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Journal of Environmental sciences 2025年第5期151卷 594-607页

作者： Shuaitao Li Haodi Liu Xun Hu Yanfen Fang Xiaofeng Cao Qifeng Chen school of Materials science&Engineering University of JinanJinan 250022China College of Biological and pharmaceutical sciences China Three Gorges UniversityYichang 443002China Technical Institute of Physics and Chemistry Chinese Academy of SciencesBeijing 100190China

Volatile Organic Compounds(VOCs)are highly harmful to human beings and other organisms,and thus the elimination of VOCs is extremely ***,La-Si co-doped TiO_(2)microsphere photocatalysts,which were prepared by a hydrothermal method,exhibited high photocatalytic activity in the decomposition of formaldehyde compared with TiO_(2).The improved activity can be attributed to the promoted separation efficiency and density of the charge carriers,as verified by the electrochemical results in combination with density functional theory *** addition,the Si dopant changed the microstructure and surface acidity,while the addition of La promoted the separation efficiency of charge *** interestingly,it was found that singlet oxygen was the key species in the activation of molecular dioxygen,and it played a pivotal role in the photocatalytic decomposition of *** work provides a novel strategy for the selective activation of dioxygen for use in the decomposition of formaldehyde.

关键词： Dioxygen molecular activation La-Si co-doped TiO_(2)microspheres Formaldehyde degradation Photocatalysis

JERISON-LEE IDENTITIES AND SEMI-LINEAR SUBELLIPTIC EQUATIONS ON HEISENBERG GROUP

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Acta Mathematica Scientia 2025年第1期45卷 264-279页

作者： Xinan MA Qianzhong OU Tian WU school of Mathematical science University of Science and Technology of ChinaHefei230026China school of Mathematics and Statistics Guangxi Normal UniversityGuilin541004China

In the study of the extremal for Sobolev inequality on the Heisenberg group and the Cauchy-Riemann(CR)Yamabe problem,Jerison-Lee found a three-dimensional family of differential identities for critical exponent subelliptic equation on Heisenberg groupℍn by using the computer in[5].They wanted to know whether there is a theoretical framework that would predict the existence and the structure of such *** the help of dimension conservation and invariant tensors,we can answer the above question.

关键词： Cauchy-Riemann Yamabe problem subelliptic equations Jerison-Lee identities

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Utilizing bivalent aptamers as first DNA agonist to activate RTKs heterodimer of different families

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Chinese Chemical Letters 2025年第1期36卷 474-477页

作者： Kun Liu Yulin Cong Xiongfeng Luo Meicun Yao Zhiyong Xie Hao Li school of pharmaceutical sciences(Shenzhen) Shenzhen Campus of Sun Yat-sen UniversityShenzhen 518107China

Heterodimerization in RTKs is of vital importance in the RTK signaling and cell *** between RTKs can result in diversity of downstream signals,increasing the ability of cells to respond to external *** RTKs heterodimerization always occur in the same families and is lack of agonists to activate the heterodimeric RTKs signaling ***,we developed the DNA agonist based on bivalent aptamers for the heterodimerized RTKs of different families,AF/AM-1,which could simultaneously activate FGFR1 and c-Met *** is the first agonist that realizing the heterodimerization and activation of FGFR1 and c-Met,two different RTK *** activation of FGFR1/c-Met heterodimer result in the down-stream signals transduction,such as the phosphorylation of Akt and Erk,inducing the cell migration and *** DNA agonist for RTK heterodimer of different families would have potential applications in the fields of biomedicine.

关键词： DNA Agonist Bivalent aptamers RTKs heterodimer

Improved oxygen electrocatalysis at Fe N4 and Co N4 sites via construction of axial coordination

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Chinese Chemical Letters 2025年第2期36卷 482-487页

作者： Ze Zhang Lei Yang Jin-Ru Liu Hao Hu Jian-Li Mi Chao Su Bei-Bei Xiao Zhi-Min Ao school of Energy and Power Engineering Jiangsu University of Science and Technology Institute for Computation in Molecular and Materials science School of Chemistry and Chemical Engineering Nanjing University of Science and Technology Institute for Advanced Materials School of Materials Science and Engineering Jiangsu University Advanced Interdisciplinary Institute of Environment and Ecology Beijing Normal University

