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Optical measurements of dissolved organic matter as proxies for COD_(Mn)and BOD_(5)in plateau lakes

Environmental Science and Ecotechnology 2024年第3期19卷 132-138页

作者： Xuan Yang Yongqiang Zhou Xiaoying Yang Yunlin Zhang Robert G.M.Spencer Justin D.Brookes Erik Jeppesen Hucai Zhang Qichao Zhou Institute for Ecological research and Pollution Control of Plateau Lakes School of Ecology and Environmental SciencesYunnan UniversityKunming650500China Institute of International River and Eco-security Yunnan UniversityKunming650500China Zhejiang College of Security Technology Wenzhou325016China Taihu Laboratory for Lake Ecosystem research State Key Laboratory of Lake Science and EnvironmentNanjing Institute of Geography and LimnologyChinese Academy of SciencesNanjing210008China Department of Earth Ocean and Atmospheric ScienceFlorida State UniversityTallahassee32306United States Water research Centre School of Biological ScienceThe University of AdelaideAdelaide5005Australia Department of Ecoscience Aarhus UniversityAarhus8000Denmark Sino-Danish Centre for Education and research Chinese Academy of SciencesBeijing100101China Limnology Laboratory Department of Biological Sciences and Centre for Ecosystem Research and ImplementationMiddle East Technical UniversityAnkara06800Turkey Institute of Marine sciences Middle East Technical UniversityErdemliMersin33731Turkey Yunnan Key Laboratory of Pollution Process and management of Plateau Lake-Watershed Yunnan Research Academy of Eco-environmental SciencesKunming650034China

The presence of organic matter in lakes profoundly impacts drinking water supplies,yet treatment processes involving coagulants and disinfectants can yield carcinogenic disinfection *** assessments of organic matter,such as chemical oxygen demand(COD_(Mn))and biochemical oxygen demand(BOD_(5)),are often ***,optical measurements of dissolved organic matter(DOM)offer a rapid and reliable means of obtaining organic matter composition *** we employed DOM optical measurements in conjunction with parallel factor analysis to scrutinize COD_(Mn)and BOD_(5)*** was performed using an independent dataset encompassing six lakes on the Yungui Plateau from 2014 to 2016(n=256).Leveraging multiple linear regressions(MLRs)applied to DOM absorbance at 254 nm(a254)and fluorescence components C1-C5,we successfully traced COD_(Mn)and BOD_(5)variations across the entire plateau(68 lakes,n=271,R^(2)>0.8,P0.9)in mesotrophic lakes compared to oligotrophic and eutrophic *** study underscores the utility of MLR-based DOM indices for inferring COD_(Mn)and BOD_(5)variability in plateau lakes and highlights the potential of integrating in situ and remote sensing platforms for water pollution early warning.

关键词： Dissolved organic matter Chemical oxygen demand Biochemical oxygen demand Water quality Yungui plateau lakes

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Prediction model on hydrolysis kinetics of phthalate monoester:A density functional theory study

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Journal of Environmental sciences 2024年第1期135卷 51-58页

作者： Tong Xu Jingwen Chen Deming Xia Weihao Tang Jiansheng Cui Chun Liu Shuangjiang Li College of Environmental Science and Engineering Hebei University of Science and TechnologyShijiazhuang 050000China Key Laboratory of Industrial Ecology and Environmental Engineering(Ministry of Education) School of Environmental Science and TechnologyDalian University of TechnologyDalian 116024China National-Regional Joint Engineering research Center for Soil Pollution Control and Remediation in South China Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and ManagementInstitute of Eco-environmental and Soil SciencesGuangdong Academy of SciencesGuangzhou 510650China

As primary degradation products of phthalate esters,phthalate monoesters(MPEs)have been widely detected in various aquatic environments and drawn growing toxicological *** kinetics that is of importance for assessing environmental persistence of chemicals remain elusive for ***,kinetics of base-catalyzed and neutral hydrolysis for 18 MPEs with different leaving groups was investigated by density functional theory *** indicate that MPEs with leaving groups having p Kaof<10 prefer dissociative transition *** are more persistent than their parents,and their hydrolysis half-lives were calculated to vary from 3.4 min to 79.2 years(p H=7–9).A quantitative structure-activity relationship model was developed for predicting the hydrolysis kinetics *** was found that p Kaof the leaving groups and electronegativity of the MPEs are key factors determining the hydrolysis *** work may lay a theoretical foundation for better understanding the chemical process that governs MPE persistence in aquatic environments.

