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Regulation of the pore structure of carbon nanosheets based electrocatalyst for efficient polysulfides phase conversions

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Journal of materials Science & Technology 2024年第4期171卷 37-46页

作者： Xiaoyang Liu Jingbo Zhang Kangli Liu Shijie Zhang Rouhan Hou Xiaoyi Hu Peng Zhang Guosheng Shao state Center for international cooperation on designer low-carbon&environmental materials(CDLCEM) School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China Zhengzhou materials Genome Institute(ZMGI) Xingyang 450100China

The practical applications of lithium-sulfur(Li-S)batteries are hampered by the sluggish redox kinetics and polysulfides shuttle in the cyclic process,which leads to a series of problems including the loss of active materials and poor cycling *** this paper,the pore structures of carbon nanosheets based electrocatalysts were precisely controlled by regulating the content of water-soluble KCl *** relationship between pore structures and Li-S electrochemical behavior was studied,which demonstrates a key influence of pore structure in polysulfides phase *** the liquid-sloid redox reaction of polysulfides,the micropores and small mesopores(d20 nm)and macropores played a decisive *** a typical exhibition,the nickel-embedded carbon nanosheets(Ni-CNS)with a high content of large mesopores and macropores can aid Li-S batteries in exhibiting stable cycling performance(760.1 mAh g^(-1)at 1 C after 300 cycles)and superior rate capac-ity(847.8 mAh g^(-1)at 2 C).Furthermore,even with high sulfur loading(8 mg cm^(−2))and low electrolyte(E/S is around 6μL mg^(-1)),the high area capacity of 7.7 mAh cm^(−2)at 0.05 C could be *** work can provide a guideline for the design of the pore structure of carbon-based electrocatalysts toward high-efficiency sulfur species redox reactions,and afford a general,controllable,and simple approach to constructing high performance Li-S batteries.

关键词： Hierarchical porous carbon network Electrocatalyst Molten salt templating method Modified separators Li-S batteries

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Sensitive humidity sensor based on moisture-driven energy generation

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Nano Research 2024年第6期17卷 5578-5586页

作者： Qingchao Ni Qing Lou Chenglong Shen Guangsong Zheng Runwei Song Jingnan Hao Jialu Liu Jinyang Zhu Jinhao Zang Lin Dong Chong-Xin Shan Henan Key Laboratory of Diamond Optoelectronic materials and Devices Key Laboratory of Materials PhysicsMinistry of Educationand School of Physics and MicroelectronicsZhengzhou UniversityZhengzhou 450052China state centre for international cooperation on designer low-carbon&environmental materials and School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China

The emergence of novel self-powered humidity sensors has attracted considerable attention in the fields of smart electronic devices and personal ***,self-powered humidity sensors have been fabricated using a moisture-driven energy generation(MEG)device based on asymmetric tubular graphitic carbon nitride(g-CN)films prepared on anodized aluminum(AAO)*** a relative humidity(RH)of 96%,the MEG device can provide an open-circuit voltage of 0.47 V and a short-circuit current of 3.51μA,with a maximum output power of 0.08μ*** inherent self-powered ability and humidity response via current variation,an extraordinary response of 1.78×106%(41%-96%RH)can be gained from the MEG *** possible power generation mechanism is that g-CN/AAO heterostructure can form ion gradient and diffusion under the action of moisture to convert chemical potential into electrical potential,evoking a connaturally sensitive response to ***-powered respiration monitoring device based on the sensor is designed to monitor human movement(sitting,warming up,and running)and sleep status(normal,snoring,and apnea),maintaining excellent stability during cumulative 12-h respiration *** self-powered humidity sensing technology has promising potential for extensive integration into smart electronic and round-the-clock health monitoring devices.

关键词： graphitic carbon nitride moisture-driven energy generation humidity sensor respiration monitoring

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A functional gel polymer electrolyte based on PVDF-HFP/gelatin toward dendrite-free lithium metal batteries

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Nano Research 2024年第4期17卷 2790-2799页

作者： Xiaoyi Hu Kangli Liu Shijie Zhang Guosheng Shao S.Ravi P.Silva Peng Zhang state Center for international cooperation on designer low-carbon and environmental materials(CDLCEM) School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China Zhengzhou materials Genome Institute(ZMGI) ZhongyuanzhiguXingyang 450100China Nanoelectronics Center Advanced Technology InstituteUniversity of SurreyGuildfordGU27XHUK

