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Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer

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Chinese Chemical Letters 2024年第5期35卷 529-533页

作者： Tiankai Sun Hui Min Zongsu Han Liang Wang Peng Cheng Wei Shi Department of Chemistry College of ChemistryNankai UniversityTianjin 300071China state key laboratory of Separation Membranes and Membrane Processes School of Environmental Science and EngineeringTiangong UniversityTianjin 300387China key laboratory of Advanced energy Materials Chemistry(MOE) Frontiers Science Center for New Organic Matter and Renewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071China Haihe laboratory of Sustainable Chemical Transformations Tianjin 300192China

Nanoplastics(NPs)in aqueous environment have become a category of emerging pollutants on account of their potential risks to both human health and *** detection of NPs is a great challenge due to the lack of sensitive and selective sensing materials with fast response time and wide sensing range of particle ***,a Tb-based coordination polymer has been synthesized for luminescent detection of nanopolystyrene with different particle sizes in aqueous solutions,showing a low limit of detection,fast response time within 10 s and high selectivity in the presence of other ***“turn-on”sensing mechanism is studied in *** work provides a facile method for the fast detection of NPs.

关键词： Coordination polymer Nano polystyrene Luminescent detection Sensing mechanism Water safety

Zn-air batteries for electric vehicles

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Tungsten 2024年第1期6卷 164-173页

作者： Nai-Qi Meng Yu-Xin Fan Jing-Sheng Cai state key laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan UniversityShanghai 200438China College of energy Soochow Institute for energy and Materials InnovationS(SIEMIS)key laboratory of Advanced Carbon Materials and Wearable energy Technologies of Jiangsu Province Soochow UniversitySuzhou 215006China Institute of New energy for Vehicles School of Materials Science and EngineeringTongji UniversityShanghai 201804China

The increasingly serious environmental challenges have gradually aroused people's interest in electric *** the last decade,governments and automakers have collaborated on the manufacturing of electric vehicles with high ***-edge battery technologies are pivotal for the performance of electric ***-air batteries are considered as potential power batteries for electric vehicles due to their high ***-air battery researches can be classified into three categories:primary batteries,mechanically rechargeable batteries,and chemically rechargeable *** majority of current studies aim at developing and improving chemically rechargeable and mechanically rechargeable Zn-air *** have tried to use catalytic materials design and device design for Zn-air batteries to make it possible for their applications in electric *** review will highlight the state-of-the-art in primary batteries,mechanically rechargeable batteries,and chemically rechargeable batteries,revealing the prospects of Zn-air batteries for electric vehicles.

关键词： energy storage Electric vehicles Bifunctional oxygen catalysts Mechanically rechargeable Zn-air batteries Chemically rechargeable Zn-air batteries

Ten-Minute Synthesis of a New Redox-Active Aqueous Binder for Flame-Retardant Li-S Batteries

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energy & environmental Materials 2024年第2期7卷 52-61页

作者： Tianpeng Zhang Borui Li Zihui Song Wanyuan Jiang Siyang Liu Runyue Mao Xigao Jian Fangyuan Hu School of Materials Science and Engineering State Key Laboratory of Fine Chemicals Frontiers Science Center for Smart Materials Oriented Chemical Engineering Technology Innovation Center of High Performance Resin Materials (Liaoning Province) Key Laboratory of Energy Materials and Devices (Liaoning Province) Dalian University of Technology state key laboratory of Fine Chemicals Frontiers Science Center for Smart Materials Oriented Chemical Engineering School of Chemical Engineering Technology Innovation Center of High Performance Resin Materials (Liaoning Province) Key Laboratory of Energy Materials and Devices (Liaoning Province) Dalian University of Technology

