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An overview and experimental analysis of WO3/TiO2 composite with enhanced electrochromic properties for smart windows application

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Tungsten 2024年第4期6卷 732-747页

作者： Ayesha Khan Mayur A.Gaikwad Jin Hyeok Kim Anamika Kadam The Institute of Science Dr.Homi Bhabha State University Optoelectronics Convergence research center and Department of materials Science and engineering Chonnam National University

Internationally,standards for electrochromic（EC） requirements in smart window applications have been established,with ongoing global initiatives aimed at elevating them to highly advanced *** paper covers a comprehensive investigation of the structural,optical,morphological,and electrochemical properties of WO3/TiO2composite ***,an experimental analysis of WO3/TiO2was envisaged by a two-step ***,WO3thin films were hydrothermally deposited onto indium-doped tin oxide-coated glass substrates using an aqueous solution of Na2WO4·2H2O at a pH value of ***,a layer of TiO2was electrodeposited onto the WO3thin films.X-ray diffraction analysis confirmed the successful formation of WO3/TiO2composite films,with the WO3phase exhibiting a hexagonal tunnel *** electron microscopy revealed the formation of porous nanorods（NRs） of WO3,uniformly coated with TiO2,resulting in a porous morphology of the WO./*** EC performance of the WO3/TiO2films was thoroughly assessed through cyclic voltammetry and chronoamperometry measurements over a potential window ranging from-2.0 to+1.2 V（versus Ag/AgCl） in a 0.5 mol·L-1LiClO4-PC *** WO3/TiO2composite films exhibited cathodic electrochromism,characterized by a reversible color change from dark blue to *** improved EC performance in comparison to pure WO3films is attributed to enhanced double ion/electron insertion and extraction ***,the WO3/TiO2composite films demonstrated excellent optical modulation properties,with a significant modulation at 633 nm（46.87%）.The coloration efficiency reached a high value of 193.25 cm2·C-1,indicating their potential for practical EC ***,the WO3/TiO2composite films displayed exceptional EC stability,with no significant degradation observed over 2500 cyclic voltammetry *** superior EC performance can be attributed to the synergistic effect between the hexagonal WO3NRs

关键词： Electrochromism Smart window Stability WO3/TiO2

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Stabilization/solidification mechanisms of tin tailings and fuming slag-based geopolymers for different heavy metals

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Frontiers of Environmental Science & engineering 2024年第5期18卷 43-55页

作者： Xian Zhou Zhengfu Zhang Hui Yang School of materials Science and engineering Kunming University of Science and TechnologyKunming650093China Kunming Metallurgical research Institute Co. Ltd.Kunming650031China

Tin mine tailings(TMT)and fuming slag(FS)contain many heavy metals(As,Cr,Cu,Zn and Mn)that cause severe pollution to the ***,geopolymers were prepared using TMT,FS and flue gas desulfurization gypsum(FGDG)to immobilize heavy metals,and their compressive strength and heavy metal leaching toxicity were *** was first determined that T4F5(TMT:FS=4:5)sample exhibited the highest compressive strength(7.83 MPa).T4F5 achieved 95%immobilization efficiency for As and Cr,and nearly 100%for Cu,Zn and Mn,showing good immobilization performance.A series of characterization analyses showed that heavy metal cations can balance the charge in the geopolymer and replace Al in the geopolymer structure to form covalent *** addition,about 2%–20%of heavy metal Fe was immobilized in hydration products,heavy metal hydroxides and non-bridging Si–O and Al–O coordination with silica-aluminate ***_(3)^(3−) was oxidized into AsO_(4)^(3−),which may form Ca–As or Fe–As ***_(2)O_(7)^(2−)was converted to CrO_(4)^(2−)under alkaline environment and then combined with OH−to form Cr(OH)3 ***^(2+)may react directly with dissolved silicate to form Mn_(2)SiO_(4) and also form Mn(OH)_(2) *** unstable Mn(OH)_(2) can be further oxidized to MnO_(2).The heavy metal cations were immobilized in the silicoaluminate lattice,while the anions tended to form insoluble *** results may benefit the industry and government for better handling of TMT,FS and solid wastes containing the abovementioned five heavy metals.

