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A defective iron-based perovskite cathode for high-performance IT-SOFCs:Tailoring the oxygen vacancies using Nb/Ta co-doping

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Journal of energy Chemistry 2024年第1期88卷 306-316,I0008页

作者： Bayu Admasu Beshiwork Xinyu Wan Min Xu Haoran Guo Birkneh Sirak Teketel Yu Chen Jun Song Chen Tingshuai Li Enrico Traversa school of Materials and energy University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina The Future Laboratory Tsinghua UniversityBeijing 100084China school of Chemical Sciences University of Chinese Academy of SciencesBeijing 100049China schoolof environment and energy South China University of Technlogy Guangzhou 50006GuangongChina Institute for Advanced Study Chengdu UniversityChengdu 610106SichuanChina

The sluggish kinetics of the electrochemical oxygen reduction reaction(ORR)in intermediatetemperature solid oxide fuel cells(IT-SOFCs)greatly limits the overall cell performance.In this study,an efficient and durable cathode material for IT-SOFCs is designed based on density functional theory(DFT)calculations by co-doping with Nb and Ta the B-site of the SrFeO_(3-δ)perovskite oxide.The DFT calculations suggest that Nb/Ta co-doping can regulate the energy band of the parent SrFeO_(3-δ)and help electron transfer.In symmetrical cells,such cathode with a SrFe_(0.8)Nb_(0.1)Ta_(0.1)O_(3-δ)(SFNT)detailed formula achieves a low cathode polarization resistance of 0.147Ωcm^(2) at 650℃.Electron spin resonance(ESR)and X-ray photoelectron spectroscopy(XPS)analysis confirm that the co-doping of Nb/Ta in SrFeO_(3-δ)B-site increases the balanced concentration of oxygen vacancies,enhancing the electrochemical performance when compared to 20 mol%Nb single-doped perovskite oxide.The cathode button cell with NiSDC|SDC|SFNT configuration achieves an outstanding peak power density of 1.3 W cm^(-2)at 650℃.Moreover,the button cell shows durability for 110 h under 0.65 V at 600℃ using wet H_(2) as fuel.

关键词： Solid oxide fuel cell Cathode Oxygen reduction reaction Power density DFT calculation

Degradation analysis and doping modification optimization for high-voltage P-type layered cathode in sodium-ion batteries

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Journal of energy Chemistry 2024年第2期89卷 1-9,I0002页

作者： Bao Zhang Yi Zhao Minghuang Li Qi Wang Lei Cheng Lei Ming Xing Ou Xiaowei Wang National Engineering Laboratory for High-Efficiency Recovery of Refractory Nonferrous Metals School of Metallurgy and EnvironmentCentral South UniversityChangsha 410083HunanChina Zhejiang Power New energy Co. LTDZhuji 311800ZhejiangChina

Advancing high-voltage stability of layered sodium-ion oxides represents a pivotal avenue for their progress in energy storage applications.Despite this,a comprehensive understanding of the mechanisms underpinning their structural deterioration at elevated voltages remains insufficiently explored.In this study,we unveil a layer delamination phenomenon of Na_(0.67)Ni_(0.3)Mn_(0.7)O_(2)(NNM)within the 2.0-4.3 V voltage,attributed to considerable volumetric fluctuations along the c-axis and lattice oxygen reactions induced by the simultaneous Ni^(3+)/Ni^(4+)and anion redox reactions.By introducing Mg doping to diminished Ni-O antibonding,the anion oxidation-reduction reactions are effectively mitigated,and the structural integrity of the P2 phase remains firmly intact,safeguarding active sites and precluding the formation of novel interfaces.The Na_(0.67)Mg_(0.05)Ni_(0.25)Mn_(0.7)O_(2)(NMNM-5)exhibits a specific capacity of100.7 mA h g^(-1),signifying an 83%improvement compared to the NNM material within the voltage of2.0-4.3 V.This investigation underscores the intricate interplay between high-voltage stability and structural degradation mechanisms in layered sodium-ion oxides.