关键词： Phthalate monoesters Phthalate esters Hydrolysis Density functional theory Quantitative structure-activity relationship

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How Does Participation in Agricultural Cooperatives Affect the Performance of Family Farms?——Empirical Evidence from 553 Planting Family Farms in Xinjiang Corps

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Journal of Systems Science and Information 2024年

作者： Zhiping HUANG Na LI Xishan Farmland The 12th Division of Xinjiang Production and Construction Corps school of Economics and management University of Chinese Academy of Sciences

Participation in agricultural cooperative organizations is an important form of industrial chain organization expansion, but also an important way to effectively reduce industrial chain transaction costs and promote the quality and efficiency improvement of new agricultural business *** on the micro-survey data of 553 family farms in Xinjiang Corps in 2021, this paper uses stochastic frontier approach to measure the business performance of family farms in Xinjiang Corps, and discusses the action mechanism and difference in the influence of participation in agricultural cooperative organizations on the business performance of family farms. The research shows that participation in agricultural cooperative organizations can significantly improve the business performance of family farms through such mechanisms as easing the constraints of farm credit financing, reducing the transaction costs of agricultural products, and promoting the adoption of agricultural technologies. Compared with food farms, cotton and fruit and vegetable family farms have more obvious performance improvement in participating in agricultural cooperative organizations. Moreover, participation in agricultural cooperation organizations has a stronger effect on the performance improvement of farms in northern Xinjiang. It is found that the vertical extension of the industrial chain between”family farm+agricultural cooperative organization” and network marketers, chain supermarkets, industrial leading enterprises and agricultural production and marketing enterprises is conducive to the improvement of the business performance of family farms, among which the performance improvement effect of”family farm+agricultural cooperative organization+network marketers” mode is more obvious. The research provides a scientific reference for deepening the expansion of the industrial chain organization and promoting the quality-oriented growth of family farms in the new era.

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Synchronous deprotonation–protonation for mechanically robust chitin/aramid nanofibers conductive aerogel with excellent pressure sensing, thermal management, and electromagnetic interference shielding

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Nano research 2024年第3期17卷 2038-2049页

作者： Xinxin Zhang Kunpeng Qian Jianhui Fang Sineenat Thaiboonrod Miao Miao Xin Feng Department of Chemistry College of SciencesShanghai UniversityShanghai 200444China research Center of Nano Science and Technology College of SciencesShanghai UniversityShanghai 200444China school of Materials sciences and Engineering Shanghai UniversityShanghai 200444China National Nanotechnology Center(NANOTEC) National Science and Technology Development Agency(NSTDA)Thailand Science ParkPathum Thani 12120Thailand

Aerogels with regularly porous structure and uniformly distributed conductive networks have received extensive attention in wearable electronic sensors,electromagnetic shielding,and so ***,the poor mechanical properties of the emerging nanofibers-based aerogels are limited in practical *** this work,we developed a synchronous deprotonation–protonation method in the KOH/dimethyl sulfoxide(DMSO)system at room temperature for achieving chitin cross-linked aramid nanofibers(CANFs)rather than chitin nanofibers(ChNFs)and aramid nanofibers(ANFs)separately by using chitin and aramid pulp as raw *** freeze-drying process,the cross-linked chitin/aramid nanofibers(CA)aerogel exhibited the synergetic properties of ChNF and ANF by the dual-nanofiber compensation *** mechanical stress of CA aerogel was 170 kPa at 80%compressive strain,increased by 750%compared with pure ChNF ***,the compressibility of CA aerogel was somewhat improved compared to ANF *** enhancement verified that the crosslinking reaction between ANF and ChNF during the synchronous deprotonation process was ***,the conductive aerogels with uniform porous structure(CA-M)were successfully obtained by vacuum impregnating CA aerogels in Ti_(3)C_(2)T_(x) MXene solution,displaying low thermal conductivity(0.01 W/(m·K)),high electromagnetic interference(EMI)shielding effectiveness(SE)(75 dB),flame retardant,and heat ***,the as-obtained CA-M aerogels were also applied as a pressure sensor with excellent compression cycle stability and superior human motion monitoring *** a result,the dual-nanofiber based conductive aerogels have great potentials in flexible/wearable electronics,EMI shielding,flame retardant,and heat insulation.

