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Recent progress of MgO-based materials in CO_(2) adsorption and conversion:Modification methods,reaction condition,and CO_(2) hydrogenation

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Chinese Chemical Letters 2024年第5期35卷 57-65页

作者： Zixuan Zhu Xianjin Shi Yongfang Rao Yu Huang key laboratory of Aerosol Chemistry&Physics State Key Laboratory of Loess and Quaternary Geology(SKLLQG)Institute of Earth EnvironmentChinese Academy of Sciences(CAS)Xi’an 710061China Center for Excellence in Quaternary Science and Global Change Chinese Academy of SciencesXi’an 710061China University of Chinese Academy of Sciences Beijing 100049China Department of Environmental Science and Engineering Xi’an Jiaotong UniversityXi’an 710049China

Integrated CO_(2) capture and conversion of(ICCC)is one of the most effective solutions to reduce anthropogenic CO_(2) emissions,which has attracted extensive public *** functional materials(DFMs),including adsorbent and catalyst,are the key components to achieve *** oxide(MgO)is an ideal adsorbent for ICCC,since it is characterized by high theoretical adsorption capacity,low cost,low energy consumption and extensive *** can also be used as DFMs in combination with the Ni *** not only can act as an adsorbent in DFMs but also enhance the catalytic performance of *** review summarizes the advantages and modification methods of MgO as adsorbent and the influence of its adsorption conditions on the adsorption ***,the important role of MgO in facilitating the catalytic conversion of CO_(2) is *** research focuses are proposed for the development of MgO based DFMs with high adsorption capacity,high stability,conversion,and selectivity as well as low cost and energy consumption.

关键词： CO_(2) ICCC MgO Adsorption Conversion

Primary and Secondary Calcite in Chinese loess Distinguished by Crystallinity and Implications for Illuviation Depth and East Asian Summer Monsoon Intensity

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Journal of Earth Science 2024年

作者： Yan Zhao Kangjun Huang Yuanqiang Guo Pan Zhang Yawen Lu Long Ma state key laboratory of Continental Dynamics， Shaanxi key laboratory of Early Life and Environment， Department of geology， Northwest University

The crystallinity has the potential to distinguish the primary and secondary calcite in Chinese loess， which then provides insights into illuviation depth and variations of the East Asian summer monsoon. However， this aspect has been rarely investigated. In this study， we defined the crystallinity of calcite as the Height/Area (H/A) ratio of the diffracted peak at crystal face (1 0 4). The H/A ratio inversely correlates with the average width of the diffracted peak， where a higher H/A ratio indicates higher crystallinity of calcite. Through the mixing and synthetic experiments， we found that the H/A ratio is minimally affected by factors such as calcite content， deposition temperature or rate but significantly influenced by the ionic impurity and the mixing proportion of different calcites. Subsequently， we examined desert samples of loess sources and loess carbonate nodules. Desert samples predominantly consist of primary calcite which inherits characteristics from cryptocrystalline limestone with high levels of ionic impurities resulting in low H/A ratio of 4.30 ± 0.51. In contrast， loess carbonate nodules contain abundant secondary calcite precipitated within soil interstices with low levels of ionic impurities leading to a significantly higher H/A ratio of 7.76 ± 0.82. Consequently， higher H/A ratios during interglacial periods compared to glacial periods are attributed to variations in relative proportions between primary and secondary calcite in loess sequences. The thickness， between the glacial-interglacial boundary and the depth where the H/A ratio starts to increase from the bottom to the top in the loess layer， can be used to indicate the illuviation depth of upper-soil carbonates and the intensity of the East Asian summer monsoon. This proxy can be further applied in long-term loess sequences to uncover the summer monsoon evolution.

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The source of lithium in Lakkor Co Salt Lake on Qinghai-Tibet Plateau,China:evidence from hydrochemical characteristics and boron isotope

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Acta Geochimica 2024年第5期43卷 933-946页

作者： Zheng Yan Li Bin Kai Li Mao-Yong He Xue Qin Wen Jiang Di Zhou Department of Geoscience and Technology Taiyuan University of TechnologyYingzexi StreetTaiyuan 030024Shanxi ProvinceChina state key laboratory of loess and Quaternary geology Institute of Earth EnvironmentChinese Academy of SciencesXi’an 710061China Qinghai Provincial key laboratory of geology and Environment of Salt Lakes Qinghai Institute of Salt LakesChinese Academy of SciencesXining 810008QinghaiChina School of Earth Science and Resources Chang’an UniversityXi’an 710000ShaanxiChina Qinghai Normal University Academy of Plateau Science and SustainabilityXining 810016China