关键词： Soidum ion batteries Layer cathode materials P-type High-voltage performance Degradation analysis

Migration Effect of Temperature on Formaldehyde in Porous Building Materials

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湖南大学学报（自然科学版） 2009年第S1期36卷 1-4页

作者： SHEN Xiao-zhong1,2,CHEN Zhen-qian1(1.school of energy and environment,Southeast University,Nanjing,Jiangsu 210096,China 2.Department of Electronic Engineering,Wuxi Institute of Commerce,Wuxi,Jiangsu 214153,China) school of energy and environment Southeast University Nanjing 210096 China Department of Electronic Engineering Wuxi Institute of Commerce Wuxi 214153 China

A coupled heat and formaldehyde migration model based on the non-equilibrium thermodynamic theory and molecule movement theory was developed.The effect of temperature on the transport coefficients was simulated,and the simulation results were validated with experimental data from the literatures.The calculation shows that air exchange rate larger than 2 h-1 should be prevented,if the purpose is only for formaldehyde emissions control.The effects of temperature on formaldehyde migration are obvious.

关键词： formaldehyde migration temperature gradient porous building materials

From longan peel waste to energy storage: Porous activated carbon as a cathode matrix for advanced Li/Na-selenium batteries

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Progress in Natural Science:Materials International 2024年第2期34卷 329-337页

作者： Mustafa Khan Suxia Yan Mujahid Ali Faisal Mahmood Yang Zheng Xiaohui Song Guochun Li Junfeng Liu Yong Wang Institute for energy Research Jiangsu University school of energy and Power Engineering Jiangsu University school of Materials Science and Engineering Hefei University of Technology

This paper explores the potential of Longan peel waste（LPw） as a sustainable and cost-effective matrix for selenium-based cathodes in Li-Se and Na-Se batteries.Following activation,we created LP2—a designation for the carbon precursor derived from LPw,activated at a 1:2 ratio of carbonized LPw to KOH.This nomenclature,where'LP' stands for 'Longan peel' and '2' reflects the optimization of this ratio,led to a hierarchical porous structure with an average pore size of 3.0307 nm and a significant BET surface area of 111.9386 m2g-1Selenium was incorporated into the LP2matrix using a simple melt diffusion technique,yielding the composite Se@LP2.In Li-Se batteries,Se@LP2exhibited an initial discharge capacity of 1033.75 mAh g-1at 0.1C.At a 1C rate,the composite demonstrated a capacity retention of 301.14 mAh g-1after 550 cycles and 380.91 mAh g-1after 100 cycles.Moreover,for Na-Se batteries,the composite showcased a capacity retention of 347.18 mAh g-1after 100 cycles at0.1C.These findings underscore LP2's potential as a viable and efficient matrix for selenium-based cathodes,revealing promising prospects for the advancement of highly efficient Li-Se and Na-Se batteries.

关键词： Hierarchical porous structure Li/Na-Se batteries Longan peel waste Melt diffusion technique Selenium-based cathode

A systematic review of the inequality of health burdens related to climate change

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Frontiers of environmental Science & Engineering 2024年第5期18卷 137-153页

作者： Xinke Song Shihui Zhang Hai Huang Qun Ding Fang Guo Yaxin Zhang Jin Li Mingyu Li Wenjia Cai Can Wang State Key Joint Laboratory of environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing100084China Department of Earth System Science Tsinghua UniversityBeijing100084China

