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Regulating metal-acid double site balance on mesoporous SiO2-Al2O3 composite oxide for supercritical n-decane cracking

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Petroleum Science 2024年第4期21卷 2881-2891页

作者： Liu-Ling Chen Jun Zhang Chun-Guang Li Li-Qun Fei Bo Wang Chen-Qi Zhang Yi Jiao Jian-Li Wang institute of New energy and Low-Carbon Technology Sichuan University Engineering research Center of combustion and cooling for Aerospace Power Ministry of Education School of Chemical Engineering Sichuan University State Key Laboratory of Industrial Vent Gas Reuse Southwest Institute of Chemical Co. Ltd Science and Technology on Scramjet Laboratory Beijing Power Machinery Research Institute

The balance between metal and acid sites directly affects the preparation of high-performance cracking catalysts with high heat sink and low ***,how to control acid-metal sites balance and its relationship with cracking performance are reported *** this work,a series of Pt/Al2O3-SiO2dual sites catalysts with different metal to acid active sites ratio(CM/CSA) were constructed by ethanolassisted impregnation method and the impact on n-decane cracking under supercritical conditions was systematically and deeply *** results showed that the conversion and carbon deposition increased gradually with varied CM/CSAand reached the balance at CM/CSAof *** proper ratio CM/CSA（0.13） can balance the deep dehydrogenation coking over metal active sites and high heat sink of cracking over acid active sites,the chemical heat sink reaches amazing 1.75 MJ/kg and carbon deposition is only22.03 mg/cm2at 750℃.Meanwhile,the few metal sites at low CM/CSAand the few strong acid sites at high CM/CSAare the main factors limiting the cracking *** CM/CSAlimit the activation of C-H bond and deep dehydrogenation of coking precursor,resulting in relative low cracking activity and carbon deposition,while high CM/CSAlimit the activation of C-C bond and increase the deep *** this contribution,design and construction of metal-acid dual sites can not only provide the technical solution for the preparation of high heat sink and low coking cracking catalyst,but also deepen the understanding of the cracking path of hydrocarbon fuel.

关键词： Metal-acid dual sites balance Catalytic cracking Hydrocarbon fuels Chemical heat sink Carbon deposition

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Numerical simulation research on multiphase flow of aviation centrifugal pump based on OpenFOAM

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Chinese Journal of Aeronautics 2024年第4期37卷 256-275页

作者： Xianwei LIU Jiangfeng FU Junjie YANG Dewen YIN Zhenhua ZHOU Huacong LI college of Power and energy Northwestern Polytechnical UniversityXi’an 710072China Norinco Group Testing and research institute Huayin 714200China AECC Xi’an Engine control Technology co.ltd. Xi’an 710077China AECC Guizhou Honglin Aero Engine control Technology co.ltd. Guiyang 550009China

This paper aims to tackle the calculation efficiency problem raised in the cavitation-flow simulation of the aviation centrifugal pump due to the fading-away interface resulting from the dissipation of numerics used in the phase-change control equation for unstructured-grid multiphase flow,and due to the limitation of flow time-step in whole flow regimes,the control equation of vapor–liquid two-phase flow considering cavitation mass transport is established firstly,modifying the momentum equation by introducing the surface tension,and adding the artificial convective flow to the phase equation to solve the numerical dissipation ***,in consideration of the local time step principle and based on the multi-dimensional general limiter algorithm with explicit solutions under the OpenFOAM platform,a solution method of steady-state VOF (Volume of Fluid) model considering cavitation two-phase change is constructed,and the feasibility of this method is verified by NACA hydrofoil and NASA flat plate ***,based on the platform developed,the cavitation performance of an aviation centrifugal pump inducer is *** research results show that the error of the calculated cavitation pressure distribution for NACA hydrofoil between the simulation test and the experimental-test is less than 5%,and the maximum error of calculated cavitation number at pump head dropping for NASA high-speed flat plate inducer between the simulation test and the experimental-test is 2.1%.The cavitation area observed in the simulation test is the same as that obtained in the high-speed photography *** on the OpenFOAM simulation method,the position of pump head dropping of the fuel centrifugal pump can be accurately *** error of the calculated cavitation number at pump head dropping between the simulation test and the experimental test is about 3.7%,showing high calculation accuracy.

