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A review of physicochemical properties of dissolved organic carbon and its impact over mountain glaciers

Journal of Mountain Science 2024年第1期21卷 1-19页

作者： NIU Hewen CHEN Mengxue KANG Shichang SHUKLA Tanuj QIN Huili GAO Wanni HUANG Shihai ZHANG Fu state Key Laboratory of Cryospheric Sciences/National Field Science Observation and research station of Yulong Snow Mountain Cryosphere and Sustainable Development Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China School of Politics and International Relations Lanzhou UniversityLanzhou 730000China University of Chinese Academy of Sciences Beijing 10049China Dagu glacier Scenic and Historic Interest Area Administration Luhua TownHeishui 615715China

Investigating the characteristics and transformation of water-soluble carbonaceous matter in the cryosphere regions is important for understanding biogeochemical process in the earth system.Water-soluble carbonaceous matter is a heterogeneous mixture of organic compounds that is soluble in aquatic environments.Despite its importance,we still lack systematic understanding for dissolved organic carbon(DOC)in several aspects including exact chemical composition and physical interactions with microorganisms,glacier meltwater.This review presents the chemical composition and physical properties of glacier DOC deposited through anthropogenic emission,terrestrial,and biogenic sources.We present the molecular composition of DOC and its effect over snow albedo and associated radiative forcings.Results indicate that DOC in snow/ice is made up of aromatic protein-like species,fulvic acid-like materials,and humic acid-like materials.Light-absorbing impurities in surface snow and glacier ice cause considerable albedo reduction and the associated radiative forcing is definitely positive.Water-soluble carbonaceous matter dominated the carbon transport in the high-altitude glacial area.Owing to prevailing global warming and projected increase in carbon emission,the glacial DOC is expected to release,which will have strong underlying impacts on cryosphere ecosystem.The results of this work have profound implications for better understanding the carbon cycle in high altitude cryosphere regions.A new compilation of globally distributed work is required,including large-scale measurements of glacial DOC over high-altitude cryosphere regions,to overcome and address the scientific challenges to constrain climate impacts of light-absorbing impurities related processes in Earth system and climate models.

关键词： Mountain glaciers Dissolved organic carbon Molecular composition Radiative forcing

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Quantifying Contribution of Recycled Moisture to Precipitation in Temperate glacier Region,Southeastern Tibetan Plateau,China

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Chinese Geographical Science 2024年第4期34卷 764-776页

作者： MA Yanwei PU Tao SHI Xiaoyi MA Xinggang YU Hongmei College of Geography and Environmental Sciences Zhejiang Normal UniversityJinhua 321004China National Field Science Observation and research station of Yulong Snow Mountain Cryosphere and Sustainable Development Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China state Key Laboratory of Cryospheric Sciences Northwest Institute of Eco-environment and ResourcesChinese Academy of SciencesLanzhou 730000China

Recycled moisture is an important indicator of the renewal capacity of regional water resources.Due to the existence of Yulong Snow Mountain,Lijiang in Yunnan Province,southeast of the Qinghai-Tibet Plateau,China,is the closest ocean glacier area to the equator in Eurasia.Daily precipitation samples were collected from 2017 to 2018 in Lijiang to quantify the effect of sub-cloud evaporation and recycled moisture on precipitation combined with the d-excess model during monsoon and non-monsoon periods.The results indicated that the d-excess values of precipitation fluctuated between–35.6‰and 16.0‰,with an arithmetic mean of 3.5‰.The local meteoric water line(LMWL)wasδD=7.91δ~(18)O+2.50,with a slope slightly lower than the global meteoric water line(GMWL).Subcloud evaporation was higher during the non-monsoon season than during the monsoon season.It tended to peak in March and was primarily influenced by the relative humidity.The source of the water vapour affected the proportion of recycled moisture.According to the results of the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)model,the main sources of water vapour in Lijiang area during the monsoon period were the southwest and southeast monsoons.During the non-monsoon period,water vapour was transported by a southwesterly flow.The recycled moisture in Lijiang area between March and October 2017 was 10.62%.Large variations were observed between the monsoon and non-monsoon seasons,with values of 5.48%and 25.65%,respectively.These differences were primarily attributed to variations in the advection of water vapour.The recycled moisture has played a supplementary role in the precipitation of Lijiang area.