Climate change significantly impacts human health,exacerbating existing health inequalities and creating new ones.This study addresses the lack of systematic review in this area by analyzing 2440 publications,focusing on four key terms:health,disparities,environmental factors,and climate change.Strict inclusion criteria limited the selection to English-language,peer-reviewed articles related to climate health hazards,ensuring the relevance and rigor of the synthesized studies.This process synthesized 65 relevant studies.Our investigation revealed that recent research,predominantly from developed countries,has broadened its scope beyond temperature-related impacts to encompass diverse climate hazards,including droughts,extreme weather,floods,mental health issues,and the intersecting effects of Coronavirus Disease 2019.Research has highlighted exposure as the most studied element in the causal chain of climate change-related health inequalities,followed by adaptive capability and inherent sensitivity.The most significant vulnerabilities were observed among populations with low socioeconomic status,ethnic minorities,and women.The study further reveals research biases and methodological limitations,such as the paucity of attention to underdeveloped regions,a narrow focus on non-temperature-related hazards,challenges in attributing climate change effects,and a deficit of large-scale empirical studies.The findings call for more innovative research approaches and a holistic integration of physical,socio-political,and economic dimensions to enrich climate-health discourse and inform equitable policy-making.

关键词： Climate change Health impact Human well-being Inequality Vulnerability

Electrochromism-induced adaptive fresh air pre-handling system for building energy saving

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Energy and Built Environment

energy and Built environment 2024年第2期5卷 300-308页

作者： Dikai Xu Mingfeng Sheng Xinpeng Zhao Hua Qian Wenqing Liang Xiaohong Zheng Dongliang Zhao school of energy and environment Southeast UniversityNanjingJiangsu 210096China Lyles school of Civil Engineering Purdue UniversityWest LafayetteIN 47907USA Department of Mechanical Engineering University of Colorado BoulderBoulderCO 80309USA

Building fresh air supply needs to meet certain regulations and fit people’s ever-growing indoor air quality de-mand.However,fresh air handling requires huge energy consumption that goes against the goal of net-zero energy buildings.Thus,in this work,an adaptive fresh air pre-handling system is designed to reduce the cool-ing and heating loads of HVAC system.The sky-facing surface of the system uses electrochromic mechanism to manipulate the optical properties and thus make full use of solar energy(solar heating)and deep space cold source(radiative cooling)by switching between heating and cooling modes.In the cooling mode,the sky-facing surface shows a transmittance of down to zero,while the reflectance is high at 0.89 on average.In the heating mode,the electrochromic glass is highly transparent,allowing the sunlight to reach the solar heat absorber.To obtain the energy-saving potential under different climates,six cities were selected from various climate regions in China.Results show that the adaptive fresh air pre-handling system can be effective in up to 55.4%time of a year.The maximum energy-saving ratios for medium office,warehouse,and single-family house can reach up to 11.52%,26.62%,and 18.29%,respectively.In addition,the system shows multi-climate adaptability and broad application scenarios,making it a potential solution to building energy saving.

关键词： Adaptive fresh air pre-handling Electrochromism Radiative sky cooling Solar air heating Building energy saving

Construction of core@double-shell structured energetic composites with simultaneously enhanced thermal stability and safety performance

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Defence Technology（防务技术） 2024年第4期34卷 134-142页

作者： Peng Wang Wen Qian Ruolei Zhong Fangfang He Xin Li Jie Chen Li Meng Yinshuang Sun Guansong He Institute of Chemical Materials China Academy of Engineering PhysicsMianyang 621900China State Key Laboratory of environment-friendly energy Materials School of Materials and ChemistrySouthwest University of Science and TechnologyMianyang 621010China

The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricated to address the above issues.The coordination complexes which consist of natural polyphenol tannic acid(TA) and Fe~Ⅲ were chosen to construct the inner shell,while the graphene sheets were used to build the outer shell.The resulting CL-20/TA-Fe~Ⅲ/graphene composites exhibited simultaneously improved thermal stability and safety performance with only 1 wt% double-shell content,which should be ascribed to the intense physical encapsulation effect from inner shell combined with the desensitization effect of carbon nano-materials from outer shell.The phase transition(ε to γ) temperature increased from 173.70 ℃ of pure CL-20 to 191.87℃ of CL-20/TA-Fe~Ⅲ/graphene composites.Meanwhile,the characteristic drop height(H_(50)) dramatically increased from 14.7 cm of pure CL-20 to112.8 cm of CL-20/TA-Fe~Ⅲ/graphene composites,indicating much superior safety performance after the construction of the double-shell structure.In general,this work has provided an effective and versatile strategy to conquer the thermal stability and safety issues of CL-20 and contributes to the future application of high energy density energetic materials.

