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Journal of Iron and Steel Research International 2024年第3期31卷 608-621页

作者： Zhe Wang Qi-long Wei Cheng-bin Shi Zhan-cheng Guo state key Laboratory of Advanced metallurgy University of Science and Technology BeijingBeijing 100083China

The effect of Al_(2)O_(3)/SiO_(2) mass ratio and CaO content on the viscosity and structure of the CaO-Al_(2)O_(3)-SiO_(2)-6MgO-1.5ZrO_(2)-1.5CeO_(2) slag was *** results show that with the increase in Al_(2)O_(3)/SiO_(2) mass ratio,the viscous flow units within the slag gradually change from Si-O-Si to Al-O-Al and ***,the substitution of Al_(2)O_(3) for SiO_(2) leads to the transformation of Si-O bonds towards weaker Al-O bonds,which weaken the bond strength of the aluminosilicate networks,thus leading to a decrease in the viscosity of *** increase in CaO content effectively promotes the depolymerization of the aluminosilicate networks,resulting in a significant decrease in the viscosity of the *** slag with Al_(2)O_(3)/SiO_(2) of 0.7-1.5 and CaO of 30 wt.%shows promise as the reference slag system for the Fe-collection smelting of spent automotive catalysts due to its good comprehensive performance.

关键词： Aluminosilicate slag Al_(2)O_(3)/SiO_(2)mass ratio CaO content Viscosity Slag structure

Fabrication and properties of lightweight zirconia with fine closed porosity

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Journal of Iron and Steel Research International 2024年第6期31卷 1449-1458页

作者： Yi-bo Zhang Hua-zhi Gu Lv-ping Fu Ao Huang Mei-je Zhang The state key Laboratory of Refractories and metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina

Lightweight refractory materials with thermal insulation properties and erosion resistance are advantageous for hightemperature *** zirconia refractories were prepared using starch as a pore-forming agent,basic magnesium carbonate as a stabilizer,and nano-zirconia as an *** effects of the nano-zirconia content on the pore and thermal insulation properties of the lightweight zirconia refractories were investigated based on the porosity,phase composition,microstructure,and thermal ***-zirconia was shown to have a high surface energy,and its addition effectively increased the driving force for sintering,reduced the sintering temperature,and promoted the sintering reaction,thereby reducing the apparent porosity and improving the density of the prepared *** to the superplasticity of nano-zirconia,the surface stress caused plastic deformation between particles,which increased the migration rate of grain boundaries and trapped more gas inside the material before it diffused to the surface,thereby enhancing the closed porosity of the *** presence of closed pores could extend the thermal conduction path,decrease the conduction rate,and hinder the conduction effect to effectively reduce the thermal conductivity of the *** a nano-zirconia content of 0.75 wt.%,the prepared lightweight zirconia had the highest closed porosity and the lowest thermal *** apparent porosity,closed porosity,and total porosity of the material were 2.8%,7.0%,and 9.8%,respectively,and the thermal conductivity at 800℃was 1.37 W m^(-1)k^(-1).

关键词： Sintering Nano-zirconia Closed pore:Thermal conductivity Refractory material

Room-temperature ferromagnetism and half-metallicity in monolayer orthorhombic CrS_(2)

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Frontiers of physics 2024年第4期19卷 137-146页

作者：雷博程李奥林周文哲王云鹏熊威陈羽欧阳方平 School of Physics Science and Technology and Xinjiang Key Laboratory of Solid-State Physics and DevicesXinjiang UniversityUrumqi 830046China School of Physics and Hunan Key Laboratory for Super-Microstructure and Ultrafast Processand Hunan Key Laboratory of Nanophotonics and DevicesCentral South UniversityChangsha 410083China School of Physics Science and Technology and Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matter PhysicsYili Normal UniversityYining 835000China powder metallurgy Research Institute and state key Laboratory of powder metallurgy Central South UniversityChangsha 410083China

