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Nano-Au-decorated hierarchical porous cobalt sulfide derived from ZIF-67 toward optimized oxygen evolution catalysis:Important roles of microstructures and electronic modulation

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Carbon energy 2024年第5期6卷 1-14页

作者： Hongyu Gong Guanliang Sun Wenhua Shi Dongwei Li Xiangjun Zheng Huan Shi Xiu Liang Ruizhi Yang Changzhou Yuan Department of New energy Materials School of Environmental and Chemical EngineeringJiangsu University of Science and TechnologyZhenjiangJiangsuChina Advanced Materials institute Qilu University of Technology(Shandong Academy of Sciences)JinanShandongChina shandong Saikesaisi Hydrogen energy Co. Ltd.JinanShandongChina Department of Materials Science and Engineering School of Materials Science&EngineeringUniversity of JinanJinanShandongChina Department of New energy Science and Engineering College of EnergySoochow Institute for Energy and Materials InnovationsSoochow UniversitySuzhouJiangsuChina

Enhancing both the number of active sites available and the intrinsic activity of Co-based electrocatalysts simultaneously is a desirable ***,a ZIF-67-derived hierarchical porous cobalt sulfide decorated by Au nanoparticles(NPs)(denoted as HP-Au@CoxSy@ZIF-67)hybrid is synthesized by low-temperature sulfuration *** well-defined macroporous-mesoporous-microporous structure is obtained based on the combination of polystyrene spheres,as-formed CoxSy nanosheets,and ZIF-67 *** novel three-dimensional hierarchical structure significantly enlarges the three-phase interfaces,accelerating the mass transfer and exposing the active centers for oxygen evolution *** electronic structure of Co is modulated by Au through charge transfer,and a series of experiments,together with theoretical analysis,is performed to ascertain the electronic modulation of Co by ***,HP-Au@CoxSy@ZIF-67 catalysts with different amounts of Au were synthesized,wherein Au and NaBH4 reductant result in an interesting“competition effect”to regulate the relative ratio of Co^(2+)/Co^(3+),and moderate Au assists the electrochemical performance to reach the highest ***,the optimized HP-Au@CoxSy@ZIF-67 exhibits a low overpotential of 340 mV at 10 mA cm^(-2)and a Tafel slope of 42 mV dec-1 for OER in 0.1 M aqueous KOH,enabling efficient water splitting and Zn-air battery *** work here highlights the pivotal roles of both microstructural and electronic modulation in enhancing electrocatalytic activity and presents a feasible strategy for designing and optimizing advanced electrocatalysts.

关键词： Au nanoparticles cobalt sulfide electronic modulation hierarchical porous structure oxygen evolution reaction

Study of the reaction mechanism for preparing powdered activated coke with SO_(2)adsorption capability via one-step rapid activation method under flue gas atmosphere

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Chinese Journal of Chemical Engineering 2024年第1期65卷 158-168页

作者： Binxuan Zhou Jingcai Chang Jun Li Jinglan Hong Tao Wang Liqiang Zhang Ping Zhou Chunyuan Ma School of Environmental Science and Engineering Shandong UniversityQingdao 266237China School of energy and Power Engineering Shandong UniversityJinan 250061China Weihai Research institute of Industrial Technology of shandong University Weihai 264209China

In this study,the impact of different reaction times on the preparation of powdered activated carbon(PAC)using a one-step rapid activation method under flue gas atmosphere is investigated,and the underlying reaction mechanism is *** indicate that the reaction process of this method can be divided into three stages:stage I is the rapid release of volatiles and the rapid consumption of O_(2),primarily occurring within a reaction time range of 0-0.5 s;stage II is mainly the continuous release and diffusion of volatiles,which is the carbonization and activation coupling reaction stage,and the carbonization process is the main in this *** stage mainly occurs at the reaction time range of 0.5 -2.0 s when SL-coal is used as material,and that is 0.5-3.0 s when JJ-coal is used as material;stage III is mainly the activation stage,during which activated components diffuse to both the surface and interior of *** stage mainly involves the reaction stage of CO_(2)and H2O(g)activation,and it mainly occurs at the reaction time range of 2.0-4.0 s when SL-coal is used as material,and that is 3.0-4.0 s when JJ-coal is used as ***,the main function of the first two stages is to provide more diffusion channels and contact surfaces/activation sites for the diffusion and activation of the activated components in the third *** the reaction mechanism would serve as a crucial reference and foundation for designing the structure,size of the reactor,and optimal positioning of the activator nozzle in PAC preparation.

