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Journal of Environmental Sciences 2024年第2期136卷 35-44页

作者： Yunhua Zhang Diming Lou Piqiang Tan Zhiyuan Hu Liang Fang School of Automotive studies Tongji UniversityShanghai 201804China

In this study,the effect of new and used catalyzed diesel particulate filter(CDPF)with different catalyst loadings on the particulate emissions including the particle mass(PM),particle number(PN),particle size distribution(PSD)and geometric mean diameter(GMD)from a diesel vehicle were investigated based on a heavy chassis *** showed that more than 97.9%of the PN and 95.4%of the PM were reduced by the CDPF,and the reduction efficiency was enhanced by the catalyst *** using the CDPF,the PSD transformed from bimodal to trimodal with the peak shifting towards smaller particle size,more nucleation mode particles were reduced compared with accumulation mode ones,but the reduction effect on the accumulation mode particles was more significantly influenced by the catalyst ***,the CDPF increased the accumulation mode particles proportion,producing a larger *** the used CDPF,its reduction effect on the particulate emissions enhanced,especially for the PM in accumulation *** PSD returned to bimodal,but the peak at accumulation mode began to be higher than that at nucleation mode,illustrating that more nucleation mode particles was *** aging of the CDPF resulted in greater effect on the PN-based PSD than that of PM-based PSD,but the effect of catalyst loading on the PN and PM emission factors was *** used CDPF further increased the GMD,and the effect of catalyst loading on the GMD was strengthened,a higher catalyst loading led to a reduction in the GMD.

关键词： Catalyzed diesel particulate filter (CDPF) Catalyst loading Aging Particle Particle size distribution Geometric mean diameter

Development of advanced anion exchange membrane from the view of the performance of water electrolysis cell

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Journal of Energy Chemistry 2024年第3期90卷 348-369,I0009页

作者： Chao Liu Zhen Geng Xukang Wang Wendong Liu Yuwei Wang Qihan Xia Wenbo Li Liming Jin Cunman Zhang Clean Energy Automotive Engineering Center Tongji UniversityShanghai 201804China School of Automotive studies Tongji UniversityShanghai 201804China

Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon *** water electrolysis technologies,the anion exchange membrane(AEM) water electrolysis has gained intensive attention and is considered as the next-generation emerging technology due to its potential advantages,such as the use of low-cost non-noble metal catalysts,the relatively mature stack assembly process,***,the AEM water electrolyzer is still in the early development stage of the kW-level stack,which is mainly attributed to severe performance decay caused by the core component,i.e.,***,the review comprehensively presents the recent progress of advanced AEM from the view of the performance of water electrolysis ***,fundamental principles and critical components of AEM water electrolyzers are introduced,and work conditions of AEM water electrolyzers and AEM performance improvement strategies are *** challenges and perspectives are also analyzed.

关键词： Hydrogen Water electrolysis Anion exchange membrane Electrolysis cell

Recent advances and future prospects on Ni_(3)S_(2)-Based electrocatalysts for efficient alkaline water electrolysis

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Green Energy & Environment 2024年第4期9卷 659-683页

作者： Shiwen Wang Zhen Geng Songhu Bi Yuwei Wang Zijian Gao Liming Jin Cunman Zhang Clean Energy Automotive Engineering Center School of Automotive StudiesTongji UniversityShanghai201804China

Green hydrogen(H_(2))produced by renewable energy powered alkaline water electrolysis is a promising alternative to fossil fuels due to its high energy density with zero-carbon ***,efficient and economic H_(2) production by alkaline water electrolysis is hindered by the sluggish hydrogen evolution reaction(HER)and oxygen evolution reaction(OER).Therefore,it is imperative to design and fabricate high-active and low-cost non-precious metal catalysts to improve the HER and OER performance,which affects the energy efficiency of alkaline water ***_(3)S_(2) with the heazlewoodite structure is a potential electrocatalyst with near-metal conductivity due to the Ni–Ni metal ***,the review comprehensively presents the recent progress of Ni_(3)S_(2)-based electrocatalysts for alkaline water ***,the HER and OER mechanisms,performance evaluation criteria,preparation methods,and strategies for performance improvement of Ni_(3)S_(2)-based electrocatalysts are *** challenges and perspectives are also analyzed.