As a critical role in battery systems,polymer binders have been shown to efficiently suppress the lithium polysulfide shuttling and accommodate volume changes in recent ***,preparation processes and safety,as the key criterions for Li-S batteries' practical applications,still attract less ***,an aqueous multifunction binder（named PEI-TIC） is prepared via an easy and fast epoxy-amine ring-opening reaction（10 min）,which can not only give the sulfur cathode a stable mechanical property,a strong chemical adsorption and catalytic conversion ability,but also a fire safety *** Li-S batteries based on the PEI-TIC binder display a high discharge capacity(1297.8 mAh g-1),superior rate performance(823.0 mAh g-1at 2 C),and an ultralow capacity decay rate of 0.035% over more than 800 *** under 7.1 mg cm-2S-loaded,the PEI-TIC electrode can also achieve a high areal capacity of 7.2 mA h g-1and excellent cycling stability,confirming its application ***,it is also noted that TG-FTIR test is performed for the first time to explore the flame-retardant mechanism of polymer *** work provides an economically and environmentally friendly binder for the practical application and inspires the exploration of the flame-retardant mechanism of all electrode components.

关键词： 3D cross-linked network environmentally friendly flame retardant Li-S batteries multifunction binder

One-step hydrothermal synthesis of few-layered metallic phase MoS2 for high-performance supercapacitors

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Progress in Natural Science:Materials International 2024年第2期34卷 429-436页

作者： Jing Xu Xulong Yuan Yujie Zhao Shaoqi Rui Qingling Jia Han Li Shun Lu Bing Li Yongxing Zhang Xuebin Zhu Anhui Province key laboratory of Pollutant Sensitive Materials and environmental Remediation Anhui Province Key Laboratory of Intelligent Computing and Applications Anhui Province Industrial Generic Technology Research Center for Alumics Materials Huaibei Normal University Chongqing Institute of Green and Intelligent Technology Chinese Academy of Sciences key laboratory of Materials Physics Institute of Solid State Physics HFIPS Chinese Academy of Sciences

In recent years,molybdenum disulfide（MoS2） has gained significant attention in the scientific *** MoS2demonstrates unique properties and potential ***,the synthesis of few-layered and high-purity 1T-MoS2is still a *** this study,we successfully employed a hydrothermal method to synthesize few-layered and high-purity *** purity of the material is controlled by a combination of sodium borohydride and ***,the few-layered 1T-MoS2exhibits exceptional performance as a supercapacitor,including the high specific capacitance(250.3 F g-1at a current density of 1 A g-1) and excellent long-trem cycling stability（90.7 % after 5000 cycles）.Meanwhile,the asymmetric device assembled by 6-FL-1TMoS2and active carbon on carbon cloths exhibits excellent flexibility and high energy and power density(23.1μWh cm-2at 600 μW cm-2,55 μWh cm-2at 12000 μW cm-2).This work provides valuable insights into the synthesis of few-layered and high-purity 1T-MoS2,opening up new avenues for further research and applications.

关键词： 1T-MoS2 Few-layered High-purity One-pot hydrothermal method Supercapacitor

Multi-spherical interactions and mechanisms of hydrocarbon enrichment in the Southeast Asian archipelagic tectonic system

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Science China Earth Sciences 2024年第2期67卷 566-583页

作者： Rixiang ZHU Hongjun WANG Huajian WANG Xiaomei WANG Bo WAN Wang ZHANG Houqin ZHU Yuke LIU Junlai LIU Qingren MENG Fang HAO Zhijun JIN state key laboratory of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing100029China state key laboratory of Enhanced Oil and Gas Recovery PetroChina Research Institute of Petroleum Exploration and DevelopmentBeijing100083China School of Earth Sciences and Resources China University of GeosciencesBeijing100083China state key laboratory of Deep Oil and Gas China University of Petroleum(East China)Qingdao266580China Institute of energy Peking UniversityBeijing100871China

