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Research progress of catalysts for direct coal liquefaction

Journal of Energy Chemistry 2025年第1期100卷 481-497页

作者： Wei Song Penggao Liu Xinyue Chen Ting Wang Chunrong He Rui Hao Kaiyu Liu state key laboratory of Chemistry and Utilization of Carbon Based Energy resources College of Chemistry Xinjiang University College of Chemistry and Chemical Engineering Henan Polytechnic University Hunan Provincial key laboratory of Chemical Power Sources College of Chemistry and Chemical Engineering Central South University

Coal direct liquefaction technology is a crucial contemporary coal chemical technology for efficient and clean use of coal resources. The development of direct coal liquefaction technology and the promotion of alternative energy sources are important measures to guarantee energy security and economic security. However, several challenges need to be addressed, including low conversion rate, inadequate oil yield, significant coking, demanding reaction conditions, and high energy consumption. Extensive research has been conducted on these issues, but further exploration is required in certain aspects such as pyrolysis of macromolecules during the liquefaction process, hydrogen activation, catalysts' performance and stability, solvent hydrogenation, as well as interactions between free radicals to understand their mechanisms better. This paper presents a comprehensive analysis of the design strategy for efficient catalysts in coal liquefaction, encompassing the mechanism of coal liquefaction, catalyst construction,and enhancement of catalytic conversion efficiency. It serves as a comprehensive guide for further research endeavors. Firstly, it systematically summarizes the conversion mechanism of direct coal liquefaction, provides detailed descriptions of various catalyst design strategies, and especially outlines the catalytic mechanism. Furthermore, it addresses the challenges and prospects associated with constructing efficient catalysts for direct coal liquefaction based on an understanding of their action mechanisms.

关键词： Direct coal liquefaction Catalysts Mechanism of action Solvent hydrogenation

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Late Paleozoic–Early Mesozoic tectonic evolution of the Zongwulong Shan-Qinghai Nanshan tectonic belt in the northern Qaidam continent， northern Tibet

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Journal of Earth Science 2025年

作者： Yonghui Zhao Chen Wu Jie Li Peter J.Haproff Lin Ding state key laboratory of Tibetan Plateau Earth System and resources Environment (TPESRE)， Institute of Tibetan Plateau Research， Chinese Academy of Sciences University of Chinese Academy of Sciences Chongqing key laboratory of Complex Oil and Gas Field exploration and Development， Chongqing University of Science and Technology Department of Earth and Ocean Sciences， University of North Carolina Wilmington

The Zongwulong Shan-Qinghai Nanshan tectonic belt of the northern Tibet Plateau experienced a protracted tectonic history， including the openings and closures of the Proto- and Paleo-Tethyan Oceans. Although the tectonic belt has been extensively studied， details regarding the tectonic processes involved in its development remain controversial. To better constrain the tectonic processes of this tectonic belt， we conducted detailed field geological mapping， zircon U-Pb geochronology， and whole-rock geochemical and Sr-Nd isotopic analyses. Our results show that intrusive rocks in the tectonic belt crystallized in ca. 292–233 Ma， perhaps in an arc/subduction setting. Geochemical and Sr-Nd isotopic data suggest that early Permian–late Triassic ultramafic-intermediate intrusions were sourced from the enriched mantle， whereas intermediate-acidic rocks were sourced from mixed crust-mantle. We present the tectonic model that involves: (1) Early Devonian–early Permian intracontinental extension occurred in the northern margin of the Qaidam continent (ca. 416 Ma–292 Ma); (2) Early Permian–late Triassic northward subduction of the Paleo-Tethyan Ocean resulted in arc magmatism (ca. 292 Ma–233 Ma); and (3) subsequent late Triassic intracontinental extension (ca. 233 Ma–215 Ma). Our results suggest that the late Paleozoic–early Mesozoic development of the Zongwulong Shan-Qinghai Nanshan was related to the opening， subduction， and slab retreat of the Paleo-Tethyan Ocean， which has key implications for the tectonic evolution of the northern Tibetan Plateau.