关键词： Aero engine Fuel centrifugal pump Multiphase flow OpenFOAM Volume of fluid

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Metal-Organic Framework Enabling Poly(Vinylidene Fluoride)-Based Polymer Electrolyte for Dendrite-Free and Long-Lifespan Sodium Metal Batteries

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energy & Environmental Materials 2024年第1期7卷 68-76页

作者： Yusi Lei Liang Yue Yuruo Qi Yubin Niu Shujuan Bao Jie Song Maowen Xu Faculty of Materials and energy Institute for Clean Energy&Advanced MaterialsSouthwest UniversityChongqing 400715China Shandong Zero-One-Four Advanced Materials co. Ltd.Feicheng 271099China

Sodium dentrite formed by uneven plating/stripping can reduce the utilization of active sodium with poor cyclic stability and,more importantly,cause internal short circuit and lead to thermal runaway and ***,sodium dendrites and their related problems seriously hinder the practical application of sodium metal batteries(SMBs).Herein,a design concept for the incorporation of metal-organic framework(MOF)in polymer matrix(polyvinylidene fluoride-hexafluoropropylene)is practiced to prepare a novel gel polymer electrolyte(PH@MOF polymer-based electrolyte[GPE])and thus to achieve high-performance *** addition of the MOF particles can not only reduce the movement hindrance of polymer chains to promote the transfer of Na^(+)but also anchor anions by virtue of their negative charge to reduce polarization during electrochemical reaction.A stable cycling performance with tiny overpotential for over 800 h at a current density of 5 mA cm^(-2)with areal capacity of 5 mA h cm^(-2)is achieved by symmetric cells based on the resulted GPE while the Na_(3)V_(2)O_(2)(PO_(4))_(2)F@rGO(NVOPF)|PH@MOF|Nacell also displays impressive specific cycling capacity(113.3 mA h g^(-1)at 1 C)and rate capability with considerable capacity retention.

关键词： dendrite-free gel polymer electrolyte metal organic framework sodium batteries

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Atomistic mechanism of high ionic conductivity in lithium ytterbium-based halide solid electrolytes:A first-principles study

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Journal of Rare Earths 2024年第1期42卷 155-162,I0006页

作者： Limin Wang Wei Xiao Lu Sun Rong Yang Jinqiu Yu Ligen Wang State Key Laboratory of Nonferrous Metals and Processes China GRINM Group Co.Ltd.Beijing100088China GRIMAT Engineering institute co. Ltd.Beijing101407China General research institute for Nonferrous Metals Beijing100088China China Automotive Battery research institute co. Ltd.Beijing101407China Rare Earth Functional Materials(Xiong'an)Innovation Center co. Ltd.Xiong'an071700China

As the next generation of commercial automotive power batteries begins replacing liquid lithium batteries,many look towards all-solid-state batteries to pioneer the ***-so lid-state batteries have attracted the attention of countless researchers around the world because of their high safety and high energy *** recent times,halide solid-state electrolytes have become a research hotspot within solid-state electrolytes because of their potentially superior *** this paper,in the framework of DFT,we investigated the atomic mechanisms of improving the ionic conductivity and stability of Li_(3)YbCl_(6).Our calculations show that both trigonal and orthorhombic Li_(3)YbCl_(6) exhibit wide electrochemical windows and metastable properties(100 meV/atom>Ehull>0 meV/atom).However,the orthorhombic Li_(3)YbCl_(6) can be stabilized at high temperatures by taking the vibrational entropy into account,which is supported by the experimental ***,it is expected that because of the Yb/Li synergistic interactions that,due to their strong mutual coulomb repulsion,influence the Li^(+)transport behavior,the orthorhombic Li_(3)YbCl_(6) might have superior ionic conductivities with appropriate Li+migration paths determined by the Yb^(3+) ***,higher ionic conductivities can be obtained by regulating the random distribution of Li^(+) *** Li^(+)-deficiency can also largely increase the ionic conductivity by invoking *** study helps gain a deeper understanding of the laws that govern ionic conductivities and stabilities and provides a certain theoretical reference for the experimental development and design of halide solid-state electrolytes.

