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Comparison of extraction abilities of deep eutectic solvents and aqueous acid solutions for extraction of rare earths and transition metals

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Journal of Rare Earths 2024年第6期42卷 1157-1164,I0006页

作者： Svetlana Drogobuzhskaya Margarita Frolova Andrey Shishov Nikita Tsvetov Tananaev Institute of Chemistry-Subdivision of the Federal Research Centre《Kola Science Centre of the Russian Academy of Sciences》 18420926a AcademgorodokApatityRussia Murmansk state Technical university 183010Sportivnaja str.13MurmanskRussia Department of Analytical Chemistry Institute of ChemistrySaint Petersburg State UniversitySpbSU.1990347/9 Universitetskaya embSt.Petersburg Russia

In recent years,deep eutectic solvents have attracted increasing interest as effective extractants for the separation of both organic substances and metals from various ***-based deep eutectic solvents are most often used as extractants for the extraction of *** this work,for the first time,the extraction efficiency of transition metals and rare earth elements(Y,Zr,Nb,La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Hf and Ta)from mining tailings and Na,K,Ca,Mg,Cu,Fe,Mn,Pb,Ba,Ni and Sr from biodiesel samples using acidic deep eutectic solvents and saturated aqueous solutions of the same acids(malonic,malic,tartaric and citric)is *** this,deep eutectic solvents based on acids and their aqueous saturated solutions were prepared and *** prepared mixtures were analyzed by IR spectroscopy to confirm the formation of eutectic *** such as the density and viscosity of the resulting mixtures were also investigated,as this can be of key importance for the efficiency of metal *** extraction of rare earth metals from mining tailings took a long time(up to several days),while the extraction of metals from fuel took no more than 30 *** emission spectral methods were used as an analysis *** is shown that the extraction efficiency with aqueous solutions is better than that with eutectic solvents,which casts doubt on the need for deep eutectic solvents use in this area.

关键词： Deepeutectic solvent Metal separation Elemental analysis Rare earth metals Biodiesel

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Fluidization stability and periodic fluctuations in gas–solid separation fluidized bed using Geldart A dense medium

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Particuology 2024年第7期90卷 522-534页

作者： Weijin Liu Dan Wang Liang Dong Enhui Zhou Tatiana Aleksandrova Chenyang Zhou Chenlong Duan Key Laboratory of Coal Processing and Efficient Utilization(China university of Mining&Technology) Ministry of EducationXuzhou 221116China School of Chemical Engineering&Technology China University of Mining&TechnologyXuzhou 221116China Department of Chemical and Biochemical Engineering The University of Western OntarioLondonOntario N6A 5B9Canada Mineral Processing Department Saint Petersburg Mining UniversitySt.Petersburg 199106Russia

Gas–solid separation fluidized bed is a typical method for coal separation without water *** A particles is also considered as the ideal dense medium to strengthen separation *** stability reflects the bed pressure fluctuations and the distribution of bubble and emulsion phases,affecting the separation *** the main frequency of pressure fluctuations can directly reflect the degree of pressure ***,the detailed fluidization stability is analyzed combined the method of standard deviation of pressure fluctuations,power spectral density,etc.,for Geldart A *** results showed that maintaining an appropriate gas velocity resulted in an average bed pressure of around 2000 *** main frequency is mainly concentrated around 1–1.5 ***,a prediction model of the main frequency of pressure fluctuations is established,and the error can be controlled within±*** investigation further proved the stable fluidization of Geldart A particles and provides a method for predicting the main frequency of pressure fluctuations in the gas–solid separation fluidized bed.