The availability of lithium resources is of great significance for the development of modern technologies,as well as for civil and military *** Qinghai-Tibet Plateau is a region known for its abundance of lithium-rich salt ***,the specific origin of lithium in these lakes is still unknown,which hinders the advancement of the lithium resource business in this *** research this issue,this study involved the collection of 20 samples from Lakkor Co Salt Lake on Qinghai-Tibet Plateau,encompassing samples of surface brine,cold springs,fresh lakes,and recharge *** composition of anions and cations in these samples was ***,the analysis extensivelyutilizedthePiperthree-linediagram,Gibbs model,and ion proportion *** findings of this study indicate that as the moves from the recharge water system to salt lake,there is a transition in water type from strong carbonate to moderate carbonate and weak carbonate,as well as Na *** research based on a similar source of both lithium and boron,utilized ion correlation analysis and boron isotope study in the Lakkor Co area,and analyzed the source and transporting process of *** main origin of lithium in Lakkor Co is the dissolution of lithiumrich rocks,recharge water systems,and deep hydrothermal *** findings are highly significant in enhancing the foundational data of lithium-rich brine resources in the Qinghai-Tibet Plateau and are beneficial for assessing the future development of such deposits.

关键词： Lithium Hydrochemical Li-rich Salt lake Boron isotope

Promoted surface charge density from interlayer Zn–N_(4) configuration in carbon nitride for enhanced CO_(2) photoreduction

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Nano Research 2024年第4期17卷 2400-2409页

作者： Xianjin Shi Yu Huang Gangqiang Zhu Wei Peng Meijuan Chen state key laboratory of loess and Quaternary geology(SKLLQG) Key Laboratory of Aerosol Chemistry and PhysicsInstitute of Earth EnvironmentChinese Academy of SciencesXi’an 710061China Center of Excellence in Quaternary Science and Global Change Chinese Academy of SciencesXi’an 710061China University of Chinese Academy of Sciences Beijing 100049China School of Physics and Information Technology Shaanxi Normal UniversityXi’an 710062China School of Human Settlements and Civil Engineering Xi’an Jiaotong UniversityXi’an 710049China

The solar-driven reduction of CO_(2) into valuable products is a promising method to alleviate global environmental problems and energy ***,the low surface charge density limits the photocatalytic conversion performance of CO_(2).Herein,a polymeric carbon nitride(PCN)photocatalyst with Zn single atoms(Zn1/CN)was designed and synthesized for CO_(2) *** results of the CO_(2) photoreduction studies show that the CO and CH_(4) yields of Zn1/CN increased fivefold,reaching 76.9 and 22.9μmol/(g·h),respectively,in contrast to the unmodified ***+plasma-etched X-ray photoelectron spectroscopy and synchrotron radiation-based X-ray absorption fine structure results reveal that Zn single atom is mainly present in the interlayer space of PCN in the Zn–N_(4) *** characterizations indicate that the interlayer Zn–N_(4) configuration can amplify light absorption and establish an interlayer charge transfer ***-assisted Kelvin probe force microscopy confirms that more photogenerated electrons are delivered to the catalyst surface through interlayer Zn–N_(4) configuration,which increases its surface charge ***,in-situ infrared spectroscopy combined with density functional theory calculation reveals that promoted surface charge density accelerates key intermediates(*COOH)conversion,thus achieving efficient CO_(2) *** work elucidates the role of internal single atoms in catalytic surface reactions,which provides important implications for the design of single-atom catalysts.

关键词： single-atom catalysts photocatalytic CO_(2)reduction interlayer modification charge transfer dynamics surface charge density

Interpreting Larix principis-rupprechtii radial growth in northern China based on the Vaganov-Shashkin model

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Journal of Forestry Research 2024年第3期35卷 99-110页

作者： Jiachuan Wang Shuheng Li Qiang Li Yili Guo Yijie Han Qi Liu Yiqi Zhao College of Urban and Environmental Sciences Northwest UniversityXi'an 710127People's Republic of China Institute of Global Environmental Change Xi'an Jiaotong UniversityXi'an 710049People's Republic of China Shaanxi key laboratory of Earth Surface System and Environmental Carrying Capacity Northwest UniversityXi'an 710127People's Republic of China state key laboratory of loess and Quaternary geology Institute of Earth EnvironmentChinese Academy of SciencesXi'an 710061People's Republic of China