关键词： CL-20 Double-shell structure Thermal stability Safety performance Tannic acid Graphene sheets

Enhanced High-Temperature Cycling Stability of Garnet-Based All Solid-State Lithium Battery Using a Multi-Functional Catholyte Buffer Layer

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Nano-Micro Letters 2024年第7期16卷 59-73页

作者： Leqi Zhao Yijun Zhong Chencheng Cao Tony Tang Zongping Shao WA school of Mines:Minerals Energy and Chemical EngineeringCurtin UniversityPerthWA 6102Australia

The pursuit of safer and high-performance lithium-ion batteries(LIBs)has triggered extensive research activities on solid-state batteries,while challenges related to the unstable electrode-electrolyte interface hinder their practical implementation.Polymer has been used extensively to improve the cathode-electrolyte interface in garnet-based all-solid-state LIBs(ASSLBs),while it introduces new concerns about thermal stability.In this study,we propose the incorporation of a multi-functional flame-retardant triphenyl phos-phate additive into poly(ethylene oxide),acting as a thin buffer layer between LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)cathode and garnet electro-lyte.Through electrochemical stability tests,cycling performance evaluations,interfacial thermal stability analysis and flammability tests,improved thermal stability(capacity retention of 98.5%after 100 cycles at 60℃,and 89.6%after 50 cycles at 80℃)and safety characteristics(safe and stable cycling up to 100℃)are demonstrated.Based on various materials characterizations,the mechanism for the improved thermal stability of the interface is proposed.The results highlight the potential of multi-functional flame-retardant additives to address the challenges associated with the electrode-electrolyte interface in ASSLBs at high temperature.Efficient thermal modification in ASSLBs operating at elevated temperatures is also essential for enabling large-scale energy storage with safety being the primary concern.

关键词： Solid-state battery Cathode electrolyte interlayer Flame-retardant additive Cycling stability Interfacial stability

An uncertainty investigation for liner impedance eduction methods

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Chinese Journal of Aeronautics 2024年第3期37卷 49-59页

作者： Weihao SHI Xiaodong JING school of energy and Power Engineering Beihang UniversityBeijing 100191China

Impedance eduction methods have been developed for decades to meet the increasing need for high-quality impedance data in the design and optimization of acoustic liners.To this end,it is important to fully investigate the uncertainty problem,to which only limited attention has been devoted so far.This paper considers the possibility of acoustically-induced structural vibration as a nonnegligible uncertainty or error source in impedance eduction experiments.As the frequency moves away from the resonant frequency,with the increase in the value of cavity reactance,the acoustic particle velocity inside liner orifices possibly decreases to the extent comparable to the vibration velocity of liner facing sheet.Thus,the acoustically-induced vibration,although generally being weak except at the inherent structural frequencies,may considerably affect the impedance eduction results near the anti-resonant frequency where the liner has poor absorption.To demonstrate the effect of structural vibration,the vibration velocity of liner facing sheet is estimated from the experimentally educed admittance of the liner samples whose orifices are sealed with tape.Further,a three-dimensional numerical model is set up,in which normal particle velocity is introduced over the solid portion of liner facing sheet to imitate structural vibration,rather than directly solving the acoustic-structural coupling problem.As shown by the results,the vibration of liner facing sheet,whose velocity is as small as estimated by the experiment,can result in anomalous deviation of the educed impedance from the impedance model near the anti-resonant frequency.The trend that the anomalous deviation varies with frequency is numerically captured.

关键词： Impedance eduction Uncertainty analysis Acoustically-induced structural vibration Anti-resonant frequency Perforated liner