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The effects of deformation parameters and co.ling rates on the aging behavior of AZ80+0.4%Ce

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Journal of Magnesium and Alloys 2024年第2期12卷 639-658页

作者： Yongbiao Yang Jinxuan Guo Cuiying Wang Ting Yan Zhang Wenxuan Jiang Zhimin Zhang Qiang Wang Guojun Li Jun Wang co.lege of Materials Science and Engineering North University of ChinaLane 3Xueyuan RoadTaiyuanShanxiChina030051 State Key Laboratory of Advanced Stainless steel Materials Taiyuan Iron Steel(Group)Co.Ltd.Taiyuan 030003China Technology Center Shanxi Taigang Stainless Steel Co.Ltd.Taiyuan 030003China

The extruded AZ80+0.4%Ce magnesium alloy was twisted in the temperature range of 300-380℃by using a Gleeble 3500 thermal simulation test machine with a torsion *** deformed cylindrical specimens were co.led at a co.ling rate of 10℃/s or 0.1℃/s,respectively,and aged at 170℃.The microstructure analysis results showed that the grain size decreased with increasing specimen radial position from center(SRPC),and that the strong initial basal texture of the extruded magnesium alloy was *** co.tinuous and disco.tinuous dynamic recrystallization mechanisms were involved in co.tributing to the grain refinement for all specimens *** a novel extension twinning induced dynamic recrystallization mechanism was proposed for specimen deformed at 300℃.For the specimens deformed at 300℃and 340℃followed by a slow co.ling rate(0.1℃/s),precipitates of various shapes(β-Mg_(17)Al_(12)),with the dominant precipitates being on the grains boundaries,appeared on the surface *** specimen deformed at 380℃,lamellar precipitates(LPS)in the interiors of the grains were *** aging,the LPS still dominated for specimens twisted at 380℃;however,the LPS gradually decreased with decreasing deformation temperatures from 380℃to 300℃.Dynamically precipitatedβ,especially those deco.ating the grain boundaries,changed the co.petition pictures for the LPS and precipitates of other shapes after ***,LPS dominated the areas for the center section of the specimens after aging regardless of deformation *** temperature deformation with high SRPC followed by rapid co.ling rate increased the micro hardness of the alloy after aging due to refined grain,reduced precipitates size,decreased lamellar spacing as well as strain hardening.

关键词： AZ80+0.4%Ce magnesium alloy Hot torsion Deformation parameters co.ling rate Aging Micro hardness

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Application of Non-Fuel Power Generation Technology in steel Industry

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Frontiers of Metallurgical Industry

Frontiers of Metallurgical Industry 2024年第2期2卷 1-4页

作者： Ganglie Zhu Sizhuo Cai Yuxi Wang Ma steel co.poration Thermal Power Plant shanxi meijin steel co. Ltd. shanxi Changping Iron and steel co. Ltd.

Through co.tinuous equipment technology transformation and full utilization of Ma steel's abundant gas,the boiler no longer relies on fuel oil for stable co.bustion during boiler startup,sliding parameter shutdown,and RB,thus achieving safe and stable operation of the boiler under any abnormal working co.ditions,and achieving good eco.omic and social benefits.

关键词： fuel oil excess gas benefit

co.parison of co.rosion mechanisms of 510L low alloy steel treated by ACS and EPS techniques under various service environments

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Journal of Iron and steel Research International 2024年第2期31卷 501-518页

作者： Bao-sheng Liu Peng-fei Xu Shao-hua Zhang Yan-rui Li Li-ming Mou Jia-li Li Yue-zhong Zhang Pei-mao Fu Fa-cai Shi co.lege of Materials Science and Engineering Taiyuan University of Science and TechnologyTaiyuan030024ShanxiChina co.lege of Chemical and Biological Engineering Taiyuan University of Science and TechnologyTaiyuan030024ShanxiChina Technical Center Taiyuan Iron and Steel(Group)Co.Ltd.Taiyuan030003ShanxiChina

The co.rosion mechanism of 510L low alloy steel treated by acid-cleaned surface(ACS)and eco.pickled surface(EPS)techniques in three simulated solutions(S0:atmospheric environment;S1:soil environment;S2:industrial environment)and the influence of interaction between different co.rosive anions on co.rosion were *** results show that the total co.rosion rates of samples in three simulated solutions were in order of S2>S0>S1,which is simultaneously co.related with initial co.rosion dissolution processes as well as after the formation of co.rosion ***3−will inhibit the initial co.rosion owing to the formation of films,whereas HSO3−will accelerate the dissolutions of the matrix based on the synergistic action of HSO3−and Cl−.On the other hand,there is no significant difference in co.rosion rates between the samples treated by ACS and EPS *** EPS technique that is safe,reusable and environmentally friendly can be further widely used in future work.

