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Co/Co_(7)Fe_(3)heterostructures with controllable alloying degree on carbon spheres as bifunctional electrocatalyst forrechargeable zinc-air batteries

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International Journal of Minerals,Metallurgy and materials 2025年第2期32卷 476-487页

作者： Junkang Chen Yongyue Zhuang Yanxin Qiao Yu Zhang Aihua Yuan Hu Zhou school of materials science and engineering Jiangsu University of Science and TechnologyZhenjiang 212003China school of Environmental and Chemical engineering Jiangsu University of Science and TechnologyZhenjiang 212003China

Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is crucial for developing rechargeable zinc-air batteries(ZABs).Herein,an alloying-degree control strategy was employed to fabricate nitrogen-doped carbon sphere(NCS)decorated with dual-phase Co/Co_(7)Fe_(3)heterojunctions(CoFe@NCS).The phase composition of materials has been adjusted by controlling the alloying *** optimal CoFe_(0.08)@NCS electrocatalyst displays a half-wave potential of 0.80 V for ORR and an overpotential of 283 mV at 10 mA·cm^(-2)for OER in an alkaline *** intriguing bifunctional electrocatalytic activity and durability is attributed to the hierarchically porous structure and interfacial electron coupling of highly-active Co_(7)Fe_(3)alloy and metallic Co *** the CoFe_(0.08)@NCS material is used as air-cathode catalyst of rechargeable liquid-state zinc-air battery(ZAB),the device shows a high peak power-density(157 mW·cm^(-2))and maintains a stable voltage gap over 150 h,outperforming those of the benchmark(Pt/C+RuO_(2))-based *** particular,the as-fabricated solid-state flexible ZAB delivers a reliable compatibility under different bending *** work provides a promising strategy to develop metal/alloy-based electrocatalysts for the application in renewable energy conversion technologies.

关键词： bifunctional electrocatalysts oxygen reduction reaction oxygen evolution reaction zinc-air battery metal/alloy carbon sphere

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Metallized polymer current collector as “stress acceptor” for stable micron-sized silicon anodes

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Journal of Energy Chemistry 2025年第2期101卷 786-794页

作者： Ziyi Cao Haoteng Sun Yi Zhang Lixia Yuan Yaqi Liao Haijin Ji Shuaipeng Hao Zhen Li Long Qie Yunhui Huang State Key Laboratory of material Processing and Die & Mold technology School of Materials Science and Engineering Huazhong University of Science and Technology Department of Chemistry Brown University

Micron-sized silicon（μSi） is a promising anode material for next-generation lithium-ion batteries due to its high specific capacity,low cost,and abundant ***,the volume expansion that occurs during cycling leads to the accumulation of undesirable stresses,resulting in pulverization of silicon microparticles and shortened lifespan of the ***,a composite film of Cu-PET-Cu is proposed as the current collector（CC） for μSi anodes to replace the conventional Cu ***-PET-Cu CC is prepared by depositing Cu on both sides of a polyethylene terephthalate（PET） *** PET layer promises good ductility of the film,permitting the Cu-PET-Cu CC to accommodate the volumetric changes of silicon microparticles and facilitates the stress release through ductile *** a result,the μSi electrode with Cu-PET-Cu CC retains a high specific capacity of 2181 mA h g-1,whereas the μSi electrode with Cu CC（μSi/Cu） exhibits a specific capacity of 1285 mA h g-1after 80 *** stress relieving effect of CuPET-Cu was demonstrated by in-situ fiber optic stress monitoring and multi-physics *** work proposes an effective stress relief strategy at the electrode level for the practical implementation of μSi anodes.