The leakage of liquid electrolyte and the formation of lithium dendrites pose challenges to safety and stability of lithium metal batteries(LMBs).The appearance of gel polymer electrolyte(GPE)has obviously improved the safety of traditional ***,the limited inhibition of GPE on lithium dendrites is detrimental to the safety of ***,a kind of poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP)/gelatin(GN)GPE with high ionic conductivity,high-temperature resistance,and flame-retardancy,was prepared by electrospinning and soaking *** the electrospinning network of PVDF-HFP,its affinity to liquid electrolytes,makes this GPE more beneficial to ions transport and the formation of ***,the GN with sol–gel properties,enhances the mechanical property(13.5 MPa)of HFP-GN ***,X-ray photoelectron spectroscopy(XPS)and density functional theory(DFT)suggest that the attraction of polar groups of GN to Li+can regulate the distribution of Li+and protect Li ***,the application of HFP-GN GPEs to LMBs with cathodes of LiFePO_(4) and LiCoO_(2) deliver excellent electrochemical performances:after 300 cycles,the LiFePO_(4)/HFP-GN GPE/Li battery keeps a low capacity decay rate of 0.09%at 5 C;after 400 cycles at 2 C,the LiCoO_(2)/HFP-GN GPE/Li cell retains a high capacity retention of 74%.This GPE is demonstrated for the application prospect of safe LMBs.

关键词： poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP) gelatin polar groups lithium metal battery lithium dendrite

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Characteristics and source apportionment of ambient volatile organic compounds and ozone generation sensitivity in urban Jiaozuo,China

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Journal of environmental Sciences 2024年第4期138卷 607-625页

作者： Pengzhao Li Chun Chen Dan Liu Jie Lian Wei Li Chuanyi Fan Liangyu Yan Yue Gao Miao Wang Hang Liu Xiaole Pan Jing Mao state centre for international cooperation on designer low-carbon and environmental materials School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China Henan Key Laboratory of environmental Monitoring Technology Henan Ecological Environment Monitoring and Safety CenterZhengzhou 450046China Jiaozuo Ecological Environment Monitoring Center of Henan Province Jiaozuo 454003China state Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China

In recent years,many cities have taken measures to reduce volatile organic compounds(VOCs),an important precursor of ozone(O_(3)),to alleviate O_(3) pollution in China.116 VOC species were measured by online and offline methods in the urban area of Jiaozuo from May to October in 2021 to analyze the compositional *** sources were analyzed by a positive matrix factorization(PMF)model,and the sensitivity of ozone generation was determined by ozone isopleth plotting research(OZIPR)*** results showed that the average volume concentration of total VOCs was 30.54 ppbv and showed a bimodal feature due to the rush-hour traffic in the morning and at *** most dominant VOC groups were oxygenated VOCs(OVOCs,29.3%)and alkanes(26.7%),and the most abundant VOC species were acetone and ***,based on the maximum incremental reactivity(MIR)method,the major VOC groups in terms of ozone formation potential(OFP)contribution were OVOCs(68.09μg/m^(3),31.5%),aromatics(62.90μg/m^(3),29.1%)and alkene/alkynes(54.90μg/m^(3),25.4%).This indicates that the control of OVOCs,aromatics and alkene/alkynes should take *** sources of VOCs were quantified by PMF,including fixed sources of fossil fuel combustion(27.8%),industrial processes(25.9%),vehicle exhaust(19.7%),natural and secondary formation(13.9%)and solvent usage(12.7%).The empirical kinetic modeling approach(EKMA)curve obtained by OZIPR on O_(3) exceedance days indicated that the O_(3) sensitivity varied in different *** results provide theoretical support for O_(3) pollution prevention and control in Jiaozuo.

关键词： Volatile organic compounds(VOCs) Online and offline measurement Ozone formation potential(OFP) Positive matrix factorization(PMF) Ozone isopleth plotting research(OZIPR) Jiaozuo

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carbon dots-derived three-dimensional-ordered macroporous host with high penetrability and catalytic activity for LSBs under lean electrolyte

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Rare Metals 2024年第6期43卷 2560-2573页

作者： Jiao-Zi Duan Hua-Yu Pei Quan Yang Xue Li Xin Ba Xue Yong Jun-Ling Guo Si-Yu Lu Green Catalysis Center College of ChemistryZhengzhou UniversityZhengzhou 450001China Country state Center for international cooperation On designer low-carbon&environmental materials School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China Hubei Institute of Quality Supervision Inspection Wuhan 430061China Department of Chemistry University of SheffieldSheffeld S37HFUK

