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Energy & Environmental materials 2024年第4期7卷 74-82页

作者： Manying Cui Hongyang Zhao Yanyang Qin Shishi Zhang Ruxin Zhao Miao Zhang Wei Yu Guoxin Gao Xiaofei Hu Yaqiong Su Kai Xi Shujiang Ding School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory for Mechanical Behavior of Materials Xi'an Jiaotong University Department of materials and Environmental Chemistry Stockholm University

Inhomogeneous lithium-ion （Li+） deposition is one of the most crucial problems,which severely deteriorates the performance of solid'State lithium metal batteries （LMBs）.Herein,we discovered that covalent organic framework （COF-1） with periodically arranged boron-oxygen dipole lithiophilic sites could directionally guide Li+even deposition in asymmetric solid polymer electrolytes.

关键词： covalent organic framework ion transport regulation lithium metal battery solid polymer electrolyte

Multi-performance evaluation of high-throughput accelerated corrosion test for high-strength low-alloy 921A steel

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Journal of Iron and Steel research International 2024年第5期31卷 1260-1278页

作者： Cong-cong Du Ming-hua Qin Zhan-fang Wu Dong-ling Li Lei Zhao Xiang-yang Li Hai-zhou Wang Beijing Advanced Innovation center for materials Genome Engineering National Center for Materials Service SafetyUniversity of Science and Technology BeijingBeijing100083China China Iron and Steel research Institute Group Co. Ltd.Beijing100081China Beijing Advanced Innovation center for materials Genome Engineering Central Iron and Steel Research InstituteBeijing100081China

The corrosion behavior of high-strength low-alloy 921A steel in a simulated marine atmospheric environment was studied using a high-throughput experimental *** corrosion behavior,corrosion morphology,and corrosion products of 921A steels were analyzed using various techniques,including corrosion mass loss method,polarization curve,white-light interferometry,scanning electron microscopy,energy-dispersive spectrometry,microbeam X-ray fluorescence spectrometry,X-ray diffraction technique,and X-ray photoelectron *** test results indicated that 921A steel exhibits better corrosion resistance than Q450NQR1 steel in simulated harsh atmospheric environments,as evidenced by a lower corrosion mass loss rate throughout the corrosion *** corrosion products of both steels consisted ofα-FeOOH,Fe_(3)O_(4),andγ-FeOOH,withα-FeOOH being more prevalent in the rust layer of 921A steel than in Q450NQR1 *** inner rust layer of 921A steel also exhibited an appositional enrichment region of Cr,Ni,Mo,and V,leading to its superior corrosion resistance compared to that of Q450NQR1 *** efficacy of high-throughput accelerated corrosion experimental methods was highlighted for evaluating the corrosion resistance of steel materials in harsh environmental *** findings suggest that 921A steel exhibits better corrosion resistance compared to Q450NQR1 steel and has the potential to be more suitable in harsh marine atmospheric *** characterization of the rust layer structures and composition reveals the parallel enrichment of certain elements in the inner rust layer of 921A steel,which enhances its corrosion resistance.

关键词： Atmospheric corrosion High-throughput experimental method High-strength low-alloy steel Corrosion characteristics Rust layer Element enrichment

Complementary multicolor electrochromic devices with excellent stability based on porous tin oxide nanosheet scaffold

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Nano research 2024年第4期17卷 3035-3042页

作者： Chenchen Bian Jinhui Wang Huanhuan Liu Yin Yan Ping Zhang Weilong Yang Sensen Jia Xiaodan Guo Guofa Cai Key Laboratory for Special Functional materials of Ministry of Education National&Local Joint Engineering Research Center for High-Efficiency Display and Lighting TechnologySchool of Materials and Engineeringand Collaborative Innovation Center of Nano Functional Materials and ApplicationsHenan UniversityKaifeng 475004China

