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Stable α-CsPbI3 with extremely red emission for expanding the color gamut

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Science China(Information Sciences) 2024年第5期67卷 311-317页

作者： Yong ZHANG Xin WEI Lei GAO Weijie ZHAO Changjiu SUN Junli WEI Mingjian YUAN Zhenhua NI Junpeng LU Hongwei LIU school of Physics and Key Laboratory of MEMS of the Ministry of Education Southeast University Key Laboratory of Advanced Energy Materials chemistry (Ministry of Education) Renewable Energy Conversion and Storage Center (RECAST) College of Chemistry Nankai University Jiangsu Key Lab on Opto-Electronic technology School of Physics and TechnologyNanjing Normal University

The wider color gamut represents the better reproducibility of the real natural colors. Perovskite materials exhibit promising potential in full-color wide-gamut displays because of the wide tunability and high saturability of their photon emission. However, the full-color wide gamut(>100% Rec.2020) has not been constructed due to the lack of the extreme red primary color(～700 nm). Herein, the widest color gamut is realized, whereinα-CsPbI3 is used to generate the extreme red primary color. An in-situ encapsulation approach is advised to stabilizeα-CsPbI3 at room temperature by means of polyvinylpyrrolidone(PVP).Theα-CsPbI3 encapsulated by PVP(denoted as P-CPI) shows highly saturated(FWHM(full width at half maximum) ～28 nm) and extremely(～697 nm) red emission. The green emission is provided by P-CPBr(CsPbBr3 with PVP) which is also synthesized using the universal in-situ encapsulation approach. With the assistance of a commercial Ga N chip, the RGB gamut is extended to the widest(151% NTSC, 113%Rec.2020).

关键词： all-inorganic perovskite wide color gamut LED display carrier recombination

A new 4-Ti-added polyoxometalate

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Tungsten 2024年第2期6卷 465-471页

作者： Hai-Lou Li Chen Lian Guo-Yu Yang MOE Key Laboratory of Cluster Science School of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 102488China

A new inorganic–organic hybrid 4-Ti-added polyoxometalate:[H_(2)N(CH_(3))_(2)]_(2)Na_(3)H_(5)[{Ti(C_(2)O_(4))(H_(2)O)}_(2){Ti(C_(2)O_(4))}_(2)(B-β-SbW_(9)O_(33))_(2)]·22H_(2)O(1)has been successfully made and further characterized by infrared spectroscopy,thermogravimetric analysis,powder X-ray diff raction and single-crystal X-ray diff *** polyoxoanion of 1 exhibits a Krebs-type structure that is constructed from two[B-β-SbW_(9)O_(33)]^(9)−fragments fused together by a belt of four additional Ti atoms decorated by oxalate ***,1 as a heterogeneous catalyst exhibits high activity for Knoevenagel condensation under mild reaction conditions.

关键词： Polyoxometalate Ti-added POM Krebs-type structure Knoevenagel condensation

An Environment‑Tolerant Ion‑Conducting Double‑Network Composite Hydrogel for High‑Performance Flexible Electronic Devices

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Nano-Micro Letters 2024年第5期16卷 352-369页

作者： Wenchao Zhao Haifeng Zhou Wenkang Li Manlin Chen Min Zhou Long Zhao State Key Laboratory of Advanced Electromagnetic technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China school of chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074People’s Republic of China

High-performance ion-conducting hydrogels(ICHs)are vital for developing flexible electronic ***,the robustness and ion-conducting behavior of ICHs deteriorate at extreme tempera-tures,hampering their use in soft *** resolve these issues,a method involving freeze–thawing and ionizing radiation technology is reported herein for synthesizing a novel double-network(DN)ICH based on a poly(ionic liquid)/MXene/poly(vinyl alcohol)(PMP DN ICH)*** well-designed ICH exhibits outstanding ionic conductivity(63.89 mS cm^(-1) at 25℃),excellent temperature resistance(-60–80℃),prolonged stability(30 d at ambient temperature),high oxidation resist-ance,remarkable antibacterial activity,decent mechanical performance,and ***,the ICH performs effectively in a flexible wireless strain sensor,thermal sensor,all-solid-state supercapacitor,and single-electrode triboelectric nanogenerator,thereby highlighting its viability in constructing soft electronic *** highly integrated gel structure endows these flexible electronic devices with stable,reliable signal output *** particular,the all-solid-state supercapacitor containing the PMP DN ICH electrolyte exhibits a high areal specific capacitance of 253.38 mF cm^(-2)(current density,1 mA cm^(-2))and excellent environmental *** study paves the way for the design and fabrication of high-performance mul-tifunctional/flexible ICHs for wearable sensing,energy-storage,and energy-harvesting applications.

