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Journal of Iron and Steel Research(International) 2024年第1期31卷 108-120页

作者： Zi-han Wang Jing Guo Han-jie Guo Bin Li school of metallurgical engineering University of Science and Technology BeijingBeijing100083China school of metallurgical engineering Xi’an University of Architecture and TechnologyXi’an710055ShaanxiChina

A high-temperature reduction roasting method was used to achieve metallic iron and zinc recovery from blast furnace gas ash(BFA).The reduction processes for Zn-containing and Fe-containing oxides were analyzed in detail by using ther-modynamic equilibrium calculation and the principle of minimum free energy.The results showed that the main reaction in the system is the reduction of ZnFe_(2)_(4)and iron oxides.Over the full temperature range,iron oxides were more easily reduced than zinc oxides.Regardless of the amount of CO contained in the system,the reduction of ZnO to Zn was difficult to proceed below the boiling point(906℃)of Zn.When the reduction temperature is below 906℃,the reduction process of zinc ferrate was ZnFe_(2)_(4)→ZnO;when the reduction temperature is above 906℃,its reduction process becomed ZnFe_(2)_(4)→ZnO→Zn(g).The metallization and dezincification rates of the BFA gradually increased with increasing reaction temperature.As the C/O ratio increased,the metallization and dezincification rates first increased and then decreased.The effect of reduction time on BFA reduction was similar to that of reaction temperature.

关键词： Blast furnace gas ash Thermodynamics Zinc removal Iron reduction High-temperature reduction roasting Integrated utilization

Biomimetic three-dimensional multilevel nanoarray electrodes with superaerophobicity as efficient bifunctional catalysts for electrochemical water splitting

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Nano Research 2023年第5期16卷 6584-6592页

作者： Dongdong Wang Yue Liu Lili Liu Dongfang Shan Guixin Shen Shanlong Peng Heng Zhang Xindong Wang State Key Laboratory of Advanced Metallurgy School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijing 100083China Energy Storage science and engineering School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijing 100083China

The design and preparation of cost-effective and durable catalysts for electrochemical water splitting are significant for the development and application of hydrogen production.Herein,inspired by the underwater superaerophobicity of fish scales,a three-dimensional multilevel nanoarray electrode with superaerophobicity was designed and fabricated by the hydrothermal method to solve the bubble shielding effect in electrochemical reactions.Benefiting from the high specific surface area,superaerophobic properties,Al doping,the Al-CoS_(2)nanosheets(NSs)/nickel foam(NF)-30 exhibits outstanding electrocatalytic activity and superior durability for electrochemical water splitting in 1 M KOH.Significantly,the Al-CoS_(2)NSs/NF-30 only required extremely low overpotential of 176 mV for oxygen evolution reaction(OER)to reach a current density of 10 mA·cm^(-2).Al-CoS_(2)NSs/NF-30 was employed as bifunctional electrode for electrochemical water splitting with a cell voltage of 1.58 V at 10 mA·cm^(-2).Meanwhile,Al-CoS_(2) NSs/NF-30 exhibited excellent durability(250 h@10 mA·cm^(-2)and 50 h@100 mA·cm^(-2)).The cobalt-based catalyst(Al-CoS_(2) NSs/NF-30)with superaerophobicity exhibits excellent performance in activity and durability,therefore is a promising electrochemical water splitting catalyst.

关键词： oxygen evolution reaction biomimetic structure superaerophobicity hydrogen evolution reaction

Reconfiguring dual-phase structure with equal micro-hardness to achieve double strength with slight ductility sacrifice

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Journal of Materials science & Technology 2023年第10期141卷 171-183页

作者： Xuebing Liu Mengcheng Zhou Xinfang Zhang school of metallurgical and Ecological engineering University of Science and Technology BeijingBeijing 10083China

The application of duplex stainless steel is severely restricted owing to its inherently low yield strength.A high yield strength of duplex stainless steel is required to address the lightweight issues and re-duce the emission of polluting gasses.Herein,excellent mechanical properties of duplex stainless steel were achieved using a flash annealing treatment to obtain austenite and ferrite phases with equal hard-ness,and the yield strength doubled without a substantial ductility sacrifice.The improvement in yield strength was caused by the grain boundary strengthening(a contribution of 60%to the yield strength)and hetero-deformation-induced strengthening(remaining 40%contribution to the yield strength)owing to the significant difference in the strain partitioning between the two phases.The high strain-hardening capability ensured ductility without a significant decrease;this correlated to the multiple microstruc-ture deformation mechanisms.These mechanisms included the synergetic deformation of the ferrite with dislocation cell formation and austenite accompanied by the sequential appearance of dislocation accumulation,stacking faults,and deformation-induced nanoscale twins and martensite.Deformation-induced multilevel stacking fault networks and high-density Lomer-Cotterll locks further improved the strain hardening response by enhancing the hetero-deformation behavior of austenite and ferrite.

关键词： Duplex stainless steel Flash annealing Equal hardness Strain partitioning Hetero-deformation

Facile synthesis of composite polyferric magnesium-silicate-sulfate coagulant with enhanced performance in water and wastewater

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International Journal of Minerals,Metallurgy and Materials 2024年第3期31卷 574-584页

作者： Xiangtao Huo Rongxia Chai Lizheng Gou Mei Zhang Min Guo school of metallurgical and Ecological engineering University of Science and Technology BeijingBeijing 100083China

The coagulation process is a widely applied technology in water and wastewater treatment.Novel composite polyferric mag-nesium-silicate-sulfate(PFMS)coagulants were synthesized using Na_(2)SiO_(3)·9H_(2)O,Fe_(2)(SO_(4))_(3),and MgSO_(4) as raw materials in this paper.The effects of aging time,Fe:Si:Mg,and OH:M molar ratios(M represents the metal ions)on the coagulation performance of the as-pre-pared PFMS were systematically investigated to obtain optimum coagulants.The results showed that PFMS coagulant exhibited good co-agulation properties in the treatment of simulated humic acid-kaolin surface water and reactive dye wastewater.When the molar ratio was controlled at Fe:Si:Mg=2:2:1 and OH:M=0.32,the obtained PFMS presented excellent stability and a high coagulation efficiency.The removal efficiency of ultraviolet UV254 was 99.81%,and the residual turbidity of the surface water reached 0.56 NTU at a dosage of 30 mg·L^(-1).After standing the coagulant for 120 d in the laboratory,the removal efficiency of UV254 and residual turbidity of the surface wa-ter were 88.12%and 0.68 NTU,respectively,which accord with the surface water treatment requirements.In addition,the coagulation performance in the treatment of reactive dye wastewater was greatly improved by combining the advantages of magnesium and iron salts.Compared with polyferric silicate-sulfate(PFS)and polymagnesium silicate-sulfate(PMS),the PFMS coagulant played a better decolor-ization role within the pH range of 7-13.

关键词： polyferric-magnesium-silicate-sulfate composite coagulants water and wastewater excellent stability high coagulation ef-ficiency decolorization

Regulating the recrystallized grain to induce strong cube texture in oriented silicon steel

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Journal of Materials science & Technology 2022年第1期96卷 126-139页

作者： Mengcheng Zhou Xinfang Zhang school of metallurgical and Ecological engineering University of Science and Technology BeijingBeijing 100083China

Cube texture contains two easy magnetization directionsparallel to rolling and transverse direction,respectively,which is the most ideal magnetic texture suitable not only for transformers but also for rotating machines.In this study,a strong cube texture with ODF density of 50.73 mrd was successfully obtained by regulating the recrystallized grain orientation using cross-rolling and pulsed electric current,compared to conventional thermal annealing(the average cube texture intensity is~10 mrd in lots of latest studies).Cross cold rolling process intentionally"created"metastable deformed cube orientation in oriented silicon steel and the specific recrystallization texture rotation path was identified under pulsed electric current in 5 min:{114}→{114}→{114}→{001}→{001}.The cube-oriented grains were induced by pulsed electric current(800℃)and rapid heating(51.9℃/s,750℃),while the cube grains were observed in the annealed samples at the high temperature(1060℃).Recrystallized grain size of pulsed samples is about twice that of the annealed sample.This phenomenon is considered that the concurrent effects of electron wind force and Joule heating affected the nucleation,growth and rotation of cube grains by reducing the nuclear barrier,producing higher grain boundary mobility and structural evolution towards a state with lower electrical resistance.This idea of current-controlled texture is worthy of popularization in more materials and the realization of an electromagnetic field to crystal orientation selection is an interesting topic.

关键词： Cube texture Cross-rolling Recrystallization Pulsed electric current EBSD

Evolution of inclusions in a pipeline steel during continuous casting and hot rolling process

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Journal of Iron and Steel Research(International) 2022年第1期29卷 175-185页

作者： Yi Wang Wei-fu Li Wen Yang school of metallurgical and Ecological engineering University of Science and Technology BeijingBeijing 100083China

Industrial trials were performed to study the evolution of inclusions in a pipeline steel during the continuous casting and hot rolling process.The main composition of inclusions changed from Al_(2)O_(3)-CaO in the liquid steel to Al_(2)O_(3)-CaO-CaS in the slab,and then to Al_(2)O_(3)-CaS in the rolled plate.Corresponding area fractions of inclusions increased from 47.0×10^(-6) to 76.7×10^(-6),and to 144.3×10^(-6).It was explained by thermodynamic calculations that the thermodynamic equilibrium between inclusions and the steel varied with the temperature.Element contents of Al,Ca,Mg,S,and O in the steel decreased during the solidification and cooling process.Due to the difference in the cooling rate,the transformation ratio of CaS increased from 61% at the slab surface to 95% in the slab center.It was also affected by the size of inclusions as smaller inclusions provided better kinetic conditions.Critical diameters of inclusions for the composition transformation were calculated.For the hot rolling process,the average aspect ratio of inclusions increased from 1.4 in the slab to 2.8 in the rolled plate.During the hot rolling process,a part of inclusions was crushed into small particles of CaS phase and Al_(2)O_(3)-CaO-MgO cores,leading to a decrease in CaS content of inclusions.

关键词： Inclusion Pipeline steel Continuous casting Hot rolling Deformation

Research, development and application of compound-vertical-retort technology for magnesium production

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Journal of Magnesium and Alloys 2023年第12期11卷 4724-4736页

作者： Rongbin Li Shaojun Zhang Peixu Yang Jinhui Liu Fengqin Liu school of metallurgical and Ecological engineering University of Science and Technology BeijingBeijing 100083China school of Material science and engineering Zhengzhou UniversityZhengzhouHenan 450001China

This paper comprehensively introduces a new magnesium production technology the compound-vertical-retort technology, involving in the related fundamental researches, core equipment development, working flow, and technical characteristics. Scale-up test and an annual1200-ton-magnesium demonstration-level test was conducted to confirm the rationality, reliability, and advancement of the equipment, system and process design. It is indicated that the new technology solved a series of problems of traditional silicothermic process including adhesion and glaze, short life of retort, low efficiency, high impurity of crystallized magnesium, large heat losses, and poor working environment,making a great technological breakthrough in this field. Representatively, the new well-designed ceramic-lined steel retort serves 2~3 times in life than the normal retorts. The magnesium yield per retort is improved 4~5 times, with purity of >99.8%. The energy consumption in reduction stage is reduced by more than 20%. The mechanical production is fully realized and operating environment is significantly improved.

关键词： Silicothermic process Magnesium Compound retort Vertical retort Mechanization

Segregation behaviors of Sc and unique primary Al3Sc in Al-Sc alloys prepared by molten salt electrolysis

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Journal of Materials science & Technology 2019年第7期35卷 1422-1431页

作者： Xuan Liu Jilai Xue Zhichao Guo Cheng Zhang school of metallurgical and Ecological engineering University of Science and Technology Beijing

This work mainly deals with the segregating behaviors of Sc and the growth of unique primary Al3Sc in AlSc alloys prepared by molten salt electrolysis. The alloys contain 0.23–1.38 wt%Sc where Sc segregation is observed. It is found that a high current density and long electrolysis time are in favor of high Sc content, and so do the high temperature and the addition level of Sc2O3. Sc content at the edge of Al based alloy(average Sc content: 0.75 wt%) can be as high as 1.09 wt%, while it is merely 0.24 wt% at the central area. The cooling rates have a strong impact on the morphology and particle size of primary Al3Sc,but a weak influence on Sc segregation. The cusped cubic and dendritic primary Al3Sc can precipitate in the prepared Al-Sc alloys. In a slightly hypereutectic Al-0.67 wt%Sc alloy, a large and cusped dendrite grows from the edge into the center. The primary and secondary dendritic arms can be as long as 600 and 250 μm, respectively. The Sc segregating behaviors in Al-Sc alloys is due to the mechanism controlled by the limited diffusion rate of Sc in liquid Al. This can involve the establishment of a near spherical discharge interface between liquid Al and the electrolyte. The Sc rich layer near Al-molten salt interface may provide the potential primary nuclei and sufficient Sc atoms for the growth of large dendritic primary Al3Sc.

关键词： Al-Sc alloys Electrolysis Segregation Primary Al3Sc Discharge reaction

Reduction behavior of iron ore powder by high-volatile coal in thermogravimetric-gas chromatographic and kinetic analysis

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Journal of Iron and Steel Research(International) 2024年第1期31卷 92-107页

作者： Rui-meng Shi Qi-yuan Mi Bin Li Xiao Shi Chong Zou Jing Guo Han-jie Guo school of metallurgical engineering Xi’an University of Architecture and TechnologyXi’an710055ShaanxiChina China International engineering Consulting Corporation Beijing100048China school of metallurgical and Ecological engineering University of Science and Technology BeijingBeijing100083China

The reduction behavior of iron ore powder by high-volatile coal was investigated,and its kinetic mechanism was clarified.The effect of volatiles in coal on the reduction reaction of iron ore was compared by utilizing a Xinjiang lignite with a high volatile content and its pyrolysis carbon produced by high-temperature pyrolysis to remove volatiles,serving as a reductant.The mass loss and gas composition of the samples during the reduction process were detected using thermo-gravimetric analysis and gas chromatography,and the morphological changes of iron ore powder were observed through scanning electron microscopy.The kinetic parameters of the iron oxide reduction reaction were calculated by the Flynn-Ozawa-Wall method,and the kinetic mechanism of volatile participation in the iron oxide reduction reaction was determined through the Coats-Redfern method.The results indicate that the coupling effect between the high-volatile coal pyrolysis and reduction reactions occurs during the second stage of the entire coupling process,which corresponds to the late stage of coal pyrolysis with a substantial release of H_(2)and CO.The volatiles in coal actively participated in the reduction reaction,reducing the initiation temperature of the reaction by around 200℃.The reduction of iron oxides by high-volatile coal was jointly promoted by the"hydrogen cycle"and"carbon cycle",resulting in a higher reduction extent and metallization rate at the end of the reaction.When high-volatile coal was used as the reductant,the average activation energy for the entire process was 76.5 kJ/mol,a significant decrease compared to the employment of pyrolysis carbon without volatiles as the reductant(1167 kJ/mol).

关键词： Direct reduction High-volatile coal Volatile Kinetics Reduction mechanism

Phase transformation behavior of titanium during carbothermic reduction of titanomagnetite ironsand

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International Journal of Minerals,Metallurgy and Materials 2016年第7期23卷 760-768页

作者： Yi-ran Liu Jian-liang Zhang Zheng-jian Liu Xiang-dong Xing school of metallurgical and Ecological engineering University of Science and Technology Beijing school of metallurgical engineering Xi'an University of Architecture and Technology

The reduction of titanomagnetite（TTM） ironsand, which contains 11.41wt% TiO_2 and 55.63wt% total Fe, by graphite was performed using a thermogravimetric analysis system under an argon gas atmosphere at 1423–1623 K. The behavior and effects of titanium in TTM ironsand during the reduction process were investigated by means of thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. During the reduction procedure, the titanium concentrated in the slag phase, where the phase transformation followed this sequence： Fe O ＋ FeTiO_3 → Fe_2 TiO_4 → FeTiO_3 → FeTi_2O_5 → TiO_2. The calculated results for the reduction kinetics showed that the carbothermic reduction was controlled by the diffusion of ions through the product layer. Furthermore, the apparent activation energy was 170.35 k J·mol^（-1）.

关键词： titanomagnetite carbothermic reduction apparent activation energy phase transformation