关键词： recycled moisture stable isotope precipitation d-excess Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)model southeastern Tibetan Plateau China

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Influence of Sub-Cloud Secondary Evaporation Effects on the Stable Isotopes in Precipitation of Urumqi glacier No.1,Eastern Tianshan

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Journal of Earth Science 2024年第1期35卷 177-189页

作者： Mengyuan Song Zhongqin Li Feiteng Wang Xin Zhang state Key Laboratory of Cryospheric Sciences Northwest Institute of Eco-Environment and ResourcesTianshan Glaciological StationChinese Academy of SciencesLanzhou 730000China College of Geography and Environmental Science Northwest Normal UniversityLanzhou 730000China College of Sciences Shihezi UniversityShihezi 832000China

In arid regions,the stable hydrogen and oxygen isotopic composition in raindrops is often modified by sub-cloud secondary evaporation when they descend from cloud base to ground through the unsaturated air.As a result of kinetic fractionation,the slope and intercept of the δ^(2)H-δ^(18)O correlation equation decrease.The variation of deuterium excess from cloud base to the ground is often used to quantitatively evaluate the influence of secondary evaporation effect on isotopes in precipitation.Based on the event-based precipitation samples collected at Urumqi glacier No.1,eastern Tianshan during four-year observation,the existence and impact of secondary evaporation effects were analyzed by the methods of isotope-evaporation model.Under high air temperature,small raindrop diameter and precipitation amount,and low relative humidity conditions,the remaining rate of raindrops is small and the change of deuterium excess is large relatively,and the slope and intercept of δ^(2)H-δ^(18)O correlation equation are much lower than those of Global Meteoric Water Line,which mean that the influence secondary evaporation on precipitation enhanced.While on the conditions of low air temperature,high relative humidity,heavy rainfall,and large raindrop diameter,the change of deuterium excess is small relatively and the remaining rate of raindrops is large,and the slope and intercept of δ^(2)H-δ^(18)O correlation equation increase,the secondary evaporation is weakened.The isotope-evaporation model described a good linear correlation between changes of deuterium excess and evaporation proportion with the slope of 0.90‰/%,which indicated that an increase of 1%in evaporation may result in a decrease of deuterium excess about 0.90‰.

关键词： stable isotopes meteoric water line deuterium excess sub-cloud secondary evaporation effect precipitation glaciers

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Global warming weakening the inherent stability of glaciers and permafrost

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Science Bulletin 2019年第4期64卷 245-253页

作者： Yongjian Ding Shiqiang Zhang Lin Zhao Zhongqin Li Shichang Kang state Key Laboratory of Cryospheric Science Northwest China Ecological Environment and Resource Research Institute Chinese Academy of Sciences Key Laboratory of Ecohydrology of Inland River Basin Chinese Academy of Sciences University of Chinese Academy Sciences Shaanxi Key Laboratory of Earth Surface System and Environmental Carrying Capacity Northwest University College of Urban and Environmental Sciences Northwest University state Cryosphere monitor and research station Northwest China Ecological Environment and Resource Research Institute Chinese Academy of Sciences state glacier monitor and research station Northwest China Ecological Environment and Resource Research Institute Chinese Academy of Sciences

The Cryosphere has been undergoing a worldwide retreat, as seen in the decrease in the areal extent and volume of glaciers and in the areal extent of permafrost. This paper presents a systematic examination of the inherent stability changes of glaciers and permafrost caused by warming. Various study results suggest that over the past 30 years, the internal temperature of glaciers and permafrost exhibits an overall accelerating warming trend. The warming rate peaked in the mid-2000s and slowed slightly for several years afterward. In recent years, however, the warming rate has seemed to pick up again. The warming of glaciers and permafrost has exerted great impact on their stability, displayed as intensified melting,increased glacier surging, enlargement of supraglacial lakes, and increased permafrost degradation.Even without a future temperature increase, some glaciers will continue to shrink, and the number of surging glaciers will increase. The transition from low-temperature to high-temperature permafrost is a noticeable warning sign of a comprehensive degradation of permafrost. These results indicate that‘‘warming" glaciers and permafrost will exert significant impacts on the hydrology, ecology, and stability of engineering in cold regions.

