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Feasibility of compacted attapulgite/diatomite amended clayey soils as gas barrier materials

Journal of Rock Mechanics and Geotechnical engineering 2024年第9期16卷 3707-3717页

作者： Heng Zhuang Wei-Yi Xia Jia-Ming Wen Min Wang Ying-Zhen Li Ning-Jun Jiang Konstantin S.Rodygin Yan-Jun Du Jiangsu Key Laboratory of Low Carbon and Sustainable Geotechnical engineering Institute of Geotechnical EngineeringSoutheast UniversityNanjing211189China Jiangsu Province Ecology and Environment protection engineering Research center of groundwater pollution prevention and control Jiangsu Environmental Engineering Technology Co.Ltd.Nanjing210036China Zijin(Changsha)engineering technology Co. Ltd.Changsha410006China Institute of Chemistry Saint Petersburg State UniversityStary Petergof198504Russia

Compacted clay liners are extensively used as barriers to control the upward diffusion of vapors of volatile or semi-volatile organic contaminants released from unsaturated contaminated soils at industrycontaminated *** study aimed to investigate the gas diffusion barrier performance of compacted clayey soils amended with three agents including attapulgite and diatomite individually,and attapulgite/diatomite *** properties including water retention,volumetric shrinkage,gas diffusion,and unconfined compressive strength were evaluated through a series of laboratory tests of amended compacted clayey *** results demonstrate that the decrease in volume proportions of interaggregate pores leads to an increase in unconfined compressive strength(qu).Both hydrophilic groups and microstructures of attapulgite and diatomite result in an increase in water retention percent(Wt)of compacted clayey soil specimens after amendment regardless of the type of agent or initial water content(w0).Furthermore,the ratio of the gas diffusion coefficient(De)to the gas diffusion coefficient in the air(Da)was significantly reduced owing to a decrease in volume proportions of inter-aggregate pores,hydrophilic group,and microstructures of attapulgite and *** electron microscope analyses revealed that rod-shaped attapulgite filled the inter-aggregate pores formed by clay particles,whereas the disc-shaped diatomite particles,characterized by micropores,failed to obstruct the interaggregate pores due to their larger particle *** intrusion porosimetry(MIP)analyses showed a reduction in pore volume in the inter-aggregate pores,leading to a reduction in the total pore volume for both the attapulgite and attapulgite/diatomite mixture amended clays,which is in accordance with the scanning electron microscope(SEM)*** findings are pertinent to the practical application of compacted clay liners as gas barriers against the upward migration of volatile or s

关键词： Compacted clay liner Attapulgite/diatomite mixture Diffusion barrier Water retention

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Single-atom Pd anchored in the porphyrin-center of ultrathin 2D-MOFs as the active center to enhance photocatalytic hydrogen-evolution and NO-removal

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Chinese Chemical Letters 2024年第9期35卷 364-368页

作者： Xingyan Liu Chaogang Jia Guangmei Jiang Chenghua Zhang Mingzuo Chen Xiaofei Zhao Xiaocheng Zhang Min Fu Siqi Li Jie Wu Yiming Jia Youzhou He Chongqing Key Laboratory of Catalysis and New environmental Materials College of Environment and ResourcesChongqing Technology and Business UniversityChongqing 400067China School of Pharmacy North Sichuan Medical CollegeNanchong 637100China Carbon Neutrality technology Application Research center College of River and Ocean EngineeringChongqing Jiaotong UniversityChongqing 400074China State Key Joint Laboratory of Environment Simulation and pollution control School of EnvironmentTsinghua UniversityBeijing 100084China National Local Joint engineering Research center for Road engineering and Disaster prevention and Reduction technology in Mountainous Areas China Merchants Chongqing Communications Technology Research and Design Institute Co.Ltd.Chongqing 400067China Chongqing Culture Relics and Archaeology Research Institute Chongqing 400013China