关键词： Electrode design Metallized polymer current collector Micron-sized Si anodes Stress relieving

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Synergistically enhanced ORR and HER performance on Co-N-C coupled in-situ generated PtCo intermetallic

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Journal of Energy Chemistry 2025年第1期100卷 721-729页

作者： Guanyu Luo Min Song Lulu An Xiao Huang Qian Zhang Chenhao Zhang Tao Shen Shuang Wang Deli Wang Key Laboratory of material Chemistry for Energy Conversion and Storage(Huazhong university of science and technology)Ministry of Education School of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina

Integrating multi-scale sites in a composite catalyst is vital to realize efficient ***,a synergistic composite catalyst consisting of Co atomic sites and in-situ generated PtCo intermetallic compounds (IMCs)(o-PtCo@CoNC) is proposed through Co pre-anchoring and subsequent impregnation-reduction *** loading of Co atoms provides a chance for in-situ generating PtCo ordered intermetallic *** remaining Co single atoms and PtCo IMCs construct synergistic electrocatalytic *** from the ordered structure,synergistic effect of Pt Co IMCs and Co single atoms,o-PtCo@CoNC exhibits excellent electrocatalytic performance for oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) with mass activity of 1.21 A mgPt-1(at 0.9 V) and5.70 A mgPt-1(at an overpotential of 100 mV),***,o-PtCo@CoNC delivers negligible loss of half-wave potential and overpotential during long-term stability test in acid solutions,with 13 mV decay after 50,000 potential cycles for ORR and a 2.7 mV decay after 20,000 potential cycles for *** integration strategy of single-atomic sites coupled IMCs paves the way for enhancing the activity and durability of Pt-based electrocatalysts.

关键词： Synergistic effect Intermetallics Single atomic sites Oxygen reduction reaction Hydrogen evolution reaction

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Low-dose X-ray induced long afterglow NIR luminescence from Cr^(3+)doped Zn_(1-x)Cd_(x)Ga_(2)O_(4)spinel solid solutions

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Journal of Rare Earths 2025年第2期43卷 246-252,I0001页

作者： Tingting Zhao Wenzhi Sun Shuya Wang Wei Meng Chunqing Fu Xiaoyan Fu Hongwu Zhang school of Chemistry and material sciences Ludong UniversityYantai264025China College of materials science and engineering Xiamen University of TechnologyXiamen361024China

The low-dose X-ray induced long afterglow near infrared(NIR)luminescence from Cr^(3+)doped Zn_(1-x)Cd_(x)Ga_(2)O_(4)spinel solid solutions was *** structure analysis shows the good formation of Zn_(1-x)Cd_(x)Ga_(2)O_(4)spinel solid solutions,which possesses a cubic spinel structure with Fd3m space *** formation of Zn_(1-x)Cd_(x)Ga_(2)O_(4)spinel solid solutions induces the obvious increase of long afterglow near infrared luminescence excited by low-dose X-ray,When the content of doped Cd^(2+)reaches 0.1,the low-dose X-ray induced long afterglow NIR luminescence is the *** importantly,only 5 s Xray irradiation can induce more than 6 h NIR afterglow emission,of which the afterglow luminescent intensity is still 5 times stronger than the background intensity after 6 *** thermoluminescent results show that under the 5 s exposure of X-ray,the trap density of Zn_(0.9)Cd_(0.1)Ga_(2)O_(4):Cr^(3+)is much higher than that of ZnGa_(2)O_(4):Cr^(3+).The replacement of Cd^(2+)ions with large radius at Zn^(2+)sites causes the increase of de fects and dislocations,which results in the obvious increase of trap co *** the addition of high-z number elements Cd^(2+)would enhance the X-ray absorption of the solid solutions,which thus can be easily excited by low-dose ***_(0.9)Cd_(0.1)Ga_(2)O_(4):1%Cr^(3+)solid solution is a potential candidate of lowdose X-ray induced long afterglow luminescent materials.

