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Tailoring BaCe0.7Zr0.1(Dy0.1|Yb0.1)0.2O3-δ electrolyte through strategic Cu doping for low temperature proton conducting fuel cells:Envisioned theoretically and experimentally

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Journal of energy Chemistry 2025年第2期101卷 692-701页

作者： Zaheer Ud Din Babar Muhammad Bilal Hanif Yan'an Li Wan-Ting Wang Hanchen Tian Cheng-Xin Li State key laboratory for Mechanical Behavior of materials School of Materials Science and Engineering Xi'an Jiaotong University Department of Inorganic Chemistry Faculty of Natural Sciences Comenius University Bratislava

This study addresses the challenge of high sintering temperatures in proton-conducting fuel cells（PCFCs）with BaCeO3-doped *** demonstrate that 1 mol% copper（Cu） doping at the B-site of BaCe0.7Zr0.1(Dy0.1|Yb0.1)0.2O3-δ（BCZDYb） improves sintering behavior,enabling densification at1400℃.However,Cu doping disrupts stoichiometry,creating barium vacancies and reducing protonaccepting cations,affecting overall *** mechanism is confirmed through density functional theory（DFT） calculations and various experimental techniques,including crystal structure analysis using X-ray diffraction（XRD） and morphology and elemental analysis via field emission scanning electron microscopy（FESEM） and energy-dispersive X-ray spectroscopy（EDS）.Electrochemical measurements are performed using the electrochemical impedance spectroscopy（EIS）.The ionic conductivity of1 mol% Cu-doped BCZDYb（BCZDYb-1） is 1.49×10-2S cm-1at 650℃,which is～3.58 times higher than that of BCZDYb sintered at 1200℃.The BCZDYb-1 exhibits ～16 times higher grain boundary conductivity when sintered at 1400℃,compared to undoped *** single cell employing BCZDYb-1 as the electrolyte achieved a power density of ～606 mW cm-2at 550℃.These results indicate that a controlled amount of Cu doping can enhance densification while maintaining high ionic co nductivity,making it suitable for practical applications in PCFCs operating at lower temperatures.

关键词： BaCe0.7Zr0.1(Dy0.1|Yb0.1)0.2O3−δ (BCZDYb) Cu-doping Densification Electrical conductivity Proton conducting fuel cells (PCFCs) Sintering

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Tailoring solvation sheath for rechargeable zinc-ion batteries:Progress and prospect

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materials Reports(energy) 2025年第1期5卷 3-18页

作者： Xiaomin Cheng Jing Dong Haifeng Yang Xiang Li Xinyu Zhao Bixian Chen Yongzheng Zhang Meinan Liu Jian Wang Hongzhen Lin i-Lab&CAS key laboratory of nanophotonic materials and Devices Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou215123China State key laboratory of Chemical Engineering East China University of Science and TechnologyShanghai200237China Anhui Provincial key laboratory of Green Carbon Chemistry Fuyang Normal UniversityFuyang236037China State key laboratory of Featured Metal materials and Life-cycle Safety for Composite Structures Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured MaterialsSchool of ResourcesEnvironment and MaterialsGuangxi UniversityNanning530004China Helmholtz Institute Ulm(HIU) D89081 UlmKarlsruhe Institute of Technology(KIT)D76021 KarlsruheGermany school of materials Science and Engineering Jiangsu UniversityZhenjiang212013JiangsuChina

Aqueous zinc-metal based batteries(AZMBs)perfectly combine safety,economy and pro-environment,but their performance is arresting limited by the interfacial instability caused by the large desolvation energy barrier of[Zn(H2O)6]^(2+)and the massive release of active water at the electrolyte/electrode *** this review,we briefly outline the solvation structure of zinc ions and the necessity of ***,the variety of strategies to solve these issues,mainly including reorganizing solvation sheath by changing electrolyte environment and accelerating interface desolvation by constructing artificial interfacial layer,are categorically discussed and systematically ***,perspectives and suggestions regarding desolvation theories,interfacial evolution,material design and analysis techniques are proposed to design highly stable zinc anodes.