关键词： Reaction mechanism Powdered activated coke preparation SO_(2)adsorption One-step rapid activation Flue gas atmosphere

Analysis and Modeling of Calendar Aging and Cycle Aging of LiCoO_(2)/Graphite Cells

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Journal of Thermal Science 2024年第3期33卷 1109-1118页

作者： WANG Wei YUAN Baoqiang SUN Qie WENNERSTEN Ronald institute of Thermal Science and Technology Shandong UniversityJi’nan250061China School of energy and Power Engineering Shandong UniversityJi’nan250061China institute for Advanced Science and Technology Shandong UniversityJi’nan250061China

Lithium-ion batteries are used in a wide range of ***,their cycle life suffers from the problem of capacity fade,which includes calendar and cycle *** effects of storage time,temperature and partial charge-discharge cycling on the capacity fade of Li-ion batteries are investigated in this *** calendar aging and cycle aging are presented based on the storage and cycling experiment on LiCoO_(2)/graphite cells under different storage temperature and different ranges of state of charge(SOC).Based on the measurement data,a one-component and a double-component aging model are presented to respectively describe the capacity fade caused by calendar and cycle *** calendar aging of LiCoO_(2)/graphite batteries is mainly affected by temperature and SOC during the *** SOC and change in SOC(ΔSOC)are the main factors affecting battery degradation during cycling operation.

关键词： Lithium-ion battery LiCoO_(2)(LCO)/graphite calendar aging cycle aging lifetime model

Influence of substrate effect on near-field radiative modulator based on biaxial hyperbolic materials

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Chinese Physics B 2024年第4期33卷 56-64页

作者：刘睿一刘皓佗胡杨崔峥吴小虎 institute of Advanced Technology Shandong UniversityJinan 250061China shandong institute of Advanced Technology Jinan 250100China School of Power and energy Northwestern Polytechnical UniversityXi'an 710072China

Relative rotation between the emitter and receiver could effectively modulate the near-field radiative heat transfer(NFRHT)in anisotropic *** to the strong in-plane anisotropy,natural hyperbolic materials can be used to construct near-field radiative modulators with excellent modulation ***,in practical applications,natural hyperbolic materials need to be deposited on the substrate,and the influence of substrate on modulation effect has not been studied *** this work,we investigate the influence of substrate effect on near-field radiative modulator based onα-MoO_(3).The results show that compared to the situation without a substrate,the presence of both lossless and lossy substrate will reduce the modulation contrast(MC)for different film *** the real or imaginary component of the substrate permittivity increases,the mismatch of hyperbolic phonon polaritons(HPPs)weakens,resulting in a reduction in *** reducing the real and imaginary components of substrate permittivity,the MC can be significantly improved,reaching 4.64 forε_(s)=3 at t=10 *** work indicates that choosing a substrate with a smaller permittivity helps to achieve a better modulation effect,and provides guidance for the application of natural hyperbolic materials in the near-field radiative modulator.

关键词： near-field radiative modulator substrate effect hyperbolic material modulation contrast

Design Research of a Novel Aftercool-Humidifier Concept for Humid Air Turbine Cycle

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Journal of Thermal Science 2024年第3期33卷 951-969页

作者： ZHANG Junzheng XU Zhen School of energy and Power Engineering Shandong UniversityJi’nan250061China shandong Engineering Laboratory for High-efficiency energy Conservation and energy Storage Technology&Equipment Shandong UniversityJi’nan250061China

Humid air turbine cycle(HAT)has potential of electrical efficiencies comparable to combined cycle,with lower investment cost and NO_(x) *** typical heat exchanger network of HAT consists of intercooler(if there is),aftercooler,recuperator,economizer and humidifier,which brings higher efficiency but makes the system more *** simplify HAT layout,a novel humidifier concept is proposed by integrating the aftercooler into traditional counter-current *** on this concept,a one-dimensional model including pressure drop and exergy calculation is established to distinguish the thermodynamic and hydrodynamic characteristics,and then the structural parameters,such as the number of rows and columns,tube diameter,pitch and type for a micro HAT are *** results show that the aftercool-humidifier plays the same role as original aftercooler and humidifier,and can match the in-tube air,out-tube air and water stream well with lower *** the case of micro HAT cycle,the volume of heat and mass transfer area can be reduced by 47%compared with traditional *** major thermal resistance occurred in the convection heat transfer process inside the tube;however,using enhanced tube cannot effectively improve the compactness of device.

关键词： humid air turbine cycle humidifier thermodynamic analysis one-dimensional model

Preparation and Electrochemical Performance Study of Catalytic Cracking Oil Slurry-based Porous Carbon Materials

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China Petroleum Processing & Petrochemical Technology 2024年第2期26卷 34-45页

作者： Liu Qi Zhao Gaiju Liu Xingge Yu Hewei Sun Rongfeng Geng Wenguang School of energy and Power Engineering Qilu University of Technology(Shandong Academy of Sciences)Jinan250353China energy Research institute Qilu University of Technology(Shandong Academy of Sciences)Jinan250014China

Catalytic cracking oil slurry is a by-product of catalytic cracking projects,and the efficient conversion and sustainable utilization of this material are issues of continuous concern in the petroleum refining *** this study,oxygen-enriched activated carbon is prepared using a one-step KOH activation method with catalytic cracking oil slurry as the raw *** as-prepared oil slurry-based activated carbon exhibits a high specific surface area of 2102 m^(2)/g,welldefined micropores with an average diameter of 2 nm,and a rich oxygen doping content of 32.97%.The electrochemical performance of the nitrogen-doped porous carbon is tested in a three-electrode system using a 6 mol/L KOH solution as the *** achieves a specific capacitance of up to 230 F/g at a current density of 1 A/***,the capacitance retention rate exceeds 89%after 10000 charge and discharge cycles,demonstrating excellent cycle *** method not only improves the utilization efficiency of industrial fuel waste but also reduces the production cost of supercapacitor electrode materials,thereby providing a simple and effective strategy for the resource utilization of catalytic cracking oil slurries.