Two-dimensional materials with high-temperature ferromagnetism and half-metallicity have the latest applications in spintronic *** on first-principles calculations,we have investigated a novel two-dimensional CrS_(2) phase with an orthorhombic *** results suggest that it is stable in dynamics,thermodynamics,and *** ground state of monolayer orthorhombic CrS_(2) is both ferromagnetic and half-metallic,with a high Curie temperature of 895 K and a large spin-flipping gap on values of 0.804 *** room-temperature ferromagnetism and halfmetallicity can maintain stability against a strong biaxial strain ranging from–5%to 5%.Meanwhile,increasing strain can significantly maintain the out-of-plane magnetic anisotropy.A density of states analysis,together with the orbital-resolved magnetic anisotropy energy,has revealed that the strain-enhanced MAE is highly related to the 3d-orbital splitting of Cr *** results suggest the monolayer orthorhombic CrS_(2) is an ideal candidate for future spintronics.

关键词： orthorhombic CrS_(2) Curie temperature magnetic anisotropy energy biaxial strain first-principles calculations

High-temperature wetting behavior between slag and refractory

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Journal of Iron and Steel Research International 2024年第6期31卷 1304-1319页

作者： Yong-xin Wang Ya-ge Li Ya-bo Gao Zhong Huang Hai-jun Zhang The state key Laboratory of Refractories and metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina

Slag corrosion is one of the main factors of the damage of refractory,and its primary manifestations involve the melting of refractory in slag and the slag penetration into refractory,both of which are highly related to the wetting behavior between slag and *** high-temperature wettability could be characterized by parameters including the surface tension,adhesion work,and spreading coefficient of the slag on refractory surface,and it could be suppressed by altering the slag/refractory interface,thus resulting in an improved anti-corrosion *** this,the key knowledges of the slag corrosion,theory of wetting behavior and test of high-temperature contact angle were firstly ***,the major factors influencing the high-temperature slag wetting behavior were discussed based on the aspects of slag composition,refractory composition,and surface ***,the future research direction was proposed in this field.

关键词： High-temperature wetting Refractory Slag corrosion Surface tension

Integrating machine learning and CALPHAD method for exploring low-modulus near-β-Ti alloys

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Rare Metals 2024年第1期43卷 309-323页

作者： Hao Zou Yue-Yan Tian Li-Gang Zhang Ren-Hao Xue Zi-Xuan Deng Ming-Ming Lu Jian-Xin Wang Li-Bin Liu School of Computer Science and Engineering Central South UniversityChangsha 410083China School of Materials Science and Engineering Central South UniversityChangsha 410083China state key Laboratory of powder metallurgy Central South UniversityChangsha 410083China

Traditional theoretical and empirical calculation methods can guide the design of β-and metastable β-alloys for bio-titanium. However, it is still difficult to obtain novel near-β-Ti alloys with low modulus. This study developed a method that combines machine learning with calculation of phase diagrams(CALPHAD) to facilitate the design of near-β-Ti alloys. An elastic modulus database of Ti–Nb–Zr–Mo–Ta–Sn system was constructed first, and then three features(the electron to atom ratio, mean absolute deviation of atom mass, and mean electronegativity) were selected as the key factors of modulus by performing a three-step feature selection. With these features, a highly accurate model was built for predicting the modulus of near-β-Ti alloys. To further ensure the accuracy of modulus prediction, machine learning with the elastic constants calculated was leveraged by CALPHAD database. The root mean square error of the well-trained model can be as low as 6.75 GPa. Guided by the prediction of machine learning and CALPHAD, three novel near-β-Ti alloys with elastic modulus below 50 GPa were successfully designed in this study. The best candidate alloy(Ti–26Nb–4Zr–4Sn–1Mo–Ta) exhibits an ultra-low modulus(36.6 GPa) after cold rolling with a thickness reduction of 20%. Our method can greatly save time and resources in the development of novel Ti alloys, and experimental verifications have demonstrated the reliability of this method.

