association mapping and bulked segregant *** genetic mapping further narrowed the interval between 21,350 and 21,401 *** locus Sindi_0812400 was identified as the SFW resistance gene and officially designated *** gene encodes a specific malectin/receptor-like protein kinase with three putative tandem kinase domains and is considered a kinase fusion *** analysis revealed that a high proportion(49.44%)of variants within the locus was located within the kinase domainⅢ,and several of which were evidently associated with the diversity in SFW response,indicating the critical role of kinase domainⅢin expression of disease *** findings provide valuable information for further functional analysis of SFW resistance genes and marker-assisted resistance breeding in sesame.

关键词： Breeding for resistance Genetic analysis Molecular analysis tandem kinase domain

Chemoselective labeling-based spermatozoa glycan imaging reveals abnormal glycosylation in oligoasthenotspermia

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Chinese Chemical Letters 2024年第4期35卷 475-480页

作者： Lijia Xu Tong Zhong Wei Zhao Bing Yao Lin Ding Huangxian Ju State Key Laboratory of Analytical Chemistry for Life Science School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China Department of Reproductive Medical center Jinling HospitalSchool of MedicineNanjing UniversityNanjing 210002China Chemistry and Biomedicine Innovation center(ChemBIC) Nanjing UniversityNanjing 210023China center of Clinical Laboratory Science The Affiliated Cancer Hospital of Nanjing Medical University&Jiangsu Cancer Hospital&Jiangsu Institute of Cancer ResearchNanjing 210009China

Spermatogenesis, maturation, capacitation and fertilization are precisely regulated by glycosylation. However, the relationship between altered glycosylation patterns and the onset and development of reproductive disorders is unclear, mainly limited by the lack of in situ imaging techniques for spermatozoa glycosylation. We developed an efficient and highly specific spermatozoa glycan imaging technique based on the robust chemoselective labeling of sialic acid(Sia) and N-acetyl-D-galactosamine(Gal/GalNAc). We further proposed a “tandem glycan chemoselective labeling” strategy to achieve simultaneous imaging of two types of glycans on spermatozoa. We applied the developed method to the spermatozoa from oligozoospermic patients and diabetic mice and found that these spermatozoa showed higher levels of Sia and Gal/Gal NAc expression than the normal groups. Moreover, spermatozoa from diabetic mice showed a severe decrease in number, viability, and forward motility, suggesting that in vivo glucose metabolism disorders may lead to an elevated level of spermatozoa glycosylation and have a correlation with the development of oligoasthenotspermia. Our work provides a research tool to reveal the relationship between glycosylation modification and spermatozoa quality, and a promising clue for the development of glycan-based reproductive markers.

关键词： Spermatozoa Glycan Chemoselective labeling Oligoasthenotspermia Fluorescence imaging