关键词： Halide solid-state electrolytes Phase stability Ionic conductivity First-principles calculations Rare earths

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Flame Morphology and Characteristic of co-Firing Ammonia with Pulverized coal on a Flat Flame Burner

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Journal of Thermal Science 2024年第5期33卷 1935-1945页

作者： WANG Shengye CUI Mingshuang LIU Pengzhong DI Yi NIU Fang China coal research institute Beijing 100013China Beijing Tiandi Rongchuang Technology co.ltd. Beijing 100013China National energy Technology&Equipment Laboratory of coal Utilization and Emission control Beijing 100013China

Ammonia as a new green carbon free fuel co-combustion with coal can effectively reduce co_(2)emission,but the research of flame morphology and characteristics of ammonia-coal co-combustion are not *** this work,we studied the co-combustion flame of NH_(3)and pulverized coal on flat flame burner under different oxygen mole fraction(X_(i,O_(2)))and NH_(3)co-firing energy ratios(E_(NH_(3))).We initially observed that the introduction of ammonia resulted in stratification within the ammonia-coal co-combustion flame,featuring a transparent flame at the root identified as the ammonia combustion *** to challenges in visually observing the ignition of coal particles in the ammonia-coal co-combustion flame,we utilized Matlab software to analyze flame images across varying E_(NH_(3))and X_(i,O_(2)).The analysis indicates that,compared to pure coal combustion,the addition of ammonia advances the ignition delay time by 4.21 ms to 5.94 *** E_(NH_(3))increases,the ignition delay time initially decreases and then ***,an increase in X_(i,O_(2))results in an earlier ignition delay *** burn-off time and the flame divergence angle of pulverized coal demonstrated linear decreases and increases,respectively,with the growing ammonia *** addition of ammonia facilitates the release of volatile matter from coal ***,in high-ammonia environments,oxygen consumption also impedes the surface reaction of coal ***,measurements of gas composition in the ammonia-coal flame flow field unveiled that the generated water-rich atmosphere intensified coal particle gasification,resulting in an elevated concentration of ***,nitrogen-containing substances and coke produced during coal particle gasification underwent reduction reactions with NO_(x),leading to reduced NO_(x)emissions.

关键词： co-firing ammonia with coal flame characteristic gas component ignition delay time burn-off time flame divergence angle flat flame burner flame morphology

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Multi-source heterogeneous data access management framework and key technologies for electric power Internet of Things

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Global energy Interconnection 2024年第1期7卷 94-105页

作者： Pengtian Guo Kai Xiao Xiaohui Wang Daoxing Li China Electric Power research institute co.ltd. Beijing 100192P.R.China

The power Internet of Things(IoT)is a significant trend in technology and a requirement for national strategic *** the deepening digital transformation of the power grid,China’s power system has initially built a power IoT architecture comprising a perception,network,and platform application ***,owing to the structural complexity of the power system,the construction of the power IoT continues to face problems such as complex access management of massive heterogeneous equipment,diverse IoT protocol access methods,high concurrency of network communications,and weak data security *** address these issues,this study optimizes the existing architecture of the power IoT and designs an integrated management framework for the access of multi-source heterogeneous data in the power IoT,comprising cloud,pipe,edge,and terminal *** further reviews and analyzes the key technologies involved in the power IoT,such as the unified management of the physical model,high concurrent access,multi-protocol access,multi-source heterogeneous data storage management,and data security control,to provide a more flexible,efficient,secure,and easy-to-use solution for multi-source heterogeneous data access in the power IoT.

关键词： Power Internet of Things Object model High concurrency access Zero trust mechanism Multi-source heterogeneous data

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The noise spectral characteristics and noise reduction schemes of screw air-source heat pump:A case study

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Building Simulation 2024年第1期17卷 53-70页

作者： Dongsheng Liu Yaohan Feng Jikang Jia Pengfei Si Ya Feng China Southwest Architecture Design and research institute co.ltd. Chengdu 610041China CSCEC Green construction Engineering research Center Chengdu 610041China

The screw air-source heat pump can cause incessant high noise levels during operation,which might hinder adoption of this energy-efficient heat ***,acoustic measurements and comparison testing were performed in this *** measurements revealed that the compressor is the main noise source of the heat pump,and it shows a multipeak frequency distribution and a wide frequency spectrum under different work conditions,with multiple peaks at 63,250,and 1000 ***,a compressor sound insulation cover with broadband absorption was proposed,and it was experimentally proven that the insulation cover can reduce the maximum sound pressure level of one unit from 89.8 dBA to 79.1 ***,we proposed several noise reduction strategies and compared their noise reduction effects using computer *** results showed that the noise problem can be effectively improved through the rational design of the sound barrier and the layout and opening options of heat *** distance between the sound barrier and heat pump and the sound attenuation due to diffraction ALa exhibit a U-shaped *** buildings of different heights,the optimal heights of noise barrier are *** 5.5-meter is the optimal height of the sound barrier for single-story *** conclusions can be applied to other building projects for heat pump noise reduction.