关键词： Aqueous zinc-metal based batteries Desolvation Electrolyte strategy Interfacial layer

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Modulation of the octahedral structure and potential superconductivity of La_(3)Ni_(2)O_(7)through strain engineering

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Science China(Physics,Mechanics & Astronomy) 2025年第3期68卷 145-152页

作者： Zihao Huo Zhihui Luo Peng Zhang Aiqin Yang Zhengtao Liu Xiangru Tao Zihan Zhang Shumin Guo Qiwen Jiang Wenxuan Chen Dao-Xin Yao Defang Duan Tian Cui key laboratory of Material Simulation Methods&Software of Ministry of Education State Key Laboratory of Superhard MaterialsCollege of PhysicsJilin UniversityChangchun130012China Center for Neutron Science and technology Guangdong Provincial Key Laboratory of Magnetoelectric Physics and DevicesState Key Laboratory of Optoelectronic Materials and TechnologiesSchool of PhysicsSun Yat-sen UniversityGuangzhou510275China MOE key laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter Shaanxi Province Key Laboratory of Advanced Functional Materials and Mesoscopic PhysicsSchool of PhysicsXi’an Jiaotong UniversityXi’an710049China Institute of High Pressure Physics School of Physical Science and TechnologyNingbo UniversityNingbo315211China

The recent transport measurements of La_(3)Ni_(2)O_(7)uncovered a“right-triangle”shape of the superconducting dome in the pressure-temperature(P-T)phase *** by this,we perform theoretical first-principles studies of La_(3)Ni_(2)O_(7)with the pressure ranging from 0 to 100 ***,we reveal a pressure dependence of the Ni-d_(z^(2))electron density at the Fermi energy(n_(z)^(E_(F)))that highly coincides with such *** this basis,we further explore the electronic structure under uniaxial *** tracking the stress response of n_(z)^(E_(F)),we propose that superconductivity can be achieved by applying only ~2GPa of compression along the c *** idea is further exemplified from the perspectives of lattice distortion,band structure,Fermi surface and superconducting phase *** also discuss the possible charge modulation under the stress and provide an insight into the relation between nz E Fand the superconducting T_(c)in La_(3)Ni_(2)O_(7)*** study provides new routes to the search of high-T_(c)superconductors in future experiments.

关键词： nickelate superconductors density functional theory strong correlated systems strain engineering

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Construction of attapulgite-based one-dimensional nanonetwork composites with corrosion resistance for high-efficiency microwave absorption

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International Journal of Minerals,Metallurgy and materials 2025年第3期32卷 689-698页

作者： Kai Xu Qingqing Gao Shaoqi Shi Pei Liu Yinxu Ni Zhilei Hao Gaojie Xu Yan Fu Fenghua Liu school of materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China Zhejiang key laboratory of Additive Manufacturing materials Ningbo Institute of Materials Technology&EngineeringChinese Academy of SciencesNingbo 315201China Northwest Yongxin Coatings Limited Company Lanzhou 730046China

Exploring high-efficiency and broadband microwave absorption(MA)materials with corrosion resistance and low cost is ur-gently needed for wide practical ***,the natural porous attapulgite(ATP)nanorods embedded with TiO_(2)and polyaniline(PANI)nanoparticles are synthesized via heterogeneous precipitation and in-situ *** obtained PANI-TiO_(2)-ATP one-di-mensional(1D)nanostructures can intertwine into three-dimensional(3D)conductive network,which favors energy *** min-imum reflection loss(RL_(min))of the PANI-TiO_(2)-ATP coating(20wt%)reaches-49.36 dB at 9.53 GHz,and the effective absorption band-width(EAB)can reach 6.53 GHz with a thickness of 2.1 *** excellent MA properties are attributed to interfacial polarization,mul-tiple loss mechanisms,and good impedance matching induced by the synergistic effect of PANI-TiO_(2)nanoparticle shells and ATP *** addition,salt spray and Tafel polarization curve tests reveal that the PANI-TiO_(2)-ATP coating shows outstanding corrosion resist-ance *** study provides a low-cost and high-efficiency strategy for constructing 1D nanonetwork composites for MA and corrosion resistance applications using natural porous ATP nanorods as carriers.

