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Covalent organic framework with 3D ordered Channel and Multi-functional Groups Endows Zn Anode with Superior Stability

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Nano-Micro Letters 2024年第4期16卷 350-363页

作者： Bin Li Pengchao Ruan Xieyu Xu Zhangxing He Xinyan Zhu Liang Pan Ziyu Peng Yangyang Liu Peng Zhou Bingan Lu Lei Dai Jiang Zhou School of Chemical Engineering North China University of Science and TechnologyTangshan 063009People’s Republic of China School of materials Science and Engineering Central South UniversityChangsha 410083People’s Republic of China state key laboratory for mechanical behavior of materials Xi’an Jiaotong UniversityXi’an 710049People’s Republic of China Hunan Provincial key Defense laboratory of High Temperature Wear‑Resisting materials and Preparation Technology Hunan University of Science and TechnologyXiangtan 411201People’s Republic of China School of Physics and Electronics Hunan UniversityChangsha 410082People’s Republic of China

Achieving a highly robust zinc(Zn)metal anode is extremely important for improving the performance of aqueous Zn-ion batteries(AZIBs)for advancing“carbon neutrality”society,which is hampered by the uncontrollable growth of Zn dendrite and severe side reactions including hydrogen evolution reaction,corrosion,and passivation,etc.Herein,an interlayer containing fluorinated zincophilic covalent organic framework with sulfonic acid groups(Cof-S-f)is developed on Zn metal(Zn@Cof-S-f)as the artificial solid electrolyte interface(SEI).Sulfonic acid group(-So_(3)H)in Cof-S-f can effectively ameliorate the desolvation process of hydrated Zn ions,and the three-dimensional channel with fluoride group(-f)can provide interconnected channels for the favorable transport of Zn ions with ion-confinement effects,endowing Zn@Cof-S-f with dendrite-free morphology and suppressed side reactions.Consequently,Zn@Cof-S-f symmetric cell can stably cycle for 1,000 h with low average hysteresis voltage(50.5 m V)at the current density of 1.5 m A cm^(-2).Zn@Cof-S-f|Mn o_(2)cell delivers the discharge specific capacity of 206.8 m Ah g^(-1)at the current density of 1.2 A g^(-1)after 800 cycles with high-capacity retention(87.9%).Enlightening,building artificial SEI on metallic Zn surface with targeted design has been proved as the effective strategy to foster the practical application of high-performance AZIBs.

关键词： Aqueous Zn ion batteries Covalent organic framework Interfacial modification Zn ion flux regulation Desolvation effect

Preparation of Self-limiting Heating Cables with Excellent Processability, mechanical Properties and PTC Effect via Thermal and Electrical Treatments

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Chinese Journal of Polymer Science 2024年第4期42卷 511-520页

作者： Tian-Hao Yang Tong Wu Qiang fu state key laboratory of Polymer materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu610065China state key laboratory of Polymer materials Engineering Polymer Research Institute of Sichuan UniversityChengdu610065China

Polymer/conductive filler composites have been widely used for the preparation of self-limiting heating cables with the positive temperature coefficient (PTC) effect. The control of conductive filler distribution and network in polymer matrix is the most critical for performance of PTC materials. In order to compensate for the destruction of the filler network structure caused by strong shearing during processing, an excessive conductive filler content is usually added into the polymer matrix, which in turn sacrifices its processability and mechanical properties. In this work, a facile post-treatment of the as-extruded cable, including thermal and electrical treatment to produce high-density polyethylene (HDPE)/carbon black (CB) cable with excellent PTC effect, is developed. It is found for the as-extruded sample, the strong shearing makes the CB particles disperse uniformly in HDPE matrix, and 25 wt% CB is needed for the formation of conductive paths. for the thermal-treated sample, a gradually aggregated CB filler structure is observed, which leads to the improvement of PTC effect and the notable reduction of CB content to 20 wt%. It is very interesting to see that for the sample with combined thermal and electrical treatment, CB particles are agglomerated and oriented along the electric field direction to create substantial conductive paths, which leads to a further decrease of CB content down to 15 wt%. In this way, self-limiting heating cables with excellent processability, mechanical properties and PTC effect have simultaneously been achieved.