The quest for efficient and durable catalysts using abundant resources has garnered significant interest in the field of bifunctional oxygen *** this contribution,we have designed a FeN4or CoN4embedded graphene-based bilayer as active layer and TMC3or TMN3doped graphene as supporting layer,named as FeN4/TMC3or FeN4/TMN3and CoN4/TMC3or CoN4/TMN3,wherein TM strands for transition *** on density functional theory calculations,our results demonstrate that the interaction formed between dual metal atoms in the bilayer interspace leads to the coordination environment altered from flat four-coordination to spatial five-coordination,further stabilizing the bilayer structure and impairing its affinity toward the O-containing *** to thermodynamic analysis,the bilayers of CoN4/CoN3,FeN4/FeC3,FeN4/CoC3,FeN4/NiC3,FeN4/ZnC3,FeN4/FeN3,FeN4/CrN3and FeN4/ZnN3are attractively promising for bifunctional oxygen electrocatalysis due to the small overpotential differenceΔη between oxygen reduction and oxygen evolution that are less than 1 *** functional theory calculations combined with machine learning analysis directly identify the key role played by the interbinding formed between bilayers,that boosts catalytic activity,which establishes a predictable framework for a fast screen for graphene-based bilayer vertical *** work opens up a new path for designing the efficient electrocatalysts via modification of coordination environment.

关键词： Density functional theory Machine learning Oxygen electrocatalysis Thermodynamic analysis

New results on finite-time stability and instability theorems for stochastic nonlinear time-varying systems

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science China(Information sciences) 2025年第2期68卷 186-199页

作者： Weihai ZHANG Liqiang YAO College of Electrical Engineering and Automation Shandong University of Science and Technology school of Mathematics and Information science Yantai University

This paper studies finite-time stability and instability theorems in the probability sense for stochastic nonlinear timevarying systems. Firstly, a new sufficient condition is proposed to guarantee that the considered system has a global ***, we propose new finite-time stability and instability criteria that relax the constraints on LV(the infinitesimal operator of Lyapunov function V) by the uniformly asymptotically stable function. On the one hand, these obtained results make up for the shortcomings of the existing results. On the other hand, the new finite-time stability theorems can be viewed as natural extensions of the existing results and also allow LV to be indefinite(negative or positive) rather than just only allow LV < ***, some simulation examples verify the validity of the theoretical results.

关键词： stochastic nonlinear systems finite-time stability finite-timeinstability uniformly asymptotically stable function

The Security of Using Large Language Models:A Survey With Emphasis on ChatGPT

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IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 1-26页

作者： Wei Zhou Xiaogang Zhu Qing-Long Han Lin Li Xiao Chen Sheng Wen Yang Xiang the school of science Computing and Engineering Technologies Swinburne University of Technology IEEE the school of Computer and Mathematical sciences the University of Adelaide Adelaide the Faculty of science and Engineering Southern Cross University the school of Information and Physical sciences the University of Newcastle

ChatGPT is a powerful artificial intelligence(AI)language model that has demonstrated significant improvements in various natural language processing(NLP) tasks. However, like any technology, it presents potential security risks that need to be carefully evaluated and addressed. In this survey, we provide an overview of the current state of research on security of using ChatGPT, with aspects of bias, disinformation, ethics, misuse,attacks and privacy. We review and discuss the literature on these topics and highlight open research questions and future *** this survey, we aim to contribute to the academic discourse on AI security, enriching the understanding of potential risks and mitigations. We anticipate that this survey will be valuable for various stakeholders involved in AI development and usage, including AI researchers, developers, policy makers, and end-users.

关键词： Artificial intelligence (AI) ChatGPT large language models (LLMs) security

Metabolic insights into gut microbiota in the pharmacology of natural medicines

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Chinese Journal of Natural Medicines 2025年第02期23卷 158-168页

作者： Zixin Chen Junchi Zhou Xiao Zheng Hao Xie Haiping Hao State Key Laboratory of Natural Medicines China Pharmaceutical University Laboratory of Metabolic Regulation and Drug Target Discovery School of Pharmacy China Pharmaceutical University

Natural medicines(NMs) demonstrate distinct advantages in the clinical management of chronic diseases. Recent years have seen growing recognition of the gut microbiota's role in the efficacy and synergy of NMs, providing new impetus for elucidating the material basis and mechanisms of NMs and their path toward modernization. A fundamental question that has emerged is how NM-microbiota interactions integrate into the multi-target holistic mechanisms of NMs, the answer to which may also illuminate new avenues for drug discovery. Metabolic regulation via small-molecule metabolites has been increasingly implicated in host-microbe interaction. This review presents an integral metabolic perspective on NMs-microbiota interaction in host health and disease. It highlights the emerging understanding of gut microbiota-related metabolic signals implicated in NM components' local and systemic actions. Additionally, it discusses key issues and prospects related to drug development and the translational study of NMs.

