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Rare Metals 2024年第9期43卷 4387-4400页

作者： Ao Xia Jia-Guang Zheng Qing-Bo Zhang Yu-Gang Shu Cheng-Guo Yan Liu-Ting Zhang Zhan-Liang Tao Li-Xin Chen school of Energy and Power Jiangsu University of Science and Technology Key Laboratory of Advanced Energy materials chemistry(Ministry of Education) Nankai University State Key Laboratory of Silicon and Advanced Semiconductor materials School of Materials Science and EngineeringZhejiang University

The facile construction of nanoscale NbHxsupported by Ti3C2（NbHx@Ti3C2） was achieved using facile ball milling strategy to improve the hydrogen desorption kinetics and reversibility of magnesium borohydride (Mg（BH4）2).The doping of 30 wt%NbHx@Ti3C2catalyst reduced the onset dehydrogenation temperature of Mg（BH4）2to 71.2℃.Additionally,the Mg（BH4）2+30NbHx@Ti3C2composite achieved remarkable hydrogen release of over 9.2 wt% at a temperature as low as 230℃,indicating unexpected dehydrogenation ***,the reversibility of NbHx@Ti3C2doped Mg（BH4）2was retained to more than 4.2 wt%after four cycles,which was increased by 68% compared to that of undoped Mg（BH4）*** strong catalysis of NbHx@Ti3C2catalyst could be attributed to the synergistic effect of NbHxand Ti3C2in hydrogen spillover and *** as a??hydrogen pump??for effective hydrogen spillover,while Ti3C2created numerous diffusion channels for hydrogen dissolution and provided the active catalytic site to facilitate the re/dehydrogenation of Mg（BH4）2.

关键词： Catalysts Hydrogen storage Magnesium borohydride Mxene

Bimetallic selenide heterostructure with directional built-in electricfield confined in N-doped carbon nanofibers for superior sodium storage with ultralong lifespan

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Journal of Energy chemistry 2024年第4期91卷 407-416页

作者： Junying Weng Degui Zou Wenyong Yuan Pengfei Zhou Minghui Ding Jin Zhou Hailin Cong Fangyi Cheng school of materials Science and engineering Shandong University of TechnologyZibo 255000ShandongChina school of chemistry and Chemical engineering Shandong University of TechnologyZibo 255000ShandongChina Key Laboratory of Advanced Energy materials chemistry(Ministry of Education) College of ChemistryNankai UniversityTianjin 300071China

Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and uniform distribution of the heterostructure is still a great ***,the regulated novel CoSe_(2)/NiSe_(2)heterostructure confined in N-doped carbon nanofibers(CoSe_(2)/NiSe_(2)@N-C)are prepared by using Co/Ni-ZIF template,in which,the CoSe_(2)/NiSe_(2)heterostructures realize uniform distribution on a micro *** from the unique heterostructure and N-doped carbon nanofibers,the CoSe_(2)/NiSe_(2)@N-C deliveries superior rate capability and durable cycle lifespan with a reversible capacity of 400.5 mA h g^(-1)after 5000 cycles at 2 A g^(-1).The Na-ion full battery with CoSe_(2)/NiSe_(2)@N-C anode and layered oxide cathode displays a remarkable energy density of 563 W h kg^(-1)with 241.1 W kg^(-1)at 0.1 A g^(-1).The theoretical calculations disclose that the periodic and directional built-in electric-field along with the heterointerfaces of CoSe_(2)/NiSe_(2)@N-C can accelerate electrochemical reaction *** in(ex)situ experimental measurements reveal the reversible conversion reaction and stable structure of CoSe_(2)/NiSe_(2)@N-C during Na+insertion/*** study highlights the potential ability of precisely controlled heterostructure to stimulate the electrochemical performances of advanced anode for SIBs.

关键词： CoSe_(2)/NiSe_(2) heterostructure Built-in electric-field Rate capability Ultralong lifespan Sodium ion batteries

On-surface synthesis and characterization of polyynic carbon chains

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National Science Review 2024年第3期11卷 192-199页

作者： Wenze Gao Wei Zheng Luye Sun Faming Kang Zheng Zhou Wei Xu Interdisciplinary materials Research Center School of Materials Science and Engineering Tongji University

Carbyne, an elusive sp-hybridized linear carbon allotrope, has fascinated chemists and physicists for decades. Due to its high chemical reactivity and extreme instability, carbyne was much less explored in contrast to the sp2-hybridized carbon allotropes such as graphene. Herein, we report the on-surface synthesis of polyynic carbon chains by demetallization of organometallic polyynes on the Au（111） surface;the longest one observed consists of ～60 alkyne units（120 carbon atoms）. The polyynic structure of carbon chains with alternating triple and single bonds was unambiguously revealed by bond-resolved atomic force microscopy. Moreover, an atomically precise polyyne, C14, was successfully produced via tip-induced dehalogenation and ring-opening of the decachloroanthracene molecule(C14Cl10) on a bilayer NaCl/Au（111） surface at 4.7 K, and a band gap of 5.8 eV was measured by scanning tunnelling spectroscopy,in a good agreement with the theoretical HOMO–LUMO gap（5.48 eV）.