Single-atom catalysts were widely used to treat atmospheric pollution and alleviate energy crises through ***,how to prevent the aggregation of single atoms during the preparation and catalytic processes remained a great ***,a novel ultrathin two-dimensional porphyrin-based single-atom photocatalyst Ti-MOF(abbreviated as TMPd)obtained through a simple hydrothermal synthesis strategy was used for photocatalytic hydrogen evolution and NO removal,in which the singleatom Pd tightly anchored in the center of porphyrin to ensure single-atom Pd stable *** with most reported MOFs-based photocatalysts,the TMPd showed an excellent hydrogen evolution rate(1.32 mmol g^(-1)h^(-1))and the NO removal efficiency(62%)under visible light *** high-angle annular dark-field scanning transmission electron microscope(HAADF-STEM)and synchrotron-radiation-based X-ray absorption fine-structure spectroscopy(XAFS)proved that pd in TMPd existed in an isolated state,and the atomic force microscope(AFM)proved the ultrathin morphology of *** calculations had demonstrated that single-atom Pd could serve as the active center and more effectively achieve electron transfer,indicating that single-atom Pd played a vital role in photocatalytic hydrogen *** addition,a possible photocatalytic pathway of NO removal was proposed based on ESR and in-situ infrared spectra,in which the catalysts anchored with single-atom Pd could produce more active substances and more effectively oxidize NO to NO_(2)^(-)or NO_(3)^(-).The results suggested that coordinating single-atom metal species as the active site in the center of porphyrin could be a feasible strategy to obtain various ultrathin porphyrin-based single-atom photocatalysts to acquire excellent photocatalytic performance further.

关键词： Porphyrin-based MOFs Single-atom Pd Ultrathin 2D nanosheets Hydrogen evolution NO removal

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Recent progress of radionuclides separation by porous materials

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Science China Chemistry 2024年第11期67卷 3515-3577页

作者： Yinghui Xie Long Yu Long Chen Cheng Chen Li Wang Fenglei Liu Yun Liao Peng Zhang Tao Chen Yihui Yuan Yuexiang Lu Boyang Huang Hui Yang Suhua Wang Shuao Wang Lijian Ma Feng Luo Yunhai Liu Baowei Hu Hongqing Wang Duoqiang Pan Wenkun Zhu Ning Wang Zhe Wang Liang Mao Shengqian Ma Xiangke Wang Guangdong Provincial Key Laboratory for Green Agricultural Production and Intelligent Equipment School of Environmental Science and Engineering Guangdong University of Petrochemical Technology School of Life Science Shaoxing University College of environmental Science and engineering North China Electric Power University State Key Laboratory of Radiation Medicine and protection School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions Soochow University College of Chemistry Sichuan University School of Chemistry and Materials Science East China University of Technology School of Chemistry and Chemical engineering University of South China Frontiers Science center for Rare Isotopes Lanzhou University State Key Laboratory of Environment-friendly Energy Materials National Co-innovation Center for Nuclear Waste Disposal and Environmental Safety Sichuan Civil-military Integration Institute School of National Defence & Nuclear Science and TechnologySouthwest University of Science and Technology State Key Laboratory of Marine Resource Utilization in South China Sea Collaborative Innovation Center of Marine Science and Technology Hainan University Institute of Nuclear and New Energy technology Tsinghua University State Key Laboratory of pollution control and Resource Reuse School of the Environment Nanjing University Department of Chemistry University of North Texas

The separation of radionuclides is critical for the sustainable development of nuclear energy. It is urgent to design and prepare functionalized materials for efficient radionuclides separation. Porous materials are considered excellent candidates for the separation of radionuclides under complex conditions due to their high specific surface areas, tunable pore structures and controllable functionalities. In this review, we summarized the design, preparation and functionalization of porous materials and their application for separation of radionuclides in the past five years, discussed the separation performance and analyzed the structure-activity relationship between various radionuclides and porous materials, and systematically clarified their characterization and mechanism of different type porous materials. We also introduced the detection, irradiation and chemical toxicity of different reflective radionuclides.

关键词： porous materials radionuclides detection separation radiotoxicity interaction mechanism

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Red soil for sediment capping to control the internal nutrient release under flow conditions

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Frontiers of environmental Science & engineering 2016年第6期10卷 63-71页

作者： Lei Xia Guo Liu Chunmei Chen Meiyan Wen Yangyang Gao State Key Laboratory of Geohazard prevention and Geoenvironment protection Chengdu University of Technology Chengdu 610059 China sichuan Provincial environmental protection Key Laboratory of groundwater pollution prevention and Resource Security Chengdu University of Technology Chengdu 610059 China

Nitrogen （N） and phosphorus （P） released from the sediment to the surface water is a major source of water quality impairment. Therefore, inhibiting sediment nutrient release seems necessary. In this study, red soil （RS） was employed to control the nutrients released from a black-odorous river sediment under flow conditions. The N and P that were released were effectively controlled by RS capping. Continuous-flow incubations showed that the reduction efficiencies of total N （TN）, ammonium （NH4＋-N）, total P （TP） and soluble reactive P （SRP） of the overlying water by RS capping were 77%, 63%, 77% and 92%, respectively, and nitrification and denitrification occurred concurrently in the RS system. An increase in the water velocity coincided with a decrease in the nutrient release rate as a result of intensive water aeration.