关键词： Zn_(1-x)Cd_(x)Ga_(2)O_(4):1%Cr^(3+) Phosphors Solid solutions X-ray induced long afterglow luminescence Rare earths

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Facile construction of heterogeneous dual-ionic poly(ionic liquid)s for efficient and mild conversion of CO_(2)into cyclic carbonates

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Journal of Environmental sciences 2025年第3期149卷 177-187页

作者： Guanqun Xie Jiaxiang Qiu Huadeng Li Hongbin Luo Shuo Li Yanbin Zeng Ke Zheng Xiaoxia Wang school of Environment and Civil engineering Dongguan University of TechnologyDongguan 523808China school of materials science and engineering Guangdong Provincial Engineering Technology Research Center of Key Material for High Performance Copper Clad LaminateDongguan University of TechnologyDongguan 523808China

In the context of peaking carbon dioxide emissions and carbon neutrality,development of feasible methods for converting CO_(2)into high value-added chemicals stands out as a hot *** this study,P[D+COO^(−)][Br^(−)][DBUH^(+)],a series of novel heterogeneous dual-ionic poly(ionic liquid)s(PILs)were synthesized readily from 2-(dimethylamino)ethyl methacrylate(DMAEMA),bromo-substituted aliphatic acids,organic bases and divinylbenzene(DVB).The structures,compositions and morphologies were characterized or determined by nuclear magnetic resonance(NMR),thermal gravimetric analysis(TGA),infrared spectroscopy(IR),scanning electron microscopes(SEM),and Brunauer-Emmett-Teller analysis(BET),*** of the P[D+COO^(−)][Br^(−)][DBUH^(+)]series as catalysts in converting CO_(2)into cyclic carbonates showed that P[D+COO^(−)][Br^(−)][DBUH^(+)]-2/1/0.6was able to catalyze epiclorohydrin-CO_(2)cycloaddition the most *** afforded chloropropylene carbonate(CPC)in 98.4%yield with≥99%selectivity in 24 hr under solvent-and additive-free conditions at atmospheric *** experiments showed that recycling of the catalyst 6 times only resulted in a slight decline in the catalytic *** addition,it could be used for the synthesis of a variety of differently substituted cyclic carbonates in good to excellent ***,key catalytic active sites were probed,and a reasonable mechanism was proposed *** summary,this work poses an efficient strategy for heterogenization of dual-ionic PILs and provides amild and environmentally benign approach to the fixation and utilization of carbon dioxide.

关键词： Dual-ionic poly(ionic liquid)s CO_(2)cycloaddition Epoxides Cyclic carbonates Heterogeneous catalysts

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Effect of chlorination and ultraviolet on the adsorption of pefloxacin on polystyrene and polyvinyl chloride

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Journal of Environmental sciences 2025年第3期149卷 21-34页

作者： Yanan Li Yaning Wu Kai Guo Weiqin Wu Meijing Yao school of Environmental science and engineering Taiyuan University of TechnologyShanxi 030600China

During thewater treatment process,chlorination and ultraviolet(UV)sterilization can modify microplastics(MPs)and alter their physicochemical properties,causing various changes between MPs and other *** this study,the impact of chlorination and UV modification on the physicochemical properties of polystyrene(PS)and polyvinyl chloride(PVC)were investigated,and the adsorption behavior of pefloxacin(PEF)before and after modificationwas *** effect of pH,ionic strength,dissolved organicmatter,heavymetal ions and other water environmental conditions on adsorption behavior was *** results showed that PS had a higher adsorption capacity of PEF than PVC,and the modification increased the presence of O-containing functional groups in the MPs,thereby enhancing the adsorption capacity of both *** had a more significant impact on the physicochemical properties of MPs compared to UV irradiation within the same time period,leading to better adsorption performance of *** optimal pH for adsorption was found to be 6,and NaCl,sodium alginate and Cu2+would inhibit adsorption to varying degrees,among which the inhibition caused by pH was the *** and UV modification would weaken the inhibitory effect of environmental factors on the adsorption of PEF by *** main mechanisms of adsorption involved electrostatic interaction and hydrogen *** study clarified the effects of modification on the physicochemical properties of MPs,providing reference for subsequent biotoxicity analysis and environmental protection studies.