关键词： Self-limiting heating cables Positive temperature coefficient Thermal treatment Electrical treatment

Integrated Active Suspension and Anti-Lock Braking Control for four-Wheel-Independent-Drive Electric Vehicles

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Chinese Journal of mechanical Engineering 2024年第1期37卷 87-98页

作者： Ze Zhao Lei Zhang Xiaoling Ding Zhiqiang Zhang Shaohua Li Liang Gu National Engineering Research Center for Electric Vehicles Beijing Institute of TechnologyBeijing 100081China state key laboratory of mechanical behavior and System Safety of Traffic Engineering Structures Shijiazhuang Tiedao UniversityShijiazhuang 050043China

This paper presents an integrated control scheme for enhancing the ride comfort and handling performance of a four-wheel-independent-drive electric vehicle through the coordination of active suspension system(ASS)and anti-lock braking system(ABS).first,a longitudinal-vertical coupled vehicle dynamics model is established by integrating a road input model.Then the coupling mechanisms between longitudinal and vertical vehicle dynamics are analyzed.An ASS-ABS integrated control system is proposed,utilizing an H∞controller for ASS to optimize load transfer effect and a neural network sliding mode control for ABS implementation.finally,the effectiveness of the proposed control scheme is evaluated through comprehensive tests conducted on a hardware-in-loop(HIL)test platform.The HIL test results demonstrate that the proposed control scheme can significantly improve the braking performance and ride comfort compared to conventional ABS control methods.

关键词： four-wheel-independent-drive electric vehicles Active suspension system(ASS) Anti-lock braking system(ABS) Vertical-longitudinal vehicle dynamics

optoelectronic Synapses Based on MXene/Violet Phosphorus van der Waals Heterojunctions for Visual‑olfactory Crossmodal Perception

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Nano-Micro Letters 2024年第6期16卷 38-52页

作者： Hailong Ma Huajing fang Xinxing Xie Yanming Liu He Tian Yang Chai Center for Advancing materials Performance from the Nanoscale(CAMP‑Nano) State Key Laboratory for Mechanical Behavior of MaterialsXi’an Jiaotong UniversityXi’an 710049People’s Republic of China Institute of Microelectronics and Beijing National Research Center for Information Science and Technology(BNRist) Tsinghua UniversityBeijing 100084People’s Republic of China Department of Applied Physics The Hong Kong Polytechnic UniversityHong KongPeople’s Republic of China

The crossmodal interaction of different senses,which is an important basis for learning and memory in the human brain,is highly desired to be mimicked at the device level for developing neuromorphic crossmodal perception,but related researches are scarce.Here,we demonstrate an optoelectronic synapse for vision-olfactory crossmodal perception based on MXene/violet phosphorus(VP)van der Waals heterojunctions.Benefiting from the efficient separation and transport of photogenerated carriers facilitated by conductive MXene,the photoelectric responsivity of VP is dramatically enhanced by 7 orders of magnitude,reaching up to 7.7 A W^(−1).Excited by ultraviolet light,multiple synaptic functions,including excitatory postsynaptic currents,pairedpulse facilitation,short/long-term plasticity and“learning-experience”behavior,were demonstrated with a low power consumption.furthermore,the proposed optoelectronic synapse exhibits distinct synaptic behaviors in different gas environments,enabling it to simulate the interaction of visual and olfactory information for crossmodal perception.This work demonstrates the great potential of VP in optoelectronics and provides a promising platform for applications such as virtual reality and neurorobotics.

关键词： Violet phosphorus MXene Van der Waals heterojunctions optoelectronic synapses Crossmodal perception

Adaptive sampling for corrugated plate digitization using a laser displacement sensor

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Science China(Technological Sciences) 2024年第5期67卷 1510-1523页

作者： WU ChengXing QI Qi CHEN BaiJin YANG JiXiang DING Han state key laboratory of Intelligent Manufacturing Equipment and Technology School of Mechanical Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China state key laboratory of Intelligent Manufacturing Equipment and Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan430074China

The surface quality of a corrugated plate directly determines the heat transfer property of the thermal power mechanical apparatus.Traditional detection methods are impractical for real-world production,being slow and destructive.In contrast,the point laser displacement sensor,employing the optical triangle method,emerges as a promising device for assessing parts with variable curvature and highly reflective surfaces.Despite its benefits,high-density sampling by an innate frequency introduces challenges such as data redundancy and a poor signal-to-noise ratio,potentially affecting the efficiency and precision of subsequent data processing.To address these challenges,adjustable frequency data sampling has been developed for this sensor,allowing adaptive sampling for corrugated plate digitization.The process begins with surface digitization to extract discrete points,which are transformed into intersection curves using the B-spline fitting technique.Subsequently,dominant points are identified,considering multigeometric constraints for curvature and arch height.finally,the sampling signal is adjusted based on the distribution information of dominant points.Comparative results indicate that the proposed method effectively minimizes redundant sampling without compromising the accurate capture of essential geometric features.

