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Simplified quantitative analysis method and its application in the insitu synthesized copper-based azide chips

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Defence technology（防务技术） 2024年第2期32卷 309-316页

作者： Jie Ren Yunfeng Li Mingyu Li Xingyu Wu Jiabao Wang Qingxuan Zeng state key laboratory of Explosion and technology Beijing Institute of TechnologyBeijing 100081China

Copper-based azide(Cu(N_(3))2 or CuN_(3),CA)chips synthesized by in-situ azide reaction and utilized in miniaturized explosive systems has become a hot research topic in recent ***,the advantages of in-situ synthesis method,including small size and low dosage,bring about difficulties in quantitative analysis and differences in ignition capabilities of CA *** aim of present work is to develop a simplified quantitative analysis method for accurate and safe analysis of components in CA chips to evaluate and investigate the corresponding ignition *** this work,Cu(N_(3))2 and CuN_(3)components in CA chips were separated through dissolution and distillation by utilizing the difference in solubility and corresponding content was obtained by measuring N_(3)-concentration through *** spectrophotometry method was optimized by studying influencing factors and the recovery rate of different separation methods was studied,ensuring the accuracy and reproducibility of test *** optimized method is linear in range from 1.0-25.0 mg/L,with a correlation coefficient R^(2)=0.9998,which meets the requirements of CA chips with a milligram-level content *** with the existing ICP method,component analysis results of CA chips obtained by spectrophotometry are closer to real component content in samples and have satisfactory ***,as its application in miniaturized explosive systems,the ignition ability of CA chips with different component contents for direct ink writing CL-20 and the corresponding mechanism was *** study provided a basis and idea for the design and performance evaluation of CA chips in miniaturized explosive systems.

关键词： Copper-based azide chips Spectrophotometry Separation method Quantitative analysis Ignition ability

Reactive molecular dynamics insight into the thermal decomposition mechanism of 2,6-Bis(picrylamino)-3,5-dinitropyridine

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Defence technology（防务技术） 2024年第3期33卷 134-146页

作者： Jianbo Fu Hui Ren Xinzhou Wu Yongjin Chen Mi Zhang Yazhi Cheng state key laboratory of Explosion Science and technology Beijing Institute of TechnologyBeijing 100081China

2,6-bis(picrylamino)-3,5-dinitropyridine(PYX)has excellent thermostability,which makes its thermal decomposition mechanism receive much *** this paper,the mechanism of PYX thermal decomposition was investigated thoroughly by the ReaxFF-lg force field combined with DFT-B3LYP(6-311++G)*** detailed decomposition mechanism,small-molecule product evolution,and cluster evolution of PYX were mainly *** the initial stage of decomposition,the intramolecular hydrogen transfer reaction and the formation of dimerized clusters are earlier than the denitration *** the progress of the reaction,one side of the bitter amino group is removed from the pyridine ring,and then the pyridine ring is *** final products produced in the thermal decomposition process are CO_(2),H_(2)O,N_(2),and H_(2).Among them,H_(2)O has the earliest generation time,and the reaction rate constant(k_(3))is the *** clusters are formed during the decomposition of PYX,and the formation,aggregation,and decomposition of these clusters are strongly affected by *** low temperatures(2500 K-2750 K),many clusters are *** high temperatures(2750 K-3250 K),the clusters aggregate to form larger *** 3500 K,the large clusters decompose and become *** the late stage of the reaction,H and N in the clusters escaped almost entirely,but more O was trapped in the clusters,which affected the auto-oxidation process of ***'s initial decomposition activation energy(E_(a))was calculated to be 126.58 kJ/*** work contributes to a theoretical understanding of PYX's entire thermal decomposition process.

关键词： PYX Thermal decomposition ReaxFF-lg MD simulations Excellent thermostable explosives

Shock-induced chemical reaction characteristics of PTFE-Al-Bi_(2)O_(3)reactive materials

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Defence technology（防务技术） 2024年第6期36卷 1-12页

作者： Chunlan Jiang Rong Hu Jingbo Zhang Zaicheng Wang Liang Mao state key laboratory of Explosion Science and technology Beijing Institute of TechnologyBeijing 100081China

A ternary system of PTFE/Al/Bi_(2)O_(3)is constructed by incorporating PTFE-based reactive material and thermite for enhancing the energy release of the PTFE-based reactive *** effects of Bi_(2)O_(3)in the PTFE/Al/Bi_(2)O_(3)on both mechanical properties and the energy release were investigated through various tests such as thermogravimetry-differential scanning calorimetry,adiabatic oxygen bomb test and split Hopkinson pressure bar *** microstructure observed through scanning electron microscope and Xray diffraction results are used to analyze the ignition and reaction mechanism of PTFE/Al/Bi_(2)O_(3).The results indicate that the PTFE/Al/Bi_(2)O_(3)are capable of triggering the exothermic reaction of molten PTFE/Bi_(2)O_(3)and Al/Bi_(2)O_(3)over the PTFE/Al reactive materials,thereby promoting *** excessive aluminum in the ternary system is beneficial for increasing energy *** ignition of shock-induced chemical reactions in PTFE/Al/Bi_(2)O_(3)is closely related to the material *** dominant mechanism for hot-spot generation under Split Hopkinson Pressure Bar test is the frictional temperature rise at the microcrack after failure.