关键词： Alkaline water electrolysis Hydrogen Electrocatalysts Ni_(3)S_(2)

Thermal characteristic evolution of lithium-ion batteries during the whole lifecycle

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Journal of Energy Chemistry 2024年第5期92卷 534-547页

作者： Guangxu Zhang Xuezhe Wei Donghai Chen Xueyuan Wang Siqi Chen Jiangong Zhu Haifeng Dai School of Materials Science and Engineering Tongji UniversityShanghai 201804China Clean Energy Automotive Engineering Center Tongji UniversityShanghai 201804China School of Automotive studies Tongji UniversityShanghai 201804China

This work extensively investigates the thermal characteristic evolution of lithium-ion batteries under different degradation paths,and the evolution mechanism through multi-angle characterization is *** different degradation paths,the evolution trend of temperature rise rate remains unchanged with respect to depth of discharge during the adiabatic discharge process,albeit to varying degrees of *** temperature rise rate changes significantly with aging during the adiabatic discharge process under low-temperature cycling and high-rate cycling *** total heat generation rate,irreversible heat generation rate,and reversible heat generation rate exhibit similar evolution behavior with aging under different degradation *** interval range of endothermic process of reversible electrochemical reactions increases and the contribution of irreversible heat to the total heat increases with *** further standardize the assessment of different degradation paths on the thermal characteristics,this work introduces the innovative concept of“Ampere-hour temperature rise”.In low-temperature cycling and high-rate cycling paths,the ampere-hour temperature rise increases significantly with aging,particularly accentuated with higher discharge ***,in high-temperature cycling and high-temperature storage paths,the ampere-hour temperature rise remains relatively stable during the initial stages of aging,yet undergoes a notable increase in the later stages of *** multi-angle characterization reveals distinct thermal evolution behavior under different degradation paths primarily attributed to different behavior changes of severe side reactions,such as lithium *** findings provide crucial insights for the safe utilization and management of lithium–ion batteries throughout the whole lifecycle.

关键词： Lithium-ion batteries Adiabatic discharge Thermal characteristics Ampere-hour temperaturerise Degradation

Evolutionary Decision-Making and Planning for Autonomous Driving Based on Safe and Rational Exploration and Exploitation

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Engineering 2024年第2期33卷 108-120页

作者： Kang Yuan Yanjun Huang Shuo Yang Zewei Zhou Yulei Wang Dongpu Cao Hong Chen College of Electronic and Information Engineering Tongji UniversityShanghai 201804China shanghai Institute of Intelligent Science and Technology Tongji UniversityShanghai 201210China School of Automotive studies Tongji UniversityShanghai 201804China School of Vehicle and Mobility Tsinghua UniversityBeijing 100084China

Decision-making and motion planning are extremely important in autonomous driving to ensure safe driving in a real-world *** study proposes an online evolutionary decision-making and motion planning framework for autonomous driving based on a hybrid data-and model-driven ***,a data-driven decision-making module based on deep reinforcement learning(DRL)is developed to pursue a rational driving performance as much as ***,model predictive control(MPC)is employed to execute both longitudinal and lateral motion planning *** constraints are defined according to the vehicle’s physical limit to meet the driving task ***,two principles of safety and rationality for the self-evolution of autonomous driving are proposed.A motion envelope is established and embedded into a rational exploration and exploitation scheme,which filters out unreasonable experiences by masking unsafe actions so as to collect high-quality training data for the DRL *** with a high-fidelity vehicle model and MATLAB/Simulink co-simulation environment are conducted,and the results show that the proposed online-evolution framework is able to generate safer,more rational,and more efficient driving action in a real-world environment.