关键词： microwave absorption corrosion resistance attapulgite TiO_(2) polyaniline

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Review of recent advances in ferrite-based materials:From synthesis techniques to electromagnetic wave absorption performance

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International Journal of Minerals,Metallurgy and materials 2025年第3期32卷 591-608页

作者： Xingliang Chen Di Lan Luoting Zhou Hailing Liu Xiyu Song Shouyu Wang Zhuanyong Zou Guanglei Wu Shaoxing key laboratory of High Performance Fibers&Products Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang ProvinceShaoxing UniversityShaoxing 312000China school of materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002China Chinatesta(Zhejiang)Testing Services Co. Ltd.Shaoxing 312000China Institute of materials for energy and Environment State Key Laboratory of Bio-fibers and Eco-textilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China

With the booming development of electronic information science and 5G communication technology,electromagnetic radi-ation pollution poses a huge threat and damage to *** novel and high-performance electromagnetic wave(EMW)ab-sorbers is an effective method to solve the above issue and has attracted the attention of many *** a typical magnetic material,ferrite plays an important role in the design of high-performance EMW absorbers,and related research focuses on diversified synthesis methods,strong absorption performance,and refined microstructure ***,we focus on the synthesis of ferrites and their composites and introduce recent advances in the high-temperature solid-phase method,sol-gel method,chemical coprecipitation method,and solvent thermal method in the preparation of high-performance EMW *** review aims to help researchers understand the advantages and disadvantages of ferrite-based EMW absorbers fabricated through these *** also provides important guidance and reference for researchers to design high-performance EMW absorption materials based on ferrite.

关键词： ferrite electromagnetic wave absorber sol-gel method magnetic material solvent thermal method

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Dual-phase interface engineering via parallel modulation strategy for highly reversible Zn metal batteries

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Journal of energy Chemistry 2025年第2期101卷 163-174页

作者： Zhean Bao Yang Wang Kun Zhang Guosheng Duan Leilei Sun Sinan Zheng Bin Luo Zhizhen Ye Jingyun Huang school of materials Science and Engineering State Key Laboratory of Silicon and Advanced Semiconductor Materials Zhejiang University Institute of Wenzhou Zhejiang University Institute of Thermal Science and Power Systems Zhejiang University Longmen laboratory of Luoyang

The reversibility and stability of aqueous Zn metal batteries（AZMBs） are largely limited by Zn dendrites and interfacial parasitic ***,we propose a parallel modulation strategy to boost the reversibility of the Zn anode by introducing N,N,N',N'-tetramethylchloroformamidinium hexafluorophosphate（TCFH） as an additive in the *** is composed of PF6-and TN+with opposite ***6-can spontaneously induce the in-situ generation of ZnF2solid electrolyte interface（SEI） on the anode,which can improve the transport kinetics of Zn2+at the interface,thus promoting the rapid and uniform deposition of Zn as well as inhibiting the growth of *** addition,TN+is enriched at the anode surface during Zn deposition through the anchoring effect,which brings a reconfiguration of the ion/molecule *** anchored-TN+reduces the concentrations of H2O and SO42-,sufficiently restraining the parasitic *** to the dual-phase interface engineering constructed of PF6-and TN+in parallel,the symmetric cell with the proposed electrolyte survives long cycling stability over750 h at 20 mA cm-2,10 mAh *** study offers a distinct viewpoint to the multidimensional optimization of Zn anodes for high-performance AZMBs.