关键词： Geldart A dense medium Fluidization stability Periodic fluctuations Pressure fluctuations frequency Gas–solid separation fluidized bed

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Isochrone Fitting of Galactic Globular Clusters—Ⅵ.High-latitude Clusters NGC 5024 (M53),NGC 5053,NGC 5272 (M3),NGC 5466,and NGC7099 (M30)

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Research in Astronomy and Astrophysics 2024年第6期24卷 170-190页

作者： G.A.Gontcharov S.S.Savchenko A.A.Marchuk C.J.Bonatto O.S.Ryutina M.Yu.Khovritchev V.B.Il'in A.V.Mosenkov D.M.Poliakov A.A.Smirnov Central(Pulkovo)Astronomical Observatory Russian Academy of SciencesPulkovskoye chaussee 65/1St.Petersburg 196140Russia Saint petersburg state university Universitetskij pr.28St.Petersburg 198504Russia Special Astrophysical Observatory Russian Academy of Sciences369167 Nizhnij ArkhyzRussia Departamento de Astronomia Instituto de FísicaUFRGSAv.Bento Gonçalves9500Porto AlegreRSBrazil Saint petersburg university of Aerospace Instrumentation Bol.Morskaya ul.67ASt.Petersburg 190000Russia Department of Physics and Astronomy Brigham Young UniversityN283 ESCProvoUT 84602USA

We fit various color–magnitude diagrams(CMDs) of the high-latitude Galactic globular clusters NGC 5024(M53),NGC 5053,NGC 5272(M3),NGC 5466,and NGC 7099(M30) by isochrones from the Dartmouth stellar Evolution Database and Bag of stellar Tracks and Isochrones for α–enrichment [α/Fe] = +*** the CMDs,we use data sets from Hubble Space Telescope,Gaia,and other sources utilizing,at least,25 photometric filters for each *** obtain the following characteristics with their statistical uncertainties for NGC 5024,NGC 5053,NGC 5272,NGC 5466,and NGC 7099,respectively:metallicities [Fe/H] =-1.93 ± 0.02,-2.08 ± 0.03,-1.60 ± 0.02,-1.95 ± 0.02,and-2.07 ± 0.04 dex with their systematic uncertainty 0.1 dex;ages 13.00 ± 0.11,12.70 ± 0.11,11.63 ± 0.07,12.15 ± 0.11,and 12.80 ± 0.17 Gyr with their systematic uncertainty 0.8 Gyr;distances(systematic uncertainty added) 18.22 ± 0.06 ± 0.60,16.99 ± 0.06 ± 0.56,10.08 ± 0.04 ± 0.33,15.59 ±0.03 ± 0.51,and 8.29 ± 0.03 ± 0.27 kpc;reddenings E(B-V) = 0.023 ± 0.004,0.017 ± 0.004,0.023 ± 0.004,0.023 ± 0.003,and 0.045 ± 0.002 mag with their systematic uncertainty 0.01 mag;extinctions AV= 0.08 ± 0.01,0.06 ± 0.01,0.08 ± 0.01,0.08 ± 0.01,and 0.16 ± 0.01 mag with their systematic uncertainty 0.03 mag,which suggest the total Galactic extinction AV= 0.08 across the whole Galactic dust to extragalactic objects at the North Galactic *** horizontal branch morphology difference of these clusters is explained by their different metallicity,age,mass-loss efficiency,and loss of low-mass members in the evolution of the core-collapse cluster NGC 7099 and loose clusters NGC 5053 and NGC 5466.

关键词： (stars:)Hertzsprung Russell and C-M diagrams (ISM:)dust extinction (Galaxy:)globular clusters:general (Galaxy:)globular clusters:individual(NGC 5024,NGC 5053,NGC 5272,NGC 5466,NGC7099)

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Liver-brain axis with alcohol:Role of fibroblast growth factor 21(FGF21)

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Genes & Diseases 2024年第2期11卷 509-511页

作者： Ke Zhang Elena Blokhina Evgeny Krupitsky Marina Vetrova Ti-Fei Yuan Hua Wang Shanghai Key Laboratory of Psychotic Disorders Brain Health InstituteNational Center for Mental DisordersShanghai Mental Health CenterShanghai Jiao Tong University School of MedicineShanghai 200030China Pavlov university Valdman Institute of PharmacologySt.Petersburg 197022Russia Bekhterev National Medical Research Center for Psychiatry and Neurology St.Petersburg 192019Russia Co-innovation Center of Neuroregeneration Nantong UniversityNantongJiangsu 226007China Department of Oncology The First Affiliated Hospital of Anhui Medical UniversityHefeiAnhui 230032China