Electrochromic devices(ECDs)have been extensively investigated as promising candidates in broad cutting-edge applications,such as smart windows,electronic labels,adaptive camouflage,***,they have suffered from either inadequate color variations or poor cycling stability for a long ***,we developed a general strategy to boost the cyclic stability and enrich the color variations of ECDs by scrupulous design of the composition and nanostructure of electrodes,in which porous tin oxide(SnO_(2))nanosheets serve as the scaffold and typical metal oxides or conducting polymers as the active electrochromic *** electrochromic composite materials,including polyaniline(PANI)@SnO_(2),V2O5@SnO_(2),and WO_(3)@SnO_(2) heterostructured nanoarrays were prepared by the facile wet-chemical *** composite electrodes exhibit remarkable electrochromic performances,e.g.,superior cycling stability(more than 2000 cycles),rich color variations(more than 5 colors for PANI@SnO_(2)),and enlarged optical *** excellent performances account for the heterogenous porous nanoarrays,which not only facilitate the intercalation/extraction of ions but also relieve the stress generated during the electrochemical *** addition,diverse prototypes of complementary multicolor ECD with excellent cycling stability(over thousands of cycles)and rich color variations(8 colors)were realized for the first *** believe that our work put forward a general strategy for developing high-quality multicolor complementary electrochromic devices.

关键词： electrochromism tin oxide metal oxide cycling stability multicolor complementary device

19.3% Efficiency ternary organic solar cells enabled by the alkyl side-chain effect of guest non-fullerene acceptors

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Science China Chemistry 2024年第8期67卷 2686-2693页

作者： Hongqian Wang Sijian Wu Daobin Yang Xueliang Yu Shuncheng Yang Pengfei Ding Pengyu Yan Zaifei Ma Jianfeng Zhang Ziyi Ge School of materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China Zhejiang Engineering research center for Energy Optoelectronic materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China State Key Laboratory for Modification of Chemical Fibers and Polymer materials Center for Advanced Low-dimension MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620China center of materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

The effect of side-chain engineering of conjugated molecules on the morphology and device performance in binary organic solar cells has been widely investigated. However, this relationship has hardly been studied in the guest components of ternary organic solar cells. In this study, a family of non-fullerene guest acceptors, namely XY-3, XY-5 and XY-7, with hydrogen substituent,straight and branched alkyl chains on the bithiophene units, respectively, were designed and synthesized to understand their effects on aggregation properties and device performance. The straight and branched alkyl chains on the bithiophene units result in sightly blue-shifted absorption compared to the hydrogen substituent and the XY-7 demonstrates the most appropriate phase separation scale and the most balanced charge transport. Consequently, the OSCs based on D18:e C9:XY-7 achieve a high shortcircuit current density(JSC) and fill factor(FF), while maintaining the enhancement of the open-circuit voltage(VOC) achieving an efficiency of 19.32%, exceeding those of D18:e C9, D18:e C9:XY-3, D18:e C9:XY-5(PCE:18.28%, 19.04%, 18.75%, respectively). These results highlight that the side-chain engineering of Y series non-fullerene acceptors as the guest acceptors has great potential in optimizing morphology properties and promoting photovoltaic performance.

关键词： organic solar cells side chain engineering ternary strategy non-fullerene energy losses

Large deflection deformation behavior of a Zr-based bulk metallic glass for compliant spinal fixation application

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Journal of materials Science & Technology 2024年第6期173卷 86-99页

作者： Diao-Feng Li Chun-Guang Bai Zhi-Qiang Zhang Hui-Bo Zhang Nan Li Jian Zhao Shi-Changxu Innovation center for Advanced materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China

A novel compliant spinal fixation designed based on the concept of compliant mechanisms can reduce the stress-shielding effect and adjacent segment degeneration(ASD)effectively,but propose higher requirements for the properties of the used *** metallic glasses(BMGs),as a kind of young biomaterials,exhibiting excellent comprehensive properties,which are attractive for compliant spinal ***,according to the practical service condition of the basic elements in compliant spinal fixation,large deflection deformation behaviors of Zr_(61)Ti_(2)Cu_(25)Al_(12)(at.%,ZT1)BMG beam,including elastic,yielding and plastic were investigated *** was shown that the theoretical nonlinear analytical solution curve as the benchmark not only with the capacity to predict the nonlinear load-deflection relation within the elastic deformation regime,but also assists to capture the yielding event roughly,which can be used as a powerful design tool for *** capture the beginning of the yielding event exactly,bending proof strength(σ_(p),0.05%)accompanied with tiny permanent strain of 0.05% was proposed and determined for BMGs in biomedical implant applications,which is of significance for setting the allowable operating limits of the basic flexible *** approach of interrupted loading-unloading cycles,plastic deformation driven by the bending moment can be classified into two typical stages:the initial stage which mainly characterized by the nucleation and intense interaction of abundant shear bands when the plastic strain below the critical value,and the second stage which dominated by the progressive propagation of shear bands and coupled with the emergence of shear offsets on tensile *** plasticity of BMG beam structures depends on the BMG's inherent plastic zone size(rp).When the half beam thickness less than that of the rp,the plastic deformation of BMGs will behave in a stable manner,which can be acted as the margin of safety effectiv