关键词： Warming Englacial temperature Permafrost Internal thermal state Stability

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Unveiling evapotranspiration patterns and energy balance in a subalpine forest of the Qinghai-Tibet Plateau:observations and analysis from an eddy covariance system

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Journal of Forestry research 2024年第3期35卷 175-188页

作者： Niu Zhu Jinniu Wang Dongliang Luo Xufeng Wang Cheng Shen Ning Wu Ning Zhangg Binghui Tian Aihong Gai Chengdu Institute of Biology Chinese Academy of SciencesChengdu 610041People's Republic of China College of Resources and Environmental Sciences Gansu Agricultural UniversityLanzhou 730070People's Republic of China Mangkang Ecological monitoring station Tibet Ecological Security Barrier Ecological Monitoring NetworkQamdo 854500People's Republic of China Northwest Institute of Eco Environmental Resources Chinese Academy of SciencesLanzhou 730000People's Republic of China

Evapotranspiration is an important parameter used to characterize the water cycle of ecosystems.To under-stand the properties of the evapotranspiration and energy balance of a subalpine forest in the southeastern Qinghai-Tibet Plateau,an open-path eddy covariance system was set up to monitor the forest from November 2020 to October 2021 in a core area of the Three Parallel Rivers in the Qing-hai-Tibet Plateau.The results show that the evapotranspira-tion peaked daily,the maximum occurring between 11:00 and 15:00.Environmental factors had significant effects on evapotranspiration,among them,net radiation the greatest(R^(2)=0.487),and relative humidity the least(R^(2)=0.001).The energy flux varied considerably in different seasons and sensible heat flux accounted for the main part of turbulent energy.The energy balance ratio in the dormant season was less than that in the growing season,and there is an energy imbalance at the site on an annual time scale.

关键词： Evapotranspiration Energy balance Subalpine forest Three Parallel Rivers region Southeast Qinghai-Tibet Plateau

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Ecological risk assessment of heavy metals in surface seawater and sediment near the outlet of a zinc factory in Huludao City, Liaoning Province, China

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Chinese Journal of Oceanology and Limnology 2016年第6期34卷 1320-1331页

作者：冯永亮陈燕珍王静宫玉峰刘希刚牟刚田华 Marine Life Science College Ocean University of China Dalian Marine Environment monitor Central station State Oceanic Administration (SOA)

At present, the methods widely applied to assess ecological risk of heavy metals are essentially single-point estimates in which exposure and toxicity data cannot be fully used and probabilities of adverse biological effects cannot be achieved. In this study, based on investigation of concentrations of six heavy metals(As, Hg, Pb, Cd, Cu, and Zn) in the surface seawater and sediment near the outlet of a zinc factory, located in Huludao City, Liaoning Province, China, a tiered approach consisting of several probabilistic options was used to refi ne ecological risk assessment for the individuals. A mixture of various heavy metals was detected in the surface seawater, and potential ecological risk index(PERI) was adopted to assess the potential ecological risk of heavy metals in the surface sediment. The results from all levels of aquatic ecological risk assessment in the tiered framework, ranging from comparison of single effects and exposure values to the use of distribution-based Hazard Quotient obtained through Monte Carlo simulation, are consistent with each other. Briefl y, aquatic Zn and Cu posed a clear ecological risk, while Cd, Pb, Hg, and As in the water column posed potential risk. As expected, combined ecological risk of heavy metal mixture in the surface seawater was proved signifi cantly higher than the risk caused by any individual heavy metal, calculated using the concept of total equivalent concentration. According to PERI, the severity of pollution by the six heavy metals in the surface sediment decreased in the following sequence: Cd>Hg>As>Pb>Cu>Zn, and the total heavy metals in the sediment posed a very high risk to the marine environment. This study provides a useful mathematical framework for ecological risk assessment of heavy metals.