关键词： catalytic cracking slurry porous carbon supercapacitor KOH activation

NAD(P)H inspired CO_(2) reduction and beyond

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Science China Chemistry 2024年第4期67卷 1044-1046页

作者： Wenjin Dong Jian Liu Qingdao institute of Bioenergy and Bioprocess Technology Chinese Academy of SciencesShandong Energy InstituteQingdao 266101China

The catalytic reduction of carbon dioxide to fuels and valueadded chemicals under mild conditions is recognized as a promising strategy to alleviate the energy *** the Calvin cycle of natural photosynthesis,CO_(2)reduction is achieved using cofactor nicotinamide adenine dinucleotide phosphate(NADPH)as a practical catalyst,shedding light on the biomimetic metal-free reduction of CO_(2).

关键词： dioxide dinucleotide catalyst

Numerical Analysis of Heat Transfer Characteristics to Supercritical CO_(2) in a Vertical Mini-Channel:Transition and Pseudo-Boiling

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Journal of Thermal Science 2024年第1期33卷 101-113页

作者： YUAN Baoqiang WANG Wei XIN Gongming DU Wenjing School of energy and Power Engineering Shandong UniversityJi'nan 250061China

Large eddy simulations have been conducted to study upward transitional flows and heat transfer characteristics of supercritical CO_(2) in a vertical *** numerical simulation was carried out on a modified buoyantPimpleFOAM solver in OpenFOAM 7,and was verified using experiment *** results indicate that increasing the Grashof numbers can reduce the flow stability and make the flow transition *** are four stages of heat transfer in the transition process,i.e.,weakened,improved,recovered and normal heat *** heat transfer phenomena in the transition process were explained from three perspectives:thermal boundary layer theory,turbulent transport and pseudo-boiling *** transfer enhancement during transition is related to the transport of supercritical molecular clusters,and these molecular clusters are regarded as pseudo-bubbles in pseudo-boiling *** flow pattern of the pseudo-phases in the dia-Widom process contains single-phase flow,steady pseudo-film flow,unsteady pseudo-film flow,partial pseudo-bubbles flow and flocculent pseudo-film ***-bubbles have similar behaviors to subcritical bubbles,i.e.,break-up,deformation,condensation and *** researches in this work are favorable for understanding the heat transfer mechanism of supercritical fluids during flow transition.

关键词： supercritical heat transfer large eddy simulation transition pseudo-boiling

Strong metal–support interaction boosts the electrocatalytic hydrogen evolution capability of Ru nanoparticles supported on titanium nitride

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Carbon energy 2024年第1期6卷 245-254页

作者： Xin Wang Xiaoli Yang Guangxian Pei Jifa Yang Junzhe Liu Fengwang Zhao Fayi Jin Wei Jiang Haoxi Ben Lixue Zhang College of Chemistry and Chemical Engineering Collaborative Innovation Center for Hydrogen Energy Key Materials and Technologies of Shandong ProvinceQingdao UniversityQingdaoShandongChina State Key Laboratory of Bio-fibers and Eco-Textiles Qingdao UniversityQingdaoShandongChina Qingdao institute of Bioenergy and Bioprocess Technology Chinese Academy of ScienceQingdaoShandongChina

Ruthenium(Ru)has been regarded as one of the most promising alternatives to substitute Pt for catalyzing alkaline hydrogen evolution reaction(HER),owing to its inherent high activity and being the cheapest platinum-group ***,based on the idea of strong metal–support interaction(SMSI)regulation,Ru/TiN catalysts with different degrees of TiN overlayer over Ru nanoparticles were fabricated,which were applied to the alkaline electrolytic *** reveal that the TiN overlayer would gradually encapsulate the Ru nanoparticles and induce more electron transfer from Ru nanoparticles to TiN support by the Ru–N–Ti bond as the SMSI degree *** study shows that the exposed Ru–TiN interfaces greatly promote the H_(2) desorption ***,the Ru/TiN-300 with a moderate SMSI degree exhibits excellent HER performance,with an overpotential of 38 mV at 10 mA cm^(−2).Also,due to the encapsulation role of TiN overlayer on Ru nanoparticles,it displays super long-term stability with a very slight potential change after 24 *** study provides a deep insight into the influence of the SMSI effect between Ru and TiN on HER and offers a novel approach for preparing efficient and stable HER electrocatalysts through SMSI engineering.

关键词： electronic structure hydrogen evolution reaction ruthenium strong metal-support interaction titanium nitride