关键词： Autonomous driving Decision-making Motion planning Deep reinforcement learning Model predictive control

Photocatalytic vinyl radical-mediated multicomponent 1,4-/1,8-carboimination across alkynes and olefins/(hetero)arenes

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Science China Chemistry 2024年第2期67卷 558-567页

作者： Shan-Shan Li Yu-Shi Jiang Xue-Ling Luo Xuming Ran Yuqiang Li Dong Wu Cheng-Xue Pan Peng-Ju Xia School of Chemistry and Pharmaceutical Sciences Guangxi Normal UniversityGuilin541004China shanghai Artificial Intelligence Laboratory Shanghai200433China The Institute for Advanced studies Wuhan UniversityWuhan430064China

We developed a highly selective and efficient multicomponent transformation by utilizing alkynes and olefins/(hetero)arenes through photoinduced energy-transfer *** reaction involves the formation of three distinct chemical bonds,namely C(sp~3)–C(sp~2),C(sp~2)–C(sp~3),and C(sp~3)–N,in a single coordinated *** strategy used a vinyl radical-mediated radical relay approach under mild conditions,exhibiting a broad substrate scope(>70 examples),excellent functional-group tolerance,and remarkable regio-and *** the utilization of a combination of experimental techniques and density functional theory(DFT),we delved deeper into the mechanistic intricacies of this distinctive *** revealed that the selective radical addition to electron-deficient alkynes,rather than olefins,was governed by the inherent reactivity of alkyl *** discovery presented a highly effective approach for the synthesis of stereodefined multisubstituted alkenes.

关键词： alkyne-olefin coupling DFT studies regio-and anti-stereoselectivity multisubstituted alkenes

Attitude control of multi-spacecraft systems on SO(3)with stochastic links failure

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Chinese Journal of Aeronautics 2024年第3期37卷 320-331页

作者： KANG Zeyu SHEN Qiang WU Shufan Chris J.DAMAREN MU Zhongcheng School of Aeronautics and Astronautics Shanghai Jiao Tong UniversityShanghai 200240China Institute for Aerospace studies University of TorontoTorontoOntario M3H 5T6Canada

In this paper,for Multi-Spacecraft System(MSS)with a directed communication topology link and a static virtual leader,a controller is proposed to realize attitude consensus and attitude stabilization with stochastic links failure and actuator ***,an MSS attitude error model suitable for a directed topology link and with a static virtual leader based on SO(3)is derived,which considers that the attitude error on SO(3)cannot be defined based on algebraic ***,we design a controller to realize the MSS on SO(3)with attitude consensus and attitude stabilization under stochastic links failure and actuator ***,the simulation results of a multi-spacecraft system with stochastic links failure and a static virtual leader spacecraft are demonstrated to illustrate the efficiency of the attitude controller.

关键词： Multi-spacecraft systems Attitude consensus Attitude stabilization Stochastic links failure Super-martingale convergence

Accurate Shortwave Radiation Simulation with a Two-Layer Aerosol Model in Xinjiang Region

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Journal of Meteorological Research 2024年第1期38卷 69-87页

作者： Guan HUANG Yonghang CHEN Qiong LIU Pengtao WANG Qianshan HE Qing HE Shuai LI Weiling SHAO Ting FAN School of Tourism&Research Institute of Human Geography Xi’an International Studies UniversityXi’an 710128 Center for Silk Road and Eurasian Civilization studies Xi’an International Studies UniversityXi’an 710128 College of Environmental Science and Engineering Donghua UniversityShanghai 201620 shanghai Meteorological Service Shanghai 200030 shanghai Key Laboratory of Meteorology and Health Shanghai 200030 Taklimakan Desert Meteorology Field Experiment Station of China Meteorological Administration Institute of Desert MeteorologyUrumqi 830002 Xinjiang Climate Centre Xinjiang Meteorological ServiceUrumqi 830002

To harness the rich solar energy resources in Xinjiang Region of Northwest China,this study tries to address the issue of lack of downward surface shortwave radiation(DSSR)observations and the need to improve the accuracy of satellite retrieval and numerical simulation of DSSR under varied sky and meteorological conditions.(1)A two-layer aerosol model specific to Xinjiang was developed to capture the vertical distributions of aerosols based on multiple data sources including lidar,GPS sounding,ground meteorological observations,and profiles from the ECMWF reanalysis version 5(ERA5)*** results show that the ERA5/PBLH(planetary boundary layer height)and ERA5/ALH(aerosol layer height)could be used to establish the two-layer aerosol model and characterize the vertical distribution of aerosols in Xinjiang Region.(2)Using the Santa Barbara Discrete Atmospheric Radiative Transfer(SBDART)model,a localized inverse model of clear-sky DSSR was *** parameter adjustment and using the optimal combination of input parameters for DSSR simulation together with the two-layer aerosol model,the model-simulated DSSR(DSSRSBD)under clear-sky conditions improved significantly compared to the initial results,with all fitting indices greatly improved.(3)In addition,the study demonstrated that the impact of the two-layer aerosol model on DSSR was more pronounced under dust conditions than clear-sky conditions.(4)Using the localized clear-sky DSSR inversion model and its required parameters,simulations were also conducted to capture the spatiotemporal distribution of DSSR under clear-sky conditions in Xinjiang from 2017 to *** annual average DSSR_(SBD)under clear-sky conditions in Xinjiang during 2017–2019 was 606.78 W m^(-2),while DSSR from CERES(DSSR_(CER))under the same conditions was generally higher(703.95 W m^(-2)).(5)It is found that satellite remote sensing products experienced data loss in high-altitude snow areas,where numerical simulation technology could ser