关键词： Heavy metals Cementitious materials Tin tailings Stabilization/solidification Redox

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A review on surface coating strategies for anti-hygroscopic of high energy oxidizer ammonium dinitramide

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Defence technology（防务技术） 2024年第3期33卷 237-269页

作者： Hongyu Yang Fuyao Chen Yiwen Hu Qiangqiang Lu Lei Xiao Yinglei Wang Fengqi Zhao Wei Jiang Gazi Hao National Special Superfine Powder engineering research center of China School of Chemistry and Chemical EngineeringNanjing University of Science and TechnologyNanjing 210094China Xi’an Modern Chemistry research Institute Xi’an 710065China

Ammonium dinitramide(ADN),which has the advantages of high energy density,no halogen and low characteristic signal,is not only considered as a new high-energy oxidizer that is expected to replace the traditional oxidizer ammonium perchlorate(AP)in solid propellants,but also a good performance explosive in ***,due to the strong hygroscopicity of ADN,its application in solid propellants and explosives is greatly *** the hygroscopicity of ADN is the key to realize the wide application of *** this paper,we systematically review the research progress of anti-hygroscopic strategies of ADN *** surface coating methods are focusing on solvent volatilization,solvent-non-solvent,melt crystallization and atomic layer deposition *** characteristics of the different methods are compared and analyzed,and the basis for the classification and selection of the coating materials are introduced in *** addition,the feasibility of material for surface coating of ADN is evaluated by several compatibility analysis *** is highly expected that the liquid phase method(solvent volatilization method,solvent-non-solvent method)would be the promising method for future ADN coating because of its effective,safety and facile ***,polymer materials,are the preferred coating materials due to their high viscosity,easy adhesion,good anti-hygroscopic effect,and heat resistance,which make ADN weak hygroscopicity,less sensitive,easier to preserve and good compatibility.

关键词： Ammonium dinitramide(ADN) Energetic materials Anti-hygroscopic Surface coating Compatibility analysis

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Mn single-atoms decorated CNT electrodes for high-performance supercapacitors

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Nano research 2024年第5期17卷 4039-4046页

作者： Qian Rong Chao Yuwen Yingkai Liu Yuanrong Liu Chunyang Wang Yang Wang Ding Zhang Zhen Wen Yunnan Key Laboratory of Opto-Electronic Information technology Institute of Physics and Electronic InformationYunnan Normal UniversityKunming 650500China Faculty of Metallurgical and energy engineering Kunming University of Science and TechnologyKunming 650093China Department of Physics and Astronomy University of CaliforniaIrvineCA 92697USA School of materials Science and engineering National Institute for Advanced MaterialsSmart Sensing Interdisciplinary Science CenterNankai UniversityTianjin 300350China Jiangsu Key Laboratory for Carbon-Based Functional materials and Devices Institute of Functional Nano and Soft Materials(FUNSOM)Soochow UniversitySuzhou 215123China

Developing highly robust and efficient electrode materials is of critical importance to promoting the energy density of current supercapacitors for ***,we report an efficient catalyst with monodispersed Mn single-atoms embedded in carbon nanotubes(Mn-CNTs)for enhancing the electrode performance of supercapacitors.A high specific capacitance(1523.6 F·g^(-1) at 1.0 A·g^(-1))can be achieved,which is about twice as high as the specific capacitance of the electrode material without the introduction of Mn ***,the asymmetric electrochemical capacitor created with Mn-CNT and activated carbon exhibits a high energy density of 180.8 Wh·kg^(-1) at a power density of 1.4 kW·kg^(-1),much higher than most reported *** study shows that the integration of Mn atoms into the CNT can enhance the charge transport capacity and the number of polar active sites of Mn-CNT and then facilitate chemical interactions between Mn-CNT and OH-.This work provides a novel strategy to enable high-energy storage in supercapacitors by introducing single-atoms into carbon nanotubes to improve electrodes’energy density and cycle life.

关键词： carbon nanotube(CNT) supercapacitor single-atoms power density energy density

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Mn-based MXene with high lithium-ion storage capacity

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Nano research 2024年第5期17卷 4181-4191页

作者： Yanyan Wu Dongqing Liu Xiaonan Wang Usman Ghani Muhammad Asim Mushtaq Jinfeng Yang Huarui Sun Panagiotis Tsiakaras Xingke Cai School of Science and Ministry of Industry and Information technology Key Laboratory of Micro-Nano Optoelectronic Information System Harbin Institute of Technology ShenzhenShenzhen 5180552 China Collaborative Innovation center of Extreme Optics Shanxi UniversityTaiyuan 030006China Institute for Advanced Study Shenzhen UniversityShenzhen 518060China College of Mechatronics and Control engineering Shenzhen UniversityShenzhen 518060China Laboratory of Alternative energy Conversion Systems Department of Mechanical EngineeringSchool of EngineeringUniversity of ThessalyPedion Areos 38834Greece

3d-transition metal(Fe,Co,Ni,and Mn)-based MXene materials have been predicted to demonstrate exceptional electrochemical performance because of their good electrical conductivity and the presence of metallic atoms with multiple charge ***,until now,there have been no reports on MXenes based on Fe,Co,Ni,and Mn,due to the lack of 3d-metal-layered ***,we successfully synthesized the first 3d-transition metal-based MXenes,Mn_(2)CT_(x) by exfoliating a layered precursor derived from the anti-perovskite bulk *** as-prepared Mn_(2)CT_(x) MXene nanosheets were employed as anode materials in lithium-ion batteries,which exhibited stable storage capacity of 764.7 mAh·g^(-1) at 0.5 C,placing its storage capacities at an upper-middle level compared with other reported MXene materials as well as other Mn-based anode ***,this study opens a new avenue for MXene research by synthesizing 3d-transition metal-based MXenes for electrochemical applications.

