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Chinese Journal Of Geochemistry 2015年第3期34卷 311-319页

作者： Ping Li Junfang Zhang Jianxu Wang Zhonggen Li State key laboratory of Environmental Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guizhou provincial key laboratory of water pollution control and resource reuse

Mercury pollution resulting from artisanal gold mining is a serious environmental problem in many developing countries. In this study, we analyzed heavy metal(loid) contamination in mine wastes from a Carlin-type gold mine in southwestern Guizhou, China. Highly elevated levels of As, Hg, Tl, Sb, and Cd—up to 5844, 28,29, 581 and 3.0 mg/kg, respectively—were observed in the mine wastes, but no significant accumulation of Cr, Ni, Cu,Zn, and Pb was found. The smelting process of gold ores had significant impacts on the enrichment of As, Tl, and Hg in the mine wastes. Due to the significant metal(loid)pollution in this gold mine, the ecological risks are classified as ‘‘very high.'' Hg and As are the major pollutants with a relative contribution of 55.9 % and 24.2 % to the risk index, respectively. Phytoremediation could be used to reduce heavy metal contamination and recycle the gold simultaneously. Hg–As–Tl pollution should be considered in gold extraction at Carlin-type gold mines.

关键词：卡林型金矿重金属污染废弃物污染发展中国家矿山废弃物西南部环境影响贵州

Occurrence, partition behavior, source and ecological risk assessment of nitro-PAHs in the sediment and water of Taige Canal, China

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Journal of Environmental Sciences 2023年第2期124卷 782-793页

作者： Jijie Kong Tao Ma Xiaoyu Cao Weidi Li Fengxiao Zhu Huan He Cheng Sun Shaogui Yang Shiyin Li Qiming Xian School of Environment Nanjing Normal UniversityNanjing 210023China School of Geography Nanjing Normal UniversityNanjing 210023China The State key laboratory of pollution control and resource reuse School of the EnvironmentNanjing UniversityNanjing 210023China Fujian provincial key laboratory of Eco-Industrial Green Technology College of Ecological and Resource EngineeringWuyi UniversityWuyishan 354300China Nanjing Institute of Environmental Sciences Ministry of Ecology and EnvironmentNanjing 210042China

Nitrated polycyclic aromatic hydrocarbons(NPAHs)are widespread organic pollutants that possess carcinogenic and mutagenic properties,so they may pose a risk to the environment and human health.In this study,the concentrations of 15 NPAHs and 16 polycyclic aromatic hydrocarbons(PAHs)in 30 surface water samples and 26 sediment samples were measured in 2018 from the Taige Canal,one of the main rivers flowing into Taihu Lake,China.The total NPAH concentrations in water and sediment ranged from 14.7 to 235 ng/L and 22.9 to 96.5 ng/g dw,respectively.9-nitrophenanthrene(nd–76.3 ng/L)was the dominant compound in surface water,while 2+3-nitrofluoranthene(1.73–18.1 ng/g dw)dominated in sediment.Among PAHs,concentration ranging from 1,097 to 2,981 ng/L and 1,089 to 4,489 ng/g dw in surface water and sediment,respectively.There was a strong positive correlation between the log octanol-water partition coefficient(Kow)and log sediment-water partition coefficient due to hydrophobic interaction.The fugacity fraction value increased with the decrease of log Kow,and chrysene was transferred from water into sediment.The residual NPAHs in surface water and sediment of the Taige Canal have partial correlation.Diesel engine and coal combustion emissions were probably the principal sources of NPAHs in surface water and sediment.The results of ecological risk assessment showed that some NPAHs inwater(e.g,1-nitropyrene and 6-nitrochrysene)and sediment(e.g.,2-nitrobiphenyl,5-nitroacenaphthene,9-nitrophenanthrene and 2+3-nitrofluoranthene)had moderate ecological risks,which should be of concern.