Fibroblast growth factor21(FGF21)is a hormone that can balance nutrient fluctuations,control metabolic processes,and maintain energy *** FGF21 is produced by a variety of cell types,including hepatocytes,adipocytes,bone cells,myocardial cells,and pancreas cells,and act on various effector tissues such as brain,adipose tissue,liver,heart,and skeletal muscle.1 The target that FGF21 interacts with is the cell-surface receptor composed of FGF receptors in complex with the single-pass transmembrane proteinβ-*** receptors are abundantly expressed,both in peripheral tissues and some regions of the CNS,such as the hypothalamus and amygdala and the locus coeruleus(LC).2 Physiologically,FGF21 can be induced by various metabolic stresses,including hunger,protein deficiency,monosaccharides,and alcohol,by acting onβ-Klotho receptor in corresponding tissues,ultimately exerting regulatory effects(Fig.1)

关键词： Klotho homeostasis alcohol

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A Dynamic Network Game of the Fintech Industry

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Journal of the Operations Research Society of China 2024年第1期12卷 5-33页

作者： David W.K.Yeung Leon A.Petrosyan Ying-Xuan Zhang SRS Consortium for Advanced study in Cooperative Dynamic Games Shue Yan UniversityHong KongChina Center of Game Theory St Petersburg State UniversitySaint PetersburgRussia Department of Finance Asia UniversityTaichung CityTaiwanChina Faculty of Applied Mathematics-Control Processes and Center of Game Theory St Petersburg StateUniversitySaint PetersburgRussia

Economies of scale,economies of scope,and technology spillover are decisive eco-nomic elements that are crucial to the development in the Fintech *** externalities are often realized through network *** this paper,we presenta dynamic network ofﬁnancialﬁrms which exhibits these decisive *** game equilibria are characterized.A Pareto efﬁcient solution involving col-laboration of allﬁrms is *** obtain a fair-share distribution of cooperativegains,the Shapley value is adopted as the sharing *** distributionmechanisms which guarantee the fulﬁlment of the Shapley value distribution in eachstage of the cooperation duration are derived.

关键词： Network game Network equilibria Shapley value Pareto efﬁcientcooperation

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A new aberrant species of the genus Sphaerostoma(Trematoda: Opecoelidae) from the Amur River basin

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Zoological Systematics 2024年第4期 352-360页

作者： Sergey G.Sokolov Sergei V.Shchenkov Evgeniy V.Frolov Sergei A.Vlasenkov A.N.Severtsov Institute of Ecology and Evolution RAS Department of Invertebrate Zoology St.Petersburg State University Sakhalin Branch of Russian Federal Research Institute of Fisheries and Oceanography

A new freshwater opecoelid species, Sphaerostoma tamarae sp. nov., is described from Rhynchocypris percnura mantschurica caught in the Syumnyur River(Amur River basin,Russia). This parasite species differs from all other congeners in the distribution of the vitelline follicles(restricted to the hindbody) and the morphology of the ventral sucker(strongly protuberant). Molecular phylogenetic analysis based on 28S rRNA gene sequences and the morphological analysis allow to tentatively assign the new species to the genus Sphaerostoma,without closing the question regarding the true genus affiliation of this species. In addition, the authors provide an argument for renaming the Plagioporinae to the Sphaerostomatinae.

