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Rare Metals 2024年第9期43卷 4198-4221页

作者： Miao Ma Li-Xiao Shen Jing Liu Bin Xu Yun-Long Zhang Lei Zhao Zhen-Bo Wang school of Chemistry and Chemical engineering Harbin Instituteof Technology College of environmental and Chemical engineering YanshanUniversity Unipower Hydrogen Technology (Jiangsu) Corporation

Proton exchange membrane fuel cells(PEMFCs) have been identified as a highly promising means of achieving sustainable energy conversion. A crucial factor in enhancing the performance of PEMFCs for further potential energy applications is the advancement in the field of catalyst engineering that has led to remarkable performance enhancement in facilitating the oxygen reduction reaction(ORR). Subsequently, it is important to acknowledge that the techniques used in preparation of membrane electrode assemblies(MEAs), the vital constituents of PEMFCs, also possess direct and critical influence on exhibiting the full catalytic activity of meticulously crafted catalysts. Here, a succinct summary of the most recent advancements in Pt catalysts for ORR was offered and their underly catalytic mechanism were discussed. Then, both laboratory-scale and industrial-scale MEA fabrication techniques of Pt catalysts were summarized. Furthermore, a detailed analysis of the connections between materials, process, and performance in MEA fabrication was presented in order to facilitate the development of optimal catalyst layers.

关键词： MEA fabrication techniques Membrane electrode assemblies Oxygen reduction reaction Pt catalysts

Temporal assembly patterns of microbial communities in three parallel bioreactors treating low-concentration coking wastewater with differing carbon source concentrations

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Journal of environmental Sciences 2024年第3期137卷 455-468页

作者： Weijia Li Yu Xia Na Li Jie Chang Jing Liu Pei Wang Xuwen He school of Chemical and environmental engineering China University of Mining and Technology-BeijingBeijing 100083China

Carbon source is an important factor of biological treatment systems, the effects of which on their temporal community assembly patterns are not sufficiently understood *** this study, the temporal dynamics and driving mechanisms of the communities in three parallel bioreactors for low-concentration coking wastewater(CWW) treatment with differing carbon source concentrations(S0 with no glucose addition, S1 with 200 mg/L glucose addition and S2 with 400 mg/L glucose addition) were comprehensively studied. Highthroughput sequencing and bioinformatics analyses including network analysis and Infer Community Assembly Mechanisms by Phylogenetic bin-based null model(iCAMP) were used. The communities of three systems showed turnover rates of 0.0029~0.0034 every 15days. Network analysis results showed that the S0 network showed higher positive correlation proportion(71.43%) and clustering coefficient(0.33), suggesting that carbon source shortage in S0 promoted interactions and cooperation of microbes. The neutral community model analysis showed that the immigration rate increased from 0.5247 in S0 to 0.6478in S2. The iCAMP analysis results showed that drift(45.89%) and homogeneous selection(31.68%) dominated in driving the assembly of all the investigated microbial *** contribution of homogeneous selection increased with the increase of carbon source concentrations, from 27.92% in S0 to 36.08% in S2. The OTUs participating in aerobic respiration and tricarboxylic acid(TCA) cycle were abundant among the bins mainly affected by deterministic processes, while those related to the metabolism of refractory organic pollutants in CWW such as alkanes, benzenes and phenols were abundant in the bins dominated by stochastic processes.

关键词： Coking wastewater treatment Temporal dynamics Network analysis Deterministic processes Stochastic processes

Tailoring NH4+ storage by regulating oxygen defect in ammonium vanadate

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Green Energy & Environment 2024年第7期9卷 1171-1182页

作者： Yanyan Liu Ziyi Feng Hanmei Jiang Xueying Dong Changgong Meng Yifu Zhang State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology College of environmental and Chemical engineering Dalian University

Defect engineering is an effective strategy for modifying the energy storage materials to improve their electrochemical ***, the impact of oxygen defect and its content on the electrochemical performances in the burgeoning aqueous NH+4storage field remains explored. Therefore, for the first time in this work, an oxygen-defective ammonium vanadate [（NH4）2V10O25·8H2O, denoted as Od-NHVO] with a novel 3D porous flower-like architecture was achieved via the reduction of thiourea in a mild reaction condition, which is a facile method that can realize the intention to regulate the oxygen defect content, with the capability of mass-production. The as-prepared OdM-NHVO with moderate oxygen defect content can deliver a stable specific capacitance output(505 F g-1, 252 mAh g-1at 0.5 A g-1with ～80% capacitance retention after 10,000 cycles), which benefits from extra active sites, unimpeded NH+4-migration path and relatively high structure integrity. In contrast, low oxygen defect content will lead to the torpid electrochemical reaction kinetics while too high content of it will reduce the chargestorage capability and induce structural disintegration. The superior NH+4-storage behavior is achieved with the reversible intercalation/deintercalation process of NH+4accompanied by forming/breaking of hydrogen bond. As expected, the assembled flexible OdM-NHVO//PTCDI quasi-solid-state hybrid supercapacitor（FQSS HSC） also exhibits high areal capacitance, energy density and reliable flexibility. This work provides a new avenue for developing materials with oxygen-deficient structure for application in various aqueous non-metal cation storage systems.