关键词： Near-β-Ti alloy Machine learning Calculation of phase diagram Low-modulus alloy Feature selection

Effect of nano-graphite on mechanical properties and oxidation resistance of ZrB_(2)-SiC-graphite electrode ceramics

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Journal of Iron and Steel Research International 2024年第6期31卷 1502-1513页

作者： Bo-lin Yang Chang-liu Kuang Zheng-long Liu Chao Yu Cheng-ji Deng Jun Ding The state key Laboratory of Refractories and metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina

ZrB_(2)-based ceramic composites were prepared by spark plasma sintering using ZrB_(2) powder prepared by molten salt method as raw material and SiC and nano-graphite as *** effects of nano-graphite addition on the physical properties and oxidation resistance of ZrB_(2)-based ceramic samples were *** results show that the addition of an appropriate amount of nano-graphite can effectively improve the density of ZrB_(2)-based ceramic composites and improve the physical properties of the *** flexural strength of the ceramic sample with 8 vol.%nano-graphite reached 418.54 MPa,which was 53.14% higher than that of ZrB_(2)-SiC ceramic material(273.31 MPa),and its oxidation resistance was also significantly *** demonstrats that the addition of an appropriate amount of nano-graphite can effectively improve the physical properties and oxidation resistance of ZrB_(2)-SiC ceramic *** prolonging its service life in application and promoting the development of ZrB_(2)-based ceramic composites,it is of great significance for clean steel smelting.

关键词： ZrB_(2)-SiC-graphite electrode ceramic ZrB_(2)-based ceramic composite Nano-graphite Physical property Oxidation resistance

Influence of in situ formed spinel in bonding phase on mechanical properties and air permeability of magnesia-chrome porous purging materials

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Journal of Iron and Steel Research International 2024年第6期31卷 1459-1472页

作者： Yi An Hao Liu Zhou-fu Wang Yan Ma Xi-tang Wang The state key Laboratory of Refractories and metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina

Magnesia-chrome porous purging plugs are crucial functional components to remove inclusions and stabilize the flow field during iron and steel ***,practical applications of magnesia-chrome porous purging materials are stil hampered by the poor scouring resistance to molten steel and unstable air permeability owing to their low mechanical properties and uncontrollable pore ***,the particle-packing type magnesiachrome porous purging materials reinforced by in situ formed spinel were prepared using fused magnesia-chrome particles and Al powders as major raw *** results show that in situ formed spinel solid solutions in bonding phase led to the decreased median pore size and increased pore surface fractal dimension from the reactions between Al powders and magnesia-chrome particles and along with high-temperature sintering,bonding between magnesia-chrome particles and the resultant mechanical properties of materials were greatly ***,the results of air permeability tests and polynomial ftting indicated that the formation of spinel solid solutions was the main contributing factor for controllable air permeability,and pressure drop of porous purging materials was positively correlated with surface fractal dimension of ***,the as-prepared porous purging materials added with 6 wt.%Al powders obtained the maximum cold crushing strength(54.2 MPa)and hot modulus of rupture(12.9 MPa)with median pore size of 24.06μm and ftting non-Darcian permeability coefficient of 0.97×10^(-6)m.

关键词： Magnesia Chrome porous purging material Metallic Al-Spinel Mechanical strength Air permeability

Reoxidation of liquid steel and evolution of inclusions during protective atmosphere electroslag remelting of Ce-containing heat-resistant stainless steel

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Journal of Iron and Steel Research International 2024年第8期31卷 1923-1935页

作者： Yu Zhao Cheng-bin Shi Shijun Wang Peng Ren Jing Li state key Laboratory of Advanced metallurgy University of Science and Technology Beijing(USTB)Beijing 100083China