关键词： corrugated plate laser displacement sensor adaptive sampling dominant point curvature arch height

Preparation of Polyurea Elastomer with flame Retardant, Insulation and Thermal Conductivity Properties

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Journal of Wuhan University of Technology(materials Science) 2024年第3期39卷 781-789页

作者：方今 DoNG Yang LU Shangkai LIU Junbang AI Lianghui 刘平 state key laboratory of Luminescent materials and Devices Research Institute of Materials ScienceSouth China University of TechnologyGuangzhou 510640China

By using 6,6-((sulfonylbis(4,1-phenylene)bis(azanediyl))bis(thiophen-2-ylm-ethylene))bis6H-di-benzo[c,e][1,2]oxaphosphinine 6-oxide(DoPo-N)as phosphorus-nitrogen flame retardant,the polyurea(PUA)with flame retardant properties(PUA/DoPo-N)was prepared.In addition,organically modified montmorillonite(oMMT)and magnesium hydroxide(MH)were used as co-effectors respectively,and the flame retardant PUA(PUA/DoPo-N/oMMT and PUA/DoPo-N/MH)were also prepared.Thermal properties,flame retardant properties,flame retardant mechanism and mechanical properties of PUA/DoPo-N,PUA/DoPo-N/oMMT and PUA/DoPo-N/MH were investigated by thermogravimetric(TG)analysis,limiting oxygen index(LoI),UL 94,cone calorimeter test,scanning electron microscopy(SEM),and tensile test.The results show that the LoI value of PUA/20%DoPo-N,PUA/18%DoPo-N/2%oMMT and PUA/15%DoPo-N/5%MH are 27.1%,27.7%,and 28.3%,respectively,and UL 94 V-0 rating is attained.Compared with PUA,the peak heat release rate(pk-HRR),total heat release(THR)and average effective heat combustion(av-EHC)of PUA/20%DoPo-N,PUA/18%DoPo-N/2%oMMT and PUA/15%DoPo-N/5%MH decrease significantly.SEM results indicate that the residual chars of PUA/20%DoPo-N,PUA/18%DoPo-N/2%oMMT and PUA/15%DoPo-N/5%MH are completer and more compact.The complex of DoPo-N/oMMT and DoPo-N/MH have synergistic flame retardancy.The mechanical properties of PUA can be improved by the addition of DoPo-N,DoPo-N/oMMT and DoPo-N/MH,respectively.The insulation performance test shows that the volume resistivity of PUA/20%DoPo-N is 6.25×10^(16)Ω.cm.furthermore,by using modified boron nitride(MBN)as heat dissipating material,the complex of PUA/MBN was prepared,and the thermal conductivity of PUA/MBN was investigated.The thermal conductivity of PUA/8%MBN complex coating at room temperature is 0.166 W/(M·K),which is a 163%improvement over pure PUA.

关键词： polyurea organic flame retardant inorganic flame retardant synergistic flame retardancy insulation thermal conductivity

Targeted regeneration and upcycling of spent graphite by defect‐driven tin nucleation

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Carbon Energy 2024年第4期6卷 91-103页

作者： Zhiheng Cheng Zhiling Luo Hao Zhang Wuxing Zhang Wang Gao Yang Zhang Long Qie Yonggang Yao Yunhui Huang Kun Kelvin fu state key laboratory of materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhanChina key laboratory of Automobile materials(Jilin University) Ministry of EducationDepartment of Materials Science and EngineeringJilin UniversityChangchunChina Electronic materials Research laboratory(key Lab of Education Ministry) School of Electronic and Information Engineeringand Instrumental Analysis CenterXi'an Jiaotong UniversityXi'anChina Department of mechanical Engineering University of DelawareNewarkUSA

The recycling of spent batteries has become increasingly important owing to their wide applications,abundant raw material supply,and sustainable development.Compared with the degraded cathode,spent anode graphite often has a relatively intact structure with few defects after long cycling.Yet,most spent graphite is simply burned or discarded due to its limited value and inferior performance on using conventional recycling methods that are complex,have low efficiency,and fail in performance restoration.Herein,we propose a fast,efficient,and“intelligent”strategy to regenerate and upcycle spent graphite based on defect‐driven targeted remediation.Using Sn as a nanoscale healant,we used rapid heating(~50 ms)to enable dynamic Sn droplets to automatically nucleate around the surface defects on the graphite upon cooling owing to strong binding to the defects(~5.84 eV/atom),thus simultaneously achieving Sn dispersion and graphite remediation.As a result,the regenerated graphite showed enhanced capacity and cycle stability(458.9 mAh g^(−1) at 0.2 A g^(−1) after 100 cycles),superior to those of commercial graphite.Benefiting from the self‐adaption of Sn dispersion,spent graphite with different degrees of defects can be regenerated to similar structures and performance.EverBatt analysis indicates that targeted regeneration and upcycling have significantly lower energy consumption(~99%reduction)and near‐zero Co2 emission,and yield much higher profit than hydrometallurgy,which opens a new avenue for direct upcycling of spend graphite in an efficient,green,and profitable manner for sustainable battery manufacture.