关键词： polyyne scanning probe microscopy carbon allotrope on-surface synthesis organometallic polyyne

Research progresses on cathode materials of aqueous zinc-ion batteries

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Journal of Energy chemistry 2024年第10期97卷 237-264页

作者： Zengyuan Fan Jiawei Wang Yunpeng Wu Xuedong Yan Dongmei Dai Xing-Long Wu Jilin Provincial Science and Technology Innovation Centre of Optical materials and chemistry Jilin Provincial International Joint Research Center of Photo-functional Materials and Chemistry School of Chemistry and Environmental Engineering Changchun University of Science and Technology Chongqing Research Institute Changchun University of Science and Technology Institute of Energy Storage and Conversion Technology College of Chemical EngineeringNingbo Polytechnic school of chemistry and Chemical engineering Henan Normal University MOE Key Laboratory for UV Light-Emitting materials and Technology School of Physics Northeast Normal University

Electrochemical energy storage and conversion techniques that exhibit the merits such as high energy density,rapid response kinetics,economical maintenance requirements and expedient installation procedures will hold a pivotal role in the forthcoming energy storage technologies *** recent years,aqueous zinc-ion batteries（AZIBs） have garnered substantial attention as a compelling candidate for large-scale energy storage systems,primarily attributable to their advantageous featu res encompassing cost-effectiveness,environmental sustainability,and robust safety ***,one of the primary factors hindering the further development of AZIBs originates from the challenge of cathode ***,the three mainstream types of mainstream cathode materials,in terms of manganese-based compounds,vanadium-based compounds and Prussian blue analogues,surfer from the dissolution of Mn2+,in the low discharge voltage,and the low specific capacity,*** strategies have been developed to compensation the above intrinsic defects for these cathode materials,including the ionic doping,defect engineering,and materials ***,this review first provides a systematic summarization of the zinc storage mechanism in AZIBs,following by the inherent merit and demerit of three kind of cathode materials during zinc storage analyzed from their structure characteristic,and then the recent development of critical strategies towards the intrinsic insufficiency of these cathode *** this review,the methodologies aimed at enhancing the efficacy of manganese-based and vanadium-based compounds are emphasis ***,the article outlines the future prospective directions as well as strategic proposal for cathode materials in AZIBs.

关键词： Aqueous zinc−ion batteries Cathode materials Optimization strategies

engineering of geometrical configurations in dual-atom catalysts for electrocatalytic applications

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Journal of Energy chemistry 2024年第7期94卷 273-287页

作者： Tao Zhang Yifan Liu Liang Xue Jingwen Sun Pan Xiong Junwu Zhu Key Laboratory for Soft chemistry and Functional materials of Ministry Education School of Chemistry and Chemical EngineeringNanjing University of Science and TechnologyNanjing210094JiangsuChina

Geometrical configurations play a crucial role in dual-atom catalysts(DACs)for electrocatalytic *** progress has been made to design DACs electrocatalysts with various geometri-cal configurations,but in-depth understanding the relationship between geometrical configurations and metal-metal interaction mechanisms for designing targeted DACs is still *** this review,the recent progress in engineering of geometrical configurations of DACs is systematically *** on the polarity of geometrical configuration,DACs can be classified into two different types that are homonuclear and heteronuclear ***,with regard to the geometrical configurations of the active sites,homonuclear DACs are identified into adjacent and bridged configurations,and heteronuclear DACs can be classified into adjacent,bridged,and separated ***,metal-metal interactions in DACs with different geometrical configurations are ***,the applications of DACs in different electrocatalytic reactions are discussed,including the oxygen reduction reaction(ORR),oxygen evolution reaction(OER),hydrogen evolution reaction(HER),and other ***,the future challenges and perspectives for advancements in DACs are *** review aims to provide inspiration for the design of highly effcient DACs towards energy relatedapplications.