关键词： Nitrated polycyclic aromatic hydrocarbons(NPAHs) Occurrence Partition behavior Source apportionment Ecological risk assessment

Retrofitting low-performance units to abate sewer overflow pollution based on mathematical model and Sobol algorithm

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Journal of Hydrodynamics 2023年第4期35卷 770-781页

作者： Zhi-chao Zhao Xiao-min Huang Hai-long Yin Jun-bo Wen Xiao-wei Fu Changjiang Institute of Survey PlanningDesign and ResearchWuhan430010China key laboratory of Yangtze River water Environment Ministry of EducationTongji UniversityShanghai200092China State key laboratory of pollution control and resource reuse College of Environmental Science and EngineeringTongji UniversityShanghai200092China Hubei provincial Engineering Research Center for Comprehensive water Environment Treatment in the Yangtze River Basin Wuhan430010China key laboratory of Urban water Supply Water Saving and Water Environment Governance in the Yangtze River Delta of Ministry of Water ResourcesShanghai200092China

Optimal retrofit of low-performance units(LPUs)is promising to abate overflow pollutant mass loading of sewer systems during wet-weathers.This study presents a combination of mathematical model and Sobol algorithm to help identify LPUs of sewer systems and design retrofitting strategies.Therefore,the solution to minimize the overflow pollutant mass loading from sewers systems can be efficiently obtained.The developed method was demonstrated at a catchment served by one wastewater treatment plant in the Chaohu City,Anhui Province of China,with five pumping stations and a total sewer length of 58.3 km.Within the catchment,there are three rivers and a small lake to receive overflows from the sewer system.Among them,one river that was mostly polluted was selected as the object of overflow pollution abatement during wet weather period.After identifying the LPUs of the sewer system and developing retrofitting strategies using Sobol sequence,the mitigation of overflow pollution during wet weather period was analyzed.Results show that the mass loading of chemical oxygen demand(COD)discharged into the target river could be reduced by 40.6%,by implementing optimal retrofit strategy of LPUs,i.e.,increasing the conveyance capacities of two pumping stations by 2.5–3.2 times and augmenting the diameters of 12 sewers by 1.25–1.29 times.To further coordinate the abatement of overflow pollution and retrofit investment,Sobol sensitivity analysis was conducted to screen the dominant LPUs to update the optimal retrofit strategy.By applying the updated strategy,the overflow COD mass loading per overflow event was close to that of non-updated strategy,while the retrofitting length of sewers was reduced by 40%.Therefore,on the basis of the presented method,decision-makers can flexibly develop retrofitting strategies of sewer system to abate overflow pollution during wet weathers in a cost-effective way.

关键词： Urban sewer system low-performance units Sobol sensitivity analysis sewer overflow optimal retrofit strategy

ZnWO_(4)-ZnIn_(2)S_(4) S-scheme heterojunction for enhanced photocatalytic H_(2) evolution

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Journal of Materials Science & Technology 2022年第27期122卷 231-242页

作者： Meng Dai Zuoli He Peng Zhang Xin Li Shuguang Wang shandong key laboratory of water pollution control and resource reuse School of Environmental Science and EngineeringShandong UniversityQingdao266237China Suzhou Research Institute Shandong UniversitySuzhou 215123China State Center for International Cooperation on Designer Low-Carbon and Environmental Materials(CDLCEM) School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China key laboratory of Energy Plants resource and Utilization Ministry of Agriculture and Rural AffairsSouth China Agricultural UniversityInstitute of Biomass EngineeringGuangzhou 510642China

The recombination of photogenerated electrons and holes is a crucial factor limiting photocatalytic H_(2)evolution.The S-scheme ZnWO_(4)-ZnIn_(2)S_(4)heterojunction with 2D coupling interfaces was successfully synthesized using a simple solvothermal method.An effective S-scheme interfacial charge migration route at the S-scheme heterogeneous interface was determined by energy band structure analyses(such as UPS,Mott-Schottky and XPS plots),which facilitates the separation of photoexcited carriers.It is worth noting that the optimal ZnWO_(4)-ZnIn_(2)S_(4)composite has an H_(2)evolution activity of 4925.3μmol g^(-1)h^(-1)with favourable photostability and stability.Meanwhile,the ZnWO_(4)-Zn In_(2)S_(4)heterojunction exhibits the maximum optical response value(2.8 m A cm-2)in the initial stage,effectively promoting the separation and migration of photogenerated carriers.The establishment of the built-in electric field direction at the interface can effectively promote the space charge separation between the ZnWO_(4)and ZnIn_(2)S_(4)nanosheets,which is favorable to the photocatalytic H_(2)evolution.This work provides valuable guidance for designing S-scheme heterojunction photocatalysts composed of two n-type semiconductors for energy and environmental applications.The recombination of photogenerated electrons and holes is a crucial factor limiting photocatalytic H_(2)evolution.The S-scheme ZnWO_(4)-ZnIn_(2)S_(4)heterojunction with 2D coupling interfaces was successfully synthesized using a simple solvothermal method.An effective S-scheme interfacial charge migration route at the S-scheme heterogeneous interface was determined by energy band structure analyses(such as UPS,Mott-Schottky and XPS plots),which facilitates the separation of photoexcited carriers.It is worth noting that the optimal ZnWO_(4)-ZnIn_(2)S_(4)composite has an H_(2)evolution activity of 4925.3μmol g^(-1)h^(-1)with favourable photostability and stability.Meanwhile,the ZnWO_(4)-ZnIn_(2)S_(4)heterojunction exhibits the maximum optical response value