关键词： Ammonium vanadate Oxygen defect Ammonium-ion storage Hybrid supercapacitors Electrochemical performance

Single-atom Ag-loaded carbon nitride photocatalysts for efficient degradation of acetaminophen:The role of Ag-atom and O_(2)

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Journal of environmental Sciences 2024年第5期139卷 12-22页

作者： Yi Yuan Wen-Long Wang Zhi-Wei Wang Jin Wang Qian-Yuan Wu Key Laboratory of Microorganism Application and Risk Control of Shenzhen Guangdong Provincial Engineering Research Center for Urban Water Recycling and Environmental SafetyInstitute of Environment and EcologyShenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China Shenzhen environmental Science and New Energy Technology engineering Laboratory Tsinghua-Berkeley Shenzhen InstituteShenzhen 518055China College of Materials Science and engineering Shenzhen UniversityShenzhen 518071China

Carbon nitride has been extensively used as a visible-light photocatalyst,but it has the disadvantages of a low specific surface area,rapid electron-hole recombination,and relatively low light *** this study,single-atom Ag was successfully anchored on ultrathin carbon nitride(UTCN)via thermal polymerization,the catalyst obtained is called *** Ag hardly changed the carbon nitride's layered and porous physical *** exhibited efficient visible-light photocatalytic performances in the degradation of various recalcitrant pollutants,eliminations of 85% were achieved by visible-light irradiation for *** with Ag improved the photocatalytic performance of UTCN by narrowing the forbidden band gap from 2.49 to 2.36 e V and suppressing electron-hole pair *** addition,Ag doping facilitated O_(2) adsorption on UTCN by decreasing the adsorption energy from -0.2 to -2.22 e V and favored the formation of O_(2)^(·-).Electron spin resonance and radical-quenching experiments showed that O_(2)^(·-)was the major reactive species in the degradation of Acetaminophen(paracetamol,APAP).

关键词： Ag single atom Carbon nitride Photocatalysis Visible light Adsorption energy Reactive species

Morphology and valence state evolution of Cu:Unraveling the impact on nitric oxide electroreduction

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Journal of Energy Chemistry 2024年第4期91卷 276-286页

作者： Ting Sun Fengyu Gao Ya Wang Honghong Yi Qingjun Yu Shunzheng Zhao Xiaolong Tang school of Energy and environmental engineering University of Science and Technology BeijingBeijing 100083China

Ammonia(NH3)serves as a critical component in the fertilizer industry and fume gas ***,the conventional NH3production process,namely the Haber-Bosch process,leads to considerable energy consumption and waste gas *** address this,electrocatalytic nitric oxide reduction reaction(NORR)has emerged as a promising strategy to bridge NH3consumption to NH3production,harnessing renewable electricity for a sustainable ***(Cu)stands out as a prominent electrocatalyst for NO reduction,given its exceptional NH3yield and ***,a crucial aspect that remains insufficiently explored is the effects of morphology and valence states of Cu on the NORR *** this investigation,we synthesized CuO nanowires(CuO-NF)and Cu nanocubes(Cu-NF)as cathodes through an in situ growth ***,CuO-NF exhibited an impressive NH3yield of 0.50±0.02 mg cm^(-2)h^(-1)at-0.6 V *** hydrogen electrode(RHE)with faradaic efficiency of29,68%±1,35%,surpassing that of Cu-NF(0.17±0.01 mg cm^(-2)h^(-1),16.18%±1.40%).Throughout the electroreduction process,secondary cubes were generated on the CuO-NF surface,preserving their nanosheet cluster morphology,sustained by an abundant supply of subsurface oxygen(s-O)even after an extended duration of 10 h,until s-O depletion ***,Cu-NF exhibited inadequate s-O content,leading to rapid crystal collapse within the same *** distinctive current-potential relationship,akin to a volcano-type curve,was attributed to distinct NO hydrogenation *** Tafel analysis revealed the exchange current density(i0)and standard heterogeneous rate constant(k0)for CuO-NF,yielding 3.44×10^(-6)A cm^(-2)and 3.77×10^(-6)cm^(-2)s^(-1)when NORR was driven by *** findings revealed the potential of CuO-NF for NO reduction and provided insights into the intricate interplay between crystal morphology,valence states,and electrochemical performance.