关键词： Dual-atom catalysts Geometrical configurations Homonuclear Heteronuclear Electrocatalysis

Highly Stretchable and Tunable Thermo-fluorochromic Polymer Elastomer through Eu3+ Dynamic Coordination Cross-linking

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Chinese Journal of Polymer Science 2024年第10期42卷 1449-1458页

作者： Qiu-Li Tan Kai Gou Jing-Zhi Tang Ming-Hui Wei Chong Wang Yi-Jing Nie Geng-Sheng Weng school of materials Science and Chemical engineering State Key Laboratory Base of Novel Functional Materials and Preparation Science Ningbo University Institute of Polymer materials School of Materials Science and Engineering Jiangsu University

Thermochromic polymers with tunable thermochromism, high stretchability and mechanical strength are of interests for optical information storage and encryption. In this work, we demonstrate a new design of thermo-fluorochromic carboxylated nitrile butadiene rubber(XNBR) elastomer cross-linked by Eu3+-COOH dynamic coordination with deprotonated imidazole (DPIm) as the ancillary ligand. The presence of DPIm not only improves the mechanical strength and stretchability, but also dramatically intensifies the fluorescence emission and lifetime of the Eu-containing elastomer. The elastomer behaves reversible thermo-fluorochromism with easily tunable transition temperature and emission intensity by the simple change of the deprotonation degree of imidazole. The facile tunable thermo-fluorochromism, exceptional mechanical strength, and high stretchability (up to about 5000%) enable the Eu-containing XNBR elastomer with potential applications in soft electronics where optical information storage and encryption are required.

关键词： Dynamic coordination Elastomer Europium Highly stretchable Thermochromism

Construction of flower-like MoS_(2)decorated on Cu doped CoZn-ZIF derived N-doped carbon as superior microwave absorber

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Nano Research 2024年第9期17卷 8250-8260页

作者： Yun Han Di Lan Mengjun Han Zihao Xia Jiaxiao Zou Zirui Jia College of chemistry and Chemical engineering Qingdao UniversityQingdao 266071China school of materials Science and engineering Hubei University of Automotive TechnologyShiyan 442002China

The rational design of composition nanostructures and morphologies of the carbon-based composites materials has a significant potential for tuning electromagnetic parameters and thereby improving their performance as electromagnetic wave(EMW)*** this work,the flower-like Cu/Co-NC/MoS_(2)(NC=N-doped carbon skeleton)composites were successfully prepared by employing CuCoZn-ZIF(ZIF=zeolitic imidazolate framework)as precursor with subsequent annealing and hydrothermal *** unique flower-like morphology and electromagnetic synergy strategy between components enable the as-obtained Cu/Co-NC/MoS_(2)composites to exhibit outstanding microwave absorption ***,the minimum reflection loss of Cu/Co-NC/MoS_(2)reaches-54.36 dB at 2.7 *** the thickness reduces to 2.2 mm,the maximum effective absorption bandwidth can be achieved as large as 6.72 *** research develops useful ideas for optimizing multicomponent microwave absorbing materials.

关键词： ternary metal-organic frameworks(MOFs) MoS_(2) flower-like morphology microwave absorption

Regulating photothermal properties of near-infrared croconaine dyes by supramolecular assembly

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Nano Research 2024年第9期17卷 8560-8570页

作者： Yangge Ren Yue Lu Juanjuan Gao Yi Ding Bo Zhu Xinyu Hou Lin Jia Department of Polymer materials School of Materials Science and EngineeringShanghai UniversityShanghai 200444China Department of Electronic Information materials School of Materials Science and EngineeringShanghai UniversityShanghai 200444China

The photochemical and photophysical properties of near-infrared(NIR)dyes are significantly influenced by their aggregation state and mesoscopic ***,beyond chemical synthesis,the regulation mechanisms for the properties of NIR dyes,particularly with respect to photothermal properties of the aggregates,are not yet fully ***,we investigate the photothermal behaviors of croconaine-based(CroA)NIR dyes containing dipeptide or amino acids *** introduction of hydrogen bonding promotesπ-πstacking of croconaine center,which can efficiently regulate aggregation states and assembly structures in *** laser irradiation,CroA aggregates undergo aggregation-dissociation transition,the in-situ monomer generation process regulates two parameters of photothermal performance:heating rates and plateau photothermal *** study reveals the regulation effect of non-covalent bonding interactions on CroA aggregates,highlighting supramolecular assembly strategy not only facilitates to construct of photothermal nanomaterials with well-defined structures,but also provides an alternative and effective method for regulating photothermal performance of NIR dyes.

关键词： croconaine dye hydrogen bonding photothermal performance supramolecular assembly chirality

Recent progress of two-dimensional metal-base catalysts in urea oxidation reaction

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Rare Metals 2024年第8期43卷 3607-3633页

作者： Qi-Xiang Huang Fang Wang Yong Liu Bi-Ying Zhang Fang-Ya Guo Zhong-Qiu Jia Hao Wang Tian-Xiang Yang Hai-Tao Wu Feng-Zhang Ren Ting-Feng Yi school of materials Science and engineering Henan University of Science and TechnologyLuoyang 471000China school of Environmental engineering and chemistry Luoyang Institute of Science and TechnologyLuoyang 471023China Henan Province International Joint Laboratory of materials for Solar Energy Conversion and Lithium Sodium Based Battery Luoyang 471023China school of chemistry and Life Sciences Suzhou University of Science and TechnologySuzhou 215009China school of materials Science and engineering Northeastern UniversityShenyang110819China

Urea oxidation reaction(UOR)is an auxiliary water electrolysis hydrogen production technology developed in recent years to replace oxygen evolution reaction and reduce energy consumption,which can produce hydrogen more efficiently by low theoretical potential,reduce the average cost of electrochemical hydrogen production,and is a frontier research hotspot for renewable hydrogen ***-dimensional(2D)nanomaterials as electrocatalysts have many favorable potential,such as it can effectively reduce the resistivity of materials and increase the specific surface area with *** paper reviews the application of 2D materials in UOR in alkaline *** a cross-sectional comparison of various material performance data including overpotential,Tafel slope,electrochemical active surface area(ECSA)and it stability test was conducted,which could illustrate the differences between materials composed of different *** addition,the main challenges hindering the progress of research on 2D materials in urea electrocatalysis processes and promising materials in this field in future are summarized and *** is believed that this review will contribute to designing and analyzing highperformance 2D urea electrocatalysts for water splitting.

关键词： Water splitting Urea oxidation reaction Two-dimensional Transition metal compounds Noble/non-noble metals

High-rate lithium-ion battery performance of a ternary sea urchin-shaped CoNiO_(2)@NiP_(6)Mo_(18)/CNTs composites

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Journal of Energy chemistry 2024年第9期96卷 516-525页

作者： Li-ping Cui Shuang Sun Kai Yu Shu Zhang Mei-lin Wang Jia-jia Chen Bai-bin Zhou Key Laboratory for Photonic and Electronic Bandgap materials Ministry of EducationSchool of Chemistry and Chemical EngineeringHarbin Normal UniversityHarbin 150025HeilongjiangChina State Key Laboratory of Physical chemistry of Solid Surfaces Department of ChemistryCollege of Chemistry and Chemical EngineeringCollaborative Innovation Centre of Chemistry for Energy MaterialsXiamen UniversityXiamen 361005FujianChina

Bimetallic oxides are attractive anode materials for lithium-ion batteries(LIBs)due to their large theoretical ***,the low conductivity,short cycle life,and poor rate capability are the bottlenecks for their further *** overcome above issues,the basket-like polymolybdate(NiP_(6)Mo_(18))and carbon nanotubes(CNTs)were uniformly embedded on the urchin-shaped CoNiO_(2)nanospheres to yield a ternary composites CoNiO_(2)@NiP_(6)Mo_(18)/CNTs via electrostatic *** multi-level morphology of urchin spinules accelerates the diffusion rate of Li^(+);CNT improves the conductivity and enhances cycle stability of the material;and heteropoly acid contributes more redox activity ***,CoNiO_(2)@NiP_(6)Mo_(18)/CNTs as an anode of LIBs exhibits a high initial capacity(1396.7 mA h g^(−1)at 0.1 A g^(−1)),long-term cycling stability(750.2 mA h g^(−1)after 300 cycles),and rate performance(450.3 mA h g^(−1)at 2 A g^(−1)),which are superior to reported metallic oxides anode of *** density functional theory(DFT)and kinetic mechanism suggest that CoNiO_(2)@NiP_(6)Mo_(18)/CNTs delivers an outstanding pseudocapacitance and rapid Li^(+)diffusion behaviors,which is due to the rich surface area of the urchin-like CoNiO_(2)with the uniform embeddedness of NiP_(6)Mo_(18)and *** study provides a new idea for optimizing the performance of bimetallic oxides and developing high-rate lithium-ion battery composites.

关键词： Bi-metal oxides Transition metal oxides Polyoxometalates Nanocomposite LIBs