关键词： PTFE/Al/Bi_(2)O_(3) Shock-induced chemical reaction Energy release

Propagation Properties of Shock Waves in Polyurethane Foam based on Atomistic Simulations

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Defence technology（防务技术） 2024年第1期31卷 117-129页

作者： Zhiqiang Hu Jianli Shao Shiyu Jia Weidong Song Cheng Wang state key laboratory of Explosion Science and technology Beijing Institute of TechnologyBeijing 100081China

Porous materials are widely used in the field of protection because of their excellent energy absorption *** this work,a series of polyurethane microscopic models are established and the effect of porosity on the shock waves is studied with classical molecular dynamics ***,shock Hugoniot relations for different porosities are obtained,which compare well with the experimental *** pores collapse and form local stress wave,which results in the complex multi-wave structure of the shock *** microstructure analysis shows that the local stress increases and the local velocity decreases gradually during the process of pore collapse to complete ***,it leads to stress relaxation and velocity *** shock stress peaks can be fitted with two exponential functions,and the amplitude of attenuation coefficient decreases with the increase of ***,the pore collapse under shock or non-shock are discussed by the entropy increase rate of the *** energy is dissipated mainly through the multiple interactions of the waves under *** energy is dissipated mainly by the friction between atoms under non-shock.

关键词： Polyurethane foam Shock wave Attenuation Atomistic simulation

Enhanced structural damage behavior of liquid-filled tank by reactive material projectile impact

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Defence technology（防务技术） 2024年第1期31卷 211-229页

作者： Jianwen Xie Yuanfeng Zheng Zhenyang Liu Chengzhe Liu Aoxin Liu Pengwan Chen Haifu Wang state key laboratory of Explosion Science and technology Beijing Institute of TechnologyBeijing 100081China

A series of ballistic experiments were performed to investigate the damage behavior of high velocity reactive material projectiles(RMPs) impacting liquid-filled tanks,and the corresponding hydrodynamic ram(HRAM) was studied in ***/Al/W RMPs with steel-like and aluminum-like densities were prepared by a pressing/sintering *** projectiles impacted a liquid-filled steel tank with front aluminum panel at approximately 1250 m/*** corresponding cavity evolution characteristics and HRAM pressure were recorded by high-speed camera and pressure acquisition system,and further compared to those of steel and aluminum *** different from the conical cavity formed by the inert metal projectile,the cavity formed by the RMP appeared as an ellipsoid with a conical *** RMPs were demonstrated to enhance the radial growth velocity of cavity,the global HRAM pressure amplitude and the front panel damage,indicating the enhanced HRAM and structural damage ***,combining the impact-induced fragmentation and deflagration characteristics,the cavity evolution of RMPs under the combined effect of kinetic energy impact and chemical energy release was *** mechanism of enhanced HRAM pressure induced by the RMPs was further revealed based on the theoretical model of the initial impact wave and the impulse ***,the linear correlation between the deformation-thickness ratio and the non-dimensional impulse for the front panel was obtained and *** was determined that the enhanced near-field impulse induced by the RMPs was the dominant reason for the enhanced structural damage behavior.

关键词： Reactive material projectile Hydrodynamic ram Enhanced structural damage Liquid-filled tank Impact

Explosion damage effects of aviation kerosene storage tank under strong ignition

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Defence technology（防务技术） 2024年第7期37卷 27-38页

作者： Shixiang Song Cheng Wang Boyang Qiao Gongtian Gu state key laboratory of Explosion Science and technology Beijing Institute of TechnologyBeijing 100081China

In order to study the blast damage effects of aviation kerosene storage tanks,the out-field explosion experiments of 8 m3fixed-roof tanks were carried *** fragments,shock wave and fireball thermal radiation of the tank in the presence of bottom oil,half oil and full oil,as well as empty tank,were investigated under internal explosion by various TNT charge contents(1.8 kg,3.5 kg and 6.2 kg).The results showed that the tank roof was the only fragment produced,and the damage forms could be divided into three *** increase of TNT charge content and oil volume enlarged the deformation of the tank,while the hole ratio presented a trend of increase first and then *** H_r,maxand V_(max)values positively increased as increasing the TNT charge content and oil volume(from empty to half oil),but decreased in full *** Pmaxvalues had a progressive increase with the increment of TNT charge content,but not the case with the increase in oil *** development of fireball was divided into three stages:tank roof‘towed'flame,jet flow flame tumbling and rising,and jet flow flame *** Dmaxand Hf,maxvalues both increased as increasing TNT charge content and oil *** oscillation phenomenon of fireball temperature was observed in the cooling *** average temperature of fireball surface was positively correlated with TNT charge content,and negatively correlated with oil volumes.