关键词： Sediment Red soil capping Flow conditions Nitrogen Phosphorus

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Analysis of hydrogeolgical characteristics and water environmental impact pathway of typical shale gas exploration and development zones in sichuan Basin, China

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Journal of groundwater Science and engineering 2019年第3期7卷 195-213页

作者： SUN Dong LIU Xin-ze YANG Hai-jun CAO Nan ZHANG Zhi-peng CHEN Yin-song LI Da-meng Chengdu Hydrogeology and engineering Geology center Sichuan Bureau of Geology and Mineral Exploration and DevelopmentChengdu 610081China sichuan environmental protection engineering and technology center for groundwater pollution prevention and control Chengdu 610081China sichuan Huadi New Energy and environmental protection technology Co. Ltd.Chengdu 610081China

Studying the influence of shale gas exploration and development on groundwater environment is the basis of guiding water environment protection in the process of shale gas exploration and *** environmental pollution is concealed,complex and *** it is difficult to control the pollution,the current commercial shale gas development zones in sichuan Basin that are mostly located in karst areas and highly sensitive to groundwater will be vulnerable to the impact of shale gas exploration and *** on the hydrogeological conditions of shale gas exploration and development area and combined with engineering analysis of exploration and development,various risk pathways that may affect the groundwater environment during process of shale gas exploration,mining well construction,mining operations and other stages were identified in this *** existing risk pathways were proved by verification of typical areas and should not be *** on the actual situation of typical areas,the countermeasures of groundwater environmental protection in the process of shale gas exploration and development in karst areas were *** is believed that the groundwater environment can be better protected by strengthening administration,research and application of new technologies,precise design,hydrogeological conditions,and research and feedback of groundwater environmental protection.

关键词： groundwater environment Shale gas Impact pathway analysis

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Enhanced formation of trihalomethane disinfection byproducts from halobenzoquinones under combined UV/chlorine conditions

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Frontiers of environmental Science & engineering 2022年第6期16卷 109-119页

作者： He Zhao Ching-Hua Huang Chen Zhong Penghui Du Peizhe Sun Beijing engineering Research center of Process pollution control Division of Environment Technology and EngineeringInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Civil and environmental engineering Georgia Institute of TechnologyAtlantaGA 30332USA State environmental protection Key Laboratory of Integrated Surface Water-groundwater pollution control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China School of environmental Science and engineering Tianjin UniversityTianjin 300072China

Halobenzoquinones(HBQs)are highly toxic disinfection byproducts(DBPs)and are also precursors of other DBPs such as trihalomethanes(THMs).The formation of THMs from HBQs during chlorine-only and UV/chlorine processes with or without bromide was investigated *** functional theory(DFT)reactivity descriptors were also applied to predict the nucleophilic/electrophilic reactive sites on HBQs and *** results were combined to explain the different behaviors of 2,6-dichloro-1,4-benzoquinone(2,6-DCBQ)and tetrachloro-1,4-benzoquinone(TCBQ)and to propose mechanism for the promoting roles of UV and hydroxylation of HBQs in THMs *** UV/chlorine,UV significantly enhanced THMs formation from 2,6-DCBQ compared to chlorine-only,mainly due to the production of OH-DCBQ^(*).Excited 2,6-DCBQ^(*)by UV benefited nucleophilic hydrolysis to produce OH-DCBQ^(*),which favored electrophilic attack by chlorine,thereby inducing more THMs ***/chlorine modestly promoted THMs formation from TCBQ compared to *** of TCBQ and UV irradiation were both important in promoting THMs formation due to the high electrophilic property of OH-TCBQ and TCBQ^(*).Meanwhile,hydroxylation of HBQs and CHCl3 formation were enhanced at higher *** work suggested that enhanced formation of THMs from HBQs should be considered in the application of combined UV and chlorine processes.