关键词： Microplastics Chlorination Ultraviolet Pefloxacin Adsorption mechanism

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Enhancement of bending toughness for Fe-based amorphous nanocrystalline alloy with deep cryogenic-cycling treatment

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china Foundry 2025年第1期22卷 99-107页

作者： Yi-ran Zhang Dong Yang Qing-chun Xiang Hong-yu Liu Jing Pang Ying-lei Ren Xiao-yu Li Ke-qiang Qiu school of materials science and engineering Shenyang University of TechnologyShenyang 110870China Qingdao Yunlu Advanced material technology Co. Ltd.Qingdao 266232ShandongChina

The effects of deep cryogenic-cycling treatment(DCT)on the mechanical properties,soft magnetic properties,and atomic scale structure of the Fe_(73.5)Si_(13.5)B_(9)Nb_(3)Cu_(1)amorphous nanocrystalline alloy were *** DCT samples were obtained by subjecting the as-annealed samples to a thermal cycling process between the temperature of the supercooled liquid zone and the temperature of liquid *** flat plate bending testing,hardness measurements,and nanoindentation experiment,it is found that the bending toughness of the DCT samples is improved and the soft magnetic properties are also slightly *** are attributed to the rejuvenation behavior of the DCT samples,which demonstrate a higher enthalpy of ***,DCT is an effective method to enhance the bending toughness of Fe-based amorphous nanocrystalline alloys without degrading the soft magnetic properties.

关键词： deep cryogenic-cycling treatment Fe-based amorphous nanocrystalline alloy bending toughness rejuvenation

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Universal design of three-dimensional porous graphene-iron based promotors for kinetically rationalized lithium-sulfur chemistry

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Journal of Energy Chemistry 2025年第1期100卷 192-200页

作者： Hua Gao Yunfeng Zhang Menglei Wang Ruoxuan Yang Shuai Feng Xuan Cao Yaping Zhang Zhongyuan Lu Yingze Song State Key Laboratory of Environment-Friendly Energy materials School of Materials and ChemistrySouthwest University of Science and TechnologyMianyang 621010SichuanChina school of material science and engineering Henan University of TechnologyZhengzhou 450001HenanChina College of Chemistry and Chemical engineering Taishan UniversityTai’an 271021ShandongChina

Lithium-sulfur(Li-S)batteries are widely deemed to be one of the most potential candidates for future secondary batteries because of their remarkable energy ***,notorious polysulfide shuttling and retarded sulfur reaction kinetics pose significant obstacles to the further application of Li-S *** rationally designed highly active electrocatalysts can facilitate polysulfide conversion,the universal and scalable synthesis strategies need to be ***,a universal synthetic strategy to construct a series of three-dimensional(3D)porous graphene-iron(3DGr-Fe)based electrocatalysts involving 3DGr-FeP,3DGr-Fe_(3)C,and 3DGr-Fe_(3)Se_(4)is exploited for manipulating the Li-S redox *** has been observed that the implementation of a 3D porous Gr architecture leads to the well-designed conductive networks,while the uniformly dispersed iron nanoparticles introduce an abundance of active sites,fostering the lithium polysulfide conversion,thereby bolstering the overall electrochemical *** Li-S battery with the 3DGr-Fe based electrocatalyst exhibits remarkable capacity retention of 94.8%upon 100 times at 0.2 ***,the soft-packaged Li-S pouch cell based on such a 3DGr-Fe electrocatalyst delivers superior capacity of 1060.71 mA h g^(-1)and guarantees for the continuous 30 min work of fan *** investigation gives comprehensive insights into the design,synthesis,and mechanism of 3DGr-Fe based electrocatalysts with high activity toward efficient and durable Li-S batteries.