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Association of ABCB1 gene polymorphisms rs1128503, rs2032582, rs4148738 with anemia in patients receiving dabigatran after total knee arthroplasty

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Chinese Journal of Traumatology 2024年第1期27卷 27-33页

作者： Alina Kasimova Dmitry Labutin Anton Gvozdetsky Svetlana Bozhkova Division of Wound Infection Prevention and Treatment Vreden National Medical Research Center of Traumatology and OrthopaedicsSt.PetersburgRussian Federation Department of Clinical Pharmacology and Evidence-based Medicine Pavlov First Saint Petersburg State Medical UniversitySt.PetersburgRussian Federation Department of Psychiatry and Addictology North-Western State Medical University named after I.I.MechnikovSt.PetersburgRussian Federation

Purpose:Dabigatran is usually prescribed in recommended doses without monitoring of the blood coagulation for the prevention of venous thromboembolism after joint ***1 is a key gene in the metabolism of dabigatran *** allele variants are likely to play a pivotal role in the occurrence of hemorrhagic ***:The prospective study included 127 patients with primary knee osteoarthritis undergoing total knee *** with anemia and coagulation disorders,elevated transaminase and creatinine levels as well as already receiving anticoagulant and antiplatelet therapy were excluded from the *** association of ABCB1 gene polymorphisms rs1128503,rs2032582,rs4148738 with anemia as the outcome of dabigatran therapy was evaluated by single-nucleotide polymorphism analysis with a realtime polymerase chain reaction assay and laboratory blood *** beta regression model was used to predict the effect of polymorphisms on the studied laboratory *** probability of the type 1 error(p)was less than 0.05 was considered statistically *** was used to correct for significance levels in multiple hypothesis *** calculations were performed using Rprogramming language ***:For all polymorphisms there was no association with the level of platelets,protein,creatinine,alanine transaminase,prothrombin,international normalized ratio,activated partial thromboplastin time and *** of rs1128503(TT)had a significant decrease of hematocrit(p=0.001),red blood count and hemoglobin(p=0.015)while receiving dabigatran therapy during the postoperative period compared to the CC,*** of rs2032582(TT)had a significant decrease of hematocrit(p=0.001),red blood count and hemoglobin(p=0.006)while receiving dabigatran therapy during the postoperative period compared to the GG,GT *** differences were not observed in carriers of ***:It might be necessary to r

关键词： Thromboprophylaxis P-glycoprotein Dabigatran Anemia SNPs

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Legumain-triggered aggregable gold nanoparticles for enhanced intratumoral retention

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Chinese Chemical Letters 2024年第7期35卷 388-393页

作者： Zhi Li Wenpei Li Shaoping Jiang Chuan Hu Yuanyu Huang Maxim Shevtsov Huile Gao Shaobo Ruan Advanced Research Institute of Multidisciplinary Sciences School of Life ScienceBeijing Institute of TechnologyBeijing 100081China Key Laboratory of Drug Targeting and Drug Delivery System West China School of PharmacySichuan UniversityChengdu 610041China Institute of Cytology of Russian Academy of Sciences(RAS) St.Petersburg 194064Russia

Insufficient intratumoral retention of nanomedicines remains the major challenge for broad implementation in clinical ***,we proposed a legumain-triggered aggregable gold nanoparticle(GNP)delivery platform(GNPs-A&C).GNPs-A&C could form intratumoral or intracellular aggregates in response to the overexpressed *** aggregates with size increase not only could reduce back-flow from interstitial space to peripheral bloodstream but also could restrict the cellular exocytosis,leading to enhanced intratumoral *** vitro studies demonstrated that GNPs-A&C possessed an excellent legumain responsiveness and the increased size was closely relevant with legumain *** vivo studies demonstrated GNPs-A&C possessed slower clearance rate and much higher intratumoral retention within legumain-overexpressed tumor compared to non-aggregable NPs,regardless of intravenous or intratumoral *** importantly,this delivery platform significantly improved the chemotherapeutic effect of doxorubicin(DOX)towards subcutaneous xenograft C6 *** effectiveness of this stimulus-responsive aggregable delivery system provides a thinking for designing more intelligent size-tunable nanomedicine that can substantially improve intratumoral retention.