关键词： NORR Ammonia Synthesis Copper Morphology Valence States Mechanism

Metal-based cathode catalysts for electrocatalytic ORR in microbial fuel cells:A review

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Chinese Chemical Letters 2024年第5期35卷 85-96页

作者： Yaxin Sun Huiyu Li Shiquan Guo Congju Li school of Energy and environmental engineering University of Science and Technology BeijingBeijing 100083China

Microbial fuel cells(MFCs)have a simple structure and excellent pollutant treatment and power generation ***,the slow kinetics of the oxygen reduction reaction(ORR)at the MFC cathode limit power *** electrochemical performance of MFCs can be improved through *** far,metal-based catalysts have shown astonishing results in the field of electrocatalysis,enabling MFC devices to demonstrate power generation capabilities comparable to those of Pt,thus showing enormous *** article reviews the research progress of meta-based MFC cathode ORR catalysts,including the ORR reaction mechanism of MFC,different types of catalysts,and preparation *** catalytic effects of different catalysts in MFC are compared and *** discussing the practical application and expanded manufacturing of catalysts,we summarize the key challenges that must be addressed when using metal-based catalysts in MFC,with the aim of providing a scientific direction for the future development of advanced materials.

关键词： Microbial fuel cells Metal-based cathode catalysts Oxygen reduction reaction Noble metal catalysts MOFs M-N-C Single-atom Transition metal oxides

A porous Eu-PTA/Tb-SSA/ZrO_(2)/ZnZrO_(3) light color adjustable phosphor:Luminescent property and application of warm white LED

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Journal of Rare Earths 2024年第8期42卷 1421-1428,I0001页

作者： Yunxiao Ma Chao Linghu Ming Yang Hui Yu Xiangting Dong Long Xia school of Chemistry and environmental engineering Changchun University of Science and TechnologyChangchun130022China school of Materials Science and engineering Harbin Institute of Technology(Weihai)Weihai264209China

Light emitting diode(LED) is the fourth generation lighting source,but it has some shortcomings such as complex chip packaging process and the unbalanced light color of phosphor in long-time *** this study,a kind of Eu-terephthalic acid/Tb-sulfosalicylate/ZrO_(2)/ZnZrO_(3)(Eu-PTA/Tb-SSA/ZrO_(2)/ZnZrO_(3))phosphor with warm white light emission properties was prepared,and the warm white light LED(wWLEDs) was successfully prepared by encapsulating Eu-PTA/Tb-SSA/ZrO_(2)/ZnZrO_(3) phosphors together with 270 nm *** ZrO_(2)/ZnZrO_(3),Tb-SSA/ZrO_(2)/ZnZrO_(3) and Eu-PTA/ZrO_(2)/ZnZrO_(3) samples show blue emission,green emission and red emission under deep ultraviolet(UV,270 nm) excitation,*** Tb-SSA and Eu-PTA are co-doped into ZrO_(2)/ZnZrO_(3) matrix with blue emission to achieve the warm white light emission,and the light color can be adjusted by controlling the doping amount of Eu^(3+)-and Tb^(3+).Through the excitation method of single-component phosphor by the single chip,the complex chip packaging process of w-LED can be *** doping rare earth organic complexes into porous ZrO_(2)/ZnZrO_(3) matrix,the problems of the light color unbalanced of phosphor and the low luminescence intensity of rare earth doped metal oxides composites can be solved.

关键词： Eu-PTA/Tb-SSA/ZrO_(2)/ZnZrO_(3) Luminescence material Light color adjustable phosphor Warm white emission W-WLEDs Rare earths

A review on Bi_(2)WO_(6)-based photocatalysts synthesis, modification, and applications in environmental remediation, life medical, and clean energy

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Frontiers of environmental Science & engineering 2024年第7期18卷 87-108页

作者： Wei Mao Xuewu Shen Lixun Zhang Yang Liu Zehao Liu Yuntao Guan Guangdong Provincial engineering Technology Research Center for urban Water Cycle and Water Environment Safety Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China State environmental Protection Key Laboratory of Microorganism Application and Risk Control School of EnvironmentTsinghua UniversityBeijing 100084China

Photocatalysis has emerged a promising strategy to remedy the current energy and environmental crisis due to its ability to directiy convert clean solar energy into chemical *** tungstate(Bi_(2)WO_(6))has been shown to be an excellent visible light response,a well-defined perovskite crystal structure,and an abundance of oxygen atoms(providing efficient channels for photogenerated carrier transfer)due to their suitable band gap,effective electron migration and separation,making them ideal *** has been extensively applied as photocatalyst in aspects including pollutant removal,carbon dioxide reduction,solar hydrogen production,ammonia synthesis by nitrogen photocatalytic reduction,and cancer *** this review,the fabrication and application of Bi_(2)WO_(6) in photocatalysis were comprehensively *** photocatalytic properties of BizwO-based materials were significantly enhanced by carbon modification,the construction of heterojunctions,and the atom doping to improve the photogenerated carrier migration rate,the number of surface active sites,and the photoexcitation ability of the *** addition,the potential development directions and the existing challenges to improve the photocatalytic performance of Bi_(2)WO_(6)-based materials were discussed.