关键词： Metallic glasses Biomaterials Compliant spinal fixation Large deflection deformation Plastic deformation

A 30-year overview of sodium-ion batteries

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Carbon Energy 2024年第6期6卷 56-98页

作者： Yun Gao Hang Zhang Jian Peng Lin Li Yao Xiao Li Li Yang Liu Yun Qiao Shu-Lei Chou School of Environmental and Chemical Engineering Shanghai UniversityShanghaiChina College of Chemistry and materials Engineering Wenzhou UniversityWenzhouZhejiangChina Institute for superconducting and Electronic materials University of WollongongWollongongNew South WalesAustralia

Sodium-ion batteries(NIBs)have emerged as a promising alternative to commercial lithium-ion batteries(LIBs)due to the similar properties of the Li and Na elements as well as the abundance and accessibility of Na *** of the current research has been focused on the half-cell system(using Na metal as the counter electrode)to evaluate the performance of the cathode/anode/*** relationship between the performance achieved in half cells and that obtained in full cells,however,has been neglected in much of this ***,the trade-off in the relationship between electrochemical performance and cost needs to be given more ***,systematic and comprehensive insights into the research status and key issues for the full-cell system need to be gained to advance its ***,this review evaluates the recent progress based on various cathodes and highlights the most significant challenges for full *** strategies have also been proposed to enhance the electrochemical performance of NIBs,including designing electrode materials,optimizing electrolytes,sodium compensation,and so ***,perspectives and outlooks are provided to guide future research on sodium-ion full cells.

关键词： commercial application electrode electrolyte sodium-ion full cell strategies

Fine-tuning growth in gold nanostructures from achiral 2D to chiral 3D geometries

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Nano research 2024年第7期17卷 6654-6660页

作者： Lili Tan Zhi Chen Chengyu Xiao Zhiyong Geng Yinran Jin Chaoyang Wei Fei Teng Wenlong Fu Peng-peng Wang State Key Laboratory for Mechanical Behavior of materials Shaanxi International Research Center for Soft MatterSchool of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an 710049China

Enriching the library of chiral plasmonic structures is of significant importance in advancing their applicability across diverse domains such as biosensing,nanophotonics,and ***,employing triangle nanoplates as growth seeds,we synthesized a novel class of chiral-shaped plasmonic nanostructures through a wet chemical strategy with dipeptide as chiral inducers,including chiral tri-blade boomerangs,concave rhombic dodecahedrons,and *** structural diversity in chiral plasmonic nanostructures was elucidated through their continuous morphological evolution from two-dimensional to threedimensional *** fine-tuning of chiroptical properties was achieved by precisely manipulating crucial synthetic parameters such as the amount of chiral molecules,seeds,and gold precursor that significantly influenced chiral structure *** findings provide a promising avenue for enriching chiral materials with highly sophisticated structures,facilitating a fundamental understanding of the relationship between structural nuances and chiroptical properties.

关键词： plasmonic nanostructures geometric chirality circular dichroism fine-tuning

ZnO/ZnS heterostructure in N-doped porous carbon for anchoring-diffusion-conversion of polysulfides for high-performance lithium-sulfur batteries

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Rare Metals 2024年第8期43卷 3661-3676页

作者： Fei Wang Rong-Wei Huang Wen-Chang Han Chun-Man Yang Wen-Hao Yang Peng Dong Chao-Ling Wu Yi-Yong Zhang Xue Li Ying-Jie Zhang National Local Joint Engineering research center for LithiumIon Batteries and materials Preparation Technology Key Laboratory of Advanced Batteries Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093China Engineering research center of Alternative Energy materials and Devices Sichuan UniversityMinistry of EducationChengdu 610065China