Global cooling began since 50 Ma,but a warm climate was maintained in the archipelagic tectonic system in Southeast Asia where a wealth of Cenozoic oil and gas resources was formed and *** the perspective of Earth system,this study analyzes Cenozoic tectonic activities,climatic and environmental evolution,and petroleum enrichment in Southeast Asia,and provides the following insights:(1)Subduction of oceanic plates and the extension of overlying continental lithosphere resulted in widespread volcanic eruptions as well as the formation of rift basins and shallow marine shelves,leading to complex interactions between deep tectonic processes and Earth’s surface including mountains,basins,and seas.(2)Microcontinental accretion and prolonged stay in equatorial low-latitude regions have changed trade winds into monsoons,altered ocean current pathways and flow rates,and profoundly affected rainfall and climate.(3)The archipelagic tectonic system,coupled with a hot and rainy climate,fostered tropical rainforests,mangroves,and phytoplankton,providing abundant organic matter and promoting the development of petroleum resources.(4)Combinations of rift basin development and marine transgression and regression led to an effective superposition of source-reservoir-seal combinations from multiplepetroleum *** deep burial of organic matter and high geothermal gradients facilitated the generation and large-scale accumulation of oil and gas.(5)Multi-spherical(such as atmosphere,biosphere,hydrosphere and lithosphere)interactions on the Earth,which resulted from the convergence of multiple tectonic plates,are believed as the primary driver for exceptional enrichments of Cenozoic oil and gas resources in Southeast *** understandings are significant for developing theories of oil and gas enrichment under the guidance of Earth System *** order to continue making significant oil and gas exploration discoveries in the deep-layers,deep-waters,and unconventio

关键词： Southeast Asia Archipelagic tectonic system Interactions of Earth’s spheres Oil and gas resources Cenozoic

Boost the Utilization of Dense FeN4 Sites for High-Performance Proton Exchange Membrane Fuel Cells

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energy & environmental Materials 2024年第3期7卷 402-409页

作者： Yanrong Li Shuhu Yin Long Chen Xiaoyang Cheng Chongtai Wang Yanxia Jiang Shigang Sun state key laboratory of Physical Chemistry of Solid Surfaces Engineering Research Center of Electrochemical Technologies of Ministry of EducationCollege of Chemistry and Chemical Engineeringand Discipline of Intelligent Instrument and EquipmentXiamen University College of Chemistry and Chemical Engineering Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan ProvinceHainan Normal University

Iron-nitrogen-carbon （Fe-N-C） catalysts for the oxygen reduction reaction（ORR） in proton exchange membrane fuel cells （PEMFCs） have seriously been hindered by their poor ORR performance of Fe-N-C due to the low active site density （SD） and site ***,we reported a melamineassisted vapor deposition approach to overcome these *** melamine not only compensates for the loss of nitrogen caused by hightemperature pyrolysis but also effectively etches the carbon substrate,increasing the external surface area and mesoporous porosity of the carbon *** can provide more useful area for subsequent vapor deposition on active *** prepared 0.20Mela-FeNC catalyst shows a fourfold higher SD value and site utilization than the FeNC without the treatment of *** a result,0.20Mela-FeNC catalyst exhibits a high ORR activity with a half-wave potential (E1/2) of 0.861 V and 12-fold higher ORR mass activity than the FelMC in acidic *** the cathode in a H2-O2PEMFCs,0.20Mela-FeNC catalyst demonstrates a high peak power density of1.30 W cm-2,outstripping most of the reported Fe-N-C *** developed melamine-assisted vapor deposition approach for boosting the SD and utilization of Fe-N-C catalysts offers a new insight into high-performance ORR electrocatalysts.

关键词： fuel cells melamine oxygen reduction reaction site density utilization

Honeycomb-like biochar framework coupled with Fe_(3)O_(4)/FeS nanoparticles as efficient heterogeneous Fenton catalyst for phenol degradation

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Journal of environmental Sciences 2024年第2期136卷 390-399页

作者： Aihua Cheng Yi He Xiaohe Liu Chi He Department of environmental Engineering College of Geology and EnvironmentXi’an University of Science and TechnologyXi’an 710054China state key laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China National Engineering laboratory for VOCs Pollution Control Material and Technology University of Chinese Academy of SciencesBeijing 101408China