The evolution of Ce-containing inclusions and its correlation with the reoxidation of liquid steel during protective atmosphere electroslag remelting(ESR)of heat-resistant steel were *** reoxidation of liquid steel took place during the ESR,resulting in the oxygen pickup from 0.0014 to 0.0053 wt.%.The inclusions in the consumable electrode,liquid metal pool and remelted ingot are Ce_(2)O_(2)S and Ce_(2)O,inclusions *** inclusions in the remelted ingot are originated from three ways:(I)the original inclusions from the electrode;(Il)the newly formed Ce_(2)O_(2)S and Ce_(2)O_(3) inclusions in the liquid metal pool by reoxidation remaining still in remelted ingot;(IlI)the newly generated Ce2O2S and Ce_(2)O_(3) inclusions during cooling and solidification of liquid *** relative proportions of Ce_(2)O_(3) inclusions in liquid metal pool and remelted ingot are 41% and 76.5%,*** inclusions ranging from 2 to 5μm in the remelted ingot take up 55%,followed by the inclusions smaller than 2μm(43%of total inclusions).The number proportion of the Ce_(2)0,inclusions in the liquid metal pool which were removed by floating up into slag is 1.96×10-5%.

关键词： Non-metallic inclusion Electroslag remelting Rare earth cerium Reoxidation Inclusion evolution

Radical involved reactive wetting and retarding mechanism of alumina refractory ceramic by molten slags under weak static magnetic field

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Journal of Iron and Steel Research International 2024年第6期31卷 1355-1366页

作者： Sheng-hao Li Ao Huang Fan-bo Zeng Hui Peng Hao-ran Wei Xue-chun Huang Sheng-qiang Song Hua-zhi Gu The state key Laboratory of Refractories and metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina

High alumina slag will cause severe corrosion at the interface of alumina refractory,and the wetting behavior of slag is a key factor influencing the corrosion resistance of refractory *** static magnetic field is a promising solution for improvement in the slag resistance of *** wetting of alumina refractory ceramics with different basicities of high alumina slags under a weak static magnetic field was analyzed,given that a weak static magnetic field can affect the corrosion behavior of refractory *** slag S_(3) as an example,when there was an external static magnetic field of 1.0 mT at 1600 ℃,the thickness of calcium aluminate reaction layer at the interface decreased by 36.7%,the denting depth of interface decreased by 35.6%,and the apparent wetting angle increased by 20%.The living radicals and their formation path in oxide melts were verified by first-principles calculation combined with electron paramagnetic resonance spectroscopy *** influence of the flux density of a weak static magnetic field on the wetting behavior of slags was also *** contact angle of the slags increased owing to the inhibitory effect of magnetic field on the radicalinvolved reaction at the interface of the slag and the alumina refractory *** relationships between the magnetic flux density,diffusion coefficient,slag microstructure(hyperfine coupling constant),and contact angle were *** provides a theoretical basis for the field control of radical involved reactive wetting between inorganic oxide slags and solid oxide ceramics.

关键词： Alumina refractory ceramic Molten slag Weak magnetic field effect Reactive wetting Free radical

A review on graphite surface modification methods towards low carbon-containing refractories

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Journal of Iron and Steel Research International 2024年第6期31卷 1291-1303页

作者： Ting-ting Zhang Jun Ding Bei-yue Ma Zheng-long Liu Chao Yu Cheng-ji Deng The state key Laboratory of Refractories and metallurgy Wuhan University of Science and TechnologyWuhan 430081HubeiChina School of metallurgy Northeastern UniversityShenyang 110819LiaoningChina

The rapid development of iron and steel metallurgy technology has promoted the continuous innovation and iteration of carbon-containing refractories for clean steel *** meet the high-quality requirements for clean steel production and full exploit the performance advantages of carbon-containing refractories in dynamic smelting environment,it is necessary to explore the role of graphite and modified graphite in carbon-containing *** on this,graphite surface modification methods,including surfactants,surface oxidation,and surface coating,and their applications in carbon-containing refractories are *** advantages and disadvantages of each method are analyzed for practical ***,combined with the existing problems,the application prospect of improved graphite in carbon-containing refractories is discussed.

关键词： Graphite Carbon-containing refractory Clean steel Surface modification Service performance