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Spatiotemporal evolution of Ediacaran-Cambrian(ca. 551–523 Ma)sponges in South China and their simulated contributions to marine oxygenation

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Science China Earth Sciences 2025年

作者： Yan YE Lei ZHANG Can CHEN Shan CHANG Yuhao YI Qinglai FENG state key laboratory of Geological Processes and Mineral resources China University of Geosciences(Wuhan) School of Earth Science China University of Geosciences(Wuhan) Department of Geology Lund University Institute of Sedimentary Geology Chengdu University of Technology key laboratory of Deep-time Geography and Environment Reconstruction and Applications of Ministry of Natural resources Chengdu University of Technology Second Geological Brigade of Hubei Geological Bureau College of Urban and Environmental Sciences Hubei Normal University exploration and Development Research Institute SINOPEC Jianghan Oilfield Company

The origin and evolution of sponges have attracted interest, not only because they are among the most basal metazoans, but also because they act as important ecological engineers in the ocean. Previous research suggested that sponge groups diversified quickly during the Cambrian Series 2, while Terreneuvian sponge fossils are conspicuously rare and poorly substantiated. Yet, an increasing number of sponge spicules have been reported from the Ediacaran-Cambrian(E-C, ca.551–523 Ma) transitional carbonates/cherts worldwide, particularly in South China, which calls for updated discussions. Ocean oxygenation has been widely proposed to play a critical role in organismal evolution, but its relationship with sponges is unclear and falls into a “chicken-egg” dilemma. In this study, we summarize reported sponge spicule distributions from five E-C sections in South China to investigate the early evolutionary pattern of siliceous sponges. According to current stratigraphic correlation,monaxons first appear in the late Ediacaran in the intrashelf basin-slope area, and then potentially expand to the continental shelf and deep basin in the lower Cambrian. In these sections, the abundance, size, and diversity of monaxons increase upwards,followed by the appearance of diaxons, triaxons and then polyactines. Despite the uncertain affinity of the sponge fossils, it is possible that siliceous hexactinellids evolved later than siliceous demosponges, given that the earliest spicule assemblages are exclusively composed of monaxons, which commonly form bundles comparable to modern demosponges. New geochemical data from the Sifangjing section, Guizhou Province and the Yanziqiao section, Hunan Province, South China show that the appearance of sponges usually corresponds to anoxic environment. In addition, we applied the recently proposed Biological Pump, Oxygen and Phosphorus(BPOP) model to trace the evolution of oceanic oxygen concentrations with the radiation of sponges. The results indic

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Pyrite Geochemistry and S-Hg Isotopes Reveal the Ore Genesis of the Hydrothermal Vein-type Cuiluan Ag-Pb-Zn Deposit in NE China

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Journal of Earth Science 2025年

作者： Lidong Zhang Changzhou Deng Yao Tang Xinran Ni Bizheng Yang Shanshan Liang Weipeng Liu Jishuang Ding Xiaohui Zeng Heilongjiang Institute of Natural resources Survey state key laboratory of Ore Deposit Geochemistry， Institute of Geochemistry， Chinese Academy of Sciences College of Earth and Planetary Sciences， Chengdu University of Technology