关键词： Halobenzoquinone Trihalomethane Chlorine disinfection UV irradiation Disinfection byproducts Combined UV/chlorine

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Chemical characterization of volatile organic compounds (VOCs) emitted from multiple cooking cuisines and purification efficiency assessments

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Journal of environmental Sciences 2023年第8期130卷 163-173页

作者： Hanyu Zhang XuejunWang Xianbao Shen Xin Li BoboWu Guohao Li Huahua Bai Xinyue Cao Xuewei Hao Qi Zhou Zhiliang Yao School of Ecology and Environment Beijing Technology and Business UniversityBeijing 100048China State environmental protection Key Laboratory of Food Chain pollution control Beijing Technology and Business UniversityBeijing 100048China Beijing Municipal Research Institute of environmental protection Beijing Key Laboratory of Urban Atmospheric Volatile Organic Compounds Pollution Control and ApplicationNational Urban Environmental Pollution Control Engineering Research CenterBeijing 100037China

Cooking process can produce abundant volatile organic compounds(VOCs),which are harmful to environment and human ***,we conducted a comprehensive analysis in which VOCs emissions from multiple cuisines have been sampled based on the simulation and acquisition platform,involving concentration characteristics,ozone formation potential(OFP)and purification efficiency *** emissions varied from 1828.5 to 14,355.1μg/m^(3),with the maximumand minimumvalues fromBarbecue and Family cuisine,*** and alcohol had higher contributions to VOCs from sichuan and Hunan cuisine(64.1%),Family cuisine(66.3%),Shandong cuisine(69.1%)and Cantonese cuisine(69.8%),with the dominant VOCs species of ethanol,isobutane and *** comparison,alcohols(79.5%)were abundant for Huaiyang cuisine,while alkanes(19.7%),alkenes(35.9%)and haloalkanes(22.9%)accounted for higher proportions from ***,carbon tetrachloride,n-hexylene and 1-butene were the most abundant VOCs species for Barbecue,ranging from 8.8%to 14.6%.The highest OFP occurred in *** sensitive species of OFP for Huaiyang cuisine were alcohols,while other cuisines were *** efficiency assessments shed light on the removal differences of individual and synergistic control *** emissions exhibited a strong dependence on the photocatalytic oxidation,with the removal efficiencies of 29.0%–54.4%.However,the high voltage electrostatic,wet purification and mechanical separation techniques played a mediocre or even counterproductive role in the VOCs reduction,meanwhile collaborative control technologies could not significantly improve the removal *** results identifiedmore effective control technologies,which were conductive to alleviating air pollution from cooking emissions.

关键词： Cooking emissions Volatile organic compounds(VOCs) VOCs categories Ozone formation potential(OFP) Purification efficiency

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A critical review of on-site inorganic arsenic screening methods

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Journal of environmental Sciences 2023年第3期125卷 453-469页

作者： Yi He Jingyu Liu Yanhua Duan Xiaofei Yuan Lulu Ma Ratan Dhar Yan Zheng Department of Sciences John Jay College and the Graduate CenterThe City University of New YorkNY 10019USA State environmental protection Key Laboratory of Integrated Surface Water-groundwater pollution control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China Guangdong Provincial Key Laboratory of Soil and groundwater pollution control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China Queensland Alliance for environmental Health Sciences(QAEHS) The University of QueenslandQLD 4102Australia Department of Earth and Physical Sciences York CollegeThe City University of New YorkNY 11451USA

Approximately 94 to 220 million people worldwide are at risk of drinking well water containing arsenic > 10 μg/L, the WHO guideline value. To identify non-compliant domestic wells, assess health risks and reduce exposure, accurate and rapid on-site inorganic arsenic screening methods are desirable because all domestic wells worldwide need to be ***, the principles, advantages and limitations of commonly used colorimetry, electrochemistry, and biosensing methods are critically reviewed, with the performance compared with laboratory-based benchmark methods. Most commercial kits are based on the classic Gutzeit reaction. Despite being semi-quantitative, the more recent and more expensive products display improved and acceptable accuracy and shorter testing time (~10 min). Carried out by trained professionals, electrochemical methods are also feasible for on-site analysis, although miniaturization is desirable yet challenging. Biosensing using whole bacterial cells or bio-engineered materials such as aptamers is promising, if incorporated with function specific nanomaterials and biomaterials. Since arsenic is frequently found as arsenite in reducing groundwater and subject to oxidation during sampling, transportation and storage, on-site separation and sample preservation are feasible but the specific methods should be chosen based on sample matrix and tested before use. To eliminate arsenic exposure among hundreds of millions of mostly rural residents worldwide, we call for concerted efforts in research community and regulatory authority to develop accurate, rapid, and affordable tests for on-site screening and monitoring of arsenic in drinking water. Access to affordable testing will benefit people who are socioeconomically disadvantaged.