Changes in annual radial growth is an important indication of climate change. Dendroclimatology studies in northern China have focused on linear statistical analysis,but lacking studies based on the process of ring formation to clarify the radial growth of trees. Tree-ring width standard chronology(STD) was established using samples of Larix principis-rupprechtii collected at 2303 m altitude on Luya Mountain. Using the Vaganov-Shashkin(VS) model to simulate growth and development, the internal physiological mechanism of radial growth is identified. It was concluded that:(1) the growing season of L. principis-rupprechtii was May to September;(2) soil moisture was a significant factor in the early and late growing seasons, and temperature was the dominant factor in its main growth period;and(3) formation of narrow ring widths was closely related to drought stress, the development of wide ring widths will be restricted by increasing future temperatures. The VS model is applicable for radial growth simulation of subalpine coniferous forests and for guiding the cultivation of local tree species in the future.

关键词： Vaganov-Shashkin model Larix principis-rupprechti Tree-ring width Annual growth

中新世气候适宜期构造运动加速全球海洋碳循环

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Science Bulletin 2024年第6期69卷 823-832页

作者：刘丰豪杜金龙黄恩清马文涛马小林 Lucas J.Lourens 田军 state key laboratory of Marine geology Tongji UniversityShanghai 200092China state key laboratory of Satellite Ocean Environment Dynamics Second Institute of OceanographyMinistry of Natural ResourcesHangzhou 310012China state key laboratory of loess and Quaternary geology Institute of Earth EnvironmentChinese Academy of SciencesXi’an 710061China Department of Earth Sciences Faculty of GeosciencesUtrecht UniversityUtrecht CB 3584Netherlands

Global warming during the Miocene Climate Optimum(MCO,~17-14 million years ago)is associated with massive carbon emissions sourced from the flood basalt volcanism and ocean crustal ***,the perturbation of tectonic carbon degassing on the interaction between climate change and carbon cycle remains ***,through time-evolutive phase analysis of new and published high-resolution benthic foraminiferal oxygen(δ^(18)O)and carbon(δ^(13)C)isotope records from the global ocean,we find that variations in the marine carbon cycle lead the climate-cryosphere system(δ^(13)Clead-δ^(18)O)on 405,000-year eccentricity timescales during the *** is in contrast to the previously reported climate-lead-carbon(δ^(18)O-lead-δ^(13)C)scenario during most of the Oligo-Miocene(~34-6 million years ago).Further sensitivity analysis and model simulations suggest that the elevated atmospheric CO_(2) concentrations and the resulting greenhouse effect strengthened the low-latitude hydrological cycle during the MCO,accelerating the response of marine carbon cycle to eccentricity *** climate processes played a more important role in regulating carbon-cycle variations when Earth's climate was in a warm regime,as opposed to the dominant influence of polar ice-sheet dynamics during the PlioPleistocene(after~6 million years ago).

关键词： Global warming Eccentricity cycle Carbon cycle Low-latitude hydrological cycle

AHFO-based soil water content sensing technology considering soil-sensor thermal contact resistance

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第7期16卷 2715-2731页

作者： Mengya Sun Peng Wu Bin Shi Jin Liu Jie Liu Juncheng Yao Yipin Lu Yunqiang Wang Xiaoyan Li School of Earth Sciences and Engineering Hohai UniversityNanjing210098China School of Earth Sciences and Engineering Nanjing UniversityNanjing210023China Department of Architecture and Civil Engineering City University of Hong Kong999077Hong KongChina state key laboratory of loess and Quaternary geology Institute of Earth EnvironmentChinese Academy of SciencesXi’an710061China

The actively heated fiber-optic(AHFO)technology has become emerged as a research focus due to its advantages of distributed,real-time measurement and good *** attributes have led to the gradual application of AHFO technology to the water content measurement of in situ ***,all existing in situ applications of AHFO technology fail to consider the effect of soilesensor contact quality on water content measurements,limiting potential for the wider application of AHFO *** address this issue,the authors propose a method for determining the soilesensor thermal contact resistance based on the principle of an infinite cylindrical heat *** is then used to establish an AHFO water content measurement technology that considers the thermal contact *** reliability and validity of the new measurement technology are explored through a laboratory test and a field case study,and the spatial-temporal evolution of the soil water content in the case is *** results demonstrate that method for determining the soilesensor thermal contact resistance is highly effective and applicable to all types of *** method requires only the moisture content,dry density,and thermal response of the in situ soil to be *** the field case,the measurement error of soil water content between the AHFO method,which takes into account the thermal contact resistance,and the neutron scattering method is only *** water content of in situ soil exhibits a seasonal variation,with an increase in spring and autumn and a decrease in summer and ***,the response of shallow soils to precipitation and evaporation is *** findings contribute to the enhancement of the accuracy of the AHFO technology in the measurement of the water content of in situ soils,thereby facilitating the dissemination and utilization of this technology.