关键词：重金属生态的风险评价锌工厂连接概率曲线蒙特卡罗潜在的生态的风险索引

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Changes in climate extremes in a typical glacierized region in central Eastern Tianshan Mountains and their relationship with observed glacier mass balance

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Advances in Climate Change research 2022年第6期13卷 909-922页

作者： Hui ZHANG Fei-Teng WANG Ping ZHOU Altai Observation and research station of Cryospheric Science and Sustainable Development State Key Laboratory of Cryospheric ScienceNorthwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China Tianshan Glaciological station State Key Laboratory of Cryospheric ScienceNorthwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China

As an icon of anthropogenic climate change,alpine glaciers are highly sensitive to climate change.However,there remain research gaps regarding trends in climate extremes in glacierized regions and their relationship with local glacier mass balance.In this study,these relationships and their underlying links were explored in a typical glacierized region in the Eastern Tianshan Mountains,China,from 1959 to 2018.All warm extremes exhibited increasing trends that intensified dramatically from the 1990s.Meanwhile,decreasing trends were found for all cold extremes except for the temperatures of the coldest days and coldest nights.All of the precipitation extremes demonstrated increasing trends,except for consecutive dry days and consecutive wet days.Statistically significant positive/negative correlations were detected between glacier mass balance and six warm extremes(TN90p,TX90p,SU99p,TR95p,TXx,and TNx)/four cold extremes(TN10p,TX10p,FD0,and ID0).Simulation results showed that the impact of the intensity/frequency of the warm extremes(TN90p,TX90p,SU99p,and TR95p)on glacier ablation was remarkable and the effect of the cold extremes(FD0 and ID0)on accumulation was also significant.Additionally,the increases in the intensity and frequency of most climate extremes seemed more remarkable in glacierized regions than in non-glacierized regions.Hence,studies on glacier-climate interactions should focus greater attention on the impacts of climate extremes on glacier evolution.

关键词： Climate extremes Typical glacierized region glacier mass balance Eastern tianshan mountains

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Response of Distribution Range Against Climate Change and Habitat Preference of Four National Protected Diploderma Species in Tibetan Plateau

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Asian Herpetological research 2023年第4期14卷 319-330页

作者： Lin SHI Xiudong SHI Yuning CAO Yayong WU Haijuan WEI Youhua CHEN Ziyan LIAO Yin QI Chengdu Institute of Biology Chinese Academy of SciencesChengdu 610041SichuanChina University of Chinese Academy of Sciences Beijing 101408China Yibin University Yibin 644007SichuanChina Tibet Autonomous Region Remote Sensing monitoring Center for Ecological Environment Lhasa 850000XizangChina Mangkang Ecological station Tibet Ecological Safety Monitor NetworkChangdu 854500XizangChina

Understanding the spatial distribution and habitat preference for rare and endangered species are essential for effective conservation practice.We examined the spatial distribution and habitat preference of four Diploderma species(Diploderma drukdaypo,D.laeviventre,D.batangense,and D.vela),which are endemic to the Qinghai-Tibet Plateau and are currently under state protection.We used the ensembles of small models(ESM)approach and predicted potential distribution ranges of the species in current and two future climate scenarios(SSP126 and SSP585).The degree of overlap between the predicted distribution ranges and existing natural reserves was further analyzed.Habitat preference was examined using a paired quadrat method.Our results predicted that D.drukdaypo has a current distribution range of 600 km^(2),which would decrease to 50 km^(2)and 55 km^(2)under the SSP126 and SSP585 respectively.For D.laeviventre,the current distribution range is 817 km^(2),with minimum changes in the two future climate scenarios(774 km^(2)and 902 km^(2)).For D.batangense,the current distribution range is 875 km^(2),which would expand to 1522 km^(2)and 3340 km^(2)in the two future climate scenarios.Similarly for D.vela,the current distribution range is 1369 km^(2),which would change to 1825 km^(2)and 2043 km^(2)respectively under the two future climate scenarios.The effect of protection of current nature reserves are likely low for those species;we found no overlap(D.drukdaypo,D.laeviventre)or little overlap(D.batangense 2.04%–3.56%,D.vela 15.52%–16.87%)between the currently designated protection area and distribution range under current and future climate scenarios.For habitat preference,stones appear to be the critical habitat element for those species although different species had different stone requirements.Taken together,we provided critical information on potential distribution ranges and habitat preference for four endangered Diploderma species,and confirmed the inadequacy of current nature reserves.The establishment of new or