关键词： synchronous deprotonation–protonation electromagnetic interference(EMI)shielding flame retardant heat insulation pressure sensing

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Sustainable Mining in the Era of Artificial Intelligence

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IEEE/CAA Journal of Automatica Sinica 2024年第1期11卷 1-4页

作者： Long Chen Yuting Xie Yutong Wang Shirong Ge Fei-Yue Wang IEEE the State Key Laboratory for management and Control of Complex Systems at the Institute of Automation Chinese Academy of SciencesBeijing 100190China the National Laboratory of Pattern Recognition at the Institute of Automation and Waytous Ltd.China the school of Computer Science and Engineering Sun Yat-Sen UniversityGuangzhou 510275GuangdongChina the school of Mechanical Electronic and Information Engineering China University of Mining and Technology BeijingBejing 100083China the school of Artificial Intelligence University of Chinese Academy of SciencesBeijing 100190China

The mining sector historically drove the global economy but at the expense of severe environmental and health repercussions,posing sustainability challenges[1]-[3].Recent advancements on artificial intelligence(AI)are revolutionizing mining through robotic and data-driven innovations[4]-[7].While AI offers mining industry advantages,it is crucial to acknowledge the potential risks associated with its widespread ***-reliance on AI may lead to a loss of human control over mining operations in the future,resulting in unpredictable consequences.

关键词： Sustainable mining consequences

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Robust reinforcement learning with UUB guarantee for safe motion control of autonomous robots

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Science China(Technological sciences) 2024年第1期67卷 172-182页

作者： ZHANG RuiXian HAN YiNing SU Man LIN ZeFeng LI HaoWei ZHANG LiXian school of Astronautics Harbin Institute of TechnologyHarbin 150001China school of management Harbin Institute of TechnologyHarbin 150001China Beijing Institute of Tracking and Telecommunication Technology Beijing 100094China

This paper addresses the issue of safety in reinforcement learning(RL)with disturbances and its application in the safety-constrained motion control of autonomous *** tackle this problem,a robust Lyapunov value function(rLVF)is *** rLVF is obtained by introducing a data-based LVF under the worst-case disturbance of the observed *** the rLVF,a uniformly ultimate boundedness criterion is *** criterion is desired to ensure that the cost function,which serves as a safety criterion,ultimately converges to a range via the policy to be ***,to mitigate the drastic variation of the rLVF caused by differences in states,a smoothing regularization of the rLVF is *** train policies with safety guarantees under the worst disturbances of the observed states,an off-policy robust RL algorithm is *** proposed algorithm is applied to motion control tasks of an autonomous vehicle and a cartpole,which involve external disturbances and variations of the model parameters,*** experimental results demonstrate the effectiveness of the theoretical findings and the advantages of the proposed algorithm in terms of robustness and safety.

关键词： motion control reinforcement learning robustness stability

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Coordination for a Closed-loop Supply Chain with Recycling Platform Considering Dynamic Setting

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Journal of Systems Science and Systems Engineering 2024年第4期33卷 425-451页

作者： Zehua Xiang Ting Ji Lingfeng Dong school of management Zhejiang UniversityHangzhou310058China school of Business Hangzhou City UniversityHangzhou310015China Alibaba Business College Hangzhou Normal UniversityHangzhou311121China

This paper presents a dynamic closed-loop supply chain(CLSC)model,incorporating a manufacturer,a retailer,and an internet recycling platform(IRP),utilizing differential game theory while considering the forgetting effect of *** model encompasses factors such as the quality level of used products and Big Data marketing(BDM),comparing optimal equilibriums under decentralized and cooperative decision *** effectively coordinate the dynamic CLSC at each time point,we propose a revenue-sharing and cost-sharing(RSCS)combined *** addition to ensuring reasonable sharing of revenues and costs,this contract allows the manufacturer to flexibly adjust wholesale prices for final products and transfer prices for used products in order to distribute profits appropriately and achieve Pareto optimality within the CLSC ***,our results indicate that there exists a threshold for Big Data marketing efficiency;high-efficiency BDM not only facilitates increased recycling on Internet platforms but also reduces unit recycling costs for ***,when implementing the combined contract,Big Data marketing efficiency does not impact the transfer price paid by manufacturers to Internet recycling platforms.