关键词： Photocatalysts H_(2)evolution S-scheme heterojunction Internal electric field ZnWO_(4)-ZnIn_(2)S_(4)nanosheets

Surface sulfur vacancies enhanced electron transfer over Co-ZnS quantum dots for efficient degradation of plasticizer micropollutants by peroxymonosulfate activation

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Chinese Chemical Letters 2022年第8期33卷 3829-3834页

作者： Yuting Gu Tingting Gao Fagen Zhang Chao Lu Wenrui Cao Ziwei Fu Chun Hu Lai Lyu key laboratory for water Quality and Conservation of the Pearl River Delta Ministry of EducationInstitute of Environmental Research at Greater BayGuangzhou UniversityGuangzhou 510006China shandong key laboratory of water pollution control and resource reuse School of Environmental Science and EngineeringShandong UniversityQingdao 266237China School of Environmental Science and Engineering Guangzhou UniversityGuangzhou 510006China Institute of Rural Revitalization Guangzhou UniversityGuangzhou 510006China

Peroxymonosulfate(PMS)activation in heterogeneous processes is a promising water treatment technology.Nevertheless,the high energy consumption and low efficiency during the reaction are ineluctable,due to electron cycling rate limitation.Herein,a new strategy is proposed based on a quantum dots(QDs)/PMS system.Co-ZnS QDs are synthesized by a water phase coprecipitation method.The inequivalent lattice-doping of Co for Zn leads to the generation of surface sulfur vacancies(SVs),which modulates the surface of the catalyst to form an electronic nonequilibrium surface.Astonishingly,the plasticizer micropollutants can be completely degraded within only tens of seconds in the Co-Zn S QDs/PMS system due to this type of surface modulation.The interfacial reaction mechanism is revealed that pollutants tend to be adsorbed on the cobalt metal sites as the electron donors,where the internal electrons of pollutants are captured by the metal species and transferred to the surface SVs.Meanwhile,PMS adsorbed on the SVs is reduced to radicals by capturing electrons,achieving effective electron recovery.Dissolved oxygen(DO)molecules are also easily attracted to catalyst defects and are reduced to O_(2)^(·-),further promoting the degradation of pollutants.

关键词： Peroxymonosulfate activation Sulfur vacancy Quantum dots ZnS Plasticizer

A study on singlet oxygen generation for tetracycline degradation via modulating the size ofα-Fe_(2)O_(3)nanoparticle anchored on g-C_(3)N_(4) nanotube photocatalyst

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Nano Research 2023年第2期16卷 2236-2244页

作者： Hongjie Zhu Minghui Li Luning Zou Youyou Hu Hongguo Hao Jianmin Dou Junjie Mao shandong provincial key laboratory of Chemical Energy Storage and Novel Cell Technology School of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059China key laboratory of Functional Molecular Solids Ministry of EducationCollege of Chemistry and Materials ScienceAnhui Normal UniversityWuhu 241002China State key laboratory of pollution control and resource reuse School of the EnvironmentNanjing UniversityNanjing 210023China Gaotang liguo chemical plant Liaocheng 252059China