关键词： Soil water content Actively heated fiber-optic(AHFO) technology Soilesensor thermal contact resistance Reliability In situ application

Development and application of photocatalytic coating for roadside NO_(x) mitigation in Hong Kong

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Chinese Chemical Letters 2024年第3期35卷 153-157页

作者： Xinwei Li Pengge Wang Shuwen Han Yu Huang Wingkei Ho Steven Sai Hang Ho Shun-cheng Lee Meng Wang Department of Civil and Environmental Engineering The Hong Kong Polytechnic UniversityHong KongChina state key laboratory of loess and Quaternary geology(SKLLQG)and key laboratory of Aerosol Chemistry and Physics Institute of Earth EnvironmentChinese Academy of SciencesXi'an 710061China Department of Science and Environmental Studies The Education University of Hong KongHong KongChina Division of Atmospheric Sciences Desert Research InstituteRenoNV 89512United States

A facile chemical method for the development of photocatalytic coating products was proposed based on practical application perspective for the Hong Kong roadside nitrogen oxides(NO_(x))***_(2)-based photocatalytic coating PC-C film with crystallized size of around 5–6 nm was synthesized with the peptization of H_(2)O_(2).The PC-C coating possesses a super-hydrophilicity surface and is proven to have a NO_(x)degradation rate of 46.8%with an optimum pH level of *** addition,the PC-C coating presents a promising photocatalytic NO_(x)degradation compared with other commercially available coating products and P25 when applied on two building materials of poly-methyl methacrylate(PMMA)and concrete surface.A weather resistance simulation and a 180-day on-site field trial were carried out the attenuation effects of photocatalytic coating applied in outdoor *** on epidemiological estimation and field investigation,hospital admissions for respiratory diseases(HARD)and mortality cases(MC)could be reduced with the application of PC-C coating along the street *** work demonstrates the feasibility of air pollution control measures for the local roadside NO_(x)using photocatalytic technology,offering promising health benefits with environmental remediation.

关键词： Photocatalysis Coating NO_(x) mitigation Hong Kong Roadside

Plant type effect overweighs seasonal variation in n-alkanoic acid biomarker on regional loess Plateau of China

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Science China Earth Sciences 2024年第8期67卷 2547-2562页

作者： Jinzhao LIU S.Nemiah LADD Jiaju ZHAO Dongna YAN Ding HE Yunning CAO Zhisheng AN state key laboratory of loess and Quaternary geology Institute of Earth EnvironmentChinese Academy of SciencesXi’an 710061China CAS Center for Excellence in Quaternary Science and Global Change Xi’an 710061China Department of Environmental Sciences University of BaselBasel 4056Switzerland Department of Ocean Science and Center for Ocean Research in Hong Kong and Macao The Hong Kong University of Science and TechnologyHong Kong 999077China

The effect of plant type on n-alkane biomarker has been widely studied,but the influence of plant type on n-alkanoic acids(n-FAs)has received less *** the effect of the distribution of n-FAs and their hydrogen isotope composition(δ^(2)H_(FA))is critical for interpreting sedimentaryδ^(2)H_(FA)values as proxies of hydroclimate and/or vegetation *** this study,we systematically investigated the distribution ofn-FAs andδ^(2)H_(FA)values across seasons on the Chinese loess Plateau(CLP).Our results showed that there were no significant seasonal differences in n-FAs distribution andδ^(2)H_(FA)values,but there were significant differences inδ^(2)H_(FA)values across plant ***δ^(2)H_(FA)values ranged from-185‰to-125‰in dicots(-161‰±28‰),and from-215‰to-170‰in monocots(-196‰±22‰)on the *** fractionation betweenδ^(2)H_(FA)values and precipitationδ^(2)H(ε_(FA-P))was also^(2)H-enriched in dicots relative to *** the regional scale of the CLP,δ^(2)H_(FA)values were not correlated withδ^(2)H values of ***,δ^(2)H_(FA)values from the CLP were similar to expectations from a global comparison,both in terms of their mean values and high variability among plants growing in sites with similarδ^(2)H values of *** some of this variability inεFA-Pis due to the effect of plant type,a careful assessment of the likely sources of waxes in terrestrial sediments is critical when usingδ^(2)H_(FA)values for paleohydroclimate reconstruction.

关键词： n-Alkanoic acid Hydrogen isotope Plant type Paleohydroclimate Chinese loess Plateau