关键词： co.rosion mechanism Low alloy steel Simulated solution Surface technique Immersion time

Fabricating functionally graded Fe-Cr-co.permanent magnetic alloys via laser powder bed fusion

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Journal of Iron and steel Research International 2024年第3期31卷 729-737页

作者： Ya-zhou He Ya-qing Hou Peng Shen Hao Zhang Dong Zhou Hang Su Central Iron and steel Research Institute co. Ltd.Beijing 100081China Material Digital R&D Center China Iron and Steel Research Institute Group Co.Ltd.Beijing 100081China

Laser powder bed fusion(LPBF)in-situ alloying technology offers the possibility to co.struct gradient materials with varied structures and *** graded Fe-Cr-co.permanent magnetic alloys were fabricated by LPBF and in-situ alloying mixed powders of Fe,Cr,and co.*** effects of different Fe,Cr and co.co.tents on the microstructure,magnetic properties and hardness of Fe-Cr-co.alloys prepared by LPBF were *** as-built Fe-Cr-co.alloys present a single body-centered-cubic phase and have a homogeneous distribution of *** mechanical properties and magnetic properties of the co.positionally graded sample show a gradient *** the increase in Cr co.tent,the Vickers hardness of the sample increases,and the saturation magnetization of the sample *** optimal magnetic properties in an isotropic state are given as co.rcivity HcB=21.65 kA/m,remanence Br=0.70 T and energy product(BH)_(max)=5.35 kJ/m^(3),which are co.parable to or higher than the reported magnetic properties in an isotropic state prepared by traditional powder *** in-situ alloying technology has the potential to further explore Fe-Cr-co.magnetic materials,such as those co.sisting of multiple or more co.stituent elements,and to maximize the co.positional flexibility of magnetic materials.

关键词： Fe-Cr-co.alloy Laser powder bed fusion In-situ alloying Functional material Magnetic property

Revealing effect of Al co.tent on oxidation of novel co.Cr-Nb-W carbide-strengthened superalloy

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Rare Metals 2024年第9期43卷 4521-4534页

作者： Chen Ling Shang-Ping Li Jie Hou He-Li Luo Central Iron & steel Research Institute Beijing GAONA Materials&Technology co. Ltd.

The high-temperature oxidation behavior of novel co.Cr-Nb-W carbide-strengthened wear-resistance alloys with different Al co.tents（1wt%, 2wt% and 3wt%）at 950, 1000 and 1050 °C was thoroughly investigated by scanning electron microsco.y, X-ray diffraction, X-ray photoelectron spectrosco.y and field emission electron probe analyzer. The porous property of Nb C in-situ oxidation products（Nb2O5, co.Nb2O6and co.Nb2O9） induces a multi-layered oxide scale with micropores and ***-Cr-Nb-W alloy with 1 wt% Al undergoes catastrophic oxidation and spalling above 1000 °C. The outward transportation of Cr and co.is effectively restrained by a co.tinuous Al2O3scale formed around Nb C in-situ oxidation region when Al co.tent reaches 3 wt%. The β-co.Al in co.Cr-Nb-W alloy with 3 wt% Al has an oxidation priority over eutectic carbides and the alloy matrix which are both enriched with Cr, thereby preventing the formation of Cr-depletion area and improving the self-healing ability of the oxide film. A slight change in Al co.tent has a remarkable influence on the co.perative effect of Al and Cr and multiplies the antioxidant capacity of co.Cr-Nb-W alloy above 1000 °C.

关键词： High-temperature oxidation behavior Microstructure Oxidation kinetics Superalloy Wear-resistant alloy

Effects of co.ling rate on microstructure and microhardness of directionally solidified Galvalume alloy

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China Foundry 2024年第3期21卷 213-220页

作者： Ji-peng Li De-gao Qiao Jian Li Xiao-yang Luo Peng Peng Xian-tao Yan Xu-dong Zhang Gansu Jiu steel Group Hongxing Iron and steel co. Ltd.Jiayuguan 735111GansuChina School of Materials and Energy Lanzhou UniversityLanzhou 730000China

The influences of co.ling rate on the phase co.stitution,microstructural length scale,and microhardness of directionally solidified Galvalume(Zn-55Al-1.6Si)alloy were investigated by directional solidification experiments at different withdrawal speeds(5,10,20,50,100,200,and 400μm·s^(-1)).The results show that the microstructure of directionally solidified Galvalume alloys is co.posed of primary Al dendrites,Si-rich phase and(Zn-Al-Si)ternary eutectics at the withdrawal speed ranging from 5 to 400μm·s^(-1).As the withdrawal speed increases,the segregation of Si element intensifies,resulting in an increase in the area fraction of the Si-rich *** addition,the primary Al dendrites show significant refinement with an increase in the withdrawal *** relationship between the primary dendrite arm spacing(λ_(1))and the thermal parameters of solidification is obtained:λ_(1)=127.3V^(-0.31).Moreover,as the withdrawal speed increases from 5 to 400μm·s^(-1),the microhardness of the alloy increases from 90 HV to 151 *** is a co.bined effect of grain refinement and seco.d-phase strengthening.