Photocatalysis is considered as an effective technique for mitigating ecological risks posed by residual tetracycline(TC).To improve the efficiency of this technique,it is necessary to enable photocatalysts to produce highly reactive species,such as singlet oxygen(1O2).However,due to the high activation energy of 1O2,photocatalysts can hardly produce 1O2 without assistance from external oxidants.Herein,we find that the size-reducedα-Fe_(2)O_(3)nanoparticles(~4 nm)that anchored on g-C_(3)N_(4)nanotube(α-Fe_(2)O_(3)@CNNT)can spontaneously generate ^(1)O_(2) for degradation of TC.In comparison,only hydroxyl radical(·OH)can be produced by g-C_(3)N_(4)nanotube loaded with~14 nmα-Fe_(2)O_(3)nanoparticles(α-Fe_(2)O_(3)/CNNT).Owing to the high reactivity of the ^(1)O_(2) species,the photocatalytic degradation rate(Kapp)of TC withα-Fe_(2)O_(3)@CNNT(0.056 min^(−1))was 1.8 times higher than that ofα-Fe_(2)O_(3)/CNNT.The experimental results and theoretical calculations suggested that reducing the size ofα-Fe_(2)O_(3)nanoparticles anchored on g-C_(3)N_(4)nanotube decreased the surface electron density ofα-Fe_(2)O_(3),which induces the generation of high-valent Fe(IV)active sites overα-Fe_(2)O_(3)@CNNT and turns the degradation pathway into a unique ^(1)O_(2) dominated process.This study provides a new insight on the generation of ^(1)O_(2) for effective degradation of environmental pollutant.

关键词： singlet oxygen degradation pathway high-valent Fe(IV) tetracycline degradation

Properties and mechanism of red mud in preparation of ultra-lightweight sludge-red mud ceramics

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Journal of Central South University 2012年第1期19卷 231-237页

作者：陆达伟齐元峰岳钦艳郗斐高宝玉 shandong key laboratory of water pollution control and resource reuse School of Environment Science and EngineeringShandong UniversityJi’nan 250100China

New ultra-lightweight sludge-red mud ceramics(ULS-RMC) were prepared by red mud(RM),clay and dried sewage sludge(DSS).The properties and mechanism of RM in the preparation of ULS-RMC were discussed.The chemical components,thermal properties and mineral phases of RM were determined by energy dispersive X-ray(EDX),differential scanning calorimetry/thermal gravimetric analysis(DSC/TGA) and X-ray diffraction(XRD),respectively.Constant dosage of DSS to clay and different amounts of RM were utilized in the preparation of ULS-RMC.Physical properties test(bulk density,grain density,water absorption and expansion ratio),XRD and scanning electron microscopy(SEM) were employed to characterize the ULS-RMC.The results show that RM exhibits high hydroscopic property and good water-retention property,and bloating property and fluxing property of RM are caused by abound of gaseous components and flux,respectively.The two chemical properties are utilized to discuss the mineral phases and microstructures differences between ULSC and ULS-RMC.

关键词：化学性质轻量级赤泥污泥机制陶瓷 X射线衍射扫描电子显微镜

Application of Fe^Ⅲ-TAML/H2O_(2) system for treatment of fluoroquinolone antibiotics

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Journal of Environmental Sciences 2021年第1期33卷 110-118页

作者： Zeyu Xian Sijia Liang Xin Jin Haoting Tian Jingyi Ling Chao Wang State key laboratory of pollution control and resource reuse School of the EnvironmentNanijing UniversityNanjing 210023China shandong Prouincial key laboratory of water and Soil Conservation and Enuironmental Protection College of Resource and EnvironmentLinyi UniversityLinyi 276005China

Over the recent past,fluoroquinolone antibiotics(FQs)have raised extensive attention due to their potential to induce the formation of resistance genes and"superbugs",thus various advanced oxidation techniques have been developed to eliminate their release into the environment.In the present study,the prototype tetraamido macrocyclic ligand(Fe^Ⅲ-TAML)/hydrogen peroxide(H2O_(2))system is employed to degrade FQs(i.e.,norfloxacin and ciprofloxacin)over a wide p H range(i.e.,p H 6-10),and the reaction rate increases with the increase in p H level.The effect of dosage of Fe^Ⅲ-TAML and H2O_(2) on the degradation of FQs is evaluated,and the reaction rate is linearly correlated with the added amount of chemicals.Moreover,the impact of natural organic matters(NOM)on the removal of FQs is investigated,and the degradation kinetics show that both NOM type and experimental concentration exhibit negligible influence on the oxidative degradation of selected antibiotics.Based on the results of liquid chromatography-high resolution mass spectrometry and theoretical calculations,the reaction sites and pathways of FQs by Fe^Ⅲ-TAML/H2O_(2) system are further predicted and elucidated.