关键词： Big Data marketing differential game closed-loop supply chain coordination internet recycling platform

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Adaptive Algorithms on Maximizing Monotone Nonsubmodular Functions

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Journal of the operations research Society of China 2024年第2期12卷 428-445页

作者： Bin Liu Hui Su Shu-Fang Gong Qi-Zhi Fang school of Mathematical sciences Ocean Universityof ChinaQingdao266100ShandongChina

Submodular optimization is widely used in large *** order to speed up the problems solving,it is essential to design low-adaptive algorithms to achieve acceleration in *** general,the function values are given by a value oracle,but in practice,the oracle queries may consume a lot of ***,how to strike a balance between optimizing them is *** this paper,we focus on maximizing a normalized and strictly monotone set function with the diminishing-return ratio under a cardinality constraint,and propose two algorithms to deal with *** apply the adaptive sequencing technique to devise the first algorithm,whose approximation ratio is arbitrarily close to 1-e^(-γ)in O(logn·log(log k/γ)) adaptive rounds,and requires O(logn^(2)·log(log k/γ)) *** by adding preprocessing and parameter estimation steps to the first algorithm,we get the second *** second algorithm trades a small sacrifice in adaptive complexity for a significant improvement in query *** the same approximation and adaptive complexity,the query complexity is improved *** the best of our knowledge,this is the first paper of designing adaptive algorithms for maximizing a monotone function using the diminishing-return ratio.

关键词： Approximation algorithm Adaptivity Nonsubmodular maximization Cardinality constraint

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Reducing children’s exposure to di(2-ethylhexyl)phthalate in homes and kindergartens in China:Impact on lifetime cancer risks and burden of disease

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Building Simulation 2024年第3期17卷 431-440页

作者： Dongsheng Tao Wen Sun Donghui Mo Yonghui Lin Wei Lv Daniel Mmereki Yousheng Xu Yanghui Ye Yuanjun Tang Chao Ye Cong Dong Zhongming Bu Zhejiang Ecowell Energy management Technology Co. LtdHangzhouChina Department of Energy and Environmental System Engineering Zhejiang University of Science and TechnologyHangzhouChina Faculty of Health sciences School of Clinical MedicineUniversity of the WitwatersrandParktown2193JohannesburgSouth Africa

Exposure to di(2-ethylhexyl)phthalate(DEHP)in the indoor environment has been linked with significant health risks for Chinese ***-phase DEHP concentrations in Chinese residences and kindergartens were estimated using a mass balance model based on the current baseline condition and control strategies(i.e.,increasing ventilation rate,reducing area of sources,using mechanical ventilation systems,and using portable air cleaners).The health benefits of each control strategy were quantified as the reduction in lifetime cancer risks(LCR)and burden of disease(BoD).In the current situation,the mean LCR and disability-adjusted life years(DALY)number attributable to indoor DEHP exposure for Chinese children were around 6.0×10^(−6) and 155 thousand,*** mean LCR and DALY might be reduced by 25%-54%and 16%-40%,respectively,by increasing air exchange rates by 100%,reducing the use of source materials by two-thirds or deploying commercial air cleaners in naturally ventilated ***,avoidable DALYs could result in a reduction of mean economic losses of 2.2-5.3 billion *** ventilation systems with filtration units may not be helpful for reducing children’s health ***-specific and tailor-made control measures are critical in lowering indoor exposure to DEHP to promote sustainable buildings and children’s health in China.

关键词： indoor air di(2-ethylhexyl)phthalate children exposure control strategies health benefits

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Centennial Analysis of Human Activity Intensity and Associated Historical Events in Heilongjiang River Sino-Russo Watershed

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Chinese Geographical Science 2024年第2期34卷 280-293页

作者： SONG Chaoxue LI Xiaoling HE Hongshi Michael SUNDE school of Geographical sciences Northeast Normal UniversityChangchun 130024China school of Natural Resources University of MissouriColumbia 65211USA

Human activities in a transborder watershed are complex under the influence of domestic policies,international relations,and global *** the forces driving human activity change is important for the development of transborder *** this study,we used global historical land cover data,the hemeroby index model,and synthesized major historical events to analyze how human activity intensity changed in the Heilongjiang River(Amur River in Russia)watershed(HLRW).The results showed that there was a strong spatial heterogeneity in the variation of human activity intensity in the HLRW over the past century(1900-2016).On the Chinese side,the human activity intensity change shifted from the plain areas for agricultural reclamation to the mountainous areas for timber *** the Russian side,human activity intensity changes mostly concentrated along the Trans-Siberian Railway and the Baikal-Amur *** variation of human activity intensity tended to respond to regional events while regionalized variation tends to reflect national policy change or broad international *** similarities and differences between China and Russia in policies and positions in international events resulted in synchronous and asynchronous changes in human activity ***,policy shifts were often confined by the natural features of the *** results reveal the historical origins and fundamental connotations of watershed development and contribute to formulating regional management policies that coordinate population,eco-nomic,social,and environmental activities.

关键词： human activity intensity changes hemeroby index centennial scale Heilongjiang River(Amur River in Russia)watershed China Russia

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