The shuttle effect of polysulfides is one of the key factors hindering the commercialization of lithiumsulfur batteries(LSBs).Owing to their high conductivity and advantageous structure,heterostructures can be used in sulfur fixation and catalysis of *** this study,a flower-shaped ZnO/ZnS heterostructure on a nitrogendoped porous carbon(NPC) sulfur host was *** ZnO/ZnS heterostructure regulates the electronic structure of the material and exhibits higher metal-like ***,the ZnO/ZnS heterostructure combines the strong adsorption property of ZnO and the high catalytic ability of ZnS to realize the anchoring-diffusionconversion of lithium poly sulfides(LiPSs).Results reveal that the developed ZnO/ZnS@NPC/S cathode has excellent electrochemical performance in LSBs,achieving a high discharge specific capacity of 1365.3 mAh·g^(-1) at 0.1C and excellent rate capability(719 mAh·g^(-1) at 2C;the capacity decay rate is only 0.042% per cycle after 1000 cycles).Even under a high sulfur loading-E/S(electrolyte/sulfur)ratio of 5.1 mg·cm^(-2)-6 μl·mg^(-1),a high specific capacity of 723.7 mAh·g^(-1) is maintained after 60 *** study provides a new strategy for a multifunctional sulfur host that can effectively alleviate the shuttle effect of LiPSs and improve the utilization of sulfur active substances.

关键词： ZnO/ZnS heterostructure Lithium-sulfur batteries Density functional theory Anchor Conversion

Facile access to C-N bonds via unexpected side reactions of Knoevenagel condensation and their application in high-efficiency organic solar cells

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Science China Chemistry 2024年第1期67卷 323-329页

作者： Daobin Yang Shuncheng Yang Hongqian Wang Lin Xie Pengyu Yan Ziyi Ge Zhejiang Engineering research center for Energy Optoelectronic materials and Devices Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China School of materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China center of materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

The construction of C-N bonds is of great importance in the fields of biology,medicine,chemistry and materials ***,the replacement of organic base from pyridine to piperidine in the Knoevenagel condensation process unexpectedly yields a series of novel organic molecules containing C-N ***,the synthesis method does not require any external transition-metals catalysis,and photo-/***,when the new compound 1b is added as a third component to a well-known binary system of PM6:Y6,the efficiency of the organic solar cell is significantly improved,resulting in an outstanding efficiency of 18.0%,which is one of the highest values reported to date for PM6:Y6-based ternary organic solar cells.

关键词： C-N bonds Knoevenagel condensation cross-coupling reaction third component organic solar cells

Theoretical Design of Defects as a Driving Force for Ion Transport in Li_(3)OBr Solid Electrolyte

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Energy & Environmental materials 2024年第3期7卷 143-153页

作者： Xingyun Luo Yanlu Li Xian Zhao State Key Lab of Crystal materials and Institute of Crystal materials Shandong UniversityJinan 250100China center for Optics research and Engineering Shandong UniversityQingdao 266237China

Due to ever-increasing concerns about safety issues in using Li ionic batteries,solid electrolytes have extensively *** Li-rich antiperovskite Li_(3)OBr has been considered as a promising solid electrolyte candidate,but it still suffers challenges to achieve a high ionic conductivity owing to the high intrinsic symmetry of the crystal ***,we presented a design strategy that introduces various point defects and grain boundaries to break the high lattice symmetry of Li_(3)OBr crystal,and their effect and microscopic mechanism of promoting the migration of Li-ion were explored *** has been found that Li_(i)are the dominant defects responsible for the fast Li-ion diffusion in bulk Li_(3)OBr and its surface,but they are easily trapped by the grain boundaries,leading to the annihilating of the Frenkel defect pair V'_(Li)+Li_(i),and thus limits the V'_(Li)diffusion at the grain *** V_(Br)defect near the grain boundaries can effectively drive V'_(Li)across the grain boundary,thereby converting the carrier of Li^(+)migration from Li,in the bulk and surface to V'_(Li)at the grain boundary,and thus improving the ionic conductivity in the whole Li_(3)OBr *** work provides a comprehensive insight into the Li^(+)transport and conduction mechanism in the Li_(3)OBr *** opens a new way of improving the conductivity for all-solid-state Li electrolyte material through the defect design.

关键词： defects density functional theory ionic migration solid electrolyte