关键词： Drug discovery Gut microbiota Metabolic signals Natural medicines Pharmacokinetics

A dual-protease-triggered chemiluminescent probe for precise tumor imaging

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Chinese Chemical Letters 2025年第2期36卷 302-306页

作者： Zhihui Zhang Ru Sun Chong Bian Hongbo Wang Zhen Zhao Panpan Lv Jianzhong Lu Haixin Zhang Hulie Zeng Yuanyuan Chen Zhijuan Cao Department of pharmaceutical Analysis School of PharmacyFudan University Minhang Branch Zhongshan HospitalFudan University China State Institute of pharmaceutical Industry Shanghai Jahwa United Co. Ltd.

Imaging detection of interlinked dual proteases is imperative for precise tumor imaging, which remains challenging due to limited modification position of specific substrate and possible steric ***, we have developed a unimolecular chemiluminescent probe(LGP-CL) tandemly activated by two proteases interlinked with liver cancer to achieve precise tumor imaging. Probe LGP-CL consists of a phenoxy-dioxetane scaffold caged by a tripeptide substrate(LGP, leucine-glycine-proline) as the sensing layer, which can be cleaved sequentially by aminopeptidase N(APN) and dipeptidyl peptidase IV(DPPIV)to turn on a strong chemiluminescent signal, and silenced by specific inhibitor of each enzyme, which accounts for an integrated logic gate(AND, OR and INHIBIT). The successful cleavage of dual proteases on the metabolic site depends on the proper structure of the tripeptide substrate, as confirmed by two probes design. Probe LGP-CL(LGP as the substrate) enables the excellent “dual-lock-dual-key” fit with a382-fold enhancement of chemiluminescent emission while no obvious signal is observed by using GPLCL(GPL as the substrate). By virtue of its rapid response(several minutes), high sensitivity and good cell viability, probe LGP-CL has been utilized to evaluate upregulated levels of proteases in vitro and in living systems, especially to distinguish liver tumor cells(Hep G2) from others(LO2, MCF-7, MCF-10a and RAW264.7). Overall, the newly developed CL probe may facilitate rapid investigation into the role played by proteases in liver diseases, enabling timely selection appropriate treatment. Therefore, our work not only sheds light on the rational design of optical probes for dual protease imaging, but provides a promising tool for clinical diagnosis and even drug discovery.

关键词： Chemiluminescent Dual-protease imaging Logic gates Phenoxy-dioxetane scaffold Tripeptide substrate

Anomaly monitoring and early warning of electric moped charging device with infrared image

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Optoelectronics Letters 2025年第3期21卷 136-141页

作者： LI Jiamin HAN Bo JIANG Mingshun school of Control science and Engineering Shandong University

Potential high-temperature risks exist in heat-prone components of electric moped charging devices, such as sockets,interfaces, and controllers. Traditional detection methods have limitations in terms of real-time performance and monitoring scope. To address this, a temperature detection method based on infrared image processing has been proposed:utilizing the median filtering algorithm to denoise the original infrared image, then applying an image segmentation algorithm to divide the image.

关键词： A

Upcycling of monomers derived from waste polyester plastics via electrocatalysis

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Journal of Energy Chemistry 2025年第2期101卷 535-561页

作者： Haoye Wang Richard Lee Smith Jr Xinhua Qi College of Environmental science and Engineering Nankai University Graduate school of Environmental Studies Tohoku University

Electrocatalysis offers efficient and targeted conversion of monomers derived from waste polyester plastics to chemical products under ambient temperature and pressure *** review provides analysis of research on electrochemical upgrading of monomers derived from waste polyester plastics published from2021 to *** for assessing upgrading of waste polyester plastics include alkaline hydrolysis pretreatment,indices of electrochemical reaction process(activity,stability,and techno-economic a nalysis),separation,and product *** of depolymerization monomers and their value-added products are summarized along with electrocatalytic mechanisms and reaction ***,cathode coupled reactions offer significant value for anodic waste plastic oxidation during electrolysis *** of bifunctional electrocatalysts can reduce the cost of coupled systems and complexity of the *** and recycling of waste plastic monomers using electrocatalytic technology should undergo downstream processing to form high-value products containing C-N and C-S derived functional groups obtained from depolymerized monomers,Electrochemical conversion and upgrading of monomers derived from waste polyester plastics can contribute to industrialization and global economies and help to realize environmental sustainability.

关键词： Coupling reaction Electrocatalysis Monomer Upgrade recycling Value-added products Waste plastics