The Xing'an-Mongolian orogenic belt is an important Ag-Pb-Zn metallogenic province in China. The study on the genesis of the newly discovered Cuiluan hydrothermal vein-type Ag-Pb-Zn deposit located in the Lesser Xing'an Range， within the eastern of Xing'an-Mongolian orogenic belt， is pivotal in understanding the metallogenic mechanism and regularity of Ag-Pb-Zn deposits in this region. This study utilizes pyrite trace elements and sulfur isotopic geochemistry， and mercury isotope of rocks and ores to constrain the genesis of the Cuiluan deposit. Pyrite geochemical data show that Ag exists in the form of galena inclusions (Ag++(Bi3+， Sb3+) ? Pb2+) in the polymetallic sulfide stage， and independent Ag-bearing minerals （matildite and gustavite） precipitate during the main mineralization stage. The small varied δ34S values （3.24‰ - 4.94‰） of pyrites from four hydrothermal stages are within the range of magmatic S isotopes， indicating that the ore-forming fluid of the Cuiluan deposit mainly originated from the magma. The Δ199Hg values of the ores are close to 0‰， which are consistent with the Δ199Hg values of mantle， further indicating that the ore-forming materials came from the lithospheric mantle. Combined with the regional tectonic evolution， we conclude that the plate subduction of Paleo-oceans in NE China triggered the partial melting of metasomatized mantle. The mantle-derived magma rose along the deep fractures and evolved ore-forming fluids， and finally caused the formation of Cuiluan quartz vein-type Ag-Pb-Zn deposit in the shallow crust. Accompany with previous documents， we infer that the fractures in the large-scale “Granite Sea” in the Lesser Xing'an Range may have significant potential for vein-type Ag-Pb-Zn exploration.

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Depositional characteristics and petroleum geological significance of wetland

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Petroleum Science 2009年第4期6卷 347-353页

作者： Jin Zhenkui Gu Junfeng Su Nina Wang Zhaofeng Huang Xiaoping state key laboratory of hydrocarbon resources and exploration China University of PetroleumBeijing 102249China Research Institute of Petroleum exploration and Development Xinjiang Oilfield CompanyPetroChinaKaramayXinjiang 834000China

Wetland is a new type of sedimentary facies proposed for the first time in this paper. It is a type of sedimentary environment, transitional between land facies and water (sea or lake) facies. In this paper, wetland is redefined as “a type of sedimentary environments whose ground surface is flat and wet throughout the year, which may be covered with very shallow water (less than 2 m deep), and is covered with lush plant growth”. Wetland is reclassified into two types, swamp wetland (swamp in brief) and wet plain wetland (wet plain in brief). Swamp deposits are coal, while wet plain deposits are dark colored mudstones or silty mudstones rich in plant fossils and carbon debris. The deposits of wet plain are different from those of lake and floodplain in the abundance of plant fossils, color, resistivity well logging curve, and other sedimentary characteristics. In boreholes, resistivity logging can be used to distinguish between wet plain mudstones and lake mudstones. Understanding the sedimentary characteristics of wet plain wetland can help to identify wet plain deposits which were formerly classified as floodplain or lake deposits. This will help to reconstruct the palaeogeography and to understand the history of basin and climate evolution accurately, and is especially important in evaluation of the hydrocarbon generating potential of a basin. With the Jurassic Sangonghe Formation of the Yanqi Basin as an example, the identification characteristics of wetland are described.

关键词： Wetland wet plain Yanqi Basin Sangonghe Formation of Jurassic braided river delta

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Differential hydrocarbon Accumulation Controlled by Structural Styles along the Southern and Northern Tianshan Thrust Belt

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Acta Geologica Sinica(English Edition) 2013年第4期87卷 1109-1119页

作者： SONG Yan ZHAO Mengjun FANG Shihu LI Benliang LIU Shaobo ZHUO Qingong key laboratory of Basin Structure and hydrocarbon Accumulation CNPC state key laboratory of Petroleum Resource and Prospecting Research Institute of Petroleum exploration and Development PetroChina

The Kuqa and the Southern Junggar foreland thrust belts, which lie to the southern and northern Tianshan, respectively, were formed under a strong compressional tectonic setting. Due to the differential propagation and deformation under the control of the décollement horizon, the structural deformation styles differ in the Kuqa and Southern Junggar thrust belts. Imbricated stacking is developed in the Kuqa thrust belt, forming a piggyback imbricated pattern of faulted anticline and fault-block structural assemblage dominated by salt structures. In contrast, wedge-shaped thrusts are developed in Southern Junggar, mainly forming vertical laminated patterns of multi-wedge-structure stacks strongly influenced by the décollement horizons. The different deformation patterns and structural styles of the north and south of Tian Shan control the contrasting characteristics of hydrocarbon accumulation in the foreland thrust belts of the Kuqa and the Southern Junggar thrust belts, including the variance in the hydrocarbon trap types, pathway systems and hydrocarbon-bearing horizons. Proven by the hydrocarbon accumulation research and exploration achievements, recent exploration targets should focus on sub-salt piggyback imbricated structural patterns in the Kuqa and the deep laminated patterns in the Southern Junggar thrust belt.