The practical energy density of lithium-sulfur batteries(LSBs)is seriously limited by the high electrolyte-to-sulfur ratios(E/S).The E/S can be reduced by employing hosts with easy-to-infiltrate structure that ensures the uniform distribution of a lean electrolyte and high catalytic activity that can suppress"shuttle effect"via accelerating the slow conversion of soluble poly sulfides to insoluble *** the easy-to-infiltrate structures,the three-dimensional-ordered macroporous(3DOM)structure is easier to scale preparation and more suitable for the existing industrial ***,it is difficult to obtain the 3DOM with(1)high penetrability due to the high viscosity of frequently-used organic polymer precursors and(2)high catalytic activity due to the low confinement effect,meaning that uniformly dispersed small-sized catalytic materials are difficult to load on ***,using carbon dots(CDs)with both organic and inorganic properties as a precursor and aggregation limiting agent,a 3DOM host with high penetrability and homodispersed Ni particles of small sizes(Ni-CDs-3DOM)was *** this host:(1)CDs precursor with suitable viscosity can improve the penetrability.(2)CDs can effectively inhibit the agglomeration of Ni particles.(3)Uniformly dispersed small-size Ni particles offer high-efficiency catalytic activity toward sulfur ***,the Ni-CDs-3DOM/sulfur cathode exhibits high sulfur utilization and stable cycling performance even under high sulfur loading(5.5 mg·cm^(-2))and low E/S(6.5μl·mg^(-1)).This work indicates the usefulness of CDs in constructing hosts for LSBs with high energy density.

关键词： Lithium-sulfur batteries carbon dots Catalytic action Easy-to-infiltrate structure Lean electrolyte

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Two-dimensional porous carbon derived from pollen with enlarged interlayer distance enhanced electrocatalytic oxidation of n-valeraldehyde to octane

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Nano Research 2024年第5期17卷 3455-3461页

作者： Meichun Qin Chaolong Liu Shouhen Xu Jianguo Tang Institute of Hybrid materials National Center of International Joint Research for Hybrid Materials TechnologyNational Base of International Sci.and Tech.Cooperation on Hybrid MaterialsCollege of Materials Science and EngineeringQingdao UniversityQingdao266071China Department of Pharmaceutics School of PharmacyQingdao UniversityQingdao266071China

Electrocatalytic n-valeraldehyde oxidation reaction was an inexpensive and eco-friendly method to control n-valeraldehyde contamination and produce high value-added ***,low-cost and readily available electrocatalysts with high current efficiency were urgently ***,two-dimensional porous carbon derived from pollen with enlarged interlayer distance was built by alkali activation method,applying in electrocatalytic n-valeraldehyde oxidation *** enlarged interlayer distance was verified by X-ray diffraction(XRD)and high-angle annular dark-field scanning transmission electron microscope(HAADF-STEM).Electrocatalytic experiments consequences showed activated biomass derived carbon possessed a higher electrocatalytic activity and octane selectivity than unactivated *** tests and in situ infrared experiments demonstrated that enlarged interlayer distance was positively correlated with specific surface area of catalysts,large specific surface area provided abundant absorption sites,facilitated the adsorption for n-valeraldehyde,and further promoted the transformation of n-valeraldehyde to *** work also provides a new avenue for creating high-performance electrocatalysts in terms of lattice engineering.

关键词： biomass derived carbon lattice expansion high specific surface area upgrade of n-valeraldehyde

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Towards Improvement of Photovoltaic Performance of Aqueous Dye-sensitized Solar Cells by Tungsten-doped Mesoporous Nanobeads TiO_2 Working Electrode

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Journal of Wuhan University of Technology(materials Science) 2019年第1期34卷 17-22页

作者： GUO Yanrong ZHANG Xiaoli state Key Laboratory of Silicate materials for Architecture Wuhan University of Technology state centre for international cooperation on designer low-carbon & environmental materials and School of Materials Science and Engineering Zhengzhou University

Tungsten doped(W-doped) TiO_2 mesoporous nanobeads, possessing high surface area and superior scattering effect, were used for photoanode preparation. The W-doping would induce a positive shift of the TiO_2 conduction band, and enhance the driving force for electron injection and collection efficiencies. The electrochemical impedance spectra indicated a retarded charge recombination and increased electron diffusion length after W-doping. By fine-tuning the W-doping concentration to 0.25%, aqueous DSCs produced a significant improved the open circuit voltage of 712 mV and a short circuit current of 7.05 mA·cm^(-2), leading to an overall increased power conversion efficiency of 3.40% at 1 000 W·m^(-2) simulated irradiation, which is roughly 25% enhancement compared to that without W-doping photoanode.