关键词： Legumain Size-tunable Enhanced retention stimulus-responsive Nanomedicine

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The sudden ocean warming and its potential influences on earlyfrozen landfast ice in the Prydz Bay, East Antarctica

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Acta Oceanologica Sinica 2024年第5期43卷 65-77页

作者： Haihan Hu Jiechen Zhao Jingkai Ma Igor Bashmachnikov Natalia Gnatiuk Bo Xu Fengming Hui School of Geospatial Engineering and Science Sun Yat-sen Universityand Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)Zhuhai 519082China Key Laboratory of Comprehensive Observation of Polar Environment(Sun Yat-sen university) Ministry of EducationZhuhai 519082China Qingdao Innovation and Development Base(Centre)of Harbin Engineering university Qingdao 266500China Key Laboratory for Polar Acoustics and Application of Ministry of Education(Harbin Engineering university) Harbin 150001China Key Laboratory of Research on Marine Hazards Forecasting National Marine Environmental Forecasting CentreBeijing 100081China Nansen International Environmental and Remote Sensing Centre St.Petersburg 199034Russia Saint petersburg state university St.Petersburg 199034Russia Antarctic Great Wall Ecology National Observation and Research station Polar Research Institute of ChinaShanghai 201209China

The ocean conditions beneath the ice cover play a key role in understanding the sea ice mass balance in the polar *** integrated high-frequency ice-ocean observation system,including Acoustic Doppler Velocimeter,Conductivity-Temperature-Depth Sensor,and Sea Ice Mass Balance Array(SIMBA),was deployed in the landfast ice region close to the Chinese Zhongshan station in Antarctica.A sudden ocean warming of 0.14℃(pst ice,from(−1.60±0.03)℃during April 16-19 to(−1.46±0.07)℃during April 20-23,2021,which is the only significant warming event in the nearly 8-month *** sudden ocean warming brought a double rise in oceanic heat flux,from(21.7±11.1)W/m^(2) during April 16-19 to(44.8±21.3)W/m^(2) during April 20-23,2021,which shifted the original growth phase at the ice bottom,leading to a 2 cm melting,as shown from SIMBA and borehole ***,the slowdown of ice bottom freezing decreased salt rejection,and the daily trend of observed ocean salinity changed from+0.02 d^(-1) during April 16-19,2021 to+0.003 d^(-1) during April 20-23,*** potential reasons are increased air temperature due to the transit cyclones and the weakened vertical ocean mixing due to the tide phase transformation from semi-diurnal to *** high-frequency observations within the ice-ocean boundary layer enhance the comprehensive investigation of the ocean’s influence on ice evolution at a daily scale.

关键词： sudden ocean warming oceanic heat flux landfast ice Zhongshan station in-situ observation

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Author Correction: ITO-free silicon-integrated perovskite electrochemical cell for light-emission and light-detection

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Opto-Electronic Advances 2024年第3期7卷 50-50页

作者： Maria Baeva Dmitry Gets Artem Polushkin Aleksandr Vorobyov Aleksandr Goltaev Vladimir Neplokh Alexey Mozharov Dmitry VKrasnikov Albert GNasibulin Ivan Mukhin Sergey Makarov Alferov university Khlopina 8/3St.Petersburg 194021Russia Department of Physics and Engineering ITMO UniversityLomonosova 9St.Petersburg 197101Russia Institute of Automation and Control Processes(IACP) Far Eastern Branch of Russian Academy of SciencesUlitsa Radio 5Vladivostok 690041Primorsky KraiRussia Peter the Great st.petersburg Polytechnic university Polytechnicheskaya 29St.Petersburg 195251Russia Skolkovo Institute of Science and Technology Nobel 3Moscow 121205Russia Qingdao Innovation and Development Center Harbin Engineering UniversityQingdao 266000China.

Correction to:Opto-Electronic Advances https://***/10.29026/oea.2023.220154 published online 26 April 2023 After the publication of this article1,it was brought to our attention that calculations of the PeLEC device elec-troluminescent(EL)efficiency contained a mistake,leading to an inaccurate quantity *** device’s maxim-um EL efficiency constitutes not‘~120 klm/W’but‘4.3 lm/W’*** details are listed below.

关键词： value. perovskite listed

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