关键词： battery recycling spent graphite targeted regeneration upcycling graphite

Hybrid assembly of conducting nanofiber network for ultra-stretchable and highly sensitive conductive hydrogels

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Journal of materials Science & Technology 2024年第2期169卷 1-10页

作者： Yalei Wang Shulong Zeng Shaohong Shi Yuheng Jiang Zhiwei Du Bingzhen Wang Xiurong Li state key laboratory of featured Metal materials and Life-cycle Safety for Composite Structures School of ResourcesEnvironment and MaterialsGuangxi UniversityNanning 530004China state key laboratory of Polymer materials Engineering Polymer Research Institute of Sichuan UniversitySichuan UniversityChengdu 610065China

Conductive hydrogels have attracted extensive attention owing to their promising application prospects in flexible and wearable electronics.However,achieving both high sensitivity and mechanical robustness remains challenging.Herein,a novel and versatile conductive hydrogel based on the hybrid assem-bly of conductive cellulose nanofiber(CNf)networks has been designed and fabricated.Assisted by the templating effect of CNfs and stabilizing effect of negatively charged poly(styrene sulfonate)(PSS),conducting polymer poly(3,4-ethylenedioxythiophene)(PEDoT)was self-organized into three-dimensional nanostructures which constructed a robust conductive network after in-situ oxidative polymerization.The unique structure derived from CNf bio-template endowed polyacrylamide(PAM)hydrogels with improved electrical conductivity and excellent mechanical performance.As a result,the as-fabricated CNf/PEDoT:PSS/PAM hydrogel exhibited an ultimate tensile strain of 1881%and toughness of 3.72 MJ/m^(3),which were 4.07 and 8.27 times higher than the CNf-free hydrogel,respectively.More significantly,the resultant hydrogel sensor showed highly desirable sensing properties,including remarkable sensing range(1100%),high gauge factor(Gf=5.16),fast response time(185 ms),and commendable durability,as well as good adhesiveness.Moreover,the hydrogel sensor was able to distinguish subtle physiological activities including phonation and facial expression,and monitor large human body motions such as finger flexion and elbow blending.Besides,it was feasible to integrate the strain sensor on the joints of robots to recognize complicated machine motion signals,showing potential in advanced human-machine interactions.

关键词： Strain sensor Cellulose nanofibers PEDoT:PSS Conductive hydrogel Templating method

Versatile MXene Gels Assisted by Brief and Low‑Strength Centrifugation

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Nano-Micro Letters 2024年第5期16卷 231-247页

作者： Weiyan Yu Yi Yang Yunjing Wang Lulin Hu Jingcheng Hao Lu Xu Weimin Liu state key laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000People’s Republic of China Shandong laboratory of Advanced materials and Green Manufacturing at Yantai Yantai 264006People’s Republic of China key laboratory of Colloid and Interface Chemistry and key laboratory of Special Aggregated materials Shandong UniversityJinan 250100People’s Republic of China

Due to the mutual repulsion between their hydrophilic surface terminations and the high surface energy facilitating their ran-dom restacking,2D MXene nanosheets usually cannot self-assemble into 3D macroscopic gels with various applications in the absence of proper linking agents.In this work,a rapid spontaneous gelation of Ti3C2Tx MXene with a very low dispersion concentration of 0.5 mg mL^(-1) into multifunctional architectures under moderate centrifugation is illustrated.The as-prepared MXene gels exhibit reconfigurable internal structures and tunable rheological,tribological,electrochemical,infrared-emissive and photothermal-conversion properties based on the pH-induced changes in the surface chemistry of Ti_(3)C_(2)T_(x) nanosheets.By adopting a gel with optimized pH value,high lubrication,exceptional specific capacitances(~635 and~408 f g^(-1) at 5 and 100 mV s^(-1),respectively),long-term capacitance retention(~96.7%after 10,000 cycles)and high-precision screen-or extrusion-printing into different high-resolution anticounterfeiting patterns can be achieved,thus displaying extensive potential applications in the fields of semi-solid lubrication,control-lable devices,supercapacitors,information encryption and infrared camouflaging.

关键词： MXene Centrifugation-assisted rapid gelation Lubrication Supercapacitor Anti-counterfeiting applications