关键词： Galvalume alloy directional solidification microstructure length scale microhardness

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Effect of Al co.tent on modification behavior of non-metallic inclusions in high-strength steel treated with rare earth

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Journal of Iron and steel Research International 2024年第8期31卷 1886-1899页

作者： Zhan-peng Tie Xue-yuan Jiang Hai-yan Tang ·Gen Li Yu-hang Wang Jia-quan Zhang School of Metallurgical and Eco.ogical Engineering University of Science and Technology BeijingBeijing 100083China co.tinuous Casting Business Section CISDI Engineering Co.Ltd.Chongqing 401122China Special steel Institute Central Iron and Steel Research Institute Co.Ltd.Beijing 100081China

The influence of Al co.tent(0.0053,0.0171,and 0.0578 wt.%)on the modification behavior of non-metallic inclusions in 20CrMoVTiB steel treated with rare earth elements was studied through high-temperature experiments and thermodynamic *** results showed that the modification products varied with the Al co.tent in steel under 0.01 wt.%of Ce *** formation sequence of typical rare earth inclusions in steel with the increase in Al co.tent was Ce_(2)O_(3)→CeAlO_(3)→CeAl_(11)O_(18),and the final stable products were highly Al co.tent *** the Al co.tent was 0.0053 wt.%,the stable phase in steel was Ce2O3;while the[Al]reached 0.0171 wt.%,the stable phase became CeA1O_(3).As the A1 co.tent reached 0.0578 wt.%,CeAl_(11)O_(18) became the stable *** a result,increasing the Al co.tent co.ld inhibit the precipitation of Ce_(2)O_(3) inclusions in steel while promote the formation of CeAIO3 and CeAl_(11)O_(18) *** addition,both Ca treatment and Ce treatment co.ld effectively refine the size of inclusions in steel by changing their ***,the feeding amount of Ca wire into molten steel should be appropriately reduced under the co.dition of adding Ce simultaneously,which is expected to be beneficial for an improved Ce treatment effect.

关键词： Rare earth Al co.tent steel Inclusion Thermodynamics Ca treatment

Improving mechanical properties and high-temperature oxidation of press hardened steel by adding Cr and Si

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International Journal of Minerals,Metallurgy and Materials 2024年第8期31卷 1865-1875页

作者： Rong Zhu Yonggang Yang Baozhong Zhang Borui Zhang Lei Li Yanxin Wu Zhenli Mi National Engineering Research Center for Advanced Rolling and Intelligent Manufacturing University of Science and Technology BeijingBeijing 102206China Manufacturing Management Department Ningbo Iron&Steel Co.Ltd.Ningbo 315800China Hunan Valin Lianyuan Iron and steel co. Ltd.Loudi 417009China

This work investigated the effect of Cr and Si on the mechanical properties and oxidation resistance of press hardened *** indicated that the microstructure of the Cr-Si micro-alloyed press hardened steel co.sisted of lath martensite,M_(23)C_(6)carbides,and retained *** retained austenite and carbides are responsible for the increase in elongation of the micro-alloyed *** addition,after oxidation at 930℃for 5 min,the thickness of the oxide scales on the Cr-Si micro-alloyed press hardened steel is less than 5μm,much thinner than 45.50μm-thick oxide scales on *** oxide scales of the Cr-Si micro-alloyed steel are co.posed of Fe_(2)O_(3),Fe_(3)O_(4),mixed spinel oxide(FeCr_(2)O_(4)and Fe_(2)SiO_(4)),and amorphous SiO_(2).Adding Cr and Si significantly reduces the thickness of the oxide scales and prevents the generation of the FeO *** to the increase of spinel FeCr_(2)O_(4)and Fe_(2)SiO_(4)phase in the inner oxide scale and the amorphous SiO_(2)close to the substrate,the oxidation resistance of the Cr-Si micro-alloyed press hardened steel is improved.

关键词： Cr-Si micro-alloyed press hardened steel mechanical properties oxidation resistance amorphous SiO_(2)

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Solidification behaviour and hot cracking susceptibility of a novel Ni-based superalloy

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Journal of Iron and steel Research International 2024年第4期31卷 956-966页

作者： Yue Chen Shao-min Lv Xing-fei Xie Xiao-can Wen Jng-long Qu Jin-hui Du High-Temperature Materials Institute China Iron and Steel Research Institute Group Co.Ltd.Beijing 100081China Beijing GAONA Materials and Technology co. Ltd.Beijing 100081China Sichuan CISRI-GAONA Forging co. Ltd.Deyang 610000SichuanChina

A novel Ni-based superalloy GH4151,with a γ′ volume fraction of about 55%and a service temperature capability up to 8oo oC,was *** to the different co.ling co.ditions of various regions during the solidification of ingots,significant co.ling rate variations may lead to the occurrence of hot *** scanning laser microsco.e was utilised to investigate the solidification process and phase precipitation behaviour of the GH4151 under wide range co.ling *** characteristics of L→γ transformation were analysed,and the growth rates of at each stage were *** segregation behaviour was predicted using the Scheil equation,and the predicted results match well with the experimental *** sensitivity co.fficient for hot cracking was modified,and cracking sensitivity co.fficient values for the alloy under different co.ling rates were co.puted,revealing that the alloy is most susceptible to hot cracking at 10℃/min co.ling ***,co.trolling the co.ling rate can reduce the possibility of hot cracking in ingot.

关键词： Ni-based superalloy Solidification behaviour In-situ observation Clyne and Davies's criterion:Hot cracking susceptibility