关键词： Bismuth tungstate Synthesis and modification Photocatalytic application environmental remediation Clean energy Medical science

Chain Elongation Using Native Soil Inocula:Exceptional n-Caproate Biosynthesis Performance and Microbial Mechanisms

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engineering 2024年第8期39卷 262-272页

作者： Lin Deng Yang Lv Tian Lan Qing-Lian Wu Wei-Tong Ren Hua-Zhe Wang Bing-Jie Ni Wan-Qian Guo State Key Laboratory of urban Water Resource and the Environment Harbin Institute of TechnologyHarbin 150090China Centre for Technology in Water and Wastewater&school of Civil and environmental engineering University of Technology SydneySydneyNSW 2007Australia

This study demonstrates the feasibility and effectiveness of utilizing native soils as a resource for inocula to produce n-caproate through the chain elongation(CE)platform,offering new insights into anaerobic soil *** results reveal that all five of the tested soil types exhibit CE activity when supplied with high concentrations of ethanol and acetate,highlighting the suitability of soil as an ideal source for n-caproate *** with anaerobic sludge and pit mud,the native soil CE system exhibited higher selectivity(60.53%),specificity(82.32%),carbon distribution(60.00%),electron transfer efficiency(165.00%),and conductivity(0.59 ms∙cm^(-1)).Kinetic analysis further confirmed the superiority of soil in terms of a shorter lag time and higher yield.A microbial community analysis indicated a positive correlation between the relative abundances of Pseudomonas,Azotobacter,and Clostridium and n-caproate ***,metagenomics analysis revealed a higher abundance of functional genes in key microbial species,providing direct insights into the pathways involved in n-caproate formation,including in situ CO_(2)utilization,ethanol oxidation,fatty acid biosynthesis(FAB),and reverse beta-oxidation(RBO).The numerous functions in FAB and RBO are primarily associated with Pseudomonas,Clostridium,Rhodococcus,Stenotrophomonas,and Geobacter,suggesting that these genera may play roles that are involved or associated with the CE ***,this innovative inoculation strategy offers an efficient microbial source for n-caproate production,underscoring the importance of considering CE activity in anaerobic soil microbial ecology and holding potential for significant economic and environmental benefits through soil consortia exploration.

关键词： Soil Chain elongation n-caproate Reverse beta-oxidation Fatty acid biosynthesis Metagenomics

Monitoring and detection of steel bridge diseases:A review

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Journal of Traffic and Transportation engineering(English Edition) 2024年第2期11卷 188-208页

作者： Chuang Cui Qinghua Zhang Dengke Zhang Wulve Lao Lemou Wu Zhenxiong Jiang National Key Laboratory of Bridge Intelligent and Green construction Southwest Jiaotong UniversityChengdu 610031China school of Civil engineering Southwest Jiaotong UniversityChengdu 610031China Jiangsu Provincial Transportation engineering construction Bureau Nanjing 210004China

Fatigue,corrosion,and bolt loosening are the main causes of structural performance degradation and collapse in steel *** monitoring of steel bridge diseases is a basic premise for ensuring high-quality operation and maintenance of steel *** this regard,a summary and analysis were conducted on the classification of steel bridge diseases,monitoring and detection methods,application statuses,and major *** main causes,research status,and development trends of steel bridge diseases are *** results showed that,for fatigue crack problems,fatigue crack initiation has a small scale,high difficulty in monitoring and detection,few methods,and low *** the cracks grow,the difficulty of monitoring and detection decreases,the number of methods increases,and the accuracy *** crack monitoring and detection are affected by the environmental and vehicular *** corrosion features are evident in steel bridges,and corrosion identification methods and technologies are rapidly *** and detecting corrosion in concealed areas is difficult and requires further improvements in monitoring and detection technologies and their *** and detection methods and supporting equipment for bolt loosening in steel bridges are rapidly *** development of intelligent monitoring and detection technologies and supporting equipment is an important research topic that urgently needs to be addressed for the full-lifecycle operation and maintenance of steel bridges and the sustainable development of bridge *** new intelligent sensing components based on high-performance materials and sensing element design theory to improve the monitoring and detection perception ability is an important development direction for steel bridge monitoring and *** on intelligent monitoring and detection technologies,standardized indicators,and related topics based on intelligent oper

关键词： Steel bridge Diseases Fatigue crack Corrosion Bolt loosening Monitoring and detection