关键词： Ionic liquids Double-network hydrogels Temperature tolerance Multifunctionality Flexible electronic devices

Polyoxometalates: metallodrug agents for combating amyloid aggregation

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National Science Review 2024年第7期11卷 279-291页

作者： Mengmeng Ma Zhenqi Liu Huisi Zhao Haochen Zhang Jinsong Ren Xiaogang Qu Laboratory of Chemical Biology and State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of Sciences school of Applied chemistry and Engineering University of Science and Technology of China

Alzheimer's disease(AD) is a devastating neurodegenerative disease that affects ～50 million people globally. The accumulation of amyloid-β(Aβ) plaques, a predominant pathological feature of AD, plays a crucial role in AD pathogenesis. In this respect, Aβ has been regarded as a highly promising therapeutic target for AD treatment. Polyoxometalates(POMs) are a novel class of metallodrugs being developed as modulators of Aβ aggregation, owing to their negative charge, polarity, and three-dimensional *** traditional discrete inorganic complexes, POMs contain tens to hundreds of metal atoms,showcasing remarkable tunability and diversity in nuclearities, sizes, and shapes. The easily adjustable and structurally variable nature of POMs allows for their favorable interactions with Aβ. This mini-review presents a balanced overview of recent progress in using POMs to mitigate amyloidosis. Clear correlations between anti-amyloid activities and structural features of POMs are also elaborated in detail. Finally, we discuss the current challenges and future prospects of POMs in combating AD.

关键词： amyloid inhibition metallodrug polyoxometalate amyloid-β Alzheimer's disease

MOF‐derived 1D/3D N‐doped porous carbon for spatially confined electrochemical CO2 reduction to adjustable syngas

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Carbon Energy 2024年第8期6卷 1-13页

作者： Wei Zhang Hui Li Daming Feng Chenglin Wu Chenghua Sun Baohua Jia Xue Liu Tianyi Ma Key Laboratory for Green Synthesis and Preparative chemistry of Advanced Materials Institute of Clean Energy ChemistryCollege of ChemistryLiaoning UniversityShenyangLiaoningChina school of Science RMIT UniversityMelbourneVictoriaAustralia school of Pharmaceutical and Chemical Engineering Taizhou UniversityTaizhouZhejiangChina Department of chemistry and Biotechnology Swinburne University of TechnologyHawthornVictoriaAustralia

Electrochemical reduction of CO_(2)to syngas(CO and H_(2))offers an efficient way to mitigate carbon emissions and store intermittent renewable energy in ***,the hierarchical one‐dimensional/three‐dimensional nitrogen‐doped porous carbon(1D/3D NPC)is prepared by carbonizing the composite of Zn‐MOF‐74 crystals in situ grown on a commercial melamine sponge(MS),for electrochemical CO_(2)reduction reaction(CO_(2)RR).The 1D/3D NPC exhibits a high CO/H_(2)ratio(5.06)and CO yield(31 mmol g^(−1)h^(−1))at−0.55 V,which are 13.7 times and 21.4 times those of 1D porous carbon(derived from Zn‐MOF‐74)and N‐doped carbon(carbonized by MS),*** is attributed to the unique spatial environment of 1D/3D NPC,which increases the adsorption capacity of CO_(2)and promotes electron transfer from the 3D N‐doped carbon framework to 1D carbon,improving the reaction kinetics of CO_(2)*** results and charge density difference plots indicate that the active site of CO_(2)RR is the positively charged carbon atom adjacent to graphitic N on 1D carbon and the active site of HER is the pyridinic N on 1D *** presence of pyridinic N and pyrrolic N reduces the number of electron transfer,decreasing the reaction kinetics and the activity of CO_(2)*** CO/H_(2)ratio is related to the distribution of N species and the specific surface area,which are determined by the degree of spatial confinement *** CO/H_(2)ratios can be regulated by adjusting the carbonization temperature to adjust the degree of spatial confinement *** the low cost of feedstock and easy strategy,1D/3D NPC catalysts have great potential for industrial application.