Achieving an efficient and stable heterogeneous Fenton reaction over a wide pH range is of great significance for wastewater ***,a pollen-derived biochar catalyst with a unique honeycomb-like structure,coupled with the dispersion of magnetic Fe_(3)O_(4)/FeS(Fe/S)nanoparticles,was synthesized by simple impregnation precursor,followed by *** prepared Fe/S-biochar catalyst demonstrated outstanding phenol degradation efficiency across a wide pH range,with 98%of which eliminated even under neutral conditions(pH 7.0).The high catalytic activity was due to the multilevel porous structure of pollenderived biochar provided enough active sites and allowed for better electron transfer,then increases oxidation ability to promote the ***,the acid microenvironment formed by SO_(4)^(2-)group from Fe/S composite extended the pH range for Fenton reaction,and S^(2-)facilitated the conversion of≡Fe^(3+)to≡Fe^(2+),resulting in remarkable degradation ***,biochar can effectively promote cycling stability by limiting Fe *** work may provide a general strategy for designing 3D framework biochar-based Fe/S catalysts with excellent performance for heterogeneous Fenton reactions.

关键词： Biomass Biochar Fenton reaction Fe_(3)O_(4)/FeS(Fe/S) Phenol degradation

Biohythane production from two-stage anaerobic digestion of food waste:A review

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Journal of environmental Sciences 2024年第5期139卷 334-349页

作者： Xiaona An Ying Xu Xiaohu Dai state key laboratory of Pollution Control and Resource Reuse School of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

The biotransformation of food waste(FW)to bioenergy has attracted considerable research attention as a means to address the energy crisis and waste disposal *** this end,a promising technique is two-stage anaerobic digestion(TSAD),in which the FW is transformed to biohythane,a gaseous mixture of biomethane and *** review summarises the main characteristics of FW and describes the basic principle of ***,the factors influencing the TSAD performance are identified,and an overview of the research status;economic aspects;and strategies such as pre-treatment,co-digestion,and regulation of microbial consortia to increase the biohythane yield from TSAD is ***,the challenges and future considerations associated with the treatment of FW by TSAD are *** paper can provide valuable reference for the improvement and widespread implementation of TSAD-based FW treatment.

关键词： Two-stage anaerobic digestion(TSAD) Food waste(FW) Methane production Hydrogen production

Heterostructure Cu_(3)P-Ni_(2)P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia

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Nano Research 2024年第6期17卷 4872-4881页

作者： Meng Jin Jiafang Liu Xian Zhang Shengbo Zhang Wenyi Li Dianding Sun Yunxia Zhang Guozhong Wang Haimin Zhang laboratory of Materials Physics Centre for Environmental and Energy NanomaterialsAnhui Key Laboratory of Nanomaterials and NanotechnologyCAS Center for Excellence in NanoscienceInstitute of Solid State PhysicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China University of Science and Technology of China Hefei 230026China Anhui Contango New energy Technology Co. Ltd.Hefei 230031China

Electrochemical nitrate reduction reaction(NO_(3)RR)is a promising means for generating the energy carrier ***,we report the synthesis of heterostructure copper-nickel phosphide electrocatalysts via a simple vapor-phase hydrothermal *** resultant catalysts were evaluated for electrocatalytic nitrate reduction to ammonia(NH_(3))in three-type electrochemical *** detail,the regulation mechanism of the heterogeneous Cu_(3)P-Ni_(2)P/CP-x for NO_(3)RR performance was systematically studied through the H-type cell,rotating disk electrode setup,and membrane-electrode-assemblies(MEA)*** a result,the Cu_(3)P-Ni_(2)P/CP-0.5 displays the practicability in an MEA system with an anion exchange membrane,affording the largest ammonia yield rate(RNH_(3))of 1.9 mmol·h^(−1)·cm^(−2),exceeding most of the electrocatalytic nitrate reduction electrocatalysts reported to *** theoretical calculations and in-situ spectroscopy characterizations uncover that the formed heterointerface in Cu_(3)P-Ni_(2)P/CP is beneficial for promoting nitrate adsorption,activation,and conversion to ammonia through the successive hydrodeoxygenation pathway.

关键词： electrocatalytic nitrate reduction to ammonia three-type reactors membrane-electrode-assemblies system operando ATR-IRRAS successive hydrodeoxygenation pathway