关键词： northern and southern TianShan structural style hydrocarbon accumulation,accumulation model

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Paleo-fluvial sedimentation on the outer shelf of the East China Sea during the last glacial maximum

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Chinese Journal of Oceanology and Limnology 2013年第4期31卷 886-894页

作者：王中波杨守业张志珣蓝先洪顾兆峰张训华 state key laboratory of Marine Geology Tongji University The key laboratory of Marine hydrocarbon resources and Environmental Geology Ministry of Land and ResourcesQingdao Institute of Marine Geology

Evidence from lithology, foraminiferal assemblages, and high-resolution X-ray fluorescence scanning data of core SFK-1 indicates tidally influenced paleo-fluvial sedimentation during the last glacial maximum (LGM) on the outer shelf of the East China Sea. The paleo-fluvial deposits consist of river channel facies and estuarine incised-valley-filling facies. Different reflections on the seismic profile across core SFK-1 suggest that the river channels shifted and overlapped. River channel deposition formed early in the LGM when sea level fell and the estuary extended to the outer shelf. Channel sediments are yellowish- brown in color and rich in foraminifera and shell fragments owing to the strong tidal influence. Following the LGM, the paleo-river mouth retreated and regressive deposition of estuarine and incised-valley-filling facies with an erosion base occurred. The river channel facies and estuarine incised-valley-filling facies have clearly different sedimentary characteristics and provenances. The depositional environment of the paleo-river system on the wide shelf was reconstructed from the foraminiferal assemblages, CaCO3 content and Ca/Ti ratio. The main results of this study provide further substantial constraints on the recognition of late Quaternary stratigraphy and land-sea interactions on the ECS shelf.

关键词： outer shelf East China Sea LGM (last glacial maximum) paleo-river channel fluvial deposition paleoenvironment

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Investigation of shale gas microflow with the Lattice Boltzmann method

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Petroleum Science 2015年第1期12卷 96-103页

作者： Xiao-Ling Zhang Li-Zhi Xiao Long Guo Qing-Ming Xie state key laboratory of Petroleum resources and Prospecting China University of Petroleum key laboratory of Shale Gas exploration Ministry of Land and Resources Chongqing Institute of Geology and Mineral Resources

In contrast to conventional gas-bearing rocks, gas shale has extremely low permeability due to its nano- scale pore networks. Organic matter which is dispersed in the shale matrix makes gas flow characteristics more complex. The traditional Darcy＇s law is unable to estimate matrix permeability due to the particular flow mechanisms of shale gas. Transport mechanisms and influence factors are studied to describe gas transport in extremely tight shale. Then Lattice Boltzmann simulation is used to establish a way to estimate the matrix permeability numerically. The results show that net desorption, diffu- sion, and slip flow are very sensitive to the pore scale. Pore pressure also plays an important role in mass fluxes of gas. Temperature variations only cause small changes in mass fluxes. The Lattice Boltzmann method can be used to study the flow field in the micropore spaces and then provides numerical solutions even in complex pore structure models. Understanding the transport characteristics and establishing a way to estimate potential gas flow is very important to guide shale gas t＇eserve estimation and recovery schemes.