关键词： Mn_(3)GaC Mn_(2)CT_(x) MXenes lithium-ion battery anode materials negative fading capacity

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Role of Multi-scale Hierarchical Structures in Regulating Wetting State and Wetting Properties of Structured Surfaces

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Journal of Bionic engineering 2024年第3期21卷 1347-1359页

作者： Yue Jiang Xinyi Li Zhichao Ma Zhihui Zhang Cuie Wen Zhonghao Jiang Nan Lin Luquan Ren Key Laboratory of Bionic engineering of Ministry of Education College of Biological and Agricultural EngineeringJilin UniversityChangchun130022China Hubei Provincial engineering technology research center for Microgrid College of Electrical Engineering and New EnergyChina Three Gorges UniversityYichang443002China School of Mechanical and Aerospace engineering Jilin UniversityChangchun130025China Centre for Additive Manufacturing School of EngineeringRMIT UniversityMelbourneVictoria3001Australia Key Laboratory of Automobile materials of Ministry of Education College of Materials Science and EngineeringJilin UniversityChangchun130025China State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin UniversityChangchun130012China

Amplifying the intrinsic wettability of substrate material by changing the solid/liquid contact area is considered to be the main mechanism for controlling the wettability of rough or structured *** theoretical analysis and experimental exploration,we have found that in addition to this wettability structure amplification effect,the surface structure also simultaneously controls surface wettability by regulating the wetting state via changing the threshold Young angles of the Cassie-Baxter and Wenzel wetting *** wetting state regulation effect provides us with an alternative strategy to overcome the inherent limitation in surface chemistry by tailoring surface *** wetting state regulation effect created by multi-scale hierarchical structures is quite significant and plays is a crucial role in promoting the superhydrophobicity,superhydrophilicity and the transition between these two extreme wetting properties,as well as stabilizing the Cassie-Baxter superhydrophobic state on the fabricated lotus-like hierarchically structured Cu surface and the natural lotus leaf.

关键词： Hierarchical structure Wetting state regulation Wetting transition Superhydrophobicity Superhydrophilicity

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电沉积Mo和Mo-Co合金纳米线用于互联电阻的电阻率改性

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engineering 2024年第1期32卷 127-137页

作者： Jun Hwan Moon Taesoon Kim Youngmin Lee Seunghyun Kim Yanghee Kim Jae-Pyoung Ahn Jungwoo Choi Hyuck Mo Lee Young Keun Kim Department of materials Science and engineering Korea UniversitySeoul 02841Republic of Korea Department of materials Science and engineering Korea Advanced Institute of Science and EngineeringDaejeon 34141Republic of Korea Advanced analysis center Korea Institute of Science and TechnologySeoul 02792Republic of Korea research Resources Division Korea Institute of Science and TechnologySeoul 02792Republic of Korea

Achieving historically anticipated improvement in the performance of integrated circuits is challenging,due to the increasing cost and complexity of the required technologies with each new *** overcome this limitation,the exploration and development of novel interconnect materials and processes are highly desirable in the microelectronics ***(Mo)is attracting attention as an advanced interconnect material due to its small resistivity size effect and high cohesive energy;however,effective processing methods for such materials have not been widely ***,we investigate the electrochemical behavior of ions in the confined nanopores that affect the electrical properties and microstructures of nanoscale Mo and Mo-Co alloys prepared via template-assisted *** in an electrolyte allow the deposition of extremely pure metal materials,due to their interac-tion with metal ions and *** this study,boric acid and tetrabutylammonium bisulfate(TBA)were added to an acetate bath to inhibit the hydrogen evolution *** accelerated the reduction of Mo at the surface by inducing surface conduction on the *** Mo nanowires with a 130 nm diameter synthesized through high-aspect-ratio nanopore engineering exhibited a resistivity of(63.0±17.9)μΩ*** also evaluated the resistivities of Mo-Co alloy nanowires at various compo-sitions toward replacing irreducible conventional barrier/liner *** intermetallic compound formed at a Mo composition of 28.6 at%,the resistivity of the Mo-Co nanowire was(58.0±10.6)μΩcm,indicat-ing its superior electrical and adhesive properties in comparison with those of conventional barriers such as TaN and ***,density functional theory and non-equilibrium Green's function calcula-tions confirmed that the vertical resistance of the via structure constructed from Mo-based materials was 21%lower than that of a conventional Cu/Ta/TaN structure.