关键词： climate change distribution range habitat preference nature reserve reptile

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氢氧同位素和水化学特征反映的祁连山老虎沟冰川径流过程（英文）

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Journal of Geographical Sciences 2016年第6期26卷 722-734页

作者：王彩霞董志文秦翔张杰杜文涛吴锦奎 College of Geography and Environmental Science Northwest Normal University state Key Laboratory of Cryospheric Sciences CAS Qilian Mountain glacier and Ecological Environment research station Cold and Arid Regions Environmental and Engineering Research Institute CAS

Stable hydrogen and oxygen isotope has important implication on water and moisture transportation tracing research. Based on stable hydrogen(δD) and oxygen(δ^(18)O) isotope using a Picarro L1102-i and water chemistry(e.g. major ions, p H, EC and TDS) measurement, this study discussed the temporal variation and characteristics of stable hydrogen and oxygen isotope, chemistry(e.g. TDS, p H, EC, Ca^(2+), Mg^(2+), Na+ and Cl-) in various water bodies including glacier meltwater runoff, ice and snow, and precipitation at the Laohugou glacier basin during June 2012 to September 2013. Results showed that δD and δ^(18)O in the meltwater runoff varied obviously with the temporal change from June to September, showing firstly increasing trend and then decreasing trend, with the highest values in July with high air temperature and strong glacier melting, which could indicate the temporal change of glacier melting process and extent. Variations of δD and δ^(18)O in the runoff were similar with that of snow and ice on the glacier, and the values were also above the GMWL, which probably implied that the glacier runoff was mainly originated from glacier melting and precipitation supply. The glacier meltwater chemical type at the Laohugou glacier basin were mainly composed by Ca-Na-HCO_3-SO_4 and Ca-Mg-HCO_3-SO_4, which also varied evidently with the glacier melting process in summer. By analyzing the temporal change of stable hydrogen and oxygen isotope and chemistry in the melting period, we find it is easy to separate the components of the snow and ice, atmospheric precipitation and melt-runoff in the river, which could reflect the change process of glacier melting during the melting period, and thus this work can contribute to the glacier runoff change study of large-scale region by stable isotope and geochemical method in future.

关键词：冰川融水径流过程水化学 O同位素老虎氧稳定同位素祁连山氢同位素

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An Improved Method Based on Shallow Ice Approximation to Calculate Ice Thickness along Flow-Line and Volume of Mountain glaciers

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Journal of Earth Science 2011年第4期22卷 441-448页

作者：李慧林李忠勤张明军李汶峰 state Key Laboratory of Cryospheric Sciences/Tianshan Glaciological station Cold and Arid Regions Environmental and Engineering Research Institute Chinese Academy of Sciences state Key Laboratory of Cryospheric Sciences/Tien Shan Glaciological station Cold and Arid Regions Environmental and Engineering Research Institute Chinese Academy of Sciences College of Geography and Environment Sciences Northwest Normal University

To evaluate the water storage and project the future evolution of glaciers, the ice-thickness of glaciers is an essential input. However, direct measurements of ice thickness are labo- rious, not feasible everywhere, and necessarily restricted to a small number of glaciers. In this article, we develop a simple method to estimate the ice-thickness along flow-line of mountain glaciers. Different from the traditional method based on shallow ice approximation （SIA）, which gives a relationship be- tween ice thickness, surface slope, and yield stress of glaciers, the improved method considers and pre- sents a simple way to calibrate the influence of valley wall on ice discharge. The required inputs are the glacier surface topography and outlines. This shows the potential of the method for estimating the ice-thickness distribution and volume of glaciers without using of direct thickness measurements.

关键词： improved method shallow ice approximation ice thickness calculation glacier volume calculation mountain glacier.

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