关键词： acoustic simulation broadband noise noise reduction air-source heat pump sound barrier

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Advances in Polymeric Carbon Nitride Photocatalysts for Enhanced co_(2)Reduction

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China Petroleum Processing & Petrochemical Technology 2024年第2期26卷 1-12页

作者： Liu Bing Sun Shangcong Song Ye Peng Bo Lin Wei SINOPEC research institute of Petroleum Processing co. Ltd.Beijing100083China

Photocatalysis has emerged as a promising alternative for converting and utilizing co_(2).Polymeric carbon nitride(PCN),typically synthesized through the one-step thermal polycondensation of nitrogen-rich precursors,has shown considerable promise due to its adjustable band structure and inherent *** the past five years,significant literature in this field has identified five primary methods for modifying PCN:morphology modulation,element doping,defect induction,co-catalyst loading,and heterojunction construction.A detailed discussion on how each modification method influences light absorption,charge separation,and surface reaction efficiencies in photocatalysis is *** on these findings,several future directions for the development of PCN-based materials are proposed,such as designing tailored PCN structures for specific photocatalytic reactions and using theoretical calculations to verify and correct results from current characterization *** the challenges associated with the large-scale synthesis of PCN materials with controllable structures and satisfactory performance,this work offers valuable insights for advancing photocatalytic PCN-based systems for large-scale solar fuel production.

关键词： carbon nitride photocatalysis co_(2)reduction modification

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Solidification behaviour and hot cracking susceptibility of a novel Ni-based superalloy

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Journal of Iron and Steel research International 2024年第4期31卷 956-966页

作者： Yue Chen Shao-min Lv Xing-fei Xie Xiao-can Wen Jng-long Qu Jin-hui Du High-Temperature Materials institute China Iron and Steel Research Institute Group Co.Ltd.Beijing 100081China Beijing GAONA Materials and Technology co. Ltd.Beijing 100081China Sichuan CISRI-GAONA Forging co. Ltd.Deyang 610000SichuanChina

A novel Ni-based superalloy GH4151,with a γ′ volume fraction of about 55%and a service temperature capability up to 8oo oC,was *** to the different cooling conditions of various regions during the solidification of ingots,significant cooling rate variations may lead to the occurrence of hot *** scanning laser microscope was utilised to investigate the solidification process and phase precipitation behaviour of the GH4151 under wide range cooling *** characteristics of L→γ transformation were analysed,and the growth rates of at each stage were *** segregation behaviour was predicted using the Scheil equation,and the predicted results match well with the experimental *** sensitivity coefficient for hot cracking was modified,and cracking sensitivity coefficient values for the alloy under different cooling rates were computed,revealing that the alloy is most susceptible to hot cracking at 10℃/min cooling ***,controlling the cooling rate can reduce the possibility of hot cracking in ingot.

关键词： Ni-based superalloy Solidification behaviour In-situ observation Clyne and Davies's criterion:Hot cracking susceptibility

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Measurement and correlation of Liquid-liquid Equilibria for 1-Hexene-n-Hexane-3-Methysulfolane

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China Petroleum Processing & Petrochemical Technology 2024年第2期26卷 81-87页

作者： Ma Rui Tian Longsheng Zhao Ming Yang Mingke Qie Siyuan SINOPEC research institute of Petroleum Processing co. Ltd.Beijing 100083China

Utilizing solvent extraction to separate alkanes and olefins from catalytic light gasoline is an effective method for maximizing the utility of gasoline *** study presents the determination of liquid-liquid equilibrium data for the ternary system of 1-hexene-n-hexane-3-methylsulfolane at 30℃,40℃,and 50℃under atmospheric *** obtained data facilitated the construction of a ternary phase diagram for the *** results showed that the extraction selectivity of 1-hexene/n-hexane exceeded 1.5 when using 3-methylsulfolane as the extraction ***,the thermodynamic consistency of the experimental data was examined using Hand’s equation and the Othmer-Tobias *** correlation coefficient,R^(2)≥0.9578,indicated the acceptable reliability of the phase equilibrium ***,the NRTL(non-random two liquid)model was used to correlate the liquid-liquid phase equilibrium data and derive the binary interaction ***,the results demonstrated that the root mean square deviation of the NRTL model correlation values from the experimental values did not exceed 2.5%.

关键词： liquid-liquid phase equilibrium 1-hexene n-hexane 3-methylsulfolane NRTL

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