关键词： Lithium-sulfur battery Universal synthesis 3D graphene-iron based promotor Electrocatalysis

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MXene Hybridized Polymer with Enhanced Electromagnetic Energy Harvest for Sensitized Microwave Actuation and Self‑Powered Motion Sensing

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Nano-Micro Letters 2025年第3期17卷 265-279页

作者： Yu‑Ze Wang Yu‑Chang Wang Ting‑Ting Liu Quan‑Liang Zhao Chen‑Sha Li Mao‑Sheng Cao school of materials science and engineering Beijing Institute of TechnologyBeijing 100081People’s Republic of China school of materials science and engineering Peking UniversityBeijing 100871People’s Republic of China school of Mechanical and material engineering North China University of TechnologyBeijing 100144People’s Republic of China Key Laboratory of Functional Inorganic material Chemistry Ministry of Education of the People’s Republic of ChinaHeilongjiang UniversityHarbin 150080People’s Republic of China

Polymeric microwave actuators combining tissue-like softness with programmablemicrowave-responsive deformation hold great promise for mobile intelligentdevices and bionic soft robots. However, their application is challenged by restricted electromagneticsensitivity and intricate sensing coupling. In this study, a sensitized polymericmicrowave actuator is fabricated by hybridizing a liquid crystal polymer with Ti3C2Tx(MXene). Compared to the initial counterpart, the hybrid polymer exhibits unique spacechargepolarization and interfacial polarization, resulting in significant improvements of230% in the dielectric loss factor and 830% in the apparent efficiency of electromagneticenergy harvest. The sensitized microwave actuation demonstrates as the shortenedresponse time of nearly 10 s, which is merely 13% of that for the initial shape memory polymer. Moreover, the ultra-low content of MXene (upto 0.15 wt%) benefits for maintaining the actuation potential of the hybrid polymer. An innovative self-powered sensing prototype that combinesdriving and piezoelectric polymers is developed, which generates real-time electric potential feedback (open-circuit potential of ~ 3 mV) duringactuation. The polarization-dominant energy conversion mechanism observed in the MXene-polymer hybrid structure furnishes a new approachfor developing efficient electromagnetic dissipative structures and shows potential for advancing polymeric electromagnetic intelligent devices.

关键词： Microwave absorption Electromagnetic response Energy harvest Self-sensing Soft actuator

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Axial coordinated iron-nitrogen-carbon as efficient electrocatalysts for hydrogen evolution and oxygen redox reactions

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Chinese Chemical Letters 2025年第1期36卷 637-642页

作者： Yanan Zhou Li Sheng Lanlan Chen Wenhua Zhang Jinlong Yang school of material science and Chemical engineering Institute of Mass SpectrometryNingbo UniversityNingbo 315211China Department of Chemical Physics University of Science and Technology of ChinaHefei 230026China Department of material science and engineering University of Science and Technology of ChinaHefei 230026China Hefei National Laboratory for Physical sciences at the Microscale CAS Key Laboratory of Materials for Energy Conversion and Synergetic Innovation Centre of Quantum Information and Quantum PhysicsUniversity of Science and Technology of ChinaHefei 230026China

Designing highly active electrocatalysts for the hydrogen evolution reaction(HER)and oxygen evolution and reduction reactions(OER and ORR)is pivotal to renewable energy ***,based on density functional theory(DFT)calculations,we systematically investigate the catalytic activity of iron-nitrogen-carbon based covalent organic frameworks(COF)monolayers with axially coordinated ligands(denotes as Fe N_(4)-X@COF,X refers to axial ligand,X=-SCN,-I,-H,-SH,-NO_(2),-Br,-ClO,-Cl,-HCO_(3),-NO,-ClO_(2),-OH,-CN and-F).The calculated results demonstrate that all the catalysts possess good thermodynamic and electrochemical *** different ligands axially ligated to the Fe active center could induce changes in the charge of the Fe center,which further regulates the interaction strength between intermediates and catalysts that governs the catalytic ***,FeN_(4)-SH@COF and Fe N_(4)-OH@COF are efficient bifunctional catalysts for HER and OER,FeN_(4)-OH@COF and FeN_(4)-I@COF are promising bifunctional catalysts for OER and *** findings not only reveal promising bifunctional HER/OER and OER/ORR catalysts but also provide theoretical guidance for designing optimum ironnitrogen-carbon based catalysts.

关键词： Axial coordinated ligands DFT calculation Hydrogen evolution reaction Oxygen evolution reaction Oxygen reduction reaction

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