关键词： tungsten-doping dye-sensitized solar cells aqueous electrolyte conduction band

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Preventing inhomogeneous elemental distribution and phase segregation in mixed Pb-Sn inorganic perovskites via incorporating PbS quantum dots

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Journal of Energy Chemistry 2022年第2期31卷 179-185页

作者： Tao Zhang Huaxia Ban Qiang Sun Han Pan Haixuan Yu Zhiguo Zhang Xiaoli Zhang Yan Shen Mingkui Wang Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074HubeiChina state centre for international cooperation on designer low-carbon&environmental materials School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001HenanChina

Inhomogeneous Pb/Sn elemental distribution and the resulted phase segregation in mixed Pb-Sn halide perovskites would result in energy disorder(band structure and phase distribution disorder),which greatly limits their photovoltaic ***,Pb S quantum dot has been synthesized and demonstrated as seeds for modulation crystallization dynamics of the mixed Pb-Sn inorganic perovskites,allowing an enhanced film quality and significantly suppressing phase *** this additive power conversion efficiency of 8%and 6%is obtained under irradiation of full sunlight in planar and mesoporous structured solar cells in combination with CsPb_(0.5) Sn_(0.5)I_(2)Br inorganic perovskite,*** finding reveals exploring the actual Pb/Sn atoms location in perovskite structure and its influence on developing efficient and stable low-bandgap perovskite solar cells.

关键词： Inorganic perovskite Phase segregation Optoelectronic material Photovoltaic device

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Enhanced efficiency and stability of perovskite solar cells by 2D perovskite vapor-assisted interface optimization

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Journal of Energy Chemistry 2020年第6期29卷 103-109,I0005页

作者： Minghui Chen Pengwei Li Chao Liang Hao Gu Weishuang Tong Shiping Cheng Weili Li Ganqing Zhao Guosheng Shao School of Chemistry and Environment Engineering Pingdingshan UniversityPingdingshan 467000HenanChina state centre for international cooperation on designer low-carbon and environmental Material(SCICDLCEM) School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001HenanChina

Organic–inorganic perovskites solar cells(PSCs)have attracted great attention due to their rapid progress in power conversion efficiency(PCE).However,there is still an enormous challenge to achieve both high efficiency and stability devices as the decomposition of perovskite materials under humid and light ***,we demonstrate that high efficiency and stability of PSCs can be obtained by the reaction of three-dimensional(3D)perovskite with 1,4-butanediamine iodide(BEAI2)*** incorporation of BEAI2 intensively promotes the crystallization of perovskite film with large grain size(~500 nm).Further characterization reveals that the post-treatment perovskite film delivered low interface trap density with long carrier lifetime(>200 ns),long carrier diffusion length(>600 nm)and large carrier mobility(>1.5 cm^2 V-1S-1).Solar cells employing such post-treatment films demonstrated 19.58%PCE without ***,the post-treatment devices can retain over 90%original efficiencies stored under ambient atmospheric conditions and exhibit better stability under 85℃and continuous illumination as a two-dimensional(2D)perovskite thin layer is formed on the surface/or at the grain boundaries of 3D *** study offers an effective way to obtain PSCs with high efficiency and stability.

关键词： Perovskite solar cells 2D/3D perovskite Post-treatment Carrier diffusion length Mobility

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Confining sulfur in intact freestanding scaffold of yolk-shell nanofibers with high sulfur content for lithium-sulfur batteries

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Journal of Energy Chemistry 2020年第12期29卷 378-387页

作者： Xilai Zhang Peng Zhang Shijie Zhang Yongshang Zhang Ruohan Hou Kangli Liu Fujun Miao Guosheng Shao School of materials Science and Engineering Zhengzhou UniversityZhengzhou 450001HenanChina state centre for international cooperation on designer low-carbon&environmental materials(CDLCEM) Zhengzhou UniversityZhengzhou 450001HenanChina Zhengzhou materials Genome Institute Xingyang 40100HenanChina

Nanostructure design holds great potential in fabricating sulfur electrodes that host a high sulfur loading and still attain high electrochemical utilization for the developing of high-energy-density lithium-sulfur(Li-S) batteries. In this contribution, we introduce the yolk-shell structure into a freestanding carbon nanofibers film and construct a complete hollow yolk-shell Ti O2/carbon nanofibers@void@TiN@carbon(TiO2-CNFs@void@Ti N@C) composite. With inherent double conductive network and strong adsorption capability for polysulfides, the Ti O2-CNFs@void@Ti N@C composite can not only provide sufficient electrical contact for the insulating sulfur, but also effectively entrap polysulfides for prolonged cycle life. As a result, an excellent capacity retention ratio of 60.9% after 1000 cycles at 1 C as well as a high capacity of688.5 mA h g^(-1) at 5 C rate is accomplished with the cells employing Ti O2-CNFs@void@TiN @C as a cathode substrate for sulfur. Moreover, the TiO2-CNFs@void@Ti N@C composite, with a high S mass loading of9.5 mg cm^(-2), delivers a superb areal capacity of 8.2 mAh cm^(-2).

关键词： TiO2 TiN Electrospinning Lithium-sulfur batteries carbon nanofibers Yolk-shell structure

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