关键词： Inorganic arsenic On-site analysis Drinking water groundwater Field test

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controlled sintering for cadmium stabilization by beneficially using the dredged river sediment

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Frontiers of environmental Science & engineering 2023年第5期17卷 105-115页

作者： Yunxue Xia Dong Qiu Zhong Lyv Jianshuai Zhang Narendra Singh Kaimin Shih Yuanyuan Tang State environmental protection Key Laboratory of Integrated Surface Water-groundwater pollution control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China Department of Civil engineering Faculty of EngineeringThe University of Hong KongHong Kong 999077China environmental Science center Decarbonisation and Resource ManagementalBritish Geological SurveyNottinghamshireKeyworth NG125GGUK

Cd-bearing solid wastes are considered to be a serious threat to the environment,and effective strategies for their treatment are urgently *** sintering has been considered as a promising method for efficiently incorporating heavy metal-containing solid wastes into various ceramic ***-rich dredged river sediment,especially Al and Si-containing oxides,can be treated as alternative ceramic precursors rather than being disposed of as solid *** examine the feasibility of using waste sediment for Cd stabilization and the phase transition mechanisms,this study conducted a sintering scheme for the mixtures of CdO and dredged river sediment with different(Al+Si):Cd mole *** investigations have been performed on phases transformation,Cd incorporation mechanisms,elemental distribution,and leaching behaviors of the sintered *** showed that Cd incorporation and transformation in the sintered products were influenced by the mole ratio of(Al+Si):*** the high-Cd series((Al+Si):Cd=6:1),CdSiO_(3),Cd_(2)SiO_(4),CdAl_(2)(SiO_(4))_(2) and Cd_(2)Al_(2)Si_(2)O_(9) were predominant Cd-containing product phases,while Cd2Al2Si2O9 was replaced by CdAl_(4)O_(7) when the mole ratio of(Al+Si):Cd was 12:1(low-Cd series).Cd was efficiently stabilized in both reaction series after being sintered at≥900℃,with<5%leached ratio even after a prolonged leaching time,indicating excellent long-term Cd *** study demonstrated that both Cd-containing phases and the amorphous Al-/Si-containing matrices all played critical roles in Cd stabilization.A promising strategy can be proposed to simultaneously reuse the solid waste as ceramic precursors and stabilize heavy metals in the ceramic products.

关键词： Dredged river sediments Cadmium Sintering Stabilization Leaching

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Contaminant removal from low-concentration polluted river water by the bio-rack wetlands

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Journal of environmental Sciences 2012年第6期24卷 1006-1013页

作者： Ji Wang Lanying Zhang Shaoyong Lu Xiangcan Jint Shu Gan Key Laboratory of groundwater Resources and Environment Ministry of EducationJilin UniversityChangchun 130021China State environmental protection Key Laboratory for Lake pollution control Engineering and Technology Center of LakeResearch Center of Lake EnvironmentChinese Research Academy of Environment SciencesBeijing 100012China College of Resources and Environment Hunan Agriculture UniversityChangsha 410128China

The bio-rack is a new approach for treating low-concentration polluted river water in wetland systems.A comparative study of the efficiency of contaminant removal between four plant species in bio-rack wetlands and between a bio-rack system and control system was conducted on a small-scale （500 mm length × 400 mm width × 400 mm height） to evaluate the decontamination effects of four different wetland *** was generally a significant difference in the removal of total nitrogen （TN）,ammonia nitrogen （NH 3-N） and total phosphorus （TP）,but no significant difference in the removal of permanganate index （COD Mn） between the bio-rack wetland and control ***-rack wetland planted with Thalia dealbata had higher nutrient removal rates than wetlands planted with other *** fine-root （root diameter 3 mm） biomass rather than total plant biomass was related to nutrient removal *** study suggested that the nutrient removal rates are influenced by plant species,and high fine-root biomass is an important factor in selecting highly effective wetland plants for a bio-rack *** to the mass balance,the TN and TP removal were in the range of 61.03-73.27 g/m^2 and 4.14-5.20 g/m^2 in four bio-rack wetlands during the whole operational *** N and P removal by plant uptake constituted 34.9%-43.81% of the mass N removal and 62.05%-74.81% of the mass P *** study showed that the nitrification/denitrification process and plant uptake process are major removal pathways for TN,while plant uptake is an effective removal pathway for TP.

关键词： bio-rack constructed wetland fine-root biomass low-concentration polluted river water plants uptake

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