关键词： electrochemical CO_(2)reduction reaction melamine sponge metal‐organic frameworks porous carbon syngas

Preparation of Chemically Recyclable Poly(ether-alt-ester) by the Ring Opening Polymerization of Cyclic Monomers Synthesized by Coupling Glycolide and Epoxides

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Chinese Journal of Polymer Science 2024年第2期42卷 168-175,I0006页

作者： Feng Ren Zhuang-Zhuang Liang Ming-Xin Niu Chen-Yang Hu Xuan Pang Key Laboratory of Polymer Ecomaterials Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun130022China school of Applied chemistry and Engineering University of Science and Technology of ChinaHefei230026China

Polyester and polyether are two key oxygenated polymers, and completely alternative sequence of poly(ester-alt-ether) could efficiently combine the advantages(including flexibility, degradability, etc.) of both segments. Currently, despite their copolymers could be synthesized from one-pot mixture of cyclic esters and epoxides, perfectly alternative microstructure is very challenging to realize and typically restricted to certain monomer pairs. Moving forward, synthesizing poly(ester-alt-ether) from commercially available and largescale monomers would be a significant advance. For example, successfully commercialized poly(glycolic acid)(PGA), which is not easily soluble in polymers due to its high crystallinity and is brittle and difficult to control the degradation cycle, would encounter a new paradigm if engineered into poly(ester-altether). In this work, starting from the design of monomer with hybrid structures, we successfully synthesized a series of 1,4-dioxan-2-one containing different substituents based on glycolide(GA) and epoxides using commercially available Salen-Cr(III) and PPNCl catalytic *** new monomers underwent ring-opening polymerization(ROP) to form a series of poly(ester-alt-ether) with perfectly alternating glycolic acid and propylene glycol repeat units under catalytic system of thiourea/base. The poly(ester-alt-ether) have significantly lower glass-transition temperature than PGA. Additionally, the poly(ester-alt-ether) can be chemically recovered to monomer using Sn(Oct)2 or 1,8-diazabicyclo[5.4.0]undecane-7-ene(DBU) as a catalyst in solution, thus establishing a closed-loop life cycle. From monomers derived from GA and epoxides, this work furnishes a novel strategy for the synthesis of poly(ester-alt-ether) with chemical recyclability.

关键词： Polyester Polyether Alternative copolymer Ring-opening polymerization

Recent advances in crystal phase induced surface-enhanced Raman scattering

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Chinese Chemical Letters 2024年第9期35卷 111-118页

作者： Ce Liang Qiuhui Sun Adel Al-Salihy Mengxin Chen Ping Xu MIIT Key Laboratory of Critical Materials technology for New Energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001China

Surface-enhanced Raman scattering(SERS)spectroscopy has emerged as a powerful analytical technique for detecting and identifying trace chemical and biological *** this review,we present an indepth discussion of recent advances in the field of crystal phase manipulation to achieve exceptional SERS *** on transition metal dichalcogenides,(hydr)oxides,and carbides as exemplary materials,we illustrate the pivotal role of crystal phase regulation in enhancing SERS *** exploring the correlation between crystal phases and SERS responses,we uncover the underlying principles behind these strategies,thereby shedding light on their potential for future SERS *** addressing the current challenges and limitations,we also propose the prospects of the crystal phase strategy to facilitate the development of cutting-edge SERS-based sensing technologies.