关键词： downward surface shortwave radiation(DSSR) aerosol vertical distribution Clouds and the Earth’s Radiant Energy System(CERES) Santa Barbara Discrete Atmospheric Radiative Transfer(SBDART) Xinjiang

Recent progress of self-supported air electrodes for flexible Zn-air batteries

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Journal of Energy Chemistry 2024年第2期89卷 110-136,I0004页

作者： Chen Xu Yanli Niu Vonika Ka-Man Au Shuaiqi Gong Xuan Liu Jianying Wang Deli Wu Zuofeng Chen School of Chemical Science and Engineering Tongji UniversityShanghai 200092China College of Environmental Science&Engineering Tongji UniversityShanghai 200092China Department of Science and Environmental studies The Education University of Hong KongHong KongChina

Smart wearable devices are regarded to be the next prevailing technology product after smartphones and smart homes,and thus there has recently been rapid development in flexible electronic energy storage *** them,flexible solid-state zinc-air batteries have received widespread attention because of their high energy density,good safety,and *** bifunctional oxygen electrocatalysts are the primary consideration in the development of flexible solid-state zinc-air batteries,and self-supported air cathodes are strong candidates because of their advantages including simplified fabrication process,reduced interfacial resistance,accelerated electron transfer,and good *** review outlines the research progress in the design and construction of nanoarray bifunctional oxygen *** from the configuration and basic principles of zinc-air batteries and the strategies for the design of bifunctional oxygen electrocatalysts,a detailed discussion of self-supported air cathodes on carbon and metal substrates and their uses in flexible zinc-air batteries will ***,the challenges and opportunities in the development of flexible zinc-air batteries will be discussed.

关键词： Bifunctional electrocatalysts Oxygen reduction reaction Oxygen evolution reaction Self-supported air electrodes Flexible zinc-air batteries

SO_(2)-Insertion induced enantioselective oxysulfonylation to access β-chiral sulfones with quaternary carbon stereocenters

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Science China Chemistry 2024年第3期67卷 908-913页

作者： Jun Zhang Xuefeng Wang Peiqi Wang Jiayuan Fang Shaoyu Li Jie Wu School of Pharmaceutical and Chemical Engineering&Institute for Advanced studies Taizhou UniversityShanghai 200438China Department of Chemistry Fudan UniversityShanghai 200438China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China School of Chemistry and Chemical Engineering Henan Normal UniversityXinxiang 453007China

β-Chiral sulfones are structural motifs widely found in natural products and bioactive molecules, while also serving as important intermediates for the synthesis of valuable chiral scaffolds. In contrast to the rapid growth of sulfur dioxide insertion chemistry over the last decade, enantioselective catalytic variants for accessing β-chiral sulfones, especially those bearing a quaternary carbon stereocenter, remain rare. Herein, we report an enantioselective copper/bisoxazoline catalyzed oxysulfonylation of alkenes to yield isoxazolinyl-containing β-chiral sulfones bearing quaternary carbon stereocenters with moderate to excellent yields and up to 96:4 er. The advantage and irreplaceability of this sulfur dioxide insertion catalytic system have been demonstrated by achieving transformations clearly unavailable with the previously reported sulfonyl chloride system. Additionally,the recoverability of the new-developed bisoxazoline ligand L9 and its reusability without any erosion of the catalytic activity and enantioselectivity further demonstrate the usefulness of the protocol.

关键词： β-chiral sulfones sulfur dioxide insertion oxysulfonylation copper catalysis enantioselectivity