关键词： Shale gas Permeability Adsorption Desorption Diffusion Slip effect

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A comparison study of tungsten-bearing granite and related mineralization in the northern Jiangxi-southern Anhui provinces and southern Jiangxi Province in South China

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Science China Earth Sciences 2017年第11期60卷 1942-1958页

作者： SU HuiMin JIANG ShaoYong state key laboratory of Geological Processes and Mineral resources Collaborative Innovation Center for Exploration of Strategic Mineral Resources Faculty of Earth Resources China University of Geosciences state key laboratory for Mineral Deposits Research Department of Earth Sciences Nanjing University

The southern Jiangxi Province(SJP) and northern Jiangxi-southern Anhui provinces(NJSAP) are the two most important tungsten metallogenic districts in South China. The SJP district is a well-known tungsten producer in South China where distributes several ore concentrated areas such as the "Chongyi-Dayu-Shangyou", "Yudu" and "Longnan-Quanan-Dingnan"areas, with many large and super large tungsten deposits including the famous Xihuashan, Piaotang, Pangushan and Dajishan deposits. In recent years, major prospecting breakthrough for W-polymetallic resources has been made in the NJSAP *** large and super large W-Cu(Mo) deposits, such as the Dahutang, Zhuxi, Dongyuan and Baizhangyan deposits, are discovered. These deposits are all genetically associated with the Yanshanian(Mesozoic) granitic magmatism. In this study, a systematic comparison of the temporal and spatial distribution, petrology, geochronology, and geochemical characteristics of the tungsten-bearing granites between the SJP and NJSAP districts has been made, with an aim to improving the understanding of the petrogenesis of the granites and associated metal enrichment mechanisms in the two tungsten ore districts in South China. The following conclusions can be drawn:(1) The ages of the tungsten-bearing granites and associated mineralization are different in the two districts, in the SJP district the ages are mainly concentrated in 165–150 Ma, whereas in the NJSAP district it displays two age periods, one is 150–140 Ma(Late Jurassic-Early Cretaceous), and the other is 135–120 Ma(Early Cretaceous).(2) The tungsten-bearing granites from both the NJSAP and SJP districts are highly fractionated granitic rocks, but the SJP granites have experienced higher degree of fractional crystallization and more extensive fluid metasomatism than the NJSAP granites.(3) The petrogeneses of the tungsten-bearing granites from the two districts are different, those from the NJSAP district originated from partial melting

关键词： Tungsten-bearing granites Material sources Metallogenic characteristics Northern Jiangxi-southern Anhui provinces Southern Jiangxi Province

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Flow field simulation of supercritical carbon dioxide jet: Comparison and sensitivity analysis

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Journal of Hydrodynamics 2015年第2期27卷 210-215页

作者：王海柱李根生田守嶒程宇雄贺振国于水杰 state key laboratory of Petroleum resources and Prospecting China University of Petroleum (Beijing) Sinopec International Petroleum exploration and Production Corporation

As a new jet technology developed in recent years, the supercritical carbon dioxide（SC-CO2） jet technology enjoys many advantages when applied in oil and gas explorations. In order to study the properties and parametric influences of the SC-CO2 jet, the flow fields of the SC-CO2 jet are simulated using the computational fluid dynamics method. The flow field of the SC-CO2 is compared with that of the water jet. The influences of several parameters on the flow field of the SC-CO2 jet are studied. It is indicated that like the water jet, the velocity and the pressure of the SC-CO2 jet could be converted to each other, and the SC-CO2 jet can generate a significant impact pressure on the wall, the SC-CO2 jet has a stronger impact pressure and a higher velocity than those of the water jet under the same conditions, the maximum velocity and the impact pressure of the SC-CO2 jet increase with the increase of the nozzle pressure drop, under the stimulation condition of this study, the influence of the SC-CO2 temperature on the impact pressure can be neglected in engineering applications, while the maximum velocity of the SC-CO2 jet increases with the increase of the fluid temperature. This paper theoretically explores the properties of the SC-CO2 jet flow field, and the results might provide a theoretical basis for the application of the SC-CO2 jet in oil and gas well drillings and fracturing stimulations.

关键词： supercritical carbon dioxide water jet confining pressure flow field drilling

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