关键词： Surface-enhanced Raman scattering Crystal phase manipulation Transition metal dichalcogenides Transition metal oxides Transition metal carbides

Flame-assisted ultrafast synthesis of functionalized carbon nanosheets for high-performance sodium storage

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Carbon Energy 2024年第7期6卷 123-133页

作者： Chen Chen Dong Yan Yew Von Lim Lei Liu Xue Liang Li Junjie Chen Tian Chen Li Youyu Zhu Jiangtao Cai Ying Huang Yating Zhang Hui Ying Yang school of chemistry and Chemical Engineering Northwestern Polytechnical UniversityXi'anChina Pillar of Engineering Product Development Singapore University of Technology and DesignSingaporeSingapore school of Electrical Engineering Xi'an University of TechnologyXi'anChina International Joint Laboratory of New Energy Materials and Devices of Henan Province School of Physics and ElectronicsHenan UniversityKaifengChina College of chemistry and Chemical Engineering Xi'an University of Science and TechnologyXi'anChina

The unique structural features of hard carbon(HC)make it a promising anode candidate for sodium-ion batteries(SIB).However,traditional methods of preparing HC require special equipment,long reaction times,and large energy consumption,resulting in low throughputs and *** our contribution,a novel synthesis method is proposed,involving the formation of HC nanosheets(NS-CNs)within minutes by creating an anoxic environment through flame combustion and further introducing sulfur and nitrogen sources to achieve heteroatom *** effect of heterogeneous element doping on the microstructure of HC is quantitatively analyzed by high-resolution transmission electron microscopy and image processing *** with density functional theory calculation,it is verified that the functionalized HC exhibits stronger Na^(+)adsorption ability,electron gain ability,and Na^(+)migration *** a result,NS-CNs as SIB anodes provide an ultrahigh reversible capacity of 542.7mAh g^(-1) at 0.1Ag^(-1),and excellent rate performance with a reversible capacity of 236.4mAh g^(-1) at 2Ag^(-1) after 1200 ***,full cell assembled with NS-CNs as the can present 230mAh g^(-1) at 0.5Ag^(-1) after 150 ***,in/ex situ techniques confirm that the excellent sodium storage properties of NS-CNs are due to the construction of abundant active sites based on the novel synthesis method for realizing the reversible adsorption of Na^(+).This work provides a novel strategy to develop novel carbons and gives deep insights for the further investigation of facile preparation methods to develop high-performance carbon anodes for alkali-ion batteries.

关键词： carbon nanosheets heteroatom doping sodium-ion battery sustainable materials

High-Performance Anion Exchange Membrane Fuel Cells Enabled by Nitrogen Configuration Optimization in Graphene-Coated Nickel for Enhanced Hydrogen Oxidation

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Energy & Environmental Materials 2024年第5期7卷 345-352页

作者： Pan Li Jiang Zhong Yanqing Fu Zhentao Du Lan Jiang Yi Han Jan Luxa Bing Wu Zdenek Sofer Qiliang Wei Weiyou Yang school of Resources Environment and Materials State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi University Institute of Micro/Nano Materials and Devices Ningbo University of Technology Department of Inorganic chemistry University of Chemistry and Technology Prague

Anion exchange membrane fuel cell （AEMFC） technology is attracting intensive attention,due to its great potential by using non-precious-metal catalysts （NPMCs） in the cathode and cheap bipolar plate materials in alkaline ***,in such case,the kinetics of hydrogen oxidation reaction （HOR） in the anode is two orders of magnitude sluggish than that of acidic electrolytes,which is recognized as the grand challenge in this ***,we report the rationally designed Ni nanoparticles encapsulated by N-doped graphene layers （Ni@NG） using a facile pyrolysis *** on the density functional theory calculations and electrochemical performance analysis,it is witnessed that the rich Pyridinic-N within the graphene shell optimizes the binding energy of the intermediates,thus enabling the fundamentally enhanced activity for HOR with robust *** a proof of concept,the resultant Ni@NG sample as the anode with a low loading(1.8 mg cm-2) in AEMFCs delivers a high peak power density of500 mW cm-2,outperforming all of those of NPMC-based analogs ever reported.

关键词： anion-exchange-membrane fuel cells density functional calculations hydrogen oxidation reaction Ni-based non-precious-metal catalysts pyridinic N-doped graphene