关键词： Fluoroquinolone antibiotics Tetraamido macrocyclic ligand Catalytic degradation Natural organic matters

Facile one-step synthesis of functionalized biochar from sustainable prolifera-green-tide source for enhanced adsorption of copper ions

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Journal of Environmental Sciences 2018年第11期30卷 185-194页

作者： Yuan Gao Xiuzhen Zhu Qinyan Yue Baoyu Gao shandong provincial key laboratory of water pollution control and resource reuse School of Environmental Science and Engineering Shandong University Jinan 250100 China key laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education) School of Environmental Science and Technology Dalian University of Technology Linggong Road 2 Dalian 116024 China

The use of biochars formed by hydrothermal carbonization for the treatment of contaminated water has been greatly limited, due to their poorly developed porosity and low content of surface functional groups. Also, the most common modification routes inevitably require post-treatment processes, which are time-consuming and energy-wasting. Hence, the objective of this research was to produce a cost-effective biochar with improved performance for the treatment of heavy metal pollution through a facile one-step hydrothermal carbonization process coupled with ammonium phosphate, thiocarbamide, ammonium chloride or urea, without any posttreatment. The effects of various operational parameters, including type of modification reagent, time and temperature of hydrothermal treatment, and ratio of modification reagent to precursor during impregnation, on the copper ion adsorption were examined. The adsorption data fit the Langmuir adsorption isotherm model quite well. The maximum adsorption capacities （mg/g） of the biochars towards copper ions followed the order of 40-8h-1.0-APBC （95.24）〉 140-Sh-O-BC （12.52）〉 140-8h-1.0-TUBC （12.08）〉 140-Sh-1.0-ACBC （7.440）〉 140-Sh-1.0-URBC （5.277）. The results indicated that biochars modified with ammonium phosphate displayed excellent adsorption performance toward copper ions, which was 7.6-fold higher than that of the pristine biochar. EDX and FT-IR analyses before and after adsorption demonstrated that the main removal mechanism involved complexation between the phosphate groups on the surface of the modified biochars and copper ions.

关键词： Hydrothermal carbonization Functionalized biochar Adsorption Heavy metal

Qualitatively and quantitatively assessing the aggregation ability of sludge during aerobic granulation process combined XDLVO theory with physicochemical properties

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Journal of Environmental Sciences 2018年第5期30卷 154-160页

作者： Shasha Yuan Mingming Gao Hui Ma Muhammad Zaheer Afzal Yun-Kun Wang Mingyu Wang Hai Xu Shu-Guang Wang Xin-Hua Wang shandong provincial key laboratory of water pollution control and resource reuse School of Environmental Science and EngineeringShandong UniversityJinan 250100China Beijing Municipal Commission of Urban Planning Tongzhou District Branch Beijing 101101China State key laboratory of Microbial Technology School of Life SciencesShandong UniversityJinan 250100China

Inexact mechanism of aerobic granulation still impedes optimization and application of aerobic granules. In this study, the extended Derjaguin, Landau, Verwey, and Overbeek（XDLVO） theory and physicochemical properties were combined to assess the aggregation ability of sludge during aerobic granulation process qualitatively and quantitatively. Results show that relative hydrophobicity of sludge and polysaccharide content of extracellular polymeric substances（EPS） increased, while electronegativity of sludge decreased during acclimation phase. After 20 days＇ acclimation, small granules began to form due to high aggregation ability of sludge. Since then, coexisted flocs and granules possessed distinct physicochemical properties during granulation and maturation phase. The relative hydrophobicity decreased while electronegativity increased for flocs, whereas that for granules presented reverse trend. Through analyzing the interaction energy using the XDLVO theory, small granules tended to self-grow rather than self-aggregate or attach of flocs due to poor aggregation ability between flocs and granules during the granulation phase. Besides, remaining flocs were unlikely to self-aggregate owing to poor aggregation ability, low hydrophobicity and high electronegativity.

关键词： Aerobic granulation XDLVO theory Aggregation ability Extracellular polymeric substances