关键词： Aviation kerosene Storage tank Internal explosion Shock wave Fireball

Assessing the energy release characteristics during the middle detonation reaction stage of aluminized explosives

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Defence technology（防务技术） 2024年第3期33卷 270-277页

作者： Kun Yang Lang Chen Danyang Liu Bin Zhang Jianying Lu Junying Wu state key laboratory of Explosion Science and technology Beijing Institute of TechnologyBeijing 100081China

Afterburning behind the detonation front of an aluminized explosive releases energy on the millisecond timescale,which prolong the release of detonation energy and the energy release at different stages also shows significant ***,at present,there are few effective methods for evaluating the energy release characteristics of the middle reaction stage of such explosives,which can have a duration of tens to hundreds of *** present work demonstrates an approach to assessing the midstage of an aluminized explosive detonation based on a water push test employing a high degree of *** this method,the explosive is contained in a steel cylinder having one end closed that is installed at the bottom of a transparent water *** detonation,the gaseous products expand in one direction while forcing water ahead of *** resulting underwater shock wave and the interface between the gas phase products and the water are tracked using an ultra-high-speed framing and streak *** shock wave velocity in water and the expansion work performed by the gaseous detonation products were calculated to assess the energy release characteristics of aluminized explosives such as CL-20 and RDX in the middle stage of the detonation *** the middle stage of the detonation process of these aluminized explosives,the aluminum reaction reduced the attenuation of shock waves and increased the work performed by gas phase products.A higher aluminum content increased the energy output while the presence of oxidants slowed the energy release *** work demonstrates an effective means of evaluating the performance of aluminized explosives.

关键词： Aluminized explosive Non-ideal detonation Water push test Energy release

Experimental and numerical demonstration of hierarchical time-delay reservoir computing based on cascaded VCSELs with feedback and multiple injections

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Science China(Information Sciences) 2024年第2期67卷 279-290页

作者： Xingxing GUO Shuiying XIANG Xingyu CAO Biling GU state key laboratory of Integrated Service Networks Xidian University state key Discipline laboratory of Wide Bandgap Semiconductor technology School of MicroelectronicsXidian University

In this paper, we propose and demonstrate experimentally and numerically a hierarchical timedelay optical reservoir computing(RC) system based on cascaded vertical-cavity surface-emitting lasers(VCSELs) with feedback and multiple injections. The prediction performance characteristics of the hierarchical time-delay RC system based on cascaded VCSELs under different reservoir layers are ***, the prediction performance of the hierarchical time-delay RC system is first improved and saturates as the number of reservoir layers increases. Besides, the impacts of key factors on predicting the hierarchical time-delay RC system are also analyzed in detail experimentally and numerically. This proposed hierarchical time-delay RC system based on VCSELs is useful for the further development of RC systems and may be beneficial to improve the ability of RC systems to solve more complex problems.

关键词： vertical-cavity surface-emitting laser reservoir computing neuromorphic photonics time-delay system information processing

Formation of mesophase microbeads from bulk mesophase pitch induced by fullerene

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新型炭材料（中英文） 2024年第4期39卷 645-654页

作者： CHEN Wen-sheng LIU Lan-tao WANG Zheng DUAN Chun-feng ZHANG Xing-wei MA Zhao-kun CHEN Xiao-hong SONG Huai-he state key laboratory of Chemical Resource Engineering Beijing Key Laboratory of Electrochemical Process and Technology for MaterialsBeijing Uni-versity of Chemical TechnologyBeijing 100029China

A transformation of naphthalene-based coalescenced mesophase pitch(NMP)to mesophase microbeads was achieved by heating a mixture of NMP and fullerene(C_(60)).This is different from the conventional process of the liquid-phase carbonization of isotropic pitch to the emergence of carbon microbeads in the matrix and finally their growth to form a 100%anisotropic bulk meso-phase,but rather a reverse *** effects of C_(60) loading and reaction temperature on the morphological transformation of mesophase were investigated by polarizing optical and scanning electron *** physical changes in the NMP induced by C_(60) were characterized by thermogravimetric analysis,Fourier transform infrared spectroscopy,X-ray diffractometry and Raman *** results show that the coalesced NMP can be converted to a spherical type at 300-320℃ with the addition of 5%C_(60),and the size of the mesophase microbeads increases with increasing ***,a model is established to ex-plain the unique induction effect of C_(60) in the transformation *** work makes the morphological transformation of MP con-trollable,and provides a new idea for the understanding and research of mesophase pitch.

关键词： Reversible transformation Fullerene induction mechanism Mesophase texture π-electron-induced effect Mesophase microbeads