关键词： Molybdenum Molybdenum-cobalt Interconnect Microstructure Electrodeposition Density functional theory

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Advanced nanofabrication for elastic inorganic aerogels

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Nano research 2024年第10期17卷 8842-8862页

作者： Xiaota Cheng Xinyi Chang Fan Wu Yalong Liao Kai Pan Hao Fong Jianyong Yu Yi-Tao Liu Bin Ding Innovation center for Textile Science and technology College of TextilesDonghua UniversityShanghai 201620China Aerospace Institute of Advanced Material and Processing technology Beijing 100074China College of materials Science and engineering Beijing University of Chemical TechnologyBeijing 100029China

Inorganic aerogels with low density,high porosity,large specific surface area,and superior mechanical properties are excellent candidate materials in fields such as thermal management,energy,catalysis,and biomedical applications.A comprehensive overview of existing elastic inorganic aerogels is provided,covering their structural units,preparation methods,mechanical performances,and ***,based on the constituent building blocks and microstructures,a detailed analysis of the mechanical properties and guidelines for elastic design of aerogels is *** with a succinct summary of prospective developmental direction,this review deliberates on the challenges and potential opportunities of elastic inorganic aerogels,with the intent of providing a versatile platform for designing new types of elastic inorganic aerogels for various applications.

关键词： inorganic aerogels compressive stretchable fabrication mechanical performances applications

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Interfacial built-in electric field and crosslinking pathways enabling WS_(2)/Ti_(3)C_(2)T_(x) heterojunction with robust sodium storage at low temperature

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Journal of energy Chemistry 2024年第2期89卷 635-645,I0014页

作者： Jiabao Li Shaocong Tang Jingjing Hao Quan Yuan Tianyi Wang Likun Pan Jinliang Li Shenbo Yang Chengyin Wang College of Chemistry and Chemical engineering Yangzhou UniversityYangzhou 225002JiangsuChina Shanghai Key Laboratory of Magnetic Resonance School of Physics and Electronic Science East China Normal UniversityShanghai 200241China Siyuan Laboratory Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy MaterialsGuangdong Provincial Key Laboratory of Nanophotonic ManipulationDepartment of PhysicsJinan UniversityGuangzhou 510632GuangdongChina Hongzhiwei technology(Shanghai)CO.LTD Shanghai 200241China

Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also ***,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold ***,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical ***,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous ***,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure ***,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained.

关键词： WS_(2)/Ti_(3)C_(2)T_(x)heterojunction Built-in electric field Ion reservoir Reaction kinetics Sodium storage performance at low temperature

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Coordination-environment regulation of atomic Co-Mn dual-sites for efficient oxygen reduction reaction

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Nano research 2024年第8期17卷 6841-6848页

作者： Caiting Sun Yarong Liu Zunhang Lv Rui Liu Changli Wang Liuhua Li Jinming Wang Yu Zhang Wenxiu Yang Bo Wang Key Laboratory of Cluster Science(Ministry of Education) Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion MaterialsAdvanced Technology Research Institute(Jinan)Advanced Research Institute of Multidisciplinary ScienceSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China Beijing Institute of technology Library Beijing Institute of TechnologyBeijing 100081China

Precisely designing atomic metal-nitrogen-carbon(M-N-C)catalysts with asymmetric diatomic configurations and studying their structure–activity relationships for oxygen reduction reaction(ORR)are important for zinc-air batteries(ZABs).Herein,a dualatomic-site catalyst(DASC)with CoN_(3)S-MnN_(2)S_(2) configuration was prepared for the cathodes of *** with Co-N-C(Mn-free)and CoMn-N-C(S-free doping),CoMn-N/S-C exhibits excellent half-wave potential(0.883 V)and turnover frequency(1.54 e·s^(−1)·site^(−1)),surpassing most of the reported state-of-the-art Pt-free ORR *** CoMn-N/S-C-based ZABs achieve extremely high specific capacity(959 mAh·g^(−1))and good stability(350 h@5 mA·cm^(−2)).Density functional theory(DFT)calculation shows that the introduction of Mn and S can break the electron configuration symmetry of the original Co 3d orbital,lower the dband center of the Co site,and optimize the desorption behavior of*OH intermediate,thereby increasing the ORR activity.

关键词： metal organic frameworks oxygen reduction reaction dual-atom catalyst coordination-environment regulation zinc-air batteries

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