关键词： Anchoring effect Aqueous Zn metal batteries Electrolyte additive Solid electrolyte interface Zn anode

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Enhanced rate capability and cycle stability of Ti2C MXene for sodium storage through an aniline molecules welding strategy

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Tungsten 2025年第1期7卷 161-171页

作者： Hao Chen Ya-Qin Wang Dong-Ting Zhang Bei Zhao Min-Peng Li Chen-Yang Li Tian-Peng Xu Mao-Cheng Liu State key laboratory of Advanced Processing and Recycling of Non-Ferrous Metals Lanzhou University of Technology school of materials Science and Engineering Lanzhou University of Technology school of Computer and Communication technology Lanzhou University of Technology

MXenes obtained significant attention in the field of energy storage devices due to their characteristic layered structure,modifiable surface functional groups,large electrochemically active surface,and regulable interlayer ***,the self-restacking and sluggish ions diffusion kinetics performance of MXenes during the alkali metal ions insertion/extraction process severely impedes their cycle stability and rate *** paper proposes an aniline molecule welding strategy for welding p-phenylenediamine（PPDA） into the interlayers of Ti2C through a dehydration condensation *** welded PPDA molecules can contribute pillar effect to the layered structure of *** pillar effect effectively maintains the structural stability during the sodium ions insertion/extraction process and effectively expands the interlayer spacing of Ti2C from 1.16 to 1.38 nm,thereby enhancing ions diffusion kinetics performance and improving the long-term cycle *** Ti2C-PPDA demonstrates outstanding Na+storage capability,exhibiting a specific capacity of 100.2 mAh·g-1at a current density of 0.1 A·g-1over 960 cycles and delivering a remarkable rate capability 81.2 mAh·g-1at a current density of 5 A·*** study demonstrates that expanding interlayer spacing is a promising strategy to enhance the Na+storage capacity and improve long-term cycling stability,which provides significant guidance for the design of two-dimensional Na+storage materials with high-rate capability and cycle stability.

关键词： Diffusion kinetics Expanding interlayer spacing Rate capability Sodium ions storage Ti2C

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Phase changes and electromagnetic wave absorption performance of XZnC(X=Fe/Co/Cu)loaded on melamine sponge hollow carbon composites

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International Journal of Minerals,Metallurgy and materials 2025年第3期32卷 566-577页

作者： Xiubo Xie Ruilin Liu Chen Chen Di Lan Zhelin Chen Wei Du Guanglei Wu school of Environmental and Material Engineering Yantai UniversityYantai 264005China school of materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002China Shandong key laboratory of Eco-Environmental Science for the Yellow River Delta Shandong University of AeronauticsBinzhou 256603China Institute of materials for energy and Environment State Key Laboratory of Bio-fibers and Eco-textilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071China

Non-stoichiometric carbides have been proven to be effective electromagnetic wave(EMW)absorbing *** this study,phase and morphology of XZnC(X=Fe/Co/Cu)loaded on a three dimensional(3D)network structure melamine sponge(MS)carbon composites were investigated through vacuum filtration followed by *** FeZnC/CoZnC/CuZnC with carbon nanotubes(CNTs)were uniformly dispersed on the surface of melamine sponge carbon skeleton and Co-containing sample exhibits the highest CNTs *** minimum reflection loss(RL_(min))of the CoZnC/MS composite(m_(composite):m_(paraffin)=1:1,m represents mass)reached-33.60 dB,and the effective absorption bandwidth(EAB)reached 9.60 *** outstanding electromagnetic wave absorption(EMWA)properties of the CoZnC/MS composite can be attributed to its unique hollow structure,which leads to multiple reflections and *** formed conductive network improves dielectric and conductive *** incorporation of Co enhances the magnetic loss capability and optimizes interfacial polarization and dipole *** simultaneously improving dielectric and magnetic losses,ex-cellent impedance matching performance is *** clarification of element replacement in XZnC/MS composites provides an effi-cient design perspective for high-performance non-stoichiometric carbide EMW absorbers.

关键词： electromagnetic wave absorption three dimensional network structure melamine sponge derived carbon non-stoichiometric carbide

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Enhancement of weathered crust elution-deposited rare earth ores leaching process with PQ-10 addition

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Journal of Rare Earths 2025年第1期43卷 180-190,I0007页

作者： Aoyang Sha Huifang Yang Zhengyan He Zhigao Xu Chenjie Wu Ming Wu Ru'an Chi key laboratory of Catalysis and energy materials Chemistry of Ministry of Education Key Laboratory of Resources Conversion and Pollution Control of the State Ethnic Affairs Commission&Hubei Key Laboratory of Catalysis and Materials ScienceCollege of Resources and Environmental ScienceSouth-Central Minzu UniversityWuhan430074China key laboratory for Green Chemical Process of Ministry of Education School of Resources&Safety EngineeringWuhan Institute of TechnologyWuhan 430073China

To solve the problems of the long development period,low mass transfer efficiency and high impurity conte nt in the in-situ leaching process of weathe red crust elution-deposited rare earth ores(WCE-DREO),cationic hydroxyethyl cellulose(PQ-10)was composited with conventional leaching agent ammonium sulfate((NH_(4))_(2)SO_(4))to form a novel composite leaching *** effects of PQ-10 concentration,leaching temperature and leaching flow rate of the composite leaching agent on the leaching kinetics and mass transfer processes of rare earth(RE)and aluminum(Al)were *** to the single leaching agent(NH_(4))_(2)SO_(4),the composite leaching agent(2 wt%(NH_(4))_(2)SO_(4)+0.02 wt%PQ-10)can reduce the RE leaching equilibrium time from 465 to 130 min and increase the RE leaching efficiency and decrease the Al leaching *** also facilitates the leaching process of WCE-DREO by increasing the peak concentrations of RE and Al,reducing the theoretical tower plate height(HETP)and improving the leaching mass transfer *** is indicated that PQ-10 can promote the leaching of *** leaching process of the composite leaching system conforms to the diffusion kinetic control *** the PQ-10 concentration is in the range of 0.005 wt%-0.020 wt%,the reaction orders of RE and Al are 0.73 and 0.54,respectively,which shows a positive effect on the leaching velocity;when the PQ-10 concentration is in the range of 0.030 wt%-0.060 wt%,the reaction orders of RE and Al are-1.16 and-0.75,respectively,which show a negative effect on the leaching *** the range of 10-50℃,the apparent activation energies of RE and Al are 15.02 and 17.31 kJ/mol,respectively,and the higher the leaching temperature,the smaller the HETP and the higher the leaching velocity and mass transfer *** increase in leaching flow rate contributes to the increase in the longitudinal diffusion velocity of the leaching agent within WCE-DREO,causing a shorter time for RE

关键词： Cationic hydroxyethyl cellulose Weathered crust elution-deposited rare earthores Leaching Novel compositeagent

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Interfacial Pt-N coordination for promoting oxygen reduction reaction

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Chinese Chemical Letters 2025年第2期36卷 509-513页

作者： Jialin Cai Yizhe Chen Ruiwen Zhang Cheng Yuan Zeyu Jin Yongting Chen Shiming Zhang Jiujun Zhang Institute for Sustainable energy/College of Sciences Shanghai University school of Chemistry and Chemical Engineering Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials Wuhan University of Science and Technology

Nitrogen-doping of carbon support（N-C） for platinum（Pt） nanoparticles to form Pt/N-C catalyst represents an effective strategy to promote the electrocatalysis of cathodic oxygen reduction reaction（ORR）in proton exchange membrane fuel cells. For fundamental understanding, clearly identifying the metalsupport effect on enhancement mechanisms of ORR electrocatalysis is definitely needed. In this work,the impact of Pt-support interaction via interfacial Pt-N coordination on electrocatalytic ORR activity and stability in Pt/N-C catalyst is deeply studied through structural/compositional characterizations,electrochemical measurements and theoretical DFT-calculations/AIMD-simulations. The resulting Pt/N-C catalyst exhibits a superior electrocatalytic performance compared to the commercial Pt/C catalyst in both half-cell and H2-O2fuel cell. Experimental and theoretical results reveal that the interfacial Pt-N coordination enables electron transfer from N-C support to Pt nanoparticles, which can weaken the adsorption strength of oxygen intermediates on Pt surface to improve ORR activity and induce the strong Pt-support interaction to enhance electrochemical stability.

关键词： N-doped carbon Oxygen